MSRA For Chemical Cleaning Fuel Gas Line at UEN - Monophase - Rev A

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A 02.05.2021 Karthikeyan Issued for approval

Date Name Note
Employer Project
Aweer Power Station ‘H’ Phase

IV
Engineer Contractor
Consortium
Originator Stamp
Date Name Document Title: Scale:

Created: 02.05.2021 Karthikeyan NTS
Method statement & Risk
Checked: 02.05.2021 A. Gornjak
Assessment for Chemical Cleaning Sheet:
Supersedes: of Fuel gas line at UEN by Mono- 253
phase Circulation method
Superseded by Size: A4 PO No.: 3761800008 File: 3761800008-E-08-M-E-65850_A
System: Fuel Gas Annex: Document No: 3761800008-E-08-M-E-65850_A
Origin. No. A
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Method statement & Risk Assessment for Chemical Cleaning of Fuel gas line at
UEN by Mono-phase Circulation method 3761800008-E-08-M-E-65750_A
1. Method Statement
Procedure:
Complete sections 1,2,3,4 – Method Statement √

Complete Risk Assessment √
Attach any additional documents and drawing as necessary √
Complete section 5- Sign and submit to Site Management Review √
1. Description of Work
Civil Electrical Mechanical √ Other (Please specify)
Location of UEN at phase 4

Al Aweer Power Station ‘H’
Start Date:
Work:
End Date:
Brief Description of Work (Purpose / Scope):
This Method Statement and Risk Assessment establishes the working steps and sequences during the
Chemical Cleaning of Fuel Gas Pipeline at UEN, H phase 4.
The purpose of method statement is to provide a detailed description of the methodology (cleaning and
removing of rust, stains and other contamination from natural gas pipeline (carbon steel pipes), to improve
the appearance of welding/work piece and restores the materials natural corrosion resistance which has been
compromised as a result of the welding process).
The chemical cleaning will be done by Monophase Circulation method which is a single fill method in three
loops.
Scope
The areas
• UEN at phase 4 - Aweer power station H Phase project
Relevant Reference and Document:
• Piping Material Specification, No: 3761800008-U-31-M-T-40012

• Fuel Gas Supply System – Main Header P&ID No: 3761800008-E-08-M-D-40236.
• Fuel Gas System - Isometric Drawings No: 3761800008-E-08-M-D-9000_A Sht 1 to 20,
3761800008-E-08-M-D-90001_A, 3761800008-E-08-M-D-90002_A, 3761800008-E-08-M-D-
90003_A, 3761800008-E-08-M-D-90004_A.
• ITP for Balance of Plant (BOP) Piping systems document No: 3761800008-B-00-M-Q-65751
• Welding Procedure specification (WPS) Refer to Doc. No. 3761800008-U-31-M-Q-65524
• Work place safety and Health Act.
• General requirements for field fabrication and erection of piping. 3761800008-U-31-M-P-65503
General Piping Procedure , 3761800008-U-31-M-P-65505 Preparation of Weld Edge and Fit-Up
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Procedure (Piping).
• General Layout.
• HSE Plan.
• Inspection and Test Plan (ITP) / Field Quality Plan (FQP). 376180008-U-OO-M-Q-60008-E
• VOL II – GO5.1 - Mechanical Equipment and Piping.
• VOL V – AO5_Specimen Project Procedure Manual.
• VOL II - G05.6 - Inspection and Testing
• VOL II - G05.5 - Corrosion Protection and Painting
• Hydraulic Testing Procedure for Balance of Plant - BOP -3761800008-U-31-M-P-65762
• DEWA SP-06 Health and Safety Procedures
• Dubai Municipality Code of Construction Safety Practice.
• HSE Technical Guidelines from Dubai Municipality.
2. CHEMICAL USED
DEGREASING PHASE:
2.1
TERGITOL™ NP-10 Surfactant / TERGITOL™ NP-6 Surfactant.
Dosing Percentage: 0.05%.
ACID PHASE:
2.2
Acid Inhibitor { EC-ArmoHib-CI-31}
Dosing Percentage: 0, 1%
Citric Acid
Dosing Percentage: 3% (w/w).
Ammonium Biflouride
Dosing Percentage: 0.5 - 1% (w/w).
PASSIVATION PHASE:
2.3
Liquid Ammonia
Dosing Percentage: Until pH in the range of 8.2 to 9.5
Sodium Nitrite
Dosing Percentage: 0.3% (w/w).
MSDS of all chemicals attached (Attachment No.: 02.2)
3. PREPARATIONS
The UEN internal piping testing packages are splitted into 7Nos of loops in each unit
3.1.
61/62/63 as shown in attachment no.1.
The loop No. 1,2,3,4,7 is installed with temporary support anchored to the ground to detach
3.2 the spool from its original position on skid , same arrangement shall be used. And loop
no.5 & 6 will be dismantled and chemical cleaned on ground.
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The loop No. 1,2,3,4,7 will be placed at same elevation on the support and locked with
3.3
temporary welded support to avoid movement of spool during chemical cleaning
Using the ISO Metric Drawing are refered to Identify the systems to be cleaned. The loops are
3.4
marked in general layout – Attachment No.1.
3.5 Line walk-down with E/E to identify the system to be cleaned and each loop
3.6 All the Fabrication / welding work & Hydro testing should be done prior to chemical cleaning.
All the required Isolation of equipment’s such as instruments like flow transmitter, sensors etc.
3.7
& All NRV to be removed and that shall identify during the line walk.
3.8 Temporary spools, adaptors etc. will be fabricated and installed prior to cleaning.
3.9 Organize electric supply for cleaning equipment – 380V-63/32A & 220V-16A and diesel required
Prepare the Area where equipment to be kept. Layout attached showing the proposed location to be
3.10
used during the cleaning process for each loop. Attachment No.1.
Equipment list including circulation pumps, waste tanks with capacity of each, lab equipment…etc.
3.11
deployed to the working location, photos of Equipment are attached as per Attachment no 01
Mobilization of equipment’s to work location after getting all the required permits from E/E as
3.12
applicable
3.13 Offloading the materials and equipment’s should be done by Trained and certified Riggers.
All lifting equipment’s used for the activity are inspected and certified and color coded by approved
3.14
TPI.
3.15 Only trained/inducted employees will work on the project with in-house training certificate
Barrication to be applied on the working area including adequate number of signage’s identifying
3.16
the process and the nature of the work.
3.17 Wherever required PTW shall be applied for the activity.
The required amount of water will be arranged and Pumped directly to chemical mixing tank and
3.18
then to line.
3.19 110% Tray to be placed down side of the diesel tanks.
3.20 Adequate number of fire extinguisher to be placed in area (Foam, Water & CO2 types).
The work area shall be adequately illuminated using appropriate lighting arrangement during the
3.21
night shift.
3.22 Appropriate fall protection shall be used while working at height and life line/proper.
3.23 Chemical cleaning shall be done with Operation Pressure : 3-4 Bars
4. CONDITION OF PIPELINES BEFORE CHEMICAL CLEANING
4.1. All pipelines should be hydro tested and certified before the start of the cleaning.
5. GENERAL SAFETY PRECAUTIONS

Chemical application is done by specialized personnel wearing special protective clothing as per
5.1.
attached PPE’s Details – Attachment No.2
5.2. RA to be discussed during the activity. Toolbox talk will be done before doing the activity
5.3. Keep away all equipment from the nearby area of application of chemicals.
5.4. No other works can be carried out in the exclusion area of chemical cleaning during the treatment.
The project activities shall comply with the requirements of Project HSE Plan and the applicable
5.5.
HSE requirements of contractor and company.
5.6. Only authorized person to be allowed at the same area during treatment.
5.7. First aid equipment, special for this job, will be on site during the whole operation.
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5.8. All safety precautions are in force at all times both during the cleaning process,
5.9. All local medical centers should be informed and equipped to give medical aid in case of accidents.
5.10. E/E and ESC PTW system to be followed.
Before starting the activity and during the activity regular checks to be made to prevent any HSE
issue and concerns. The area activity will be barricaded to prevent other workforce entering and
5.11. coming in contact / receiving chemicals from the activities. Check list to be implemented by the
supervisor to check, prevent and mitigate any HSE issue. Barricade to be maintained and monitored
during the activity.
5.12. MSDS shall be available at site for all chemicals employed.
Waste water disposal to be done through a third party licensed waste management company and to
5.13.
be treated under local laws and regulation.
All the necessary precautions shall be taken to avoid burns/harm from chemicals while performing
5.14.
the cleaning works.
All Mandatory PPE identified shall be worn (Safety Helmet, safety shoes, coverall, eye protection,
5.15.
appropriate hand gloves for the task) – Attachment No.02
Any additional PPE’s (Aprons, Face masks, respirators, fall arrestors etc.) shall be worn when
5.16.
required. (Attachment No.: 02).
110 % Capacity tray to be placed under diesel tanks only.
All the chemicals tanks are supplied with a level indicator & made from a compatible materials to
5.17. hold this kind of chemicals (Referred to tank data sheet attachments No. 02) Tanks data sheet is
attached) & all waste storage tanks will be provided with level meter and to be kept outside of the
existing plant.
5.18. During operation, vents should always be kept open.
5.19. LOTO procedure to be applied if required.
5.20. Hard Barrication to be applied around the Auxiliary Boiler during the operation.
5.21 Safety shower & Eye wash to be maintained in the vicinity.
6. Chemical Cleaning Method
6.1. looping Plan
6.1.1 The chemical cleaning will be performed as per the loop shown in (Attachment No.: 01)
Filter skid will be connected to the system during all the cleaning stages including the
6.1.3
pressure test, Flushing, and the chemical cleaning stages.
6.2. Filling
6.2.1 Fill the system with potable water from the water tanker to a 20 m3 mixing tank and
filling the system through the temporary circulation pump.
6.2.2 During filling all the vents are kept open until water has reached the vents.
6.2.3 All return lines are kept closed until all vent lines have given water
6.3. Pressure Test
Prior to the actual cleaning the system is filled with water and a leak test of the
6.3.1
temporary lines.
6.3.2 Pressure testing is used to find leaks in the (temporary) cleaning system. Leaks typically
occur at valves, joints or connections in the system.
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The test pressure during a pressure test is normally set to 150 % of the pump shut off
pressure. The operating pressure of the pump during the chemical cleaning is max. 3-
6.3.3 4 bar. The pressure is gradually increased to reach 150% of pump shut off pressure &
the system will be controlled from the main header and out-let valves (As per
Circulation Flow Diagram).
The pressure test to be conducted for all the temporary setup (piping & Hoses) during
6.3.4
the pressure testing.
6.3.5 The Pressure test of the system is performed after the lines are filled and vented to
remove the air.
The Test Shall be 2 hours
6.3.6 Temporary arrangement circuit, will be kept open during the cleaning procedure, by
connecting all the inlet, outlet, and vent points to the mixing tank, considering the
mixing tank is an open tank
6.3.7 A walk down of the system and pumping skid shall be performed.
6.3.8 All temporary lines and all temporary valves shall be checked for leakages, during the
pressure test.
6.3.9 When leakages have been found, shall be repaired after the pressure test. The section(s)
where the leak occurred shall be tested again after the repair.
6.3.10 At the conclusion of the test, the system is carefully depressurized by controlled
releasing of water to the mixing tank or to the effluent storage.
The pump is set to a lower (operating pressure) or will be shutdown.
6.3.11 Refer to attachment 3 - Inspection and test plan (ITP) / Section 2.
6.4. Flushing
Once the leak test and the system was depressurized install the filtration unit starting with a 20
6.4.1 micron filter in the return hose to the chemical mixing / circulation tank to collect the debris and
other foreign particles.
Periodically check the filter in return line for any debris/foreign particles (Every 1 hour filter bags
6.4.2 to be checked).
Some amount of discoloration on filter is acceptable. If required use 10 micron filter also.
6.4.3 Once filter is clean and inspected, Same solution can be used for next step No.: 6.5
The Maximum Flushing Velocity is 2.00 m/s during the flushing only.
6.4.4 - Refer to Pumps data sheet – Attachment No.: 02.5
All debris shall be removed from the system during the flushing.
Flushing Parameters
Temperature :Ambient
Turbidity : visually clear
6.4.5
Time: Every 30 Min.
Solution Samples for testing will be collected from the sampling valve on the return line only.
Filter : Some amount of discoloration is acceptable
Time : Every 1 Hour
6.5. Degreasing Phase
6.5.1
The One sample piece to be placed in the return/outlet temporary line, and just before mixing tank
A d On the same solution of Step 6.4.3 the concentration of 0.05% of the Degreasing agent
6.5.2
TERGITOL NP-10 Surfactant / TERGITOL NP-6 Surfactant is dosed.
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Dosing will be on the chemical mixing / circulation tank.

This step is essential for a good result of the acid cleaning.
The Velocity is limited to 1.20 m/s as maximum during the chemical cleaning.
6.5.3 The solution is heated with an auxiliary boiler to a temperature of 50-60°C – Attachment No.02.6.
6.5.4 After the degreasing phase the saturation of the solution is checked with a MN test strip.
Same solution can be used for next step.
6.5.5 Sampling location will be from the sampling valve on the return line only.
Degreasing Phase Parameters:

6.5.6 Temperature : 50-60°C.
Marchery Nagel test : No color changes in the MN-Strips will be accepted
6.6 Acid phase

6.6.1
An acid cleaning is done in order to remove rust/magnetite (iron oxides), silicates and mill scales.
To the degreasing solution on step 6.5. Dose 0.1% Corrosion Inhibitor (EC-ArmoHib-CI-31)
6.6.2 The inhibitor is added to lower the corrosion rate of the acidic solution and prevent the acid to
attack the base material.
Dosing will be on the chemical mixing / circulation tank.
6.6.3 Maintain the temperature of the solution at the chemical mixing / circulation tank in the range of
45- 55 °C.
The inhibitor in the solution is tested after approximately 1 hour of circulation, with steel WOOL
6.6.4
test.
Sampling location will be from the sampling valve on the return line only.
6.6.5
If the steel WOOL test shows no visible hydrogen then Proceed to Step 6.6.6
6.6.6
Dose 3% (w/w) of citric acid to a solution.
6.6.7 Then 0.5 - 1% (w/w) of Ammonium Bi-fluoride is added to the solution.
6.6.8 Maintain the pH value in between 2.0 – 3.0.
Every 30 minutes a sample is taken and the concentration of iron and acid to be measured.
6.6.9
Solution Samples for analytical testing will be collected from the sampling valve on the return line
only.
If the iron concentration is stabilized for two subsequent samples with a margin of +/-5%, the
6.6.10
cleaning is finished, but at least 4-6 hours of acid cleaning is done to ensure the cleanliness & all
the analysis value to be graphed.
6.6.11 Solution Samples for analytical testing will be collected from the sampling valve on the return line
only.
6.6.12 After finalizing the acid phase, the solution partially drained if the Iron concentration more than 15
g/l and partially refilled with water to reach a concentration less than 15 g/l Fe.
6.6.13 After finalizing the acid phase, the solution is NOT drained and passivation phase will continue if
the Iron concentration less than 15 g/l.
6.6.14
Acid Phase Parameters
Temperature : 45-55 °C
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Inhibitor steel wool : No visible hydrogen gas (Every 30 Min.)
Acid Concentration : 3% and this will reduce with time. (Every 30 Min.)
pH Value : 2.0 – 3.0
Iron concentration : stabilized for 2 measurements (with a maximum of 15g/l).

And a margin of +/- 5%. (Every 30 minutes)
6.6.15 Refer to attachment 3 - inspection and test plan (ITP) / Section 5.
6.7 Passivation
6.7.1
The system is kept full with acid phase solution (Step 6.6.14)
6.7.2
The water temperature to be maintained at heated to 40-50 ‘C.
6.7.3 The solution is then neutralized with ammonia to a pH value of 8.2 - 9.5.
6.7.4 The pH value should be checked on all sub systems. When the pH is homogeneous throughout the
system sodium nitrite is added. 0.3% (w/w).
6.7.5
Passivation Phase Parameters:
Temperature : 40-50 ‘C
pH (neutralization): 8.2 – 9.5
Residual Nitrite : > 1500 ppm

Note: Solution Samples for analytical testing will be collected from the sampling valve on the return line
only.
6.8 Draining
After the passivation phase lines will be drained from the lowest point under Dry Air pressure to
6.8.1 Corodex waste tank for neutralization and disposal and the draining will be done from the
temporary drain fixed to the temporary spool as showed in the flow diagram & Vent Point can be
utilized as a purging point during the Dry Air blowing.
6.8.2
All drain lines to be connected to Corodex waste collection tanks.
6.8.3
Operation of 24 Hrs. will be applied during chemical cleaning & Draining.
6.8.4
Final Inspection Parameters:
pH (neutralization) : 8.2 – 9.5
Visual Appearance :- Visual Check with Torch in Accessible Area of Pipes.

- Bore scope inspection limited to 40 mtr. Length from the accessible
areas.
- Discoloration in the pipes will be acceptable.

6.9 Air Blowing
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Pipe to be blown with compressed oil free dry air to remove any remains of water & Until Dew
Point of -5 C°.
Portable DEW Point meter will be used during the inspection to check the out coming air.
6.9.1
Data Sheet is Attached.
System will be checked at lowest point for any remaining water.
Air Compressor and Dryer data sheet are attached –Attachment No.: 02
Temp humidity meter data sheet attached - Attachment No.: 02
7. QA/QC Requirements :
As per Project Specification
Chemical cleaning inspection and test plan (ITP). Refer to attachment 3.
8. Waste Water Disposal:

REFER TO ATTACHMENT 2
 Waste will be collected in Corodex provided 40 ft. containers.
 Neutralization of the waste water to pH
 Third party lab analysis report to be collected prior to waste disposal for DM approval.
 Disposal permit to be requested through DM portal.
 A third party contractor approved by Dubai municipality is engaged for collection through tankers and
disposal of the waste following the local rules and regulation.
9.0 Operational details:
Permit To Work Activity Type and Special Needs:

:
√ Work at heights √ Electrical Tools
√ Yes Confined Space Electrical √ Special PPE:
Installations
√ Manual Lifting Welding Equipment Please specify
Chemical cleaning PPE
No √ Crane Operation Gas/Gas Cylinders Co-activity:
If yes please specify Excavator √ Chemicals Please specify
√ Plant/Equipment Dangerous Goods Others:

Other Machines √ Heavy Transport Please specify
(Please Specify)
Road Block
Using of Hazardous substances
√ Yes No
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Material Safety Data Sheet available (To be attached with MSRA) Yes √ No
Any special handling procedures available (To be attached with MSRA) Yes √ No
Temporary Services Required:
Electricity Yes √ No
Lighting Yes √ No For night shift, specifically.
Water Yes √ No
Other Yes √ No Compressed Air
10. Resources:
A. Man-Power (on site):
Project Manager No. 01

Project Engineer No. 01
Day Shift Supervisor No. 01
Night Shift Supervisor No. 01
Chemical Cleaning Technicians (Day & Night ) No. 08
10.1. Equipment:
APPROX. DIMENSION (LXWXH)

SNO. MATERIAL NAME UNIT QUANTITY IN M
900 M3/HOURS CHEMICAL CLEANING
1 PUMP SKID - CS NO. 02 1.5X2X1.2
2 20 M3 MIXING TANK - CS NO. 01 2X1.5X1
3 2" DIAGPHRAGM PUMP – PTFE NO. 02 0.8X0.5X1
4 STEAM BOILER NO. 01 6X2X3
60 M3 WASTE TANK – CS LINED WITH
5 GRP. NO. 04 12X2.6X2.4
6 TOOL CONTAINER NO. 01 6.1X2.5X2.44
7 OFFICE/ LAB CONTAINER NO. 01 6.1X2.5X2.44
8 CHEMICAL STORAGE CONTAINER NO. 02 6.1X2.5X2.44
8 STEAM HOSE NO. 200 2X2X2
9 2" CHEMICAL HOSE METER 1000 5X5X2
10 4" CHEMICAL HOSE METER 700 30 X2X2
11 6" CHEMICAL HOSE METER 700 30 X2X2
12 2" SS VALVES NO. 30
13 1" SS VALVES NO. 10
14 SS HOSE CAMLOCKS NO. 60
15 FIRST AID KIT NO. 01
16 SAFETY SHOWER & EYE WASH NO. 01 2X2X2
17 8000 GAL. FIBER GLASS TANKS NO. 04 6.1X2.5X2.44
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10.2- TESTING EQUIPMENT

DEGREASING PHASE
1 MN PAPER FOR DEGREASING NOS. 2 FOR SECTION 6.5
ACID PHASE
1 HACH DR 900 NOS. 1 FOR SECTION 6.6
2 MN TEST STRIPS FOR IRON AS REQUIRED FOR SECTION 6.6
3 PH PAPER AS REQUIRED FOR SECTION 6.6 / 6.7
PASSIVATION PHASE
1 MN TEST STRIPS FOR NITRITE AS REQUIRED FOR SECTION 6.7
2 WHITE TORCH NOS. 2 FOR SECTION 6.7
3 PH PAPER AS REQUIRED FOR SECTION 6.7
10.3 - CHEMICAL QUANITITY
DEGREASING PHASE
1. DEGREASER LTR. 475 2 DRUMS
ACID PHASE
2. INHIBITOR LTR. 600 3 DRUMS
3. CITRIC ACID KG 15,000 600 BAGS
4. ABF KG 2,500 83 BAGS
PASSIVATION PHASE
5. AMMONIA LTR. 12,000 – 15,000 55 - 69 UN DRUMS
6. SODIUM NITRITE KG 1,500 50 BAGS
GENERAL
7. DIESEL FUEL AS REQUIRED
8. GREASE, OIL & COOLANT WATER AS REQUIRED
11. Complete the Risk Assessment Form:

Att. 03 the Risk Assessment form by developing all of points mentioned in the section 2, 3
above.
Attach plans and drawing as required.
Number of Risk Assessment pages: 21
List of Attachments : (Drawings, Photo, Certificates, Safety Data Sheet, etc.)

Environmental Aspect & Impact Risk
Assessment
1. Fuel Gas General Arrangement drawing 3.

