Professional Documents
Culture Documents
2 Hazards identification
Classification of the substance or mixture:
Information concerning particular hazards for human and environment:
The product has to be labelled in accordance with applicable regulations.
Label elements:
Labelling according to EU guidelines:
Observe the general safety regulations when handling chemicals.
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials.
Code letter and hazard designation of product:
Xi Irritant
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Page 2/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing Date: 12.01.2011 Version number 1.0 Revision: 12.01.2011
(Contd. of page 1)
37 Wear suitable gloves.
60 This material and its container must be disposed of as hazardous waste.
Other hazards:
Results of PBT and vPvB assessment:
PBT: Not applicable.
vPvB: Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures:
Description:
Mixture of substances listed below with non-hazardous additions.
For further information, please refer to the product technical data sheet.
Dangerous components:
55965-84-9 Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl- 0,0-1,0%
2Hisothiazol-3-one [EC no. 220-239-6] (3:1)
T R23/24/25
C R34
Xi R43
N R50/53
Additional information: For the wording of the listed risk phrases refer to section 16.
DR
Page 3/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing Date: 12.01.2011 Version number 1.0 Revision: 12.01.2011
(Contd. of page 2)
5 Firefighting measures
Extinguishing media:
Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray.
Special hazards arising from the substance or mixture: No further relevant information available.
Advice for firefighters:
Protective equipment: Wear self-contained respiratory protective device.
Additional information:
Collect contaminated fire fighting water separately. It must not enter the sewage system.
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Page 4/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing Date: 12.01.2011 Version number 1.0 Revision: 12.01.2011
(Contd. of page 3)
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the
workplace.
Additional information: Based on the lists valid at the date of MSDS creation.
Exposure controls:
PERSONAL PROTECTIVE EQUIPMENT
General protective and hygienic measures: Avoid contact with the eyes and skin.
Respiratory protection: In case of brief exposure or low pollution use respiratory filter device.
Protection of hands: Protective gloves.
Material of gloves: PVC gloves.
Eye protection:
Tightly sealed goggles.
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Page 5/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing Date: 12.01.2011 Version number 1.0 Revision: 12.01.2011
(Contd. of page 4)
Change in conditions:-
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: > 100°C
Flash point: > 100°C
Not determined
Decomposition temperature: Not determined.
Self-igniting: Product is not self-igniting.
Danger of explosion: Product does not present an explosion hazard.
EXPLOSION LIMITS
Lower: Not determined.
Upper: Not determined.
Vapour pressure: Not determined.
Density at 20°C: ~1,0 g/cm³
Relative density: Not determined.
Vapour density: Not determined.
Evaporation rate: Not determined.
Solubility in/Miscibility with:-
Water: Fully miscible.
Segregation coefficient (n-octanol/water): Not determined.
VISCOSITY
Dynamic: Not determined.
Kinematic: Not determined.
Other information: No further relevant information available.
11 Toxicological information
Information on toxicological effects:
ACUTE TOXICITY
Primary irritant effect:-
on the skin: May be irritating to the skin on prolonged contact.
on the eye: May be irritating to the eyes.
Sensitization: Sensitization possible through skin contact.
GBD
(Contd. on page 6)
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Page 6/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing Date: 12.01.2011 Version number 1.0 Revision: 12.01.2011
12 Ecological information
Toxicity:
AQUATIC TOXICITY No further relevant information available.
Persistence and degradability: No further relevant information available.
BEHAVIOUR IN ENVIRONMENTAL SYSTEMS
Bioaccumulative potential: No further relevant information available.
Mobility in soil: No further relevant information available.
ADDITIONAL ECOLOGICAL INFORMATION
General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Results of PBT and vPvB assessment:
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects: No further relevant information available.
13 Disposal considerations
Waste treatment methods:
Recommendation:
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
14 Transport information
LAND TRANSPORT ADR/RID (cross-border)
ADR/RID class: -
-
Remarks: Not Regulated.
Inland shipping ADN:
ADN/R Class: -
(Contd. on page 7)
GBD
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Page 7/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing Date: 12.01.2011 Version number 1.0 Revision: 12.01.2011
(Contd. of page 6)
-
Marine pollutant: No.
Remarks: Not Regulated.
AIR TRANSPORT ICAO-TI AND IATA-
DGR
ICAO/IATA Class: -
-
Remarks: Not Regulated.
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture:
Labelling according to EU guidelines:
Xi Irritant
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2Hisothiazol-3-one [EC no.
220-239-6] (3:1)
Risk phrases:
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Page 8/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing Date: 12.01.2011 Version number 1.0 Revision: 12.01.2011
(Contd. of page 7)
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
Relevant phrases:
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R34 Causes burns.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Department issuing MSDS:
EHS Department, EMEA Region, Grace Performance Chemicals, Ajax Avenue, Slough, Berks. SL1 4BH
DR