2. Supply Line Loops 4.
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12. Applicant responsibility
The Applicant is responsible to ensure that all of the conditions as stated in this MS/RA are implemented
and that the full content of the MS/RA is transferred to and clearly understood by all personnel involved
via a signed tool-box-talk prior to the commencement of the work. A copy of the MS/RA must be
available at the work area at all times for reference and review.
Applicant
Subcontractor
Construction Site Manager

Karthikeyan 02.05.2021
Name Signature Date
Frederic Shaji
HSE Manager 02.05.2021
Name Signature Date
EPC Contractor
Construction Site Manager

Name Signature Date
QC Engineer
Name Signature Date
Field Engineer
Name Signature Date
HSE Manager
Name Signature Date
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Attachment (A)
Chemical Cleaning Phases Table
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Fuel Gas Line Chemical Cleaning - Reference Table
Dose
Medium Inspection/Sample
Chemical Cleaning Phases Medium Steps Agent Percentag PH Value Temperature Duration Test Methodology Acceptance Criteria Draining Required
Velocity Collection Intervals
e
Deminarlized or
Phase-01 Water Filling - N/A N/A - Ambient N/A 2 Days N/A N/A N/A No
Potable Water
Deminarlized or
Phase-02 Pressure Testing - N/A N/A Ambient N/A 2 Days Visual Test For Leaks After Two Hours Not Leak Detected No
Potable Water
A- Visually A- Turbidity is Visually clear
Deminarlized or A-Every 30 minutes
Phase-03 Flushing - N/A N/A - Ambient 2.00 m/s 4 Days B- 20 micron filter to be B- Some amout of discoloration is No
Potable Water B- Every 1 hour
installed on the return hose acceptable
Deminarlized or ERGITOL NP-10 Surfactant /

Phase-04 Degreasing - 0.05% - 50-60 °C 1.2 m/s 1 day Marchery Nagel Test Every 1 hour No color changes in the MN-Strips No
Potable Water TERGITOL NP-6 Surfactant
Corrosion Inhibitor (EC-
Step-01 0.1% - Steel WOOL for Inhibitor Once before Acid Dosing Free from H2 Bubbles
ArmoHib-CI-31)
Iron Concentration to be
Deminarlized or Marchery Nagel Test Strip For stabilized for 2 measurements
Phsae - 05 Acid Cleaning Step-02 Citric acid 3% - 45- 55 °C 1.2 m/s 1 day Every 30 minutes No
Potable Water Iron (with a maximum of 15g/l). and a
margin of +/-5%
Step-03 Ammonium Bi-fluoride 0.5-1% - HACH DR 900 Every 30 minutes Acid Percentage 3%
Step-04 2.0 – 3.0 PH PAPER Every 30 Minutes PH Value 2.0 - 3.0
Step-01 Liquied Ammonia 8.2 - 9.5 PH PAPER Every 30 minutes PH Value 8.2 - 9.5
Deminarlized or After Passivation
Phsae - 06 Passivation 40- 50 °C 1.2 m/s 1 day
Potable Water Step-02 Sodium Nitrite 0.3% - MN TEST STRIPS FOR NITRITE Every 30 minutes Residual Nitrite > 1500 ppm Completion
Phsae - 07 Draining N/A - N/A N/A N/A N/A N/A 2 Days N/A N/A N/A N/A
Phsae - 08 Air Blowing Nitrogen or Dry Air - N/A N/A N/A N/A N/A 3 Days Dew Point Portable Meter N/A Dew Point of -5 C° N/A
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Attachment No.01
A- Temporary Equipment Arrangement Location Per

Each Loop
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Temporary Arrangement
40 Meters
12.6 M 12.6 M 8M
2.6 M
2.6 M
2.5 M
Waste Tank Waste Tank Waste Tank
10 meters
12.6 M 12.6 M 8M
2.5 M
2.6 M
2.6 M
Waste Tank Waste Tank Waste Tank

WASTE COLLECTION TANKS
20 Meters
6.2 M
2.6 M
Chemical Storage Container

8 meters
6.2 M
Hoses & Hard Piping Storage Area
2.6 M
Chemical Storage Container
CHEMICAL STORAGE AREA
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Temporary Arrangement
40 Meters
6M
6M 2.5 M
2M 2.6 M
8M
2.6 M
Mixing Tank
2M
2M
2.6 M
Steam Boiler Lab Container

Air Compressor
Waste Tank
10 meters
Pump 1 Pump 2 6M
2M
2M
2.6 M
2M 2M
Tools Container
Hoses & Fittings Storage Area
CHEMICAL CLEANING AREA
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Waste storage tank Photo
40 feet waste storage tank – 60 m3/Tank.
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FILTER SKID
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DIESEL PUMP – 900 m3/Hr.
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MIXING TANK – 20 m3
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5 TONS STEAM BOILER
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ATTACHMENT NO.01.1
Photograph of Internal
Cleaning of pipes
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ATTACHMENT NO.02
Disposal Company Detail
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ATTACHMENT NO.02.1
Emergency Response Plan
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Emergency Response Plan Page 1 of 10
Subject For Chemical Cleaning of Fuel Gas Lines
Doc. No. CMS/DEWA/ERP Rev. 00
EMERGENCY RESPONSE PLAN
Contents
1. Emergency Response Plan ......................................................................................................2
1.1 Purpose ..............................................................................................................................2
1.2 Designated Positions and Responsibilities ..........................................................................2
1.3 Emergency Response Action Leader (on-site) ....................................................................2
1.4 Emergency Response Priorities ..........................................................................................2
1.5 Action Required...................................................................................................................3
1.6 Have the Following Information Available for the Contact Person........................................3
1.7 Contact Person to Provide the Following Information ..........................................................3
1.8 Corodex Emergency Contact Numbers: ..............................................................................4
1.9 Reporting of Incidents .........................................................................................................4
2. Spill Response Plan..................................................................................................................4
2.1 Classification of Spill ...........................................................................................................4
2.1.1 Minor Spill.....................................................................................................................4
2.1.2 Major Spill.....................................................................................................................4
2.2 Measures taken by Corodex for containing spill...................................................................4
- Chemical transfer pumps will be kept on drip trays. .............................................................4
- Chemical cleaning tanks will be provided with drip trays ......................................................4
- Diesel tanks will be kept in 110 % containment....................................................................4
- Spill kits will be kept near chemical cleaning setup area and waste storage area.................4
- all waste tanks provided will have level gauge .....................................................................4
2.3 In Case of Spillage: .............................................................................................................5
2.3 Chemical Spill Team ...........................................................................................................5
Team Leader ........................................................................................................................5
3. Medical Facilities On-Site .........................................................................................................5
4. Security .................................................................................................................................5
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1. Emergency Response Plan
1.1 Purpose
The Emergency Response Plan has three basic functions:
▪ To Protect People
▪ To Protect the Environment
▪ To Protect Property
The aim and the objective is to provide guidelines for effectively controlling and managing
emergencies through a coordinated emergency response plan using CMS personnel, who form
the emergency response team. This is in line with the CMS Environmental Procedures Manual.
1.2 Designated Positions and Responsibilities

CMS Project Manager who is designated Project Incident Response Manager shall liaise with
the Project On-Scene Response Officer at the specific Job site, to coordinate any support
required by the On-Site Response Officer. Project On-Scene Response Officer
The Project On-Scene Officer will be the Site Senior Person in Charge on shift. He/ she is
responsible for taking command of all emergency situations at the On-Site location. He/ she will
seek assistance by calling the Project Incident Response Manager he/ she will also liaise with the
CONTRACTOR/COMPANY Site Representatives.
1.3 Emergency Response Action Leader (on-site)

The Shift Supervisor will be the Emergency Response Action Leader and will be responsible for
mobilizing the CMS response team to control all emergency situations. The Emergency
Response Action Leader will liaise with the On-Scene Response Officer by direct contact.
Members of the Response Team
▪ Engineers
▪ Supervisors
▪ Technicians
Note: Any or all of the above personnel can be mobilized depending on the nature and
requirement of the response.
1.4 Emergency Response Priorities

The Emergency Response Priorities of the teams are:
a. Prevent employee, public and environmental exposure to potentially hazardous materials
and situations.
b. Prevent any spillage migrating from the scene to surrounding areas, particularly waterways.
c. Ensure prompt and appropriate response to minimize risks and severity.
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1.5 Action Required

1. Inform the COMPANY Site Representative and keep all non-essential personnel away from
the area, to providehardbarricade and signage’sthatunauthorizedpersonnelwas notallowed.
2. Consult the MSDS (Material Safety Data Sheet) for product information if required for
spillage of any hazardous substance (Also ensuring that all specified PPE is worn prior to
tackle any such spillage by the Chemical Spill Team.)
3. If conditions are safe to do so, reduce the degree of hazard by closing or blocking off the
area, and start cleaning or containment operations.
4. Proceed or delegate someone to call the emergency number shown on the project
Emergency Response Contact List, located in Appendix B, (Emergency Response Plan).
5. Consult medical personnel immediately and relate information required as listed below.
1.6 Have the Following Information Available for the Contact Person
1. Nature of the incident – oil/chemical spill? Vehicle accident? Medical emergency? Snake
bite?
2. Name / mode of transport.
3. Products/chemicals involved - names of UN numbers from the MSD Sheets.
4. Location and details of incident.
5. Extent of personal injuries, if any. Include patient’s name, location, time of incident, age,
medical condition, and passport number, contact phone number, fax number (if available)
chemical products, ifany.
6. Caller names, location, telephone number, and fax number (if available.) Caller to stand by
phone for call back.
7. Contacted person will notify the Key Personnel listed in the Emergency Response
Procedure.
1.7 Contact Person to Provide the Following Information

1. First aid or medical aid for: Person(s) who may have had exposure to chemical(s) – MSDS.
2. Toxicity of chemical(s) – MSD Sheets
3. Fire-fighting and toxicity of chemical(s)
4. Cleaning up spill(s) – MSDS sheets.
5. Disposal of chemical(s), damage drums, sacks or cans – MSD Sheets
6. Contacting medical personnel – provided by the main contractor
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1.8 Corodex Emergency Contact Numbers:
▪ CMS Project Manager (Ghazy) – +971507627878

▪ CMS Project Engineer (Fadi Ismail) – +971508637220
Once the decision is taken to medevac personnel they have the authority to make the medical
decisions required to commence medevac procedures. Non-qualified personnel are not permitted
to make medical decisions.
1.9 Reporting of Incidents
In the event of an Accident/Medical Emergency or accidental discharge/spill, it is the responsibility

of the local CMS staff to report directly to the Site Senior Person in Charge who will record all
details provided on the Daily Site Report Form. The Site Senior Person in Charge shall consult
and inform the CMS area office management and also the CONTRACTOR site representative
within the pre-agreed timescales.
2. Spill Response Plan
In addition to above emergency measures, spills will be dealt with following

additional control measures:-
2.1 Classification of Spill

2.1.1 Minor Spill
A minor spill is any incident where damage or degradation to the surrounding area or environment
takes place; this includes spillage or accidental discharge of any oil, chemical (gas, vapor, liquid,
powder) or waste material. This also includes excessive indisposed litter/rubbish left on the job
location.
Any accident where environmental damage could have taken place but was fully contained (e.g.
spillage to a sealed bund or concrete pad) and was fully recoverable and could not enter the
surrounding environment in any way (AIR, DRAINS/SEWERS, WATER COURSES) shall be
recorded and reported as Near Miss.
2.1.2 Major Spill
Any spillage that is not able to be fully contained and enters the environment shall be considered
a Major spill and will be recorded / reported and handled as such.
2.2 Measures taken by Corodex for containing spill

- Chemical transfer pumps will be kept on drip trays.
- Chemical cleaning tanks will be provided with drip trays
- Diesel tanks will be kept in 110 % containment
- Spill kits will be kept near chemical cleaning setup area and waste storage area.
- all waste tanks provided will have level gauge.
- All the tanks are compatible with the liquid

Page 103they will store.
of 294
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2.3 In Case of Spillage:-
1. In case of chemical spillage, immediately shut off the system if the leak is due to circulation
of fluid.
2. First priority should be trying to arrest the leak.
3. Simultaneously a team should make use of spill kit and chemical absorbent granules to
absorb fluid which leaked.
4. Then we will collect all the things (cotton rag, sand or soil, etc.) that were contaminated by
the chemical spill and dispose it accordingly with our licensed waste disposal contractor as
per UAE law.
2.3 Chemical Spill Team:
CMS team who will be the in-charge and respond in case of chemical spill incident.
Team Leader:
Fadi Ismail
Shakir Iqbal
Members:
Mustafa
Fouad
Mammoud
Fami
Pramod
Omar
3. Medical Facilities On-Site

1. One of the CMS crew will have been trained in Basic First Aid; he/she will be
responsible for minor ailments and first aid cases.
2. He will also be responsible for maintaining the First Aid Kit located in the CMS test cabin.
3. CMS will provide a designated area for eye wash and safety shower which is always
be functional in case of emergency.
4. Security
Prior to mobilization, CMS Personnel shall be briefed on the present global and local security
situation and advised of any present security level, which may be in force or could be put in force
at the time of operations commencing.
If Personnel are in country and a security level is enforced, it is the responsibility of the Project
Manager to ensure that information is available on a daily basis and to update personnel as and
when it changes. The CMS Project Manager shall liaise with other specialized staff to ensure the
information provided to the field staff is timely and accurate.
It is very important for everyone to understand that it is CMS policy not to compromise the
security and safety of its employees. And that employees, too, have a responsibility to
themselves, to their families and to the company to be constantly vigilant, to be aware of the
security level if any and to be fully versed in the actions that are required for implementation
should the need arise.
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IN HOUSE TRAINING FOR CHEMICAL CLEANING WORKS

Date: 25.07.2020
Following perssonel,s are well trained for chemical cleaning and pickling passivation activities they are
competent for chemical handling and perform the chemical cleaning activity in a safe and professional manner.
1 JOEL QUADROS ENGINEER

2 FADI MOHAMMED ISMAIL ENGINEER
3 WASIM AHMED CHEMICAL TECNICIAN
4 MOUSTAFA MAREE SOLIMAN CHEMICAL TECNICIAN
5 SAMIR SABRY IBRAHIM CHEMICAL TECNICIAN
6 FOUAD SABRY IBRAHIM CHEMICAL TECNICIAN
7 TANVEER AHMED CHEMICAL TECNICIAN
8 EL FATHIH CHEMICAL TECNICIAN
9 MAHMOUD ABDEL FATHAH CHEMICAL TECNICIAN
10 PRAMOD HARI PRASAD CHEMICAL TECNICIAN
11 MUHAMMAD SHAKIR ENGINEER
12 GUL KHAN CHEMICAL TECNICIAN
13 MAHMOUD THAHA CHEMICAL TECNICIAN
14 PRANAV PATEL CHEMICAL TECNICIAN
15 OMAR FALAH ISSA CHEMICAL TECNICIAN
16 ANIL KUMAR CHEMICAL TECNICIAN
17 REJI VENU SHEELA CHEMICAL TECNICIAN
18 SUDEVAN SAJU CHEMICAL TECNICIAN
19 HAMDY SAEED CHEMICAL TECNICIAN
20 YASHEN FAMI SUPERVISOR
Trainer Signature & Stamp
Mikko Toivonen
Corodex marine services
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IN HOUSE TRAINING FOR CHEMICAL SPILLAGE CLEAN UP AND FURTHER PREVENTION

Date: 16.06.2020
Following perssonel,s are well trained for chemical spillage clean up and further prevention in a
safe and professional manner.
TEAM LEADER DESIGNATION

TEAM MEMBERS
Mikko Toivonen
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IN HOUSE TRAINING FOR CHEMICAL CLEANING WORKS

Date:25.07.2020
Following perssonel,s are well trained for chemical cleaning and pickling passivation activities they are
competent for chemical handling and perform the chemical cleaning activity in a safe and professional manner.
1 JOEL QUADROS ENGINEER

3 WASIM AHMED CHEMICAL TECNICIAN
8 EL FATHIH CHEMICAL TECNICIAN
9 MAHMOUD ABDEL FATHAH CHEMICAL TECNICIAN
10 PRAMOD HARI PRASAD CHEMICAL TECNICIAN
12 GUL KHAN CHEMICAL TECNICIAN
13 MAHMOUD THAHA CHEMICAL TECNICIAN
14 PRANAV PATEL CHEMICAL TECNICIAN
15 OMAR FALAH ISSA CHEMICAL TECNICIAN
16 ANIL KUMAR CHEMICAL TECNICIAN
17 REJI VENU SHEELA CHEMICAL TECNICIAN
Mikko Toivonen
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IN HOUSE TRAINING FOR CHEMICAL SPILLAGE CLEAN UP AND FURTHER PREVENTION

Date:16.06.2020
Following perssonel,s are well trained for chemical spillage clean up and further prevention in a
safe and professional manner.
TEAM LEADER DESIGNATION

TEAM MEMBERS
Mikko Toivonen
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ATTACHMENT NO.02.2
MSDS
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web: http://www.nfil.in
mailto: bulkfluoride@nfil.in
NAVIN FLUORINE INTERNATIONAL LTD 2nd Floor, Suntek Centre,
37/40, Subhash Road, Vile Parle
(East), Mumbai-400057. India.
PRODUCT SPECIFICATION
Title: AMMONIUM BIFLUORIDE Document No. : NFIL/QC/SPEC/FP/051/00
(NH4HF2) Effective Date : 05/11/2008
Material Code : FLU008001
Packing : Normal & UN-Certified 35 kg & 25 kg Bags.
Storage Specification : Stored in dry condition at room temperature.
Structural Formula :
Molecular Formula : H5F2N
Molecular Weight : 57.04
Synonyms : Ammonium hydrogen fluoride; ammonium difluoride
Sr.
TEST SPECIFICATION
No.
Product Specification:
1 Appearance/ Description White Hygroscopic flakes
Moisture
2 0.30% Max.
NH4HF2
3 98.50% Min.
• Customer should discuss with business unit at bulkfluoride@nfil.in for the other
requirements than specified.
• Analytical Method No. NFIL/QC/WI/FP/051.
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MATERIAL SAFETY DATA SHEET (MSDS)
Ammonium bifluoride
1. CHEMICAL IDENTITY
Chemical name Ammonium bifluoride
Synonym Ammonium hydrogen difluoride
Chemical Formula H5F2N
2. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredients Name CAS No.: 1341-49-7
EC No: 215-676-4
3. PHYSICAL / CHEMICAL DATA
Boiling Point 239.50C@760 mmHg Vapour Pressure 1 hPa @ 20 0 C
Melting Point 125 deg C Solubility in water 630 G/L water (20°C)
Vapour Density Not available Appearance white solid
Specific Gravity 1.50
pH 3.5 @ 5% solution Odour Slightly pungent
Physical State Solid Other
4. FIRE / EXPLOSION HAZARD DATA
Flammability Non Flammable Flash Point Not applicable.
Auto ignition temperature Not applicable LEL Not available
Explosion sensitivity to impact UEL Not available
Explosion sensitivity to static electricity
Hazardous Combustion products
Hazardous Polymerization Will not occur
Pyrophoric material Corrosive
Organic Peroxide Oxidizer
Explosive material Other
5. STABILITY & REACTIVITY DATA
Chemical Stability Stable under normal temperatures and pressures. Deliquescent
(tending to absorb atmospheric water vapor and become liquid)
Incompatibility Acids, bases
Conditions to avoid Dust generation, moisture, temperatures above 300°C
Hazardous reaction / Hydrogen fluoride gas, ammonia and/or derivatives
decomposition products.
6. HEALTH HAZARD DATA
Effects of exposure / symptoms Eye: Causes eye burns. May cause chemical conjunctivitis and
corneal damage.
Skin: Contact with liquid causes severe burns and ulceration.
May penetrate the skin and cause severe tissue and bone
destruction. May cause skin rash (in milder cases), and cold and
clammy skin with cyanosis or pale color.
Ingestion: Harmful if swallowed. May cause severe and
permanent damage to the digestive tract. May cause kidney
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damage. May cause perforation of the digestive tract. Causes

severe digestive tract burns with abdominal pain, vomiting, and
possible death. Inorganic fluorides can be harmful. Acute
exposure to fluorine compounds can lead to digestive tract
burns, and abdominal pain. Fluoride can reduce calcium levels
leading to fatal hypocalcemia. May cause systemic effects.
Inhalation: Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation,
edema of the larynx and bronchi, chemical pneumonitis and
pulmonary edema. Aspiration may lead to pulmonary edema.
Depletes calcium levels in the body which can lead to
hypocalcemia and death. May cause systemic effects.
Chronic: Chronic inhalation and ingestion may cause chronic
fluoride poisoning (fluorosis) characterized by weight loss,
weakness, anemia, brittle bones, and stiff joints. May cause
digestive tract disturbances. Effects may be delayed. Chronic
exposure to fluoride compounds may cause systemic toxicity.
7. TOXICOLOGICAL INFORMATION
LD 50 / LC50 Not available
Exposure Limit 2.5 mg/m3 TWA (as F) (listed under Fluorides).
8. ECOLOGICAL INFORMATION
No information available
9. PREVENTIVE MEASURES / EXPOSURE CONTROL / PERSONAL PROTECTION
Engineering Control Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety
goggles as described by OSHA's eye and face protection
regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin
exposure.
Clothing: Wear appropriate protective clothing to prevent skin
exposure.
Respirators: A respiratory protection program that meets
OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or
European Standard EN 149 must be followed whenever
workplace conditions warrant respirator use.
10. HANDLING & STOROGE
Normal handling Wash thoroughly after handling. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not
get in eyes, on skin, or on clothing. Keep container tightly
closed. Do not ingest or inhale. Discard contaminated shoes. Use
only with adequate ventilation.
Storage Recommendation Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Corrosives area. Keep away from
acids. Keep away from strong bases. Store protected from
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moisture.
11. EMERGENCY / FIRST AID MEASURES

Fire Fire Extinguishing For small fires, use dry chemical, carbon dioxide, or
Medium water spray. For large fires, use dry chemical,
carbon dioxide, alcohol-resistant foam, or water
spray.
Exposure / First Inhalation Get medical aid immediately. Remove from
Aid Measure exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is
difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial
respiration using oxygen and a suitable mechanical
device such as a bag and a mask
Skin Get medical aid immediately. Immediately flush
skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated
shoes.
Eyes Get medical aid immediately. Do NOT allow victim
to rub eyes or keep eyes closed. Extensive irrigation
with water is required (at least 30 minutes).
Ingestion Do not induce vomiting. If victim is conscious and
alert, give 2-4 cupfuls of milk or water. Never give
anything by mouth to an unconscious person. Get
medical aid immediately
Special Procedure
12. ACCIDENTAL RELEASE MEASURE
Spills/Leaks Vacuum or sweep up material and place into a suitable disposal container.
Avoid runoff into storm sewers and ditches which lead to waterways. Clean up
spills immediately, observing precautions in the Protective Equipment section.
Avoid generating dusty conditions. Provide ventilation.
13. DISPOSAL CONSIDERATIONS
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous
waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to ensure
complete and accurate classification.
14. TRASPORT INFORMATION
Proper shipping Name AMMONIUM HYDROGENDIFLUORIDE, SOLID
Hazard Class 8
UN Number UN1727
Packing Group II
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Hazard Label
15. REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T C
Risk Phrases:
R 25 Toxic if swallowed.
R 34 Causes burns.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
16. NAME OF FIRM - NAVIN FLUORINE INTERNATIONAL LIMITED
Mailing address Post Office - Bhestan, Surat, PIN 395 023, Gujarat, India
Telephone +91-261-2890325 to 2890329
Fax +91-261-2890288
DISCLAIMER
Information contained in this Material Safety Data Sheet is believed to be reliable but no
representation; guarantee or warranties of any kind are made as to its accuracy, suitability for a
particular application or results to be obtained from them. It is up to the user / distributor to ensure
that the information contained in the material safety data sheet is relevant to the product
manufactured / handled or sold by him as the case may be. There would be no warranties expressed
or implied in the respect of the adequacy of this document for any particular purpose
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SAFETY DATA SHEET

AMMONIA SOLUTION 0.910 25%
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Product name: AMMONIA SOLUTION 0.910 25%
CAS number: 1336-21-6
EINECS number: 215-647-6
Index number: 007-001-01-2
Use / description of product: Corrosive.
Company name: VIJAY GAS INDUSTRY
B-65 ADDITIONAL MIDC,
ANAND NAGAR, AMBERNATH EAST 421506
MAHARASHTRA, INDIA
TEL : 0251-2474547/2620869/ +91 9870272706 / 33
2. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous ingredients: AMMONIA SOLUTION 0.910 25% 30-50%
3. HAZARDS IDENTIFICATION
Main hazards: Causes burns. Very toxic to aquatic organisms.
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4. FIRST AID MEASURES (SYMPTOMS)
Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may cause
coughing or wheezing.
4. FIRST AID MEASURES (ACTION)
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the
affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer to
hospital if there are burns or symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10
minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If
unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon
as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious and
breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or lies
down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available.
Transfer to hospital as soon as possible.
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5. FIRE-FIGHTING MEASURES
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to
cool
containers.
Exposure hazards: Corrosive. In combustion emits toxic fumes.
Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact
with skin
and eyes.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and
away from
danger point. Mark out the contaminated area with signs and prevent access to unauthorised
personnel. Do not attempt to take action without suitable protective clothing - see section 8 of
SDS. Turn leaking containers leak-side up to prevent the escape of liquid.
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific
substance.
Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by
an appropriate method.
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7. HANDLING AND STORAGE
Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area.
Do
not handle in a confined space. Avoid the formation or spread of mists in the air.
Storage conditions: Store in cool, well ventilated area. Keep container tightly closed.
Suitable packaging: Must only be kept in original packaging.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.
Hand protection: Impermeable gloves.
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Impermeable protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
State: Liquid
Colour: Colourless
Odour: Characteristic odour
Solubility in water: COMPLETE
Boiling point/range°C: 68
Melting point/range°C: -16 TO -95
Flash point°C: N/A
Autoflammability°C: >500
Relative density: 0.96-0.88
pH: >10
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10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions.
Conditions to avoid: Heat.
Materials to avoid: Strong oxidising agents. Strong acids.
Haz. decomp. products: In combustion emits toxic fumes.
11. TOXICOLOGICAL INFORMATION
Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms.
12. ECOLOGICAL INFORMATION
Mobility: Readily absorbed into soil.
Persistence and degradability: Biodegradable.
Bioaccumulative potential: No bioaccumulation potential.
Other adverse effects: Negligible ecotoxicity.
13. DISPOSAL CONSIDERATIONS
Disposal of packaging: Arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.
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14. TRANSPORT INFORMATION
ADR / RID
UN no: 2672 ADR Class: 8
Packing group: III Classification code: C5
Shipping name: AMMONIA SOLUTION
Labelling: 8 Hazard ID no: 80
IMDG / IMO
UN no: 2672 Class: 8
Packing group: III EmS: 8-06/
Marine pollutant: NO Labelling: 8
IATA / ICAO
UN no: 2672 Class: 8
Packing group: III Packing instructions: 819(P&CA); 813(PAO)
Labelling: 8
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15. REGULATORY INFORMATION
Hazard symbols: Corrosive.
Dangerous for the environment.
Risk phrases: R34: Causes burns.
R50: Very toxic to aquatic organisms.
Safety phrases: S24/25: Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28: After contact with skin, wash immediately with plenty of water.
S29/56: Do not empty into drains, dispose of this material and its container at hazardous or
special waste collection point.
S36/37/39: Wear suitable protective clothing, gloves and eye / face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S60: This material and its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
Note: The regulatory information given above only indicates the principal regulations specifically
applicable to the product described in the safety data sheet. The user's attention is drawn to
the possible existence of additional provisions which complete these regulations. Refer to all
applicable national, international and local regulations or provisions.
16. OTHER INFORMATION
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall
be used only as a guide. This company shall not be held liable for any damage resulting from
handling or from contact with the above product.
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Material Safety Data Sheet
EC-ArmoHib-CI-31
1. Identification of Product and Company
Concorde Corodex Group

P.O.Box: 12282, Dubai, UAE
Tel: + 971 4 3472900
Fax: + 971 4 3477072
Product: EC-ArmoHib-CI-31
Use: Corrosion Inhibitor
2. Composition / Information on ingredients

Aqueous solution containing: CAS#
Alkoxylated Fatty Amine, salts, & Organic acid proprietary
3. Hazards Identification
Emergency overview: WARNING! Causes Eye irritation

Hazard Statement: May be harmful if swallowed, may causes skin irritation
May cause allergic skin reaction
May be harmful to environment if released in large amounts.
Precautionary Statements: Wash skin thoroughly after handling, Do not eat drink or smoke when using this product.
Wear protective gloves/eye protection/face protection. This material and its container must
be disposed of as hazardous waste.
4. First-aid Measures
Ingestion: Do Not induce vomiting unless directed to do so by medical personnel. Never give anything
by mouth to an unconscious person. If large quantity of this material are swallowed, call a
physician immediately. Loosen tight clothing such as tie, collar, belt or waist board.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration/ If breathing is
difficult, give oxygen. Get medical attention.
Skin contact: In case of contact, immediately flush skin with plenty of water for at least 30 minutes while
removing contaminated clothing and shoes, Cold water may be used. Wash clothing before
reuse. Thoroughly clean shoes before re use. Get medical attention.
Eye Contact: In case of contact with eyes, rinse with plenty of water. Cold water may be used Get
medical attention immediately. Remove contact lenses. Protect unharmed eye. Keep eye
wide open while rinsing.
General Advice: Immediate medical attention is required, Move out of dangerous area.
5. Fire-fighting Measures
Flammability of the product: May be combustible at high temperature

Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Special Hazards from substance: Do not allow run-off from fire fighting to enter drains or water courses.
Special Protective Equipment: In case of fire, wear self contained breathing apparatus for fire fighters.
Further Information: Collect contaminated fire extinguishing water separately. This must not be discharged into
drains. Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations.
EC-ArmoHib-CI-31 01.1013 Page 1 of 3 12.31.13
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MSDS EC-ArmoHib-CI-31
6. Accidental Release Measures

Personal Precautions: For personal protection see section 8. use personal protective equipment. Ensure adequate
ventilation.
Environmental Precautions: Do not flush into ground, water ways or sanitary sewer system.
Treat runoff as hazardous.
Methods For Cleaning Up: In case of spills, Soak up with inert absorbent materials such as sand, siliceous earth, acid
binder, saw dust. Store in closed containers and Dispose of waste according to applicable
legislation. Wash spill area with plenty of water.
7. Handling and Storage

Handling: Provide adequate ventilation, and local exhaust as needed. Do not breath vapors. Avoid
contact with skin, eyes, and clothing. After handling or contact wash hands
thoroughly.
Storage: Store container tightly closed in a cool dry & well ventilated area away from incompatible
substances. Keep away from heat, sparks, and flame. Keep away from sources of ignition.
Keep container closed when not in use.
8. Exposure controls/ Personal protection

Exposure controls: Provide good ventilation and/or an exhaust system in the work area. Ensure that eye
wash stations and safety showers are close to work station location.
Eyes: Use tightly fitted chemical safety goggles as described by OSHA's eye and face protection
regulations.
Respiratory tract: In the case of vapor formation use a respirator with an approved filter.
Hand Protection: For prolonged or repeated contact use protective gloves.
Skin & Body Protection: Use protective suit according to the amount and concentration of the dangerous substance
at the work place.
Hygiene Measure: Handle in accordance with good industrial hygiene and safety practice. When using do not
smoke, eat or drink. Wash hands before breaks and at the end of workday. Wash
contaminated clothing prior to re-use.
9. Physical and Chemical Properties (Typical specification)

Form: Liquid
Appearance: Brown
pH (1% sol): <7.0
Specific gravity: 0.92-1.1
Solubility in other solvents: Soluble in Alcohols
Solubility in water: Soluble
Note: These physical properties are typical values for this product and are subject to change
10. Stability and Reactivity

Stability: Stable under recommended storage conditions.
Hazardous Polymerization: Will not occur
Conditions To Avoid: Incompatible materials, ignition sources, moisture, exposure to air, excessive heat.
Reactive with Oxidizing Agents, acids, slightly reactive with alkalis.
Materials To Avoid: Oxidizing agents
Hazardous decomposition : No hazardous decomposition products are known.
products
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MSDS EC-ArmoHib-CI-31
11. Toxicological Information

Acute effects on Skins: May cause sensitization by skin contact. Moderately irritating to the skin.
Acute effects on Eyes: Severely irritating to eyes.

Special Remarks on other Toxic Effects on Humans: Alkoxylated Fatty Amine salts based: skin & eyes based on data (similar
materials), Alkoxylated Organic acid: Skin & eyes based on data (similar materials
12. Ecological Information
Ecotoxicity: Not available.

BOD5 and COD: Not available.
Biodegradability: Readily biodegradable
13. Disposal Considerations

Waste disposal: Do not dispose waste into sewer. Do not contaminate waterways or ditches with chemical
or used container. Chemical waste generators must determine whether a discarded
chemical is classified as a hazardous waste. US EPA guidelines for the classification
determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must
consult state and local hazardous waste regulations to ensure complete and accurate
classification. Spills and excess chemicals should be treated as chemical waste .
Dispose of waste according to applicable legislation. Product may not be released into
water without pre-treatment (biological sewage plant).
14. Transport Information
Contaminated packaging: Recommendation: Handle contaminated packages in the same way as the substance
ADR: Not dangerous goods
IATA: Not dangerous goods
IMDG Not dangerous goods
RID Not dangerous goods
Not classified as dangerous in the meaning of transport regulations.
Important notice: This data sheet is a supplement to the technical instructions but does not replace them. The data are given in good faith based on information derived from our knowledge of the product at the
date of issue of this document. Each user is responsible to determine that the product is suitable for the user's intended application and that such usage complies with applicable legislative and administrative rules
and guidelines. This data sheet may contain dotted lines (....), which may indicate the missing of phrases in the computerized database.
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Citric acid Anhydrous

SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH); 1272/2008 & 453/2010 (CLP)
Version: 1
Date: 28/02/2011
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
1.1 Product identifier
Chemical Name Citric acid
Trade name Citric acid Anhydrous
CAS No. 77-92-9
EINECS No. 201-069-1
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified use(s) Used as a sour agent, buffering agent and antioxidant in the food industry; a
correctant in pharmaceutical industry; used in detergents, buffering and
chelating, sizing and as a sequestrant.
Uses advised against No uses advised against
1.3 Details of the supplier of the Safety Data Sheet
Company Identification Weifang Ensign Industry Co., Ltd.
No. 1567, Changsheng Street, Changle, Weifang, 262400, Shandong Province, China
Telephone 0086-536-6298198
6298125
Fax No 0086-536-6234587
Contact name Wei
Xiaoming
Liu Yi
Email sales@ensignworld.com
1.4 Emergency telephone number 0086-536-6298125

0086-536-6298198
SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
2.1.1 Regulation (EC) No. 1272/2008 (CLP) Warning. H319: Causes serious eye irritation
2.1.2 Directive 67/548/EEC & Directive Xi; Irritant. R36
1999/45/EC
2.2 Label elements
2.2.1 According to Regulation (EC) No. 1272/2008 & 453/2010 (CLP)
Hazard Pictogram
Signal word(s) Warning

Hazard statement(s) H319: Causes serious eye irritation
Precautionary statement(s) P264. Wash hands thoroughly after handling.
P280 Wear eye protection.
P305 + P351 + P338. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
2.2.2 According to Directive 67/548/EEC & Directive 1999/45/EC
Hazard Symbol
Irritant
Risk Phrases R36. Irritating to eye
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Safety Phrases S26. Avoid contact with eyes. In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice
2.3 Other hazards Not known
2.4 Additional Information Not known
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substance
Composition %W/W EC No. CAS No
Citric acid 99.5 to 100.5 201-069-1 77-92-9
SECTION 4: FIRST AID MEASURES
4.1 Description of first aid measures

Inhalation Move to fresh air.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If irritation
persists, call a physician.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a
physician.
Ingestion Do NOT induce vomiting. Drink 1 or 2 glasses of water. Never give anything
by mouth to an unconscious person. Consult a physician.
4.2 Most important symptoms and Serious eye damage/eye irritation: Eye Irrit. 2
effects, both acute and delayed
4.3 Indication of immediate medical Consult a physician.
attention and special treatment needed
SECTION 5: FIRE-FIGHTING MEASURES

5.1 Extinguishing Media
5.1.1 Suitable Extinguishing Media Use alcohol-resistant foam, carbon dioxide, dry powder or water fog.
5.1.2. Unsuitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
5.2 Special hazards arising from the substance or Oxides of carbon
mixture
5.3 Advice for fire-fighters In the event of fire, wear self-contained breathing apparatus and wear suitable
protective clothing.
Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations
5.4 Additional information Explosion hazard from the generation of dust.
SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment Use personal protective equipment.
and emergency procedures
6.2 Environmental precautions Do not flush substance into surface water or sewage system.
6.3 Methods and material for containment and Sweep up or vacuum up spillage and collect in suitable container for disposal.
cleaning up
6.4 Reference to other sections Section 8
SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling Avoid contact with skin and eyes. Use only in well-ventilated areas. Do not
breathe vapours/dust
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7.2 Conditions for safe storage, including Keep locked up or in an area accessible only to qualified staff
any incompatibilities
Storage Store in tightly closed original container in a dry, cool and well ventilated
place. Keep in original container.
Incompatible materials Strong oxidising substances, strong alkalis.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters
8.1.1 Occupational Exposure Limits No values assigned
8.1.2 Biological limit values No values assigned
8.2 PNECs and DNELs

DNELs - Health No true DNEL for systemic toxicity can be derived. Local effects, eye
irritation should be considered.
PNEC/PEC – Environment
Compartment PNEC
Aquatic PNECaqua – freshwater (mg/l) 0.44
PNECaqua - marine water (mg/l) 0.044
PNECfreshwater-sediment (mg/kg d.w.) 3.46. (Equivalent to 0.752 mg/kg wwt)
The PNECmarine-sediment mg/kg d.w. 34.6. (Equivalent to 7.52 mg/kg wwt)
Terrestrial (PNECsoil mg/kg d.w.) 33.1
Sewage treatment plant PNEC STP (mg/l) >1000
Atmospheric Compartment Not applicable
8.3 Exposure controls

8.3.1 Appropriate engineering controls Minimise the risk of dust inhalation. Provide adequate ventilation.
8.3.2 Personal protection equipment
Eye/face protection Safety glasses with side-shields
Skin protection (Hand protection/ Other) Avoid contact with skin, eyes and clothing. Wash hands before breaks and at
the end of workday. Protective gloves must satisfy the specifications of EU
Directive 89/686/EEC and EN 374
Respiratory protection Provide adequate ventilation. Wear respirator where dust level exceeds 10
mg/m3.
Thermal hazards Not applicable

8.3.3 Environmental Exposure Controls Do not allow to enter drains, sewers or watercourses
8.3.4 Hygiene measures Do not smoke in the work area. Wash at the end of each work shift and before
eating, smoking and using the toilet. Wash promptly if skin becomes
contaminated. Promptly remove any clothing that becomes contaminated.
When using do not eat, drink or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
Appearance Solid, crystalline
Colour White
Odour Odourless
pH (Value) 1.7 (100g/l)
Melting Point Approx.153 °C at 1,013 hPa
Boiling point/boiling range (°C): Decomposes before boiling
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Flash Point (°C) Not known

Flammability Non flammable
Density 1.665 g/cm³ at 20°C
Solubility (Water) 590 g/L at 20°C
Solubility (Other) Soluble in alcohol
Partition Coefficient (Log Kow: -n- -0.2 to -1.8
Octanol/water)
Decomposition Temperature (°C) Not known
Explosive properties Not explosive
Oxidising properties Not oxidising
9.2 Other information The fraction below 100 μm = 84.1%; the D50 of the fraction below 100 μm
Granulometry = at 31.99 μm.
Dissociation constant pKa: 3.13, 4.76 and 6.4 at 25°C
SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity Reacts with alkaline materials
10.2 Chemical stability Stable under normal conditions
10.3 Conditions to avoid Exposure to heat and moisture.
10.4 Incompatible materials Sodium nitrite, potassium nitrite
10.5 Hazardous Decomposition Product(s) Oxides of carbon.
SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
11.1.1 Substances
Acute toxicity
Ingestion LD50 (mouse) 5400 mg/kg bw
Inhalation No data
Skin Contact. LD50 (dermal): >2000 mg/kg bw
Skin corrosion/irritation Mild skin irritant
Eye Contact Irritating
Respiratory or skin sensitization –skin Not a sensitizer
Mutagenicity Not a mutagen
Carcinogenicity Not a carcinogen
Reproductive toxicity Not a reproductive toxin
STOT - single exposure Not known
STOT - repeated exposure Not known
Aspiration hazard Not known
11.2 Other information Not known
SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity
Fish LC50 (48hr) 440 mg/l
D. Magna LC 50 (24hr) 1535 mg/l
Algae (8 d mat. (nominal) based on cell density 425 mg/l
12.2 Persistence and degradability Biodegradable
12.3 Bioaccumulative potential No expected to bioaccumulate
12.4 Mobility in soil Not applicable
12.5 Results of PBT and vPvB assessment Not a PBT or a vPvB
12.6 Other adverse effects Not known
SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods Disposal to licensed waste disposal site in accordance with local Waste
Disposal Authority.
Revision: Citric acid Anhydrous Page: 4/5
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SECTION 14: TRANSPORT INFORMATION

14.1 Land transport (ADR/RID) Not subject to transport regulations.
14.2 Sea transport (IMDG) Not subject to transport regulations.
14.3 Air transport (ICAO/IATA) Not subject to transport regulations.
14.4 Transport in bulk according to Annex II of Not known
MARPOL73/78 and the IBC Code
SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture substance
15.1.1 EU regulations User to follow EU directives and regulations
Authorisations and/or restrictions on use Not applicable
15.1.2 National regulations User to follow national regulations
SECTION 16: OTHER INFORMATION
The following sections contain revisions or new statements: Version 1.

LEGEND
LTEL Long Term Exposure Limit
STEL Short Term Exposure Limit
STOT Specific Target Organ Toxicity
DNEL Derived No Effect Level
PNEC Predicted No Effect Concentration
References:
Chemical Safety Report for citric acid and citrates
Regulation (EC) No. 1272/2008 & 453/2010 (CLP)
Directive 67/548/EEC & Directive 1999/45/EC
Risk Phrases and Safety Phrases
R36: Irritating to eyes
S26: Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Hazard statement(s) and Precautionary statement(s)
H319: Causes serious eye irritation
P264: Wash hands thoroughly after handling.
P280: Wear eye protection.
P305 + P351 + P338. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
Training advice: Ensure staff and workers receive adequate training with regular updates in the handling of chemicals
Additional Information. Not known
Information contained in this publication or as otherwise supplied to users is believed to be accurate and is given in good faith, but it is for
the users to satisfy themselves of the suitability of the product for their own particular purpose. Weifang Ensign Industry Co., Ltd. gives no
warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is
excluded except to the extent that exclusion is prevented by law. Weifang Ensign Industry Co., Ltd. accepts no liability for loss or damage
(other than that arising from death or personal injury caused by defective product, if proved), resulting from reliance on this information.
Freedom under Patents, Copyright and Designs cannot be assumed.
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Safety Data Sheet in accordance with

Regulation (EU) No.453/2010
DODICOR 2565 Page 1(11)
Substance key: SXR005069 Revision Date: 27.08.2013

Version : 6 - 0 / EU Date of printing : 19.03.2015
SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier
Trade name
DODICOR 2565
Material number: 107643
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector : Mineral Oil
Type of use : Corrosion inhibitor for the petroleum industry
Exposure scenarios: see section 15.2.
1.3. Details of the supplier of the safety data sheet

Identification of the company
Clariant Produkte (Deutschland) GmbH
65926 Frankfurt am Main

Telephone no. : +49 69 305 18000
Information about the substance/mixture
Corp Product Stewardship
e-mail: MSDS.CorpPS_BU_OMS@clariant.com
1.4. Emergency telephone number

00800-5121 5121 (24 h)
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according EC Directive (67/548/EEC or 1999/45/EC, as amended)
Category of Hazard symbol R - phrases
danger/Category
Harmful Harmful if swallowed.
Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.
2.2. Label elements

Labelling in accordance with EC-Directives (67/548/EEC or 1999/45/EC, as amended)
hazard warning labelling compulsory
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Symbols/Indications of danger
Harmful
R phrases
22 Harmful if swallowed.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
28.2 After contact with skin, wash immediately with water and soap.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
2.3. Other hazards

No additional hazards are known except those derived from the labelling.
SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Quaternary arylammonium chloride in aqueous solution
Hazardous ingredients
Ethanediol
Concentration : 45 %
CAS number : 107-21-1
EC number: 203-473-3
Index Number 603-027-00-1
REACH - Registration 01-2119456816-28, 01-2119456816-28-0000, 01-2119456816-
number according to 28-0003, 01-2119456816-28-XXXX
article 20(3):
Classification hazard substance EC
Xn Harmful R 22
GHS classification EC
Specific target organ Category 2 H373
toxicity - Repeated
exposure
Acute toxicity Category 4 H302
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1-(Benzyl)quinolinium chloride
Concentration : 35 - 40 %
CAS number : 15619-48-4
Classification hazard substance EC
Xn Harmful R 22
R 52/53
GHS classification EC
Acute toxicity Category 4 H302
Chronic aquatic toxicity Category 3 H412
The text of the R-phrases is shown in section 16.
The text of the H-phrases is shown in section 16.
SECTION 4: First aid measures

4.1. Description of first aid measures
General information
Remove soiled or soaked clothing immediately
After inhalation
When inhaled remove to fresh air and seek medical aid.
After contact with skin
In case of contact with skin wash off immediately with soap and water
After contact with eyes
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice
After ingestion
Summon a doctor immediately.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms
No symptoms known currently.
Hazards
No hazards known at this time.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment
Treat symptomatically.
SECTION 5: Firefighting measures

5.1. Extinguishing media
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Suitable extinguishing media

water spray jet
alcohol-resistant foam
carbon dioxide
dry powder
5.2. Special hazards arising from the substance or mixture

In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Carbon dioxide (CO2)
5.3. Advice for firefighters

Special protective equipment for firefighting
Use self-contained breathing apparatus
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Wear suitable personal protective equipment.
Ensure adequate ventilation.
6.2. Environmental precautions

Do not allow to enter drains or waterways
6.3. Methods and material for containment and cleaning up

Pick up with absorbent material (eg sand, sawdust). Rinse away rest with water
6.4. Reference to other sections

Additional information
Information regarding Safe handling, see chapter 7.
Information regarding personal protective measures see, chapter 8.
Information regarding Waste Disposal, see chapter 13.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Open and handle container with care.
Hygiene measures
Wash hands before breaks and after work.
Use barrier skin cream.
Remove soiled or soaked clothing immediately and clean thoroughly before using again.
Advice on protection against fire and explosion
Observe the general rules of industrial fire protection
7.2. Conditions for safe storage, including any incompatibilities
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Requirements for storage areas and containers

Keep container tightly closed in a cool, well-ventilated place.
7.3. Specific end use(s)

No further recommendations.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Exposure limit values
ethylene glycol
CAS number : 107-21-1
Regulatory basis / Regulatory list Revision Type of value Values Remarks

Europe. Commission Directive 2000-06-16 Limit Value - 52 mg/m3
2000/39/EC establishing a first list of eight hours 20 ppm
indicative occupational exposure limit
values
EU. Commission Directive 2000/39/EC
establishing a first list of indicative
occupational exposure limit values in
implementation of Council Directive
98/24/EC.
Europe. Commission Directive 2000-06-16 Short term 104 mg/m3
2000/39/EC establishing a first list of exposure limit 40 ppm
indicative occupational exposure limit
values
EU. Commission Directive 2000/39/EC
establishing a first list of indicative
occupational exposure limit values in
implementation of Council Directive
98/24/EC.
DNEL/DMEL values
DNEL/DMEL values are not available.
PNEC values
PNEC values are not available.
8.2. Exposure controls

General protective measures
Avoid contact with eyes
Respiratory protection : Use respiratory protection in case of insufficient exhaust

ventilation or prolonged exposure
Hand protection : For long-term exposure:
Butyl rubber gloves
Minimum breakthrough time / gloves : 480 min
Minimum thickness / gloves 0,7 mm
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For short-term exposure (splash protection):

Nitrile rubber gloves.
Minimum breakthrough time / gloves : 30 min
Minimum thickness / gloves 0,4 mm
These types of protective gloves are offered by various
manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.
Eye protection : safety glasses
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Form : Liquid
Particle size : Not applicable
Colour : brownish
Odour : aromatic
Odour threshold : not tested.
pH value : 3,5 - 5 (20 °C, 10 g/l)
Pourpoint : < -20 °C
Boiling temperature : approx. 100 °C
Flash point : > 100 °C
Evaporation rate : not tested.
Lower explosion limit : not tested.
Upper explosive limit : not tested.
Combustion number : Not applicable
Minimum ignition energy : not tested.
Vapour pressure : approx. 0,02 hPa (20 °C)
Data relate to solvent
Vapour density relative to air : not tested.
Solubility in water : (20 °C)
soluble
Soluble in ... : fat
not tested.
Octanol/water partition Not applicable
coefficient (log Pow) :
Ignition temperature : not tested.
Self-ignition temperature : Not applicable
Thermal decomposition : not tested.
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Viscosity (dynamic) : 40 mPa.s (20 °C)

Viscosity (kinematic) : not tested.
Explosive properties : Explosive according to EU supply regulations : no data
Oxidizing properties : Not applicable
9.2. Other information

Density : approx. 1,15 g/cm3 (20 °C)
Method : DIN 51757
Bulk density : Not applicable
SECTION 10: Stability and reactivity

10.1. Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2. Chemical stability

Stable.
10.3. Possibility of hazardous reactions

When handled and stored appropriately no dangerous reactions are known
10.4. Conditions to avoid

Avoid contact with strong alkaline materials.
10.5. Incompatible materials

not known
10.6. Hazardous decomposition products

When handled and stored appropriately, no dangerous decomposition products are known
SECTION 11: Toxicological information

11.1. Information on toxicological effects
Information related to the product itself:
Acute oral toxicity : LD50 500 - 2.000 mg/kg (rat)
Method : OECD 401
Acute dermal toxicity : not tested.
Acute inhalation toxicity : not tested.
Irritant effect on skin : non-irritant (rabbit)
Method : OECD 404
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Irritant effect on eyes : non-irritant (rabbit eye)

Method : OECD 405
Sensitization : not tested.
Repeated dose toxicity: not tested.
Assessment of mutagenicity : not tested.
Assessment of not tested.
carcinogenicity :
Assessment of toxicity to not tested.
reproduction :
Assessment of teratogenicity : not tested.
Specific target organ toxicity not tested.
(STOT) - single exposure :
Specific target organ toxicity not tested.
(STOT) - repeated exposure :
Information related to the component: Ethanediol

Acute oral toxicity : LD50 4.700 mg/kg (rat)
Acute toxicity estimate 500 mg/kg
Method : Converted acute toxicity point estimate
Source : Acute toxicity point estimate based on EU GHS
classification data
SECTION 12: Ecological information

12.1. Toxicity
Fish toxicity : not tested.
Daphnia toxicity : EC50 36,7 mg/l (48 h, Daphnia magna)
Method : OECD 202
Algae toxicity : not tested.
Bacteria toxicity : EC50 495 mg/l
Method : DIN 38412 T.8
12.2. Persistence and degradability

Biodegradability : > 60 % (35 d)
Method : OECD 301 B
The product is not readily biodegradable according to OECD
criteria but is inherently biodegradable.
Chemical oxygen demand 1.472 mg/g
(COD) :
12.3. Bioaccumulative potential
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Bioaccumulation: not tested.
12.4. Mobility in soil

Transport and distribution not tested.
between environmental
compartments :
12.5. Results of PBT and vPvB assessment

No data available.
12.6. Other adverse effects

Additional ecotoxicological remarks
No data available.
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product
In accordance with local authority regulations, take to special waste incineration plant
SECTION 14: Transport information

Section 14.1. to 14.5.
ADR not restricted
ADN not restricted
RID not restricted
IATA not restricted
IMDG not restricted
14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (International
Bulk Chemicals Code)
No transport as bulk according IBC - Code.
SECTION 15: Regulatory information
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15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
Other regulations
Apart from the data/regulations specified in this chapter, no further information is available
concerning safety, health and environmental protection.
15.2. Chemical safety assessment

No Chemical Safety Assessment (CSA) is yet available for the substance, or for the
component substances, contained in this product.
Exposure scenarios - links
Please select the specified addresses from the internet in order to see the exposure
scenarios.
URL Short title
https://reachdialogsystem.clariant.com/ESDocs/EXS000005.pdf Monoethylene glycol - all
exposure scenarios
SECTION 16: Other information

Observe national and local legal requirements
Text of the R-phrases assigned to the ingredients/components mentioned in section 3 :
22 Harmful if swallowed.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
List of the text of the hazard statements mentioned section 3 (H-phrases) :
H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Legend
ADN European Agreement concerning the International Carriage of Dangerous
Goods by Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous
Goods by Road
AOX Adsorbable organic bound halogens
CAS Chemical Abstracts Service
DMEL Derived Minimal Effect Level (genotoxic substances)
DNEL Derived No Effect Level
EC50 Half maximal effective concentration
GHS Globally Harmonized System
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
LC50 Lethal Concentration 50%
LD50 Lethal Dose 50%
MARPOL International Convention for the Prevention of Pollution From Ships
NOAEC No Observed Adverse Effect Concentration
NOAEL No Observed Adverse Effect Level
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NOEC Non Observed Effect Concentration

OEL Occupational Exposure Limit
PBT Persistent, Bioaccumulative, Toxic
PEC Predicted Environmental Concentration
PNEC Predicted No Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID International Rule for Transport of Dangerous Substances by Railway
SVHC Substances of Very High Concern
vPvB very Persistent and very Bioaccumulative
Decimal notation: "thousands" places are identified with a dot (for example, "2.000 mg/kg"
means "two thousand mg/kg"). Decimal places are identified with a comma (for example,
"1,35 g/cm3" means "one point three five g/cm3").
This information corresponds to the present state of our knowledge and is intended as a
general description of our products and their possible applications. Clariant makes no
warranties, express or implied, as to the information's accuracy, adequacy, sufficiency or
freedom from defect and assumes no liability in connection with any use of this information.
Any user of this product is responsible for determining the suitability of Clariant's products
for its particular application. Nothing included in this information waives any of Clariant's
General Terms and Conditions of Sale, which control unless it agrees otherwise in writing.
Any existing intellectual/industrial property rights must be observed. Due to possible
changes in our products and applicable national and international regulations and laws, the
status of our products could change. Material Safety Data Sheets providing safety
precautions, that should be observed when handling or storing Clariant products, are
available upon request and are provided in compliance with applicable law. You should
obtain and review the applicable Material Safety Data Sheet information before handling
any of these products. For additional information, please contact Clariant.
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WEIFANG JADA CHEMICAL TECHNOLOGY CO.,LTD
MSDS OF SODIUM NITRITE
1. Product Identification
Synonyms: Nitrous acid, sodium salt
CAS No.: 7632-00-0
Molecular Weight: 69.00
Chemical Formula: NaNO2
Product Codes:
J.T. Baker: 3780, 3782
Mallinckrodt: 7824
2. Composition/Information on Ingredients
Ingredient CAS No Percent Hazardous

--------------------------------------- ------------
Sodium Nitrite 7632-00-0 98.5- 100% Yes
3. Hazards Identification
Emergency Overview
--------------------------
DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
HEAT, SHOCK, OR CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE OR
EXPLOSIVE DECOMPOSITION. HARMFUL IF SWALLOWED, INHALED OR ABSORBED
THROUGH SKIN. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.
SAF-T-DATA(tm) Ratings (Provided here for your convenience)

---------------------------------------------------------------------
Health Rating: 2 - Moderate (Poison)
Flammability Rating: 0 - None
Reactivity Rating: 3 - Severe (Oxidizer)
Contact Rating: 2 - Moderate (Life)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER
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GLOVES
Storage Color Code: Yellow (Reactive)
---------------------------------------------------------------------
Potential Health Effects

----------------------------------
Inhalation:
Toxic. Causes irritation to the respiratory tract and systemic poisoning with symptoms paralleling
ingestion.
Ingestion:
Toxic. Can irritate the mouth, esophagus, stomach, etc. Excessive amounts effect the blood and blood
vessels. Signs and symptoms of nitrite poisoning include intense cyanosis, nausea, dizziness, vomiting,
collapse, spasms of abdominal pain, rapid heart beat, irregular breathing, coma, convulsions, and death
due to circulatory collapse. Estimated lethal dose 1 to 2 grams.
Skin Contact:
Causes irritation, redness and pain. May be absorbed through the skin causing systemic poisoning;
symptoms may parallel ingestion.
Eye Contact:
Causes irritation, redness, and pain.
Chronic Exposure:
Repeated exposure through any route may cause symptoms similar to acute toxicity.
Aggravation of Pre-existing Conditions:
No information found.
4. First Aid Measures

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an
unconscious person. Get medical attention.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and
shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation
develops.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids
occasionally. Get medical attention immediately.
5. Fire Fighting Measures
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Fire:
Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or
combustibles may cause ignition. Increases the flammability of any combustible material.
Explosion:
Contact with oxidizable substances may cause extremely violent combustion. May explode when heated
to 537C (1000F) or on severe impact or on contact with cyanides, ammonium salts, cellulose, lithium,
potassium plus ammonia, and sodium thiosulfate.
Fire Extinguishing Media:
Water or water spray in early stages of fire. Foam may also be used, but avoid the use of multi-purpose
dry chemical fire extinguishers where contact with sodium nitrite may occur. Water streams may scatter
molten material.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing
apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
Decomposition of sodium nitrite may leave a caustic residue.
6. Accidental Release Measures

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective
equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the
air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening
with water. Pick up spill for recovery or disposal and place in a closed container. US Regulations
(CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities.
The toll free number for the US Coast Guard National Response Center is (800) 424-8802.
7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage
and moisture. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from
incompatibles, combustibles, organic or other readily oxidizable materials. Containers of this material
may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and
precautions listed for the product.
8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
None established.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
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Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at
its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document,
Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible,
a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants,
cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances
where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate,
to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible.
Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties

Appearance: White or yellowish-white crystalline granules.
Odor: Odorless.
Solubility: 85.2 g/100 g water @ 20C (68F)
Density: 2.17
pH: 9.0 Aqueous solution
% Volatiles by volume @ 21C (70F): 0
Boiling Point: > 320C (> 608F)
Melting Point: 271C (520F)
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.
10. Stability and Reactivity

Stability:
This material is stable in closed containers at room temperature. Material slowly oxidizes to sodium
nitrate when exposed to air. Very hygroscopic.
Hazardous Decomposition Products:
Oxides of nitrogen.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Reacts vigorously with reducing materials and is incompatible with many substances including
ammonium salts, cellulose, cyanides, lithium, potassium plus ammonia, sodium thiosulfate,
aminoguanide salts, butadiene, phthalic acid, phthalic anhydride, reducants, sodium amide, sodium
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disulphite, sodium thiocyanate, urea, wood and organic matter.

Conditions to Avoid:
Heat, flame, ignition sources, shock, friction, incompatibles.
11. Toxicological Information
Oral rat LD50: 180 mg/kg; inhalation rat LC50: 5500 ug/m3; irritation: eye rabbit: 500 mg/24H mild.
Investigated as a tumorigen, mutagen, reproductive effector.
------\Cancer Lists\------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- -----------
Sodium Nitrite (7632-00-0) No No None
12. Ecological Information

Environmental Fate:
No information found.
Environmental Toxicity:
96 Hr LC50 rainbow trout (juvenile):0.19 mg/L (flow-through) Dangerous to the environment. Very toxic
to aquatic organisms.
13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a
RCRA approved waste facility. Processing, use or contamination of this product may change the waste
management options. State and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information

Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: SODIUM NITRITE
Hazard Class: 5.1, 6.1
UN/NA: UN1500
Packing Group: II
Information reported for product/size: 12KG
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International (Water, I.M.O.)

-----------------------------
Proper Shipping Name: SODIUM NITRITE
Hazard Class: 5.1
UN/NA: UN1500
Packing Group: II
Information reported for product/size: 12KG
15. Regulatory Information

--------\Chemical Inventory Status - Part 1\------------------
Ingredient TSCA EC Japan Australia
---------------------------------------------- ---- --- -----
Sodium Nitrite (7632-00-0) Yes Yes Yes Yes
-------\Chemical Inventory Status - Part 2\------------------------

--Canada--
Ingredient Korea DSL NDSL Phil.
--------------------------------------------- ----- --- ----
Sodium Nitrite (7632-00-0) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\---------

-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- ---
Sodium Nitrite (7632-00-0) No No Yes No
--------\Federal, State & International Regulations - Part 2\-----

-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ --
Sodium Nitrite (7632-00-0) 100 No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No

SARA 311/312: Acute: Yes Chronic: No Fire: Yes Pressure: No
Reactivity: Yes (Pure / Solid)
Australian Hazchem Code: 1[T]
Poison Schedule: S5
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.
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16. Other Information

NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 1 Other: Oxidizer
Label Hazard Warning:
DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. HEAT,
SHOCK, OR CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE OR EXPLOSIVE
DECOMPOSITION. HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN.
CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.
Label Precautions:
Keep from contact with clothing and other combustible materials.Store in a tightly closed container.
Remove and wash contaminated clothing promptly.Avoid contact with eyes, skin and clothing.Avoid
breathing dust.Use with adequate ventilation.Wash thoroughly after handling.
Label First Aid:
If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by
mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with
plenty of water for at least 15 minutes. In all cases, get medical attention.
Product Use: Laboratory Reagent.
Revision Information: No Changes.
SIGNED BY: WEIFANG JADA CHEMIAL TECHNOLOGY CO.,LTD
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ATTACHMENT NO.02.3
COSHH
Page 154 of 294

Page 111 of 249
Annexure 1: COSHH Risk Assessment Sheet REV:01
Control Of Substances Hazardous to Health - Risk Assessment Sheet

Department: Business Improvement and Standard Section/Unit: Health & Safety Section
Describe the activity or

work process. Use for cleaning pipelines.
(Include how long and how
often this is carried out and
the quantity of substance
used)
Location of process FG Pipe lines Over the entire site
being carried out?
Identify the persons at risk: Employees X Contractors Public
(including trainees) (including students)
Name the substance involved in the Sodium Nitrite

process and its manufacturer.
(A copy of a current safety data sheet for this
substance should be attached to this
assessment)
Classification (state the category of danger)
Other Notes:
Very Toxic Extremely
X Irritant
Flammable
X Toxic Sensitising Highly

Flammable
Corrosive Biological X Flammable
X Harmful X Oxidising X Environmental
Health Hazard
Page 1 of 4 SP15: Procedure for Control of Substances Hazardous to Health

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Hazard Type
Gas Vapour Mist Fume Dust Liquid Solid Other (State)
Route of Exposure
x X X X
Inhalation Skin Eyes Ingestion Other (State)
Workplace Exposure Limits (WELs) please indicate n/a where not applicable Not Applicable
Long-term exposure level (8hrTWA): N/A Short-term exposure level (15 mins): N/A
State the Risks to Health from Identified Hazards

1. Danger! Strong Oxidizer.
2. Contact with other material may cause fire or Explosive decomposition.
3. Harmful if swallowed, Inhaled or Absorbed.
4. Causes irritation to skin, eye and respiratory tract.
5. Inhalation: Toxic. Causes irritation to the respiratory tract and systemic poisoning with symptoms paralleling ingestion.
6. Injection: Toxic. Can irritate the mouth, esophagus, stomach, etc. Excessive amounts effect the blood and blood vessels. Signs and symptoms of
nitrite poisoning include intense cyanosis, nausea, dizziness, vomiting, collapse, spasms of abdominal pain, rapid heartbeat, irregular breathing,
coma, convulsions, and death due to circulatory collapse. Estimated lethal dose 1 to 2 grams.
7. Skin Contact: Causes irritation, redness and pain. May be absorbed through the skin causing systemic poisoning.
8. Eye Contact: Causes irritation, redness, and pain.
9. Repeated exposure through any route may cause symptoms similar to acute toxicity.
10. Contact with oxidizable substances may cause extremely violent combustion.
11. Incompatibilities: Reacts vigorously with reducing materials and is incompatible with many substances including ammonium salts, cellulose,
cyanides, lithium, potassium plus ammonia, sodium thiosulfate, aminoguanide salts, butadiene, phthalic acid, phthalic anhydride, reducants,
sodium amide, sodium disulphite, sodium thiocyanate, urea, wood and organic matter.
12. Conditions to Avoid: Heat, flame, ignition sources, shock, friction, incompatibles.
13. Dangerous to the environment. Very toxic to aquatic organisms.
Control Measures: (for example extraction, ventilation, training, supervision). Include special measures for vulnerable groups, such as disabled people and pregnant workers. Take
account of those substances that are produced from activities undertaken by another employer’s employees.
1. Training and awareness for handling of Chemicals to the working Crew.
2. Communicated the MSDS to the working Crew.

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3. Storage: Handle container with care, keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage and
moisture. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles, combustibles, organic or other
readily oxidizable materials. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all
warnings and precautions listed for the product.
4. Wear suitable Personnel Protective Equipment’s. Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is
possible. Maintain eye wash fountain and quick-drench facilities in work area, Wear impervious protective clothing, including boots, gloves, lab
coat, apron or coveralls, as appropriate, to prevent skin contact
5. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-
purifying respirators do not protect workers in oxygen-deficient atmospheres
6. Take the Hygiene measures like Wash hands before breaks and after work, Use barrier skin cream, Remove soiled or soaked clothing immediately
and clean thoroughly before using again.
7. Take the environmental exposure controls like. Do not allow to enter drains or waterways.
8. It cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a approved waste facility.
9. Accidental Release Measures: Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment, Clean up
spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by
moistening with water. Pick up spill for recovery or disposal and place in a closed container.
Relevant Information available in :
1. MSDS - Material safety data sheet
Is health surveillance or monitoring required?

Yes X No
Personal Protective Equipment (state type and standard) Notes:
Not required, if all control measures are in
X place and if the quantity of such machines are
higher in number.
Dust mask Visor
X X
Respirator Goggles
X X
Gloves Overalls
X
Footwear Other

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First Aid Measures

1. Skin contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before
reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.
2. Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention
immediately
3. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical
attention.
4. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Storage
1. Handle container with care, keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage and
moisture. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles, combustibles, organic or
other readily oxidizable materials. Containers of this material may be hazardous when empty since they retain product residues (dust, solids);
observe all warnings and precautions listed for the product.
Disposal of Substances & Contaminated Containers
Hazardous Waste X Skip Return to Depot Return to Supplier X Other
(If Other Please State):
Is exposure adequately controlled?

Yes X No
Risk Rating Following Control Measures
High Medium Low X
Assessed by: Fredrick Date: 18-08-2020 Review Date:
Approved by: Aleksander Gornjak
Project Manager’s Name and Signature.

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used)
being carried out?
Name the substance involved in the EC-ArmoHib-CI-31

assessment)
Other Notes:
X Irritant
Flammable
Toxic Sensitising Highly

Flammable
X Corrosive Biological X Flammable
X Harmful Oxidising X Environmental
X Health Hazard

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Hazard Type
Route of Exposure
x X X X

1. Causes Eye Irritation.
2. May be harmful if swallowed, may causes skin irritation, may cause allergic skin reaction, May be harmful to environment if released in large
amounts.
3. Do not eat drink or smoke when using this product.
1. Training and awareness to the working Crew.
3. Ensured there is sufficient ventilation of the area.
4. Storage: Store in cool, Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Keep container tightly closed, Kept
chemicals in Original packing.
5. Use the Personnel Protective Equipment’s (Use tightly fitted chemical safety goggles, In the case of vapor formation use a respirator with an
approved filter, For prolonged or repeated contact use protective gloves. Use protective suit according to the amount and concentration of the
dangerous substance at the work place. etc.,)
6. Take the Hygiene measures like Handle in accordance with good industrial hygiene and safety practice. When using do not smoke, eat or drink.
Wash hands before breaks and at the end of workday. Wash contaminated clothing prior to re-use.
7. Suitable extinguishing media for the surrounding fire should be used.
8. Take the environmental exposure controls like do not flush into ground, water ways or sanitary sewer system. Treat runoff as hazardous. In case
of spills, Soak up with inert absorbent materials such as sand, siliceous earth, acid binder, saw dust. Store in closed containers and Dispose of
waste according to applicable legislation. Wash spill area with plenty of water.

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Yes X No
higher in number.
Dust mask Visor
X X
Respirator Goggles
X X
Gloves Overalls
(Use tightly fitted chemical safety goggles, In the
X X case of vapor formation use a respirator with an
approved filter, For prolonged or repeated contact
Footwear Other use protective gloves. Use protective suit
according to the amount and concentration of the
dangerous substance at the work place etc.,)
First Aid Measures
1. Skin contact: In case of contact, immediately flush skin with plenty of water for at least 30 minutes while removing contaminated clothing and
shoes, Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before re use. Get medical attention.
2. Eye contact: In case of contact with eyes, rinse with plenty of water. Cold water may be used Get medical attention immediately. Remove
contact lenses. Protect unharmed eye. Keep eye wide open while rinsing.
3. Ingestion: Do Not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If
large quantity of this material are swallowed, call a physician immediately. Loosen tight clothing such as tie, collar, belt or waist board.
4. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration/ If breathing is difficult, give oxygen. Get medical attention.
Storage
1. Storage in accordence with local regulation for flamable liquids.
2. Store container tightly closed in a cool dry & well ventilated area away from incompatible substances. Keep away from heat, sparks, and flame.
Keep away from sources of ignition. Keep container closed when not in use.

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Yes X No
High Medium Low X

Page 162 of 294
Page 119 of 249


used)
being carried out?
Name the substance involved in the DODICOR 2565

assessment)
Other Notes:
Irritant
Flammable

Flammable
Corrosive Biological X Flammable
Health Hazard

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Hazard Type
Route of Exposure
x X X X

1. Harmful if swallowed.
2. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
3. Special hazards arising from the substance or mixture: In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO) Carbon
dioxide (CO2).
4. Possibility of hazardous reactions.
5. Avoid contact with strong alkaline materials.
6. Exposure to heat and moisture.
3. Storage: Handle container with care, Keep container tightly closed in a cool, well-ventilated place.
4. Wear suitable Personnel Protective Equipment’s.
5. Take the Hygiene measures like Wash hands before breaks and after work, Use barrier skin cream, Remove soiled or soaked clothing immediately
and clean thoroughly before using again.
6. Take the environmental exposure controls like. Do not allow to enter drains or waterways. Methods and material for containment and cleaning up:
Pick up with absorbent material (eg sand, sawdust). Rinse away rest with water

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Yes X No
higher in number.
Dust mask Visor
X X
Respirator Goggles
X X
Gloves Overalls
X
Footwear Other
First Aid Measures
1. Skin contact: In case of contact, wash off immediately with soap and water.
2. Eye contact: In case of contact with eyes, Rinse thoroughly with plenty of water and seek medical advice.
3. Ingestion: Never give anything by mouth to an unconscious person. Consult a physician immediatly.
4. Inhalation: If inhaled, remove to fresh air and seek medical aid.
Storage
2. Handle container with care, keep container tightly closed in a cool, well-ventilated place.

Yes X No
High Medium Low X

SP15: Procedure for Control of Substances Hazardous to Health
Page 3 of 4
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Page 166 of 294
Page 123 of 249


used)
being carried out?
Name the substance involved in the Citric acid

assessment)
Other Notes:
X Irritant
Flammable

Flammable
Corrosive Biological Flammable
Harmful Oxidising X Environmental
Health Hazard

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Hazard Type
Route of Exposure
x X X X

1. Causes Eye Irritation.
2. Special hazards arising from the substance or mixture: Oxides of carbon.
3. Reacts with alkaline materials.
4. Exposure to heat and moisture.
3. Minimise the risk of dust inhalation. Provide adequate ventilation.
4. Avoid contact with skin and eyes. Use only in well-ventilated areas. Do not breathe vapours/dust.
5. Storage: Keep locked up or in an area accessible only to qualified staff, Store in tightly closed original container in a dry, cool and well-ventilated
place. Keep in original container
6. Use the Personnel Protective Equipment’s (Safety glasses with side-shields, Protective gloves, Wear respirator where etc.,)
7. Take the Hygiene measures like Do not smoke in the work area. Wash at the end of each work shift and before eating, smoking and using the
toilet. Wash promptly if skin becomes contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or
smoke. Suitable extinguishing media for the surrounding fire should be used.
8. Take the environmental exposure controls like. Do not allow to enter drains, sewers or watercourses, Do not flush substance into surface water or
sewage system. Sweep up or vacuum up spillage and collect in suitable container for disposal.

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Yes X No
higher in number.
Dust mask Visor
X X
Respirator Goggles
X X
Gloves Overalls
X
Footwear Other
First Aid Measures
1. Skin contact: In case of contact, Wash off immediately with plenty of water for at least 15 minutes. If irritation persists, call a physician.
2. Eye contact: In case of contact with eyes, Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
3. Ingestion: Do NOT induce vomiting. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Consult a physician.
4. Inhalation: If inhaled, Move to fresh air.
Storage
2. Keep locked up or in an area accessible only to qualified staff, Store in tightly closed original container in a dry, cool and well-ventilated place.
Keep in original container.

Yes X No

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High Medium Low X

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used)
being carried out?
Name the substance involved in the Ammonium bifluoride

assessment)
Other Notes:
X Irritant
Flammable May be combustible at high
temperature.
X Toxic X Sensitising Highly During fire, Toxic gases (Co,Co2) are
Flammable formed.
X Health Hazard

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Hazard Type
X x
Route of Exposure
x X X X

1. Effects of exposure may cause eye burns, chemical conjunctivitis and corneal damage.
2. Skin contacts with liquid causes Severe burns and ulceration, May penetrate the skin and cause severe tissue and bone destruction. May cause
Skin rash) in milder cases), and cold and chammy skin with cyanosis or pale color.
3. Its harmful if swallowed. May cause severe and permanent damage to the digestive tract, may cause kidney damage,May cause perforation of the
digestive tract. Causes severe digestive tract burns with abdominal pain, vomiting and possible death. Inorganic fluorides can be harmful.Acute
exposure to fluorine compounds can lead to digestive tract burns & abdominal pain. Fluoride can reduce calcium levels leading to fatal
hypocalcemia, May cause systemic effects.
4. Inhallation causes chemical burns to the respiratory tract, Inhallation may be fatal as a result odf spasm, Inflammation, edema of larynx and
bronchi, chemical pnemonitis and pulmonary edema. Aspiration may lead to pulmonary edema. Depletes calcium level in the body which can lead
to hypocalcemia and death. May cause systemic effects.
5. Chronic Inhalation and injection may cause chronic fluoride poisoning (fluorisis) charecterized by weight loss,weakness, anemia, brittle bones and
stiff joints. May cause digestive tract distrubances. Effects may be delayed.Chronic expose to fluoride compounds may cause systemic toxicity..
3. Facilitties storing or utilizing this material should be equipped with an eue wash facility and a safety shower. Use Adequate ventilation to keep
airbone concertations low.
4. Storage: Keep container closed when not in use and store in a cool, dry, well ventilated area away from incompatible substances. Stay protected
from moisture and keep away from acids and corrosives area.
5. Keep away from heat, sparks and flame.
6. Use the Personnel Protective Equipment’s (safety goggles, Chemical resistant Gloves, Coverall and respiratory protection etc.,)
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7. Take the Hygiene measures like wash hands after handling.

8. Take the environmental exposure controls like minimize the dust generation and accumulation,
9. Ensure that eyewash stations and safety showers are proximal to the work station location.
10. Provision of adequate Fire extinguishers like dry chemical power,CO2, foam and water spray for large amount of fire.

Yes X No
higher in number.
Dust mask Visor
X X
Respirator Goggles
X X
Gloves Overalls
X
Footwear Other
First Aid Measures
1. Inhalation: Get medical aid immediately.Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and
a suitable mechanical device such as a bag and a mask.
2. Skin contact: Get medical aid immediately.Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
3. Eye contact: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at
least 30 minutes)
4. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately
Storage
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2. Keep container closed when not in use and store in a cool, dry, well ventilated area away from incompatible substances. Stay protected from
moisture and keep away from acids and corrosives area.

Yes X No
High Medium Low X

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used)
being carried out?
Name the substance involved in the AMMONIA SOLUTION 0.910 25%

assessment)
Other Notes:
Extremely
X Very Toxic X Irritant
Flammable

Flammable
X Health Hazard

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Hazard Type
Route of Exposure
x X X X

1. Effects of exposure may cause burns, Very toxic to aquatic organisms.
2. Corrosive and Dangerous to the environment.
3. Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate
4. Eye Contact: Corneal burns may occur. May cause permanent damage.
5. Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding from the mouth or nose.
6. Inhallation: There may be shortness of breath with a burning sensation in the throat. Exposure may cause coughing or wheezing.
3. Ensured there is sufficient ventilation of the area.
4. Storage: Store in cool, Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Keep container tightly closed, Kept
chemicals in Original packing.
5. Use the Personnel Protective Equipment’s (Self-contained breathing apparatus must be available in case of emergency. Impermeable gloves.
Tightly fitting safety goggles. Ensure eye bath is to hand, Impermeable protective clothing etc.,)
6. Take the Hygiene measures like wash hands after handling.
7. Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool.
8. Take the environmental exposure controls like do not discharge into drains or rivers. Contain the spillage using bunding.


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Yes X No
higher in number.
Dust mask Visor
X X
Respirator Goggles
X X
Gloves Overalls
(Self-contained breathing apparatus must be
X X available in case of emergency. Impermeable
gloves. Tightly fitting safety goggles. Ensure eye
Footwear Other bath is to hand, Impermeable protective clothing
etc.,)
First Aid Measures
1. Skin contact: Get medical aid immediately.Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected
skin with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or symptoms of poisoning.
2. Eye contact: Bath the eye with running water for 15 minutes. Transfer to hospital for specialist examination.
3. Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10 minutes. If unconscious, check for breathing
and apply artificial respiration if necessary. If unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon as
possible.
4. Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious and breathing is Ok, Place in the recovery
position. If conscious, ensure the casualty sits or lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available.
Transfer to hospital as soon as possible.
Storage
2. Keep container closed when not in use and store in a cool, dry, well ventilated area away from incompatible substances. Stay protected from
moisture and keep away from acids and corrosives area.

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Yes X No
High Medium Low X

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ATTACHMENT NO.02.4
PPE Information
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LIST OF CHEMICALS AND PERSONAL PPE’S:
1. PPE’S LIST DURING CHEMICAL CLEANING:
A. FULL FACE MASK
FULL FACE MASK CATRIDGE
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Specifications
Accessories Yes
Brand 3M™
Cartridge or Filter Type Gas and Vapor
Clip-on Welding Shield Yes
3M™ Full Facepieces FF-400, 3M™ Half Facepiece Reusable Respirators
Compatible Respirator 6000 Series, 3M™ Half Facepiece Reusable Respirators 7000 Series
Compatible with 3M™
PAPR Systems Yes
Compatible with 3M™
Supplied Air System Yes
Compatible with
Welding Shield Yes
Connection Type Bayonet
Cool Flow™ Exhalation
Valve Yes
Drop-down Feature Yes
Enhanced Comfort Yes
Enhanced Durability Yes
Eye Protection Yes
Features Low Profile
For Use With Reusable Respirators
Ammonia, Chlorine, Chlorine Dioxide, Formaldehyde, Hydrogen Chloride,
Gas & Vapor Protection Hydrogen Fluoride, Hydrogen Sulfide, Methylamine, Organic Vapor, Sulfur
Type Dioxide
Multigases: organic vapor, chlorine, chloridric acid, chlorine dioxide,
sulphur dioxide, hydrogen sulphide (only for escape),
Hazard Type ammonia/methylamine, formaldehyde and hydrogen fluoride
Maintenance Free No
Market Aerospace, Maritime, Defense, Homeland Security
National Stock Number 4240014557259, 4240015856633, 4240014557370
Nuisance Odor Relief (<
OSHA PEL) N/A
Overall Height (Imperial) 3.4 in, 3.4 in
Overall Length
(Imperial) 4.2 in
Particulate Protection Acid Gas, Ammonia, Formaldehyde, Methylamine, Organic Vapor
Ammonia, Chlorine, Chlorine Dioxide, Formaldehyde, Hydrogen Chloride,
Hydrogen Fluoride, Hydrogen Sulfide, Methylamine, Organic Vapors, Sulfur
Protection Focus Dioxide
Purpose Cartridges & Filters
Assembly and Mechanical, Batch-Charging, Chemical Clean-up, Chemical
Transfer, Cleaning, Composite Finishing, Final Finish, Handling, Hazardous
Waste Handling, Laboratories, Maintenance, Manufacturing, Paint
Recommended Preparation, Painting, Parts Cleaning, Petrochemical, Pharmaceuticals,
Application Pouring Molten Metal, Remediation, Seal Coatings, Welding
Facility Sanitation, Food Processing, Food Safety, General Manufacturing,
Recommended Industry Mining, Oil & Gas, Transportation
Segment Personal Safety
Silicone Faceseal Yes
Six-point Head Harness Yes
Spare Parts Yes
Speaking Diaphragm Yes
Standards/Approvals Ammonia, Chlorine, Chlorine Dioxide, Formaldehyde, Hydrogen Chloride,
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Hydrogen Fluoride, Hydrogen Sulfide, Methylamine, Organic Vapors, Sulfur

Dioxide
Details
 NIOSH approved for protection against certain organic vapors, acid gases,
ammonia, methylamine and formaldehyde
 Swept-back design allows an enhanced field of view and comfort
 Bayonet compatibility allows use with many 3M half and full facepiece
designs
 Wide range of applications reduces inventory needs
 Simple installation and usage requirements reduces training requirements
NIOSH approved against certain organic vapors, acid gases, ammonia,
methylamine or formaldehyde. Use with 3M™ Half and Full Face pieces 6000,
7000 and FF-400 Series with bayonet filter holders.
The 3M™ Multi Gas & Vapor Cartridge 6006 helps provide gas and vapor
protection in a variety of environments. The cartridge may be used for gas and
vapor concentrations up to 10 times the Permissible Exposure Limit (PEL) with
half face pieces or 50 times PEL with quantitatively fit tested full face pieces.
Recommended applications for the cartridge include assembly, batch-charging,
chemical clean-up, chemical transfer, cleaning, hazardous waste handling,
painting, pouring molten metal. Inventory needs and training requirements for
safety equipment are reduced because this respirator cartridge selection works
for many different applications. Industries in which this cartridge is commonly
used include chemicals, mining, oil and gas, and primary metals.
This multi gas and vapor cartridge works with 3M™ Half and Full Face pieces
6000, 7000 and FF-400 Series with bayonet holders. The cartridge is NIOSH
(National Institute for Occupational Safety and Health) approved for
environments containing certain organic vapors, chlorine, hydrogen chloride,
chlorine dioxide, sulfur dioxide, hydrogen sulfide, ammonia, methylamine,
formaldehyde or hydrogen fluoride. The cartridge has been assigned the color
code “olive” in the NIOSH system.
Breathing gases and vapors can pose a risk to your health. NIOSH, a Federal
government regulatory agency, has tested and approved the 3M™ Organic Vapor
Cartridge 6006 to help reduce exposure to certain gases and vapors
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B. FACE MASK FILTERS & ADAPTORS
C. RUBBER SHOES
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D. CHEMICAL RESISTANT GLOVES
E. CHEMICAL RESISTANT COAT
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2. MANDATORY PPE’S LIST:
Mandatory PPE’S
1- Full Sleeves Coveralls with Reflective Tape
2- Safety Helmet
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3- Leather and PU Steel Toe Leather Safety Shoes
4- Safety Goggles
5- Hand Gloves
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ATTACHMENT NO.02.5
Tank Testing Report/ Compressor /Dryer/

Pump/TEMPERATURE HUMIDITY METER
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FLUKE 971 TEMPERATURE

HUMIDITY METER
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ATTACHMENT NO.02.6
Boiler Information
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INDEX
1 TECHNICAL CHARACTERISTICS ............................................................................... 2

1.1 GENERAL ................................................................................................................................................2
1.2 CHARACTERISTICS ...............................................................................................................................2
1.3 TECHNICAL DATA ..................................................................................................................................3
2 ACCESSORIES ............................................................................................................. 4
2.1 PRESSURE .............................................................................................................................................4
2.1.1 Pressure gauge (Fig. 2) ................................................................................................................4
2.1.2 Operation pressure switch ............................................................................................................5
2.1.3 Safety pressure switch ..................................................................................................................5
2.1.4 Safety valves .................................................................................................................................6
2.2 LEVEL ......................................................................................................................................................6
2.2.1 Level indicator gauge ....................................................................................................................6
2.2.2 Automatic level regulator and water level limits (Fig. 6) ................................................................7
2.3 FEED WATER .........................................................................................................................................7
3 INSTALLATION ............................................................................................................. 8
3.1 SITING .....................................................................................................................................................8
3.2 WATER CONNECTIONS ........................................................................................................................8
3.3 ELECTRIC CONNECTIONS ...................................................................................................................9
3.4 SMOKESTACK ........................................................................................................................................9
3.5 BURNER ..................................................................................................................................................9
3.5.1 Boiler - Burner coupling.................................................................................................................9
4 BOILER OPERATION ................................................................................................. 10
4.1 FIRST START-UP .................................................................................................................................10
4.2 NORMAL OPERATION .........................................................................................................................10
5 MAINTENANCE........................................................................................................... 11
5.1 ORDINARY ............................................................................................................................................11
5.2 PERIODIC ..............................................................................................................................................11
5.2.1 Periodic control (every 6 hours of use) .......................................................................................11
5.3 SCHEDULED .........................................................................................................................................13
5.4 CONSERVATION DURING WHEN OUT OF SERVICE .......................................................................13
5.4.1 Dry conservation .........................................................................................................................13
5.4.2 Wet conservation ........................................................................................................................13
6 WATER CHARACTERISTICS ..................................................................................... 14
6.1 OPERATING WATER - LIMITING VALUES .........................................................................................15
6.2 FREQUENCY OF THE ANALYSES ......................................................................................................15
7 TROUBLESHOOTING ................................................................................................ 16
8 WATER LEVEL LIMITS .............................................................................................. 17
8.1 GENERAL ..............................................................................................................................................17
8.2 TYPICAL APPLICATIONS .....................................................................................................................18
8.3 ELECTRICAL CONNECTIONS .............................................................................................................18
8.4 STEAM GENERATOR OPERATION ....................................................................................................19
8.5 FIRST START-UP .................................................................................................................................19
8.6 MAINTENANCE .....................................................................................................................................19
8.6.1 Ordinary ......................................................................................................................................19
8.6.2 Periodic control (every 6 hours of use) .......................................................................................19
8.6.3 Extraordinary maintenance (water level limits substitution) ........................................................21
8.7 TROUBLESHOOTING ...........................................................................................................................21
8.8 DATA LABEL .........................................................................................................................................22
1
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TECHNICAL CHARACTERISTICS
1 TECHNICAL CHARACTERISTICS
1.1 GENERAL
The ASB series steam boilers are type semi-fixed, horizontal smoke-tube type, complete with accessories.
The boilers are suitable for operation with pressurised burners for gas, fuel oil or heavy oil.
Safety, reliability, high efficiency and high quality saturated steam are the characteristics of our boilers.
Please consult the instructions with attention.
2
This high-pressure steam (12-15 kgf/cm ) generator uses a combustion chamber with three-gas-passes, wet
floor-externally-fired boiler. For operation at up to 3000 kg/h of steam generated there is partial exoneration
(in Europe) in the employment of specialist boiler operators. Local requirements as to personnel qualification
MUST be taken into account for the country where the unit is installed.
1.2 CHARACTERISTICS

st nd
Working pressure switches for operation (controlling the 1 and 2 burner flame).
 Locking pressure switches (stops the burner on reaching the maximum steam pressure; the boiler is
manually reset from the control panel).
 Automatic level regulator (2 probes connected to an electronic conductivity relay maintain the water
level between the set levels).
 Water level limits (2 probes connected to two independent electronic conductivity relays stop the burner
if the water level falls below the safe minimum; reset is manual on the control panel).
2
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TECHNICAL CHARACTERISTICS
1.3 TECHNICAL DATA
Fig. 1
LEGEND 12 Barrel drain 24 Feed water pumps
1 Switchboard 13 Burner plate 25 Salinity check
2 Control pressure switches 14 Steam take-off 26 Chill
3 Locking pressure switch 15 Non return valve 27 Level gauges drain
4 Pressure gauge 16 Inspection door
5 Level gauges 17 Safety valves N1 Steam take-off fitting
6 Pump stop probes 18 Feed water N2 Feed water fitting
7 Pump start probes 19 Suction pumps filters N3 Safety valve drain fittings
8 1st safety level probe 20 Smokestack connection N4 Boiler drain fitting
9 2nd safety level probe 21 Flame inspection hole N5 Safety valves fittings
10 Front plates 22 Boiler drain
11 Probes holder barrel 23 Pneumatic drain valve
NOTE: drawing and legend refer to highest option models. Therefore, all accessories mentioned in
the legend might me not equipped with standard models; please refer to the provided
accessory drawing.
Length Width Net Height Height with accessories Chimney Dia Dry weight
Model
mm mm mm Mm mm Kg
ASB 2000 3750 1400 2600 2930 300 6700
* 80°C feeding water
3
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ACCESSORIES
2 ACCESSORIES
ASB steam boilers are fitted with a series of accessories that can be subdivided as follows:
• Safety accessories (safety valves, water level limits, safety pressure switches).
• Observation accessories (level gauges, pressure gauge, flame inspection).
• Control accessories (level ad pressure switches).
• Feed water accessories: centrifugal pump, stop valves.
• Manual operation accessories (stop valves, purge valve).
In the following description the accessories are subdivided as to the physical parameter they control
(pressure and level).
2.1 PRESSURE
2.1.1 Pressure gauge (Fig. 2)
The pressure gauge is Bourdon type consisting of a flat elliptical

section metal tube, bent to an arc. One end of the tube is open and
communicates with the boiler where the pressure is to be
measured; the other end, closed and free to move is connected by
a lever system to a toothed arc and to the gauge indicator hand.
The gauge shows in red the design pressure.
The gauge is carried on a three-way valve to allow the following

operations:
 Communication between boiler and gauge (normal operation
position).
 Communication between gauge and the atmosphere (position
necessary to purge the siphon).
 Communication between the boiler, the gauge and a test
gauge (position necessary to verify the gauge).
Fig. 2
4
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ACCESSORIES
2.1.2 Operation pressure switch

Device that controls the boiler pressure and holds the pressure between the set maximum and minimum
values.
Instructions for adjustment.

The electric switch has three screws (2-1-3 from right to left).
On reaching the set pressure, the contact 2-1 switches to 2-3.
Adjustment of the pressure switch (Fig. 3):
a) Turn the knob (1) until the scale indicator (2) reaches the pressure at which the burner shall restart.
b) Remove the cover of the pressure switch and position the drum (3) at the value selected for the pressure
differential (stopping the burner) as to the diagram Fig. 4.
Example:
* Type of pressure switch: RT 5
* Scale indicator 9 bar
* Drum indicator: 4 corresponding to 2,1 bar
* Burner start: 9 bar
* Burner stop: 11,1 bar
Fig. 3 Fig. 4
2.1.3 Safety pressure switch
This switch is set at a higher pressure than the maximum of the control pressure switch, but always lower
than the opening pressure of the safety valves.
The safety pressure switch acts in the case of a fault to the control pressure switch and stops the burner
permanently. Restarting the burner can only occur after the steam pressure has fallen and after a manual
reset on the switchboard.
This pressure switch is adjusted in a similar manner to that of the control pressure switch, with the only
precaution that the drum indicator is set to 1 so that the differential is effectively nil.
5
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ACCESSORIES
2.1.4 Safety valves
These valves have the function of discharging steam when the maximum design pressure of the boiler is
reached.
The valves used on boilers are of the type Spring (Fig. 5).
The boiler operator must pay much attention to the safety valves and
carry out careful and diligent maintenance. The safety valve is the
most important and sensitive accessory on the boiler and represents
the best guarantee that the internal pressure of the boiler does not
exceed the design pressure.
As during normal operation of a boiler, the safety valve never acts, it
is good practice to check that the valve is free, i.e. that the
valve plug is not stuck to the seat, by acting on the side lever until
the valve starts to discharge steam.
WARNING
The safety valve installed on steam boilers must have the discharge
piped to outside the boiler room. Particular care must be taken in
designing the discharge line; we show some here.
• The discharge line should e of diameter at least equal to that of
the discharge flange on the safety valve.
• Only wide radius curves must be used in the discharge line.
• The entire discharge line must be built to avoid the formation of
condensation locks. There must be therefore adequate slopes to
ensure complete drainage.
Particular care must be taken if the valve seat and plug are to be
ground; if this operation becomes necessary due to leaks, use
abrasives based on silicon carbide or oil based carborundum. Carry
out the first grinding operation using fine grain abrasive, finishing
with a very fine grain abrasive.
Fig. 5
2.2 LEVEL
2.2.1 Level indicator gauge
The level indicator consists of a pair of valves connected to a sight glass box containing a prismatic glass.
This device is connected to the boiler both above and below the normal water level, while the lower part is
fitted with a purge valve so that any sludge can be removed, to keep the glass clean. Using these valves, the
efficiency of the level control system can be verified periodically by carrying out the following operations:
• Open for a few seconds and then close the purge valve. If the water disappears from the sight glass and
then appears again with ample level oscillation, then it can be considered that the level operates correctly. If
on the other hand the water returns slowly or stops at a level differing form the preceding level, then on of
the communications may be obstructed. To make sure which of the two is obstructed, and to attempt a
purge, close the steam valve leaving the water valve open, then open the purge valve. This valve must
release water taking with it any sludge formed in the pipes. Then close the water valve and open the steam
valve: steam should be released from the purge valve. Closing the purge valve and leaving the two water
and steam valves open, the water should return to the initial level. If this does not occur, the communication
pipes between the level and the boiler must be cleaned.
6
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ACCESSORIES
2.2.2 Automatic level regulator and water level limits (Fig. 6)
The physical principle employed to detect and control the water level is based on the electrical conductivity of
the water. The control device consists of a part sited in the control panel (electronic relays) and of probes of
differing lengths immersed in the barrel and boiler shell.
Operation of the system provides for:
 Automatic pump start and stop: Two probes inserted in the barrel, of which the longer starts, and the
shorter stops the pump, connected to a single control relay in the control panel.
 Burner stop at low water level: two probes, inserted in the boiler and connected to two distinct control
relays in the control panel, stop the burner permanently if the water level drops below the admissible level.
Barrel probes:
6 Pump stop
7 Pump start
Boiler probe:
nd
8 2 safety burner stop and
alarm on.
st
9 1 safety burner stop and
alarm on.
N.B.: we suggest that as

well as the acoustic alarm
in the boiler room, a further
acoustic alarm be provided
in an area where personnel
is normally present.
Fig. 6
2.3 FEED WATER
An electric centrifugal pump supplies the water. The inlet side of the pump must never be under suction
pressure, but always under positive pressure due to the difference in height between the pump itself and the
feed water tank. While a pump can operate under suction head from a cold water tank (up to 5-6 m), if the
water is hot the pump cannot operate and indeed needs the water to be delivered under a certain pressure.
The height of the feed water tank varies with the temperature, as shown in the following table:
Feed water temperature Positive water head

(Celsius) (metres)
60 1
70 2
80 3
90 4,5
WARNING
 Avoid the use of feed water at temperatures lower than 60 Celsius, being rich in Oxygen and
therefore such as to cause corrosion.
 To avoid pump cavitation problems, the feed water temperature should not be higher than 90
Celsius.
7
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INSTALLATION
3 INSTALLATION
3.1 SITING
Our steam boilers are supplied as units and do not need any foundation work. A flat even floor only is
needed, that can be raised by 5-10 cm.
3.2 WATER CONNECTIONS
The steam boilers once positioned are connected to the system as follows (Fig. 7):
Water
From the condensate collection tank (10) (if existing; otherwise from the treated water tank) to the suction
side of the feed water pump (9).
Steam
From the main steam take-off valve (3) to the user services (distributor or others), from the safety valve
outlets (6) to outside the boiler room in a safe position.
Drains
From the level indicator drains (16) and the boiler drain (17) to the drainage network.
Fuel
Connection to the burner foreseen for fuel oil or natural gas.
Fig. 7 – System diagram
LEGEND 10. Condensate collection tank

1. Boiler 11. Water level
2. Smokestack 12. Water treatment
3. Steam take-off 13. Water supply
4. Burner 14. Breather
5. Pressure switches 15. Condensate tank drain
6. Safety valves 16. Level indicator drain
7. Condensate return 17. Boiler drain
8. Electric pump supply 18. Safety valve drain
9. Feed water pump 19. Example of user service
8
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INSTALLATION
3.3 ELECTRIC CONNECTIONS
The boilers are provided with a switchboard (protection level IP 55) completely assembled to the various
boiler accessories.
Before connecting the switchboard, make sure that the electric system has been correctly installed, checking
in particular the efficiency of the earthing system.
Wiring diagram
Refer to the diagram supplied with the specific switchboard.
3.4 SMOKESTACK
The connection from the boiler to the base of the smokestack must slope upwards in the direction of the gas
flow, with a slope that should be at least 10%. The path should be as short and as possible and the bends
and connections designed as to the rules used in the design of air ducts.
For lengths of up to 2 metres, the same diameter as the boiler flue gas outlet can be used (see the technical
specification table). For more tortuous paths, the diameter must be suitable increased.
The smokestack must in any case be dimensioned as to applicable regulations. It is advisable to pay great
attention to the inside diameter, insulation, gas tightness, ease of cleaning and to the fitting required for
taking flue gas samples for combustion analysis.
3.5 BURNER
The suitable burner shall be a two-stage burner or a modulating burner; this avoids large pressure
variations consequent on sudden stream demands.
Further, and above all with natural gas, every burner start-up is preceded by a long period of preventilation of
the combustion chamber, with consequent loss of heat to the smokestack.
3.5.1 Boiler - Burner coupling
Verify that the spaces between the burner sleeve and the plug are suitable filled with flame-resistant ceramic
insulation.
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BOILER OPERATION
4 BOILER OPERATION
4.1 FIRST START-UP
 Verify that all fittings are tight.

 Verify that the feed water pipes are clean, carrying out a series of washing operations with drainage to
waste before final boiler filling.
 Close the drain valves, the steam take-off valve and the level drains.
 Verify that the lifting lever of the safety valves is free of moving in order to ensure the steam
discharge at the set pressure, which is marked on the valve.
 Open the level control valves and the feed water valve (upstream of the feed water pump).
 Check that the upper man-way is correctly closed.
WARNING!
 Loosen the anti vibration bolts which are fitted on the front doors hinges (1 Fig. 8) before opening the doors.
 Remove the holding bolts from the rear leg of the boiler base (2 Fig. 8) after positioning the boiler
and in any case before first start-up, in order to allow boiler expansion during operation.
1 2
Fig. 8
Start the boiler as follows:
1) Switch on the control panel by turning the main switch.
2) Check that the drive shaft of the feed water pump is free to turn. By starting the pump manually for an
instant, check that the shaft turns in the correct direction.
3) Set the pump switch to AUT and verify that burner cannot start before the attainment of the minimum level;
4) Check that the pump stops when the maximum level is reached by observing the level indicators and
checking the positions of the indicator valves.
5) Press and keep pressed the safety water level reset button for at least 10 seconds, the conductivity relay
being of the delayed type.
6) Open the boiler drain and check on the level indicator at what level the pump-start probe acts.
7) Set the pump switch to “0” leaving the drain open and check the actuation level of the safety probes with
respect to the minimum level reference plate.
8) Close the drain and set the pump switch to AUT
9) Switch on the burner and bring the boiler up to pressure adjusting the operation pressure.
WARNING: On boilers with a man-way and head-way, during the first start-up it is important to tighten progressively the
nuts on the man-way cover as the pressure increase. Otherwise a hazardous situation is created due to steam leaks
that quickly deteriorate the gasket creating a dangerous situation for the boiler room personnel.
4.2 NORMAL OPERATION

With cold start-ups, verify that:
 The boiler is full of water to the minimum level;
 The increase of the water volume due to heating does not raise the water level too far: if necessary drain
the boiler at regular intervals to bring the visible level back to the centre of the water level sight glasses;
 On reaching the set pressure, the steam take-off valve can be opened very gradually in order to heat the
steam delivery lines eliminating any condensate that may be present in the pipework;
 The man-way gasket does not leak.
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MAINTENANCE
5 MAINTENANCE
5.1 ORDINARY
 Periodically purge the level gauges, probe holder if fitted and the boiler, to avoid the accumulation of
sludge.
 Check the efficiency of the control and regulation instruments, examining carefully the electrical parts
(connections included) and the mechanical parts (pressure switches); it is advisable to replace every year
the ceramic probe-holders.
 Carry out burner maintenance (as to the specific instructions);
 Check the tightness of flange bolts and the state of the gaskets;
 Check the conditions of the boiler door internal covering after loosening the anti vibration bolts on the
hinges, in order to allow door opening;
 Clean the flue-gas tube bundle;
 Carry out correct maintenance to the pump (bearings, mechanical seal);
 Check for wear to the discharge valves; these tend to wear more quickly, due to the abrasive effect of the
sludge during blow-down;
5.2 PERIODIC
5.2.1 Periodic control (every 6 hours of use)
From time to time (every 6 hours of use) the thermal plant must be inspected by qualified personnel to check
the efficiency of all safety accessories:
 Safety pressure switch
 Water level limits
The system can be reset if no anomalies have been encountered: power off the panel for approx. 20
seconds, power on the main switch and press the reset buttons.
For further details follow the flow chart below:
11
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MAINTENANCE
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MAINTENANCE
5.3 SCHEDULED
All boilers must be periodically stopped for careful inspection and maintenance: the time interval between
stops is established by experience, by the operating conditions, by the quality of the feed water and by the
type of fuel used.
Before entering the boiler shell for inspection or for cleaning, check carefully that there is no possibility of
entry of water or steam via the pipework to which the boiler is connected. Every valve must be locked and if
necessary isolated by removing a piece of pipework or by inserting a blind flange.
The parts under pressure must be carefully examined internally to identify any encrustation, corrosion and
other potential sources of danger linked to the feed water.
All deposits must be removed mechanically or chemically and the effective thickness of the structures
must be verified using suitable instruments to determine that they are equal to or greater than the
design values. All pustules or other types of corrosion must be scraped and cleaned with a steel wire brush
to white metal. Leaks between fire tubes and tube plates must be carefully examined: any welding must be
done in all cases observing legal obligations, without forgetting that a steam boiler is a pressure vessel with
danger of explosion and subject to control by competent authorities.
During inspection also verify all the accessories, with priority to safety valves, level probes and pressure
switches.
5.4 CONSERVATION DURING WHEN OUT OF SERVICE

Often during periods of disuse the worst cases of corrosion appear. The operations to be carried out to
guarantee correct conservation of the boiler depend essentially on the duration of the stop.
The boiler can be subjected to dry conservation if the period of disuse is long, or to a wet conservation for
short stops or if the boiler has a back-up function and must be ready to come on-line in a short time.
In both cases, the necessary operations tend to eliminate the causes of possible corrosion.
5.4.1 Dry conservation

The boiler must be drained and dried carefully, then placing in the boiler shell a hygroscopic substance (for
example lime or silica gel etc)
5.4.2 Wet conservation

Drain the water and clean the generator completely. Fill the body up to the normal operation level and after a
brief evaporation period it is essential to purge into the atmosphere to eliminate all dissolved gases. Then fill
the generator completely, dosing a sufficient amount of DEHA (diethyl hydroxyl amine) to develop a residue
concentration of more than 100 ppm that prevents attacks of oxygen dissolved in the water. Also add
trisodium phosphate, until the total alkalinity reaches over 400 ppm. Now close all the connections.
Control all the connections to make sure that there are no leaks and take water specimens at regular
intervals noticing that the alkalinity value has not had alterations.
A “wet” conservation” is always advisable because there are greater guarantees of perfect conservation and
a smaller interval to reach operation conditions.
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WATER CHARACTERISTICS
6 WATER CHARACTERISTICS
All the values listed as follow are taken by tables 5.1 and 5.2, figure 5.1 and 5.2 contained in the EN 12953-
10 (rules related to quality features of feeding and working of boiler water).
For steam generators there are some regulations that require limit values for water characteristics.
However, limits should be adopted for all generators as stated by qualified companies that recommend the
type of treatment to be carried out basing on careful analysis of the available water. Many faults and
sometimes serious accidents are caused by the use of water with non-conforming features.
FEEDWATER - LIMIT VALUES (entering the boiler)

Tab. 1
Characteristics Unit of measurement Pressure  20 bar
Aspect Clear, limpid, no foam, suspended solids
Direct conductivity at 25 °C S/cm < 6000
pH at 25°C --- > 9,2
Total hardness (Ca+Mg) mmol/l < 0,01
Iron (Fe) mg/l < 0,3
Copper (Cu) mg/l < 0,05
Silica (SiO2) mg/l See chart 1.1
Oxygen (O2 )(2) mg/l < 0,05
Oily substances mg/l <1
Organic concentration ------ Note 1
Note 1. Organic substances are generally a mixing of residues. Their composition and acting is difficult to predict. The
organic substances can be dissolved to form carbonic acid or other dissolving silicates which increase acid conductivity
causing corrosion and deposits. They can also foam and/or trig which will be kept as low as possible.
Chart. 1.1
Alkalinity Silicate
0,5 mmol/l 80 mg/l
5 mmol/l 105 mg/l
10 mmol/l 135 mg/l
15 mmol/l 160 mg/l
Note 2. These values are to be accepted when a thermal deaerator is installed. If not so, it is good practice to heat the
water in the tank at least to 80°C (refer to Chapt. 2.7 – Feed water) to reduce the content of dissolved gasses (O2 e
CO2). Be sure to use chemical conditioners to deoxygenate feed water and to reduce CO2 corrosion.
14
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WATER CHARACTERISTICS
6.1 OPERATING WATER - LIMITING VALUES
Chart. 2
Characteristics Unit of measurement Pressure  20 bar
Aspect Clear, limpid, no foam, suspended solids
Direct conductivity at 25 °C S/cm < 6000
pH at 25 °C ------ from 10,5 to 12
Total alkalinity mmol/l from 1 to 15
Silica (SiO2 ) mg/l See chart 1.1
Phosphates (PO4 ) mg/l from 10 to 30
Organic concentration ------ Note 1
6.2 FREQUENCY OF THE ANALYSES
The frequency of analysis is determined evidently as a function of the use of the boiler and of the quality of
the water used; it is advisable in any case to check the pH, the total hardness and the alkalinity of the feed
and boiler waters at least every two days. Once a month, especially under conditions of variable operation, it
is advisable to subject meaningful samples of the boiler and feed waters to complete analysis.
It is also advisable to inspect the return condensate for traces of any highly contaminating oily substances
(reduction of evaporation from the water surface in the boiler caused by a layer of oil).
15
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TROUBLESHOOTING
7 TROUBLESHOOTING
FAULT PROBABLE CAUSE SUGGESTED REMEDY

Safety valve/s opening Maximum pressure exceeded, as set on Adjust the safety pressure switches
the valve. Must be equal to the boiler and / or limit switches.
design pressure.
Loss of the adjustment of the safety Check and then adjust the valve using
valve a reference gauge
Small leaks from the safety Dirt on the valve seat Clean the seat by opening the valve
valve/s manually a few times
Marks on the valve seat Dismantle the valve and regrind the
valve seat with very fine abrasive.
Pump stopped Pump overload relay has acted Check the motor current
Check the relay setting
Pump shaft seized Maintenance to the pump
Pressure safety switch operates Pressure limit switch set too high Adjust the pressure limit switch
Pressure limit switch faulty Replace the pressure limit switch
Pressure switch pipe coil blocked Clean or replace the pipe coil
Safety level 1 or 2 operates Water level detection interrupted Steel probe encrusted
Connection cable interrupted
Safety level relay faulty Temporary replacement of the safety
electronic relay with one of the two
relays in the panel.
If the problem disappears, replace the
faulty relay.
No water feed See faults "feed water"
Feed water insufficient Pump seized See faults "Pump stopped"
Pump suction filter blocked Clean the filter
Level control faulty Temporary replacement of the
electronic control relay with one of
those present in the panel.
If the problem disappears, replace the
faulty relay.
Level probes short circuited Dismantle the control probes for
inspection of the ceramic insulation
Pump cavitation Suction head (difference in height
between supply tank and pump)
insufficient in relation to the water
temperature
Clean the pump suction filter
Reduce the head loss in the pipe
between collector tank and the pump
by increasing the pipe section
Pump rotation direction Invert two phases (three-phase pump)
Burner always ON Erroneous electrical connection to the Consult the wiring diagram
panel
Safety level relays faulty See “Intervention safety level 1 or 2”
Control and/or safety pressure switches Check the adjustment of the pressure
inactive switches
Check the pressure switch
connections to the control panel
Burner always OFF Problems with the burner See the specific burner Manual
Burner fuses interrupted Replace the fuses
No consent to the burner from the control Replace the control pressure switch
pressure switch
No consent to the burner from the safety See “Intervention safety level 1 or 2”
level relay
Erroneous connection to the control Consult the wiring diagram
panel
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WATER LEVEL LIMITS
8 WATER LEVEL LIMITS
8.1 GENERAL
The water level limits consists in: n. 2 level rods, n. 2 probes, electrical cables, n. 2 electronic relays. The
device prevents the lowering of the level of water in the steam generators and the consequent overheating of
the membrature.
The principle of survey and control of the level is based on water conductivity. In order to guarantee
the correct operation of the device, following conditions must be fulfilled:
 Water conductivity > 250 S/cm

 Water temperature < 210°C
 Pressure < 20 bar
(See. " Operating water " - Tab. 2 ).
EXAMPLE: PROBES TANK FOR SAFETY AND REGULATION
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WATER LEVEL LIMITS
8.2 TYPICAL APPLICATIONS
Boiler probes:
6 Pump stop
7 Pump starting
8 1st burner cut-out safety device and alarm ON.
9 2nd burner cut-out safety device and alarm ON
NOTE: it is recommended that an alarm bell is installed in the boiler

room as well as a sound or visual alarm in highly visited rooms.
8.3 ELECTRICAL CONNECTIONS

Refer to the diagram supplied with the specific switchboard.
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WATER LEVEL LIMITS
8.4 STEAM GENERATOR OPERATION

(Water level limits)
8.5 FIRST START-UP
• Start the boiler, as follows:
1 Power up the boiler control panel

2 Make sure that the motor-driven pump drive shaft is free to rotate and that rotation direction is correct.
3 Set the pump selector switch on AUT and verify that burner cannot start before the attainment of the
minimum level;
4 Make sure that the pump stops when the maximum level is reached, observing level indicators and
checking the position of their cocks;
5 Maintain safety level reset pressed for 10 sec because it is employed an electronic delayed relay
6 Open the boiler discharge and check on the level indicator the intervention point of probe pump start
7 Set the pump selector switch on "0", leaving the discharge open, and check the intervention level of
safety probes, referring to the minimum level information plate;
8 Close the discharge, place pump selector switch to AUT;
8.6 MAINTENANCE
8.6.1 Ordinary
 Bleed periodically (level indicators, probe-holder barrel if any, boiler) to avoid mud deposits.
 Check the efficiency of the regulation and control instruments by inspecting carefully the electrical (also
connections); it is also recommended that the probe-holder ceramic plugs are replaced every year
8.6.2 Periodic control (every 6 hours of use)

From time to time (every 6 hours of use) the thermal plant must be inspected by qualified personnel to check the efficiency of
all safety accessories:
 Water level limits
 Safety valve
The system can be reset if no anomalies have been encountered: power off the panel for approx. 20 seconds, power on the
main switch and press the reset buttons.
For further details follow the flow chart below:
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WATER LEVEL LIMITS
20
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WATER LEVEL LIMITS
8.6.3 Extraordinary maintenance (water level limits substitution)
To replace the water level limits or parts of it, follow strictly the instructions below:
1. Ensure that the new ceramic plug is intact
2. Check the length of the rod
3. Ensure that the rod is coaxial to the plug axis
4. Inspect the electrical system and, in particular, ensure that the resistance of the electric circuit linking the
ceramic plug to the electrical panel is intact (resistance must be over 10 MOhm)
5. Ensure that the automatic level control consisting of the two ceramic plugs and their conductivity-relays,
work well
8.7 TROUBLESHOOTING
FAULT POSSIBLE CAUSE RECOMMENDED REMEDY

Safety intervention level 1 or 2 Interrupted water level monitoring Scaled stainless steel bar
Broken connection cable
Faulty safety level relay Temporary replace the safety electronic
relay with one of the two relays in the
panel.
If this is the problem, replace definitively
the faulty relay.
Water does not load See “Loading” inconv.
Insufficient water load Blocked pump See. “Blocked pump” inconv.
Dirty pump sucking filter Clean the filter
Level regulation anomaly Temporary replace the safety electronic
relay with one of the two relays in the
panel.
If this is the problem, replace definitively
the faulty relay.
Level regulation probes short circuit Dismantle the adjustment probes to
inspect visually the ceramic insulation
Pump cavitatation Insufficient head (=different height
between the collecting vessel and the
pump levels) in comparison with water
temperature
Clean the pump sucking filter
Decrease the pipe resistance between the
collecting vessel and the pump by
increasing the passage section
Pump sense of rotation Invert one of the two phases (three-phase
pump)
Burner always on Incorrect electrical panel connection Consult the electric diagram
Faulty level safety relays See “Safety intervention level 1 or 2”
Regulation pressure and/or safety switches Check the pressure switches regulation
OFF Check the pressure switches connection
to the electrical panel
Burner always off Burner problems See burner manual
Interrupted burner fuses Replace fuses
Lack of burner consent from the regulation Replace regulation pressure switch
pressure switch
Lack of burner consent from the level safety See “Safety intervention level 1 or 2”
relays
Incorrect electrical panel connection Consult the electric diagram
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WATER LEVEL LIMITS
8.8 DATA LABEL
Alitaliya Industries.
Sharjah – United Arab Emiraets
Tel: +971 6 533 5880
Fax + 971 6 533 4880
mail@alitaliya.com www.alitaliya.com
LIVELLOSTATO DI SICUREZZA
WATER LEVEL LIMITS Boiler serial number
Model GP1
Serial number
Water conductivity
> 250 S/cm
PS max 20 bar
TS max 210°C
Fluid Acqua / Water
Date
Boiler final test date
Volt / Freq. / Pot. - Power 24 VAC / 50-60 Hz / 3 VA
Approval
WATER LEVEL LIMIT SHALL BE TESTED

PERIODICALLY FOR A MAX OF 6 HOURS
(see TECHNICAL MANUAL)
22
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Sharjah – United Arab Emiraets, industrial area # 4 , warehouse # 46

Tel: +971 6 533 5880 - Fax + 971 6 533 4880
mail@alitaliya.com - www.alitaliya.com
The data reported are indicative only and are not binding. Our company reserves the right to introduce alterations at any time, as it
deems fit and proper for the development of the product.
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ATTACHMENT NO.02.7
Environmental Emergency Protocol
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Environmental Emergency Protocol
Environmental
Release/Spill
Call Emergency Response Team

(ERT No: +971564771230)
Yes
Is It
Controllable?
NO
Control Spill with
Raised Alarm
Spill Kits or Shut Off
Manual or Electrical
valves
Report to
Evacuate the Area &
Elsewedy
Report to Assembly
Project Director/
Point
HSE Manager
Investigate & Report to

Elssewedy
Report to
Project Director/
Elssewedy
HSE Manager
Declare Emergency
NO YES
Call
Call Emergency response
Team Is External Help Civil defense-997
required?
Control Spill with Spill Provide first Aid/Medical

Move any Casualty to
Kits or Shut Off valves Treatment if anybody
safety Away from gas/Spill
injured/ Exposed to
Chemicals
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ATTACHMENT NO.03
ITP of Mono Phase
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INSPECTION AND TEST PLAN

AWEER POWER STATION “H” PHASE IV
LEGEND
CLIENT: EM HIDROMONTAZA
W:Witness
WORK DESCRIPTION: CHEMICAL CLEANING OF FUEL GAS PIPELINE
H: Hold Point
SUBCONTRACTOR: CORODEX RI:RANDOM INSPECTION
DOC REF.: CMS/EMH/ITP/00 S: SURVIELANCE
ACCEPTED RANGE
SR.# DESCRIPTION CONTROLLI QUALITY TEST CORODEX EMH ESI DEWA
NG CHARACTERSTICS TO FREQUENC VALUE CODE/STAN
DOCUMENT BE VERIFIED Y DARD
Visual
appearance of Chemical Visual Check With Once Check Chemical
CS pipe internal Cleaning Torch In Accessible Whether There Cleaning W H W W
Procedure Area Of Pipes Is Debris Or Procedure
1 surface (before
chemical Foreign
cleaning) Material Inside
The Pipes. The
internal rust &
welding flakes.
Borescope
inspection on
the accessible
areas limited
to 40 meter
length.
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The test
pressure
during a W W RI RI
The temporary The test pressure
piping, Hoses are Once pressure during test is
tested first (the a pressure test normally
pumping skid, is normally set set to 150
both headers and to 150 % of the % of the
the effluent line pump shut off pump shut
are included in the pressure. off
testing). pressure.
Chemical
Leak Test Cleaning
2 Procedure Visually check Once No leaks Chemical H W W W
temporary Joints for should be Cleaning
leaks found on Procedure
Temporary
Joints
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Temperature Once Ambient Chemical

Cleaning H W W W
Procedure
Chemical Turbidity 30 MIN. visually clear Chemical

Cleaning Cleaning H W W W
3 Flushing Procedure Procedure
Filter 1 HOUR Some amount Chemical

of Cleaning H W W W
discoloration is Procedure
acceptable
W RI RI S
MN Test 1 HOUR Use MN Paper Chemical
to Check Oil Cleaning
Content In Procedure
Water. No
color changes
on the MN
Paper will be
accepted.
4 Degreasing, Chemical W RI RI S
Cleaning
Procedure Temperature Once 50 C to 60C. Chemical
Cleaning
Procedure
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Free from H2 Chemical

Chemical Inhibitor test (steel 60 bubbles Cleaning H W W W
Cleaning wool) Minutes. Procedure
Procedure
Chemical Fe (g/l) 30 Stable for 2 Chemical H W RI S

Cleaning Minutes. hours (+/- 5%). Cleaning
Procedure Procedure
Chemical Citric acid 30 Sufficient acid Chemical W RI S S

Cleaning concentration Minutes. Cleaning
5 Acid cleaning
Procedure Procedure
Chemical pH value 30 2.0 – 3.0 Chemical W RI S S

Cleaning Minutes. Cleaning
Procedure Procedure
Chemical pH value 30 8.2 - 9,5 Chemical W S S S

Cleaning Minutes. Cleaning
Procedure Procedure
Neutralization
6 &Passivation
Residual Nitrite 30 >1500 ppm H W RI S

1500 ppm Minutes.
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Chemical
Cleaning
Procedure
Visual Check W W W W
with Torch in
Accessible
Area of Pipes.
Chemical Slight
Cleaning Visual Appearance Final Discoloration
Procedure On The Weld
7 Final Inspection Joint Is
Acceptable Chemical
Cleaning
Procedure
Borescope W W W W
inspection on
the accessible
areas limited
to 40 meter
length.
with Torch &
Bore scope in
Accessible
Area of Pipes.
Slight
Discoloration
On The Weld
Joint Is
Acceptable
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for the sample
piece which
kept in the
mixing tank
W W W W
SILVER GRAY
FINISH
COLOR
CORODEX MARINE SERVICES EM HIDROMONTAZA CLIENT CLIENT

NAME: NAME: NAME: NAME:
DATE: DATE: DATE: DATE:
SIGN.: SIGN.: SIGN.: SIGN.:
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Job Log no:
Client:
Contractor: Sub-Contractor: Job no.:
Site:
Job: Date:
1. Leak Test:
Date Time Pressure (Bar) Remarks
2. Degreasing Phase
Oil.
Temp
Date Time M-N pH Remarks
C
test paper
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3. Acid Phase
IronTot. Acid WOOL Temp
Date Time pH Remarks
as Fe+2 Concentration Test C
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4. Passivation Phase
Temp
Date Time Nitrite Conc. (PPM) pH Remarks
C
CORODEX TRADING CO LLC HIDROMONATZA CLIENT CLIENT

Name: Name: Name: Name:
Date: Date: Date: Date:
Signature: Signature: Signature: Signature:
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ATTACHMENT NO.04
Sample Reports & Photograph of

Chemical Cleaning works
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SOHAR3 IPP CCGT

FINAL REPORT FOR CHEMICAL CLEANING OF Page 3 of 10
Subject
HRSG -22
Doc. No. OM004-G200-ZZZ-G001-MEZ-5340020-00 Rev. 00
1. Introduction:
HRSG 22 has been chemically cleaned as per the approved procedure. The chemical cleaning
procedure was meant for the removal of debris, oil/grease, rust, and mill scales. The chemical cleaning
procedure consisted of the below steps:
1.1 Temporary Connections set-up:

All temporary connection prepared and installed properly as per the marked P& ID provided with the
procedure.
Filling of boiler was completely from bottom side to ensure no air pocket to take place inside the HRSG.
Vents fitted in all sections to release the air during filling and generated gases during the chemical
phases.
1.2 Sample Pieces:
Total of 7 sample pieces were given by client and placed in LP drum, IP drum, HP drum and our
chemicals mixing tank. Photos for the weight and conditions of the sample pieces were taken at the
presence of the client representative and kept for record.
1.3 Leak test

After completion of all temporary connection, leak test took place to make sure the system is leak free
before introducing any chemicals in the system. Leak testing was witnessed by client and owner
representatives.
1.4 Pre-flush
We filled the system with fresh water to remove all loose debris, dust, and any physical contamination in
the system. Flushing continued until all waters come from the system got clear and reached the
turbidity/TDS as per the procedure.
1.5 Degreasing
Introduced degreasing agent to remove all oil/grease from the system. Water heated to temperature 55
C. Quantity of 270 Liters of degreasing agent was added to the HRSG-22 for the degreasing.
Degreasing phase continued until no oil/grease was found while testing by oil/grease test strips.
1.6 Acid cleaning

Acid phase cleaning was done by dosing acid inhibitor, 380 Kgs, then citric acid (3%) adjusted pH with
ammonia to 3.5, and then added Ammonium Bi fluoride (0.5%) acid phase continued until iron stabilized
in all sections/ Circuits of HRSG-22. Acid phase was performed at temperature 65.
Recirculation of acid was done separately in each section then last two hours recirculated all system
simultaneously.
1.7 Passivation,
Passivation was done by adding ammonia of quantity 16,600 liters to the existing solution until pH
adjusted to 9.0-9.5 in all sections vents, drains, and sampling points. Recirculation continued until we
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SOHAR3 IPP CCGT

Subject
HRSG -22
ensured the pH is stable and consistent in the whole HRSG 22, then added 0.3 % sodium Nitrite and
continued recirculation until Nitrite stabilized.
1.8 Final Flushing
After visual inspection passed, we flushed the system the ammoniated DM water from top side to
remove any residues. We flushed with the pH at 9 to 9.5.
All details of the above-mentioned steps were mentioned in the procedure.
2. Analytical Results:
Chemical cleaning was done as per the procedure, and during each phase, the required
testing/analyses were performed and recorded accordingly, all analyses are shown below in this
report (appendix-1)
3. Inspection:
3.1 Visual Inspection:
After completion of all chemical cleaning activities, steam drums were opened in 20.0918 at 04:30
am, kept open for ventilation and inspected visually by IES representative, then official inspection
done by the representatives of the concerned parties of the job (TIEJUN and SHINAS) in 20.09.18 at
10:30 pm and the visual inspection accepted by all concerned parties.
Please refer to the attached documents for the photos of Visual Inspection before and after the Chemical
Cleaning.
All sample pieces were checked visually by inspection attendees and they found all samples were
satisfactory to their standard. Samples then weighed, and weight recorded and found satisfactory as
well.
Please refer to the attached documents for the photos of weights of the sample pieces before and after
the Chemical Cleaning.
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SOHAR3 IPP CCGT

Subject
HRSG -22
Appendix – 1:
Analytical results for the phases of the HRSG 12 chemical cleaning:
1- Degreasing phase:
Hour Oil in Remarks

Date Time Temperature
count Water
16.09 06:00 0 55 Continue Heating
16.09 10:00 4 59 Dosing Degreasing agent
16.09 11:00 5 60 Recirculation in all HRSG sections
16.09 12:00 6 62 Recirculation in all HRSG sections
16.09 14:00 8 NA 64 Monitoring and testing
16.09 17:00 11 NA 61 No oil found
16.09 18:00 12 NA 60 No oil found
2- Acid phase:
Time Steel
Iron Citric
Date Hr Wool pH Temperature Remarks
Time ppm Acid %
count test
16.09 14:00 0 0 0 62 Steam boiler re-run
16.09 19:00 5 0 0 63 Adding acid inhibitor
16.09 21:00 7 0 0 ok 3.1 64 start dosing 3% of citric acid
17.09 24::00 10 400 3.5 ok 3 64 Test acid inhibitor
17.09 01:00 11 510 3.46 ok 3 64 Recirculation continues
17.09 02:00 12 600 3.43 ok 3.2 63 Dosing 3% of citric acid is complete
17.09 03:00 13 790 3.35 ok 3.7 64 Dosing of Ammonia
17.09 05:00 15 960 3.3 ok 3.5 65 Monitoring and testing
17.09 19:00 29 3500 2.6 ok 3.4 61 Iron stabilizes
17.09 21:00 31 3540 2.52 ok 3.3 60 Iron Stabilizes
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SOHAR3 IPP CCGT

Subject
HRSG -22
3- Passivation Phase:
Hour Temp. Nitrite Remarks

Date Time pH
count ppm
17.09 21:00 0 3.3 60 Dosing of Ammonia
18.09 24:00 3 4 57 Dosing of Ammonia
18.09 17:00 42 9.2 47 3000 Dosing of Sodium Nitrite
18.09 19:00 44 9.2 46 2950 Recirculation of Sodium Nitrite
19.09 01:00 50 9.2 43 2570 Start draining of HRSG 21 and Feed Water System
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SOHAR3 IPP CCGT

Subject
HRSG -22
Graph -1: Acid phase analyses:
Page 256 of 294

Page 213 of 249
SOHAR3 IPP CCGT

Subject
HRSG -22
Graph-2: Acidity Change during acid phase:
Page 257 of 294

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SOHAR3 IPP CCGT

Subject
HRSG -22
Graph - 3: Passivation phase: pH -Time.
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SOHAR3 IPP CCGT

Subject
HRSG -22
Graph -4: Passivation phase: Nitrite - Time
10
Page 259 of 294

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DRUM BEFORE CLEANING DRUM AFTER CLEANING
INLETS BEFORE INLETS AFTER
Page 260 of 294

Page 217 of 249
Page 261 of 294

Page 218 of 249
SOHAR 3 IPP CCGT
VISUAL INSPECTION PHOTOS
CMS/JL-04/HRSG/018
Page 262 of 294

Page 219 of 249
SOHAR 3 IPP CCGT
CMS/JL-3/HRSG/018
DRUM BEFORE DRUM AFTER
CHECK VALVE INTERNAL
Page 263 of 294

Page 220 of 249
SOHAR 3 IPP CCGT
CMS/JL-3/HRSG/018
Page 264 of 294

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SOHAR 3 IPP CCGT
CMS/JL-3/HRSG/018
INLET BEFORE INLET AFTER
FEEDWATER PUMPS INLET CHECK VALVE INTERNAL
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INLETS BEFORE INLETS AFTER
Page 266 of 294

Page 223 of 249
Page 267 of 294

Page 224 of 249
ATTACHMENT NO.05
RISK ASSESSMENT
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DUBAI ELECTRICITY AND WATER AUTHORITY

Health and Safety Risk Assessment Form
Project Name: AWEER Power Station "H" Phase IV Assessment Date: 02/05/2021
Activity/Area/Equipment: Method statement & Risk Assessment for Chemical Cleaning of Ref. No.: 3761800008-E-08-M-E-65750_A
Fuel gas line at UEN by Mono-phase Circulation method/As listed in MS
Assessor(s): Sumit Bajpai (Site Engineer)/ Fredrick (Safety Officer) Rev Date:
Reviewed By: Karthikeyan (Site Manager) Next Rev Date:01/11/2021
Rev.No .A
SP06: Annexure III B
Risk Rating Final Risk Rating

Legal
Existing control Measures Additional control Measures
Likelihood
Likelihood
Final Risk
requirements
Severity
Severity
Number
Number
Person(s) with mechanism from with mechanism from
Risk
HAZARDS Hazard Effect To be
at risk hierarchy of control for each hierarchy of control for each
complied
identified hazard identified hazard
(Yes/No)
Task No.: 01-: Transportation of Materials Using Heavy Vehicles/ Equipment’s & & Mobilization.
• Failure of Personnel Workers/ Yes 1. Ensured all relevant valid 1 10 5 50 1) Maintain Safe Distance (at 1 10 1 10
Heavy injury / People Supervisors DM COSP DEWA PTW, DEWA LC and least 2mtr) from the
vehicles/In being run over Chapter -20 ESC permit are obtained moving vehicles &
adequate or crushed & prior to mobilization of Pedestrian access shall
strapping/ while As applicable Personnel, Plant & be separated.
Incompetent movement of Equipment. 2) Do not leave the vehicle
drivers/ heavy vehicles 2. Ensured all Employees unattended in running
operators/ may cause attend the ESC Site Safety condition.
Over fatality. Induction & mandatory 3) Shall Maintain SWL.
Speeding/ Property Internal training prior
Unknown damage mobilization.
location/ 3. Ensured Valid DEWA &
Unsecured ESC Entry Pass for all
load. material, personnel and
Vehicles & equipment’s as
per the DEWA & ESC
Security Procedure.
4. Only authorized and
competent operator/driver
has been deployed on site.
The driver and operator
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Rev.No .A
have valid UAE driving
license and heavy
equipment operator
physically fit & Required
Valid Third party for Heavy
equipment operator
5. Ensure the Availability of
material Shipment location
map.
6. Ensured the material stored
in proper location & free of
obstruction for access.
7. Ensured the transport
vehicles have adequate
capacity and Ensured loads
are Strapping Properly
before the transportation.
8. Ensured reverse alarm
functioning for all type of
vehicles. Ensure there is no
overtake and not use cell
phone while driving &
operations.
9. Follow the Site Speed Limit
& Ensured the Banksman/
escort vehicle while
movement of heavy
vehicles & equipment’s.
Dewa Security or Dewa
Escort pass holder only can
perform the Escort.
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10. Welfare facilities (Rest
shelter A/C, drinking water
station & ablution unit etc.)
has been in place.
11. Ensured proper and
Adequate PPE.
Task No.: 02 Un loading of Materials using Crane/ Forklift and other Lifting Gears.
*Failure of Personnel Workers, Yes 1. Ensured all relevant valid 2 10 5 100 1. Specific pre task TBT & 2 10 1 20
lifting Injury, Fatality/ operators DM COSP DEWA PTW, LC and ESC PTW. STARRT shall be conducted &
equipment/lifti Property and Chapter-21&22 2. Ensured approved lifting plan communicate the MSRA to the
ng tackles, Damage supervisors & available for 10 ton and above & work crew. Provision of MSRA
Crane As applicable communicated the approved copy in field.
collapse, lift lifting plan to work crew (Crane
jack failure, & Forklift operators, riggers, 2. Provision of trained &
unsafe Banksman’s, rigging supervisor competent banksman.
slinging and & helpers) through specific TBT.
rigging, 3. Shall undertake pre-entry 3. Provision of amber light and
Communicatio inspection of all Heavy Reverse alarm functioning for all
n Failure, No equipment’s by EMH EHS & crane, Forklift and all Heavy
lifting Plan ESC EHS & Shall affix the equipment’s and vehicles.
sticker by ESC EHS. Forklift operator shall wear face
4. Ensured All Crane, Fork lift & shield during chemical
Heavy Equipment have valid offloading.
UAE registration card & Valid
DAC approved third party 4. Do not leave the crane,
certification. Forklift or equipment in running
5. Ensured the crane operator & conditions.
Forklift Operator have valid UAE
driving license & competent 5.Comply with the DEWA
emergency procedure and ESC
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certified by DM approved third emergency response plan and
party institution. display DEWA emergency
6. Ensured crane, Forklift and contact numbers and control
heavy equipment operator room, Security numbers & ESC
physically fit. emergency numbers.
7. Ensured the competent
Rigger & Rigging Supervisor 6. Provision of visible safety &
have valid DM approved third restriction signage’s and safety
party certification is allowed to barriers to avoid un authorized
giving Signals to the Crane, entry.
Forklift and Other heavy
equipment’s.
8. Ensured all lifting tackles
inspected and tested by DAC
approved third party inspection
& DEWA monthly color code
system has been followed.
9. Ensured all crane, Forklift
lifting equipment clearly marked
with its SWL (safe working load)
and identification number.
10. Ensured fabricated and
Damaged lifting accessories not
used.
11. Ensured Using double Tag
line used for lifting.
12. Ensured the Load Secured
with forklift while Shift the
Materials and followed Site
speed limit.
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13. Ensured safe rigging
practices & not undertake any
short cut.
14.Ensured the area and access
for Crane, Forklift & all
equipment & checked that the
soil is of sufficient load bearing
capacity to undertake crane &
Forklift work.
15. Ensured not allowed People
to stand underneath a
suspended load.
16.Use of adequate PPE in
place.
Task No.03: Manual Handling
*Unskilled & Backache, Workers Yes 1.Mechanical aids (hydraulic 1 5 5 25 1.Provide Internal manual 1 5 1 5
untrained workers/ HAV, Slipped DM COSP trolley) has been used to lift handling training to the work
Unavailability of disc, Knee, Chapter-7.4.1 materials. crew.
ankle and & 2.Safe manual handling
mechanical
Shoulder, As applicable techniques have been adopted. 2.Conduct the pre task TBT and
devices/ Due to Personal 3. Sufficient space and safe communicated MSRA , COSHH
Ergonomical Injury, access prior to lift has been & MSDS to work crew.
Hazards, Lack of Inhalation, ensured.
knowledge about irritation Fire, 4.Ensured Never exceed 3. Ladders only to be used as
chemical, Exposure Eye damage. allowable load limit. means of access. No tools to be
to Chemical Dermatological .5. Ensured all Chemicals is carried up through ladder.
Mucous handled by a competent &
aerosols /acid /
membrane trained person with a sound 4.Comply with the DEWA
Spillage Infection & knowledge of the health hazards emergency procedure and ESC
respiratory associated with such chemicals. emergency response plan and
Problems for 6. Ensured all personnel has display DEWA emergency
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Rev.No .A
people with been completed the adequate contact numbers and control
allergies, Hazardous Substances in- room, Security numbers & ESC
chemical house training from ESC. emergency numbers.
splash 7. Ensured all chemical MSDS
and COSHH Risk Assessment
available in Chemical storage
area and Site location and it has
been maintained regularly.
8.Ensured employees handling
chemicals must wash their
hands and face after finishing
works.
9. Ensured Adequate PPE
(Chemical Resistant Gloves,
Half face mask & Face shield
and Rubber Boot, etc) provided
as per MSDS.
10. All Works has been
performed under the close
supervision.
Task No.04: Pre fabrication & Hot works (cutting, grinding & welding)
*Defective portable Fire, burn, Foreman/ Yes 1. Specific Hot work from DEWA 1 10 5 50 1.Conducting the pre task TBT 1 10 1 10
power tools inhalation, Supervisor/ DM COSP ESC PTW required and DEWA and communicated MSRA.
(welding machine, electrocution Engineer & Chapter- LC has been Issued.
may cause Workers 14,15&16 2.Hot works area is shielded 2.Ensure Civil Defense Certified
grinder etc.) /
fatality, & with fire retardant tarpaulin & fire fire watchman is available at hot
Unskilled workers, suffocation blanket to control the sparks and work area and need to check hot
As applicable
multiple power Ensured all combustible work area before the scope and
connections. material eliminated from hot need to stand by for 30 minutes
work locations, after the hot area.
3.Earthing is provided to close
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Rev.No .A
the welding area and welding 3.Unauthorized person’s entry
machine is grounded. restricted. Incompatible works
4.Ensured Suitable Fire not be allowed near the hot work
extinguisher has been provided. area.
5. Ensured Cylinder gauge and
regulator free from damage. 4. Follow DEWA and ESC
6. Ensured the proper cylinder emergency response plan and
key has been used and display DEWA & ESC
Fabricated or home-made emergency Team contact
cylinder key is not allowed to numbers and Security numbers.
use.
7. Non-returnable valves and 5. Provision of close supervision
Flashback arrestor are installed and Safety coverage.
in cutting set to gas cylinders
on each hose. 6. Provision of proper barrication
8. Ensure the hoses are free and adequate safety signage in
from any crack or damage. place.
9. Ensured crimping type hose
has been used in cutting set
and jubilee clamp is not allowed
to use in Cutting Set.
10. Cylinders are being kept
upright & tied off / kept in
trolleys and cylinder cap in
place and operational gap has
been provided (if it is required
only).
11. All welding machine &
Temporary generator is
inspected and color coded
12. Compliance of proper &
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adequate PPE.
Task No.: 05- Scaffolding and Work at height activities.
*Personnel fall & Serious Workers Yes 1. Ensured DEWA PTW, LC & 2 10 5 100 1.Conducting specific TBT to 2 10 1 20
falling object. injuries/ and DM COSP ESC PTW has been obtained communicate the MSRA to the
/Untrained Fatality Supervisors Chapter-8 prior to start work & Ensured work force before task. Ensure
scaffolders & Safe work platform provided the MSRA copy available in field.
As applicable with edge protection for
(scaffolds) and all work at 2. All personnel shall attend the
heights activities. ESC work at height training.
2.Ensured Double lanyard, full
body safety harness with shock 3. Working at height rescue
absorber has been used & team available on site &
100% tie off required above Coordinate with ESC ERT team
1.8mtr working at height to perform during high angle
activities. rescue from height and under
3.Ensured the soil stability and suspension trauma & mock drill
provided base plate for to be conducted.
scaffolding structures. 4. Provision of Adequate
4.Ensured Only competent warning signs.
scaffolders (certified by DM
approved third party institution) 5.Provision of First aider
perform for scaffolding erection available on site.
and Dismantling and
modification work. 6.Provision of tool Container to
5.Ensured all scaffolding avoid falling object while un
components suitable quality and bolting activity.
being in good condition and free
from corrosion or other defect. 7. All raising and lowering of
6. Ensured Adequate number of material to be carried out in a
ties and bracings has been controlled manner i.e. Hand to
provided to the scaffold. hand, by rope & pulley, fitting
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7. Ensured Scaffolds must have bag.
base plate even when setting on
a concrete floor. 8. Work at height activity shall
8. Ensured ladders Secured not be carried out during
with use of ladder clamp and its adverse weather condition like
only used for accessing heavy rain or wind.
location at height.
9.Ensured 3-point contact has 9.Provision of Close
been maintained. Supervision and Safety
10.Ensured competent Coverage.
supervisors-controlled Working
at Height works.
11.Ensured all Scaffolds are
inspected by scaffolding
inspector (certified by DM
approved third party institution)
prior to use.
12.Ensured No personnel
allowed to work directly below
the scaffold erection activities.
Area is barricaded and
eliminated unauthorized
personnel.
13.Ensured proper
housekeeping at higher
elevation platforms & no
stacking of material.
14. Ensured tool Lanyard used
to prevent the accidental fall of
tools.
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15. Ensured Never throw
materials or allow them to drop
(Bombing).
16. Ensured Suitable and
sufficient warning signage shall
be displayed for the awareness
and controlling of unauthorized
entry in work areas.
17.Compliance of proper &
adequate PPE.
18. Good Housekeeping.
Task No.06: Chemical and Hazardous Substances (if any).
*Incompetent Environmental Workers Yes 1.Ensured all Chemicals is 1 5 5 25 1.Good housekeeping shall be 1 5 1 5
persons/Lack of pollutions burn, DM COSP handled by a competent & maintained.
knowledge about Inhalation, Chapter18 trained person with a sound
chemical. Mixing of irritation Fire, & knowledge of the health hazards 2.Suitable warning signage shall
chemicals. Eye damage. As applicable associated with such chemicals. be provided.
Exposure to Dermatological 2. Ensured all personnel has
Chemical aerosols Mucous been completed the adequate
/acid / Spillage and membrane Hazardous Substances in- 3. Vacuum facility shall be used
Environment Infection & house training from ESC. instead of using blower for
Hazard. respiratory 3. Ensured all chemical MSDS cleaning purpose.
Problems for and COSHH Risk Assessment
people with available in Chemical storage 4. Conducting the pre task TBT
allergies, area and Site location and it has and communicated MSRA,
chemical been maintained regularly. COSHH & MSDS to work crew.
splash & body 4.Ensured employees handling
parts Injury. chemicals must wash their 5. Proper warning signage with
hands and face after finishing emergency contact number
Causes eye works. provided.
burns. May 5.Ensured all the chemical and
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Rev.No .A
cause other auxiliaries are stored in a 6.Emeergency Eye wash
chemical shaded, proper ventilated and Station Shall be provided.
conjunctivitis isolated from fire hazard.
and corneal 6.Ensured the storage is 7. Trained First aider available
damage checked on regular basis for in site.
any leakage or accumulation of
Contact with fumes. 8. Comply with the DEWA
liquid causes 7. Ensured Drip trays has been emergency procedure and ESC
severe burns provided. emergency response plan and
and ulceration. 8. Ensured No Smoking or any display DEWA emergency
May penetrate naked flames are strictly contact numbers and control
the skin and prohibited in the storage area room, Security numbers & ESC
cause severe and Signages in place. emergency numbers.
tissue and 9. Ensured Provision of Fire
bone extinguisher and Spill kit
destruction available on adequate location.
Inhalation: (Chemical Resistant Gloves,
Causes Half face mask & Face shield
chemical burns and Rubber Boot, etc) provided
to the as per MSDS.
respiratory 11. Eyes: Wear appropriate
tract. protective eyeglasses or
Inhalation may chemical safety goggles
be fatal as a 12. Skin: Wear appropriate
result of protective gloves to prevent skin
spasm, exposure.
inflammation, 13.. Respirators: A respiratory
edema of the protection is mandatory.
larynx and 14.. Wash thoroughly after
bronchi, handling.
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chemical 15.. Do not breathe dust, vapor,
pneumonitis mist, or gas.
and pulmonary 16.. Do not get in eyes, on skin,
edema. or on clothing.
Aspiration may 17... Do not ingest or inhale.
lead to 18. Discard contaminated
pulmonary shoes.
edema.
Depletes
calcium levels
in the body
which can lead
to
hypocalcemia
and death.
May cause
systemic
effects
Ingestion:
Harmful if
swallowed.
May cause
severe and
permanent
damage to the
digestive tract.
May cause
kidney
damage. May
cause
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Rev.No .A
perforation of
the digestive
tract. Causes
severe
digestive tract
burns with
abdominal
pain, vomiting,
and possible
death.
Inorganic
fluorides can
be harmful.
Acute
exposure to
fluorine
compounds
can lead to
digestive tract
burns, and
abdominal
pain. Fluoride
can reduce
calcium levels
leading to fatal
hypocalcemia.
May cause
systemic
effects.
Task No.07: Chemical Cleaning/Flushing activity in FG pipe lines.
Wrong Connection Damage Workers, Yes 1. Ensured DEWA PTW, LC 2 5 5 50 1. Shall conduct the pre task 2 5 1 10
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& incorrect routing property, Supervisor/ DM COSP and ESC LOTO permit has TBT and communicate
of hoses. Contamination Environme Chapter18 been obtained prior to start approved MSRA to work crew
/Unexpected & Personnel nt. & work. and keep the MSRA copy in the
/uncontrolled injury As applicable 2. Ensured valid Site note has work place.
release of been issued for chemical 2. Shall carried out any work
chemicals or cleaning/flushing works. over or near where cleaning
flushing medium/ 3. Ensured Only trained and flushing is being conducted.
Improper filling Competent person perform the 3. Carbon Steel/ GRP line tank
system / Task under proper and shall be used for mixing and
Overflowing or competent supervision. filling works. Provision of Proper
spillages of 4. Ensured Pump skid, mixing access to the Tank.
chemicals. tank, chemical dosing pump, 4. provision of Flow metre level
water transfer pump, water to avoid over flow in Storage
tanker, Air Compressor etc., Tank.
has been place correctly as 5. All personnel shall have
mention in correct as per "Stop Work" authority whenever
Method of statement and Lay there is concern for safety
out. during Cleaning operations.
5. Ensured Air compressor/ 6. PH level (as per MS) shall
manifold and gauges are not exceed. If it is exceeding, It
calibrated and Certified by will be neutralizing by Manual
approved third party. Dozing Pump.
6. Ensured safety wipe check 7. Provision of adequate in-
has been provided in all air house training from ESC for
compressor hose connections. Hazardous Substances,
7. Ensured Pump skid, mixing working in operational area &
tank, chemical dosing pump, LOTO.
water transfer pump, Hoses, 8. Chemical cleaning/Flushing
Boiler , Gauges and Fittings in progress signages, hard
(coupling) having Technical barricades or other protective
Data Sheet and has been barriers shall be placed in a
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Rev.No .A
inspected and monthly color manner and Adequate
code in place. watchmen shall be provided to
8. Ensured all hose coupling avoid the Unauthorized entry.
joints having lock pin (used for Provision of Safe zone to
additional secure) and PVC drip protect personnel and the public
tray has been provided in all from unanticipated pressure
hose coupling joints and Ensure release or equipment failure.
all hoses and hose fittings are 9. Never tighten connections
free from crack/damage. that are under pressure. If a
9. Ensured the physical Pre leak develops, you must
inspection has been conducted depressurize to a safe level and
with the DEWA, ESC team then re-tighten.
before the cleaning/flushing 10. Ensure that the pipeline and
activities. equipment will not exceed its
10. Ensured adequate Vents maximum pressure as
has been installed as per MS. mentioned in MS Additional 5%
Ensured the vents are open (if capacity and pressure gauges
required) during water filling. shall use for cleaning/ flushing
Vent relief valve and gauges purpose.
has been certified. 11. If require Valves shall be
11. Ensured Drains and vent of Isolated and LOTO procedure
all instrument manifold has shall follow, proper scaffold
been open to avoid over shall built over the fence for
pressurization (if required). hoses crossing or routing
12. Ensured continuous purpose and Fencing and
monitoring of both end and of surrounding area shall be
all joint for any leakage of isolated and Ensure the Proper
pressure / failure. drainage system in place.
13. Ensured No repair and re 12. The pressure pump/air
works made while line under compressor shall be attended
operational. constantly by an authorized
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14. Ensured Do not holding or person.
increasing the pressure more 13. DM approved Certified fire
than stipulated time as watchmen’s shall be provided.
mentioned in method 14. All chemical flushing water
statement. Shall be disposed off through
15. Ensured all chemical MSDS DEWA/DM approved disposal
and COSHH Risk Assessment vender and disposal certificate
available in Chemical storage shall be submitted to
area and Site location and it ESC/DEWA.
has been maintained regularly. 14. Shall follow the DEWA
16. Ensured all the chemical emergency procedure and ESC
and other auxiliaries are stored emergency response plan and
in a shaded, proper ventilated display DEWA emergency
and isolated from fire hazard. contact numbers and control
17. Ensured No Smoking or any room, Security numbers & ESC
naked flames are strictly emergency numbers.
prohibited in work location and
storage area.
18. Ensured all the system has
been depressurized before
leaving the site
19. Ensured Adequate Fire
extinguisher and Spill kit has
been provided
provided as per MSDS.
Task No.08: Temporary Electrical power supply and use of Hands and Power tools
*Manual handling/ Personnel workers Yes 1. Ensured All Electrical Power 1 10 5 50 1. Conducting specific TBT to 1 10 1 10
Potential pinch injury, DM COSP tools has been inspected communicate the MSRA to the
points/poor Electrocution Chapter monthly and color coded by work force before start the
posture/potential may cause 7.4.1, authorized electrician. task.
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works at height and fatality, hand Chapter14 &16 2. Ensured undertake daily 2. Power tool guards must be
fall/ falling object/ injury, cut, & inspection for DB with using correctly fitted before use. The
electrocution abrasions, As applicable checklist and its recorded. speed of grinding machines
muscle, 3. Ensured conducted the Prior must be properly governed and
strains, burn, inspection & affix the sticker by checked. The maximum (RPM)
fire &Property the ESC EHS. DEWA/ESC should be marked on the tool.
damage monthly color code & inspection Only the correct disc should be
process is followed. fitted for the grinder in use. Fit
3. Ensured all electrical power grinding discs properly. The
supply through 30mA RCD and source of power must be
Grounded. isolated from power-driven
4. Ensured using insulated & tools.
right tool for right job. 3. Use of approved industrial
5. Ensured Operatives is aware sockets.
of potential pinch point and
using of Proper PPE. 5.provision of Fire points with
6. Ensured all damaged tools suitable Fire extinguisher. (
has been segregated & returned CO2 ).
to store for disposal. 6. Always Follow the LOTO
7.Eusured un attended power system.
tools has switched 7. Provision of Suitable earthing
off/disconnected & all tool has for all temporary power supply
been stored in tool kits when equipment.
not required.
8. Ensured not using 8. All Site DB boxes to be kept
Homemade & Fabricated tools. padlocked. All tools
9. Ensured hand tool has disconnected from electrical
lanyard for prevent the falling supply prior to cleaning /
object. servicing etc.
10. Ensured trained &
Authorized personnel has been 9. Hazard Signage to be placed
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complete the Electrical DB and on all Electrical panels and
Power Installation under Display the Contact number of
supervision of competent Authorized electricians.
electrical supervisor.
11. Ensured using 220/110-volt
power tools with Dead man
switch.
12.. Wash thoroughly after

handling.
13. Minimize dust generation

and accumulation.
14. Do not breathe dust, vapor,

mist, or gas.
15. Do not get in eyes, on skin,

or on clothing.
16. Keep container tightly

closed. Do not ingest or inhale.
17. Discard contaminated
shoes.
18. Use only with adequate
ventilation
Task No.9: Heat Stress, Mid-day Break
*Hot Environment/ Heat Stroke/ Workers Yes 1. Ensured Control of the 2 10 5 100 1.In case of emergency 2 10 0.5 10
Humidity/ Un Exhaustion. and DM safe & Temperature using engineering immediately call for Medical
availability of rest Dehydration, supervisors Healthy solutions. attention.
Dizziness, Summer 2. Ensured Provision of 2.Move the person to a cool
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shelter & Cool Headache, Guideline adequate water coolers/cool and shady area.
water Nausea, & water and using fans or Air 3. Do not leave the person
Cramp, Rapid As applicable conditioning. alone. If person is
weak Pulse 3. Ensured Provision of unconscious, do not give them
and breathing, mechanical aids-where possible water.
Loss of to reduce the physical work 4.Continue to cool their body
appetite rate. temperature until medical
4. Ensured Scheduling works assistance arrives and they can
Fatal or serious
only when the temperature is be taken to a medical facility for
health effects below asset level or at cooler further cooling and monitoring
times of the day and Increased of body temperature and
the work rest cycles. functions.
5. Ensured No alone working 5.Monitor the condition of your
and Avoided direct sun light co-worker periodically.
exposure. 6. Heat related illness could
6. Ensured Buddy System has cause a person to become
been maintained. confused or loss of
7. Ensured enough cool consciousness. A close
water/drinks is available in the supervision by a competent
workplace and encouraged supervisor is warranted during
workers to drink it frequently.is entire activity.
small amount even if not feeling 7.All workmen should aware
thirsty. Encourage them to about sites facility and
increase the salt intake with emergency contact numbers &
meals than usual. Provision of Internal awareness
8. De hydration Urine Chart training & Tool box talk about
has been displayed in the toilet Heat stress to workers/
& welfare facility area. Especially new workers.
9. Adequate electrolytes and 8. Reduce the working hours.
(ORS) & Hygienic ice cube for Assign two groups shift wise for
Cool water has been provided. a particular job. Personal
Page 244 of 249

Rev.No .A
9. First Aid/ Medical facilities cooling systems and breathable
shall be available all the times fabrics which helps workers in
at work site. hot environments. Providing
10. Ensured Complying with periodic rest breaks with cool
DM Mid-day break Schedule. refreshment and rest facilities in
11. Ensured Provision of Air cooler conditions.
conditioner rest room during
Mid-day break hours.
Task No.10: Waste Management & House keeping
*Lack of Training/ Slip/Trip and workers Yes 1. Ensured Conducting the pre 2 5 5 50 1.Conducted TBT & awareness 2 5 1 10
Cultural behavior Falls, Fire DM COSP task TBT performed. training to the works force about
Chapter_ 3.17 2. Ensured segregate the waste management system.
& Electrical & mechanical
As applicable dismantling material and 2. Provision of housekeeping
properly stacked and team.
barricaded the area in permitted
place. 3. Display the Proper
3. Ensured Using mechanical label/signage in all waste skip in
Devises to avoid manual multi languages.
handling.
4. Ensured Proper & valid 4. Provision of close food waste
material Exit pass required for skip.
removing the materials from
site. 5. All Chemicals and
5. Ensured Kept the work area Contaminated Shall be
neat and clean. disposed off through DM
6.Ensured Access routes is approved disposal vender and
clean from all obstruction to managed as Per project CEMP
avoid chances of slip, trip and
fall.
Page 245 of 249

Rev.No .A
7. Ensured Maintaining proper
cable management.
8. Ensured Provision of
adequate skip for Food /
General plastic and paper
waste.
9. Adequate PPE Has been
Used As per MSDS.
Task No.11: Emergency Response
* Unauthorized Severity of All Yes 1. Ensured the pre task TBT 2 10 1 20 1.Close supervision required all 2 10 0.5 10
entry into the Illness will employees DM safe & performed and Introducing the the times.
existing operational increase if not Healthy first aid team.
area. given Guidelines 2. Ensured Strictly Following 2.Restricted the Unauthorized
* Lack of training immediate & the DEWA emergency entry.
and Awareness/ medical As Applicable procedure and ESC ERT team
fire, toxic gas attention & 3. Adequate fire point and
plan & displayed DEWA
release/chemical fatality Emergency spill shall be
spill, workplace emergency contact numbers, provided.
violence control room, Security numbers
& ESC emergency numbers.
3. Ensured Emergency access
way maintained clear at all
times.
4. Ensured All the workers has
been trained for emergency
plan procedures.
5. Ensured MSRA & MSDS
provided and communicated to
work force.
Page 246 of 249

Rev.No .A
6. Ensured and Informed the
evacuation procedure and
Assembly point location to work
Crew.
Task No.12: Night working activities (If applicable)
*Improper Slip and Trip Site Yes 1. Ensured PTW obtained from 2 5 5 50 1. Provide more supervision to 2 5 1 10
illumination, Body injury Workers/ DM Technical Dewa for the night work ensure workers are more
workers fatigue. muscle strain Supervisor Guidelines activates. closely monitored.
GU-66 2. Ensured Authorized
& Supervisor responsible for the 2. Avoid assigning complex
As Applicable adequate lighting provided on tasks to night shift.
working area.
3. Ensured Lighting has been 3. Approved first-aider must be
comfortable and not exposed available in case of emergency.
employees or surrounding for
disturbing glare. 4. Additional emergency vehicle
4. Ensured Lighting fixture should be kept in standby.
suitable for the area as installed
5.Ensured Job rotation
implemented and break given
on regular intervals
6. Ensured First aid facilities
and oral rehydrates such as
Cold Drinking Water, Tang,
Glucose etc
7. Ensured Avoid alone
working.
8. Ensured Minimum 100 lux
illumination provided.
9. Ensured EHS coverage shall
be available full time.
Page 247 of 249

Rev.No .A
Assessors Reviewed by: Approved by:
Name: Fredrick (Safety Officer)

Sumit Bajpai (Site Engineer) Name: Karthikeyan (Site Manager) Name: Aleksander Gornjak (Project Manager)
Date: 02.05.2021 Date: 02.05.2021 Date: 02.05.2021
Signature: Signature: Signature:
No .of people affected Severity of injury Likelihood of occurrence

1-5 Persons 1 1 Negligible 1 Improbable 0.5
6-50 Persons 2 2 Minor 2 Remote 1
50+ persons 3 3 Major 5 Possible 5

Public/ Vulnerable
persons affected 3 3 Fatal 10 Likely 10
(Ref. Annexure IIID)
h
Page 248 of 249

Rev.No .A
Notes :
• If the Public or Vulnerable persons could be affected by the work activities,

the appropriate weighting should be applied.
• Negligible Injuries include bumps, small cuts, and abrasions etc.
• Minor injury Includes those injuries that could result in time off work, etc.
• Major injury Includes broken limbs, injury to eyes, asphyxiation.etc
• Improbable: Probability close to Zero.
• Remote: Unlikely.
• Possible: Could Occur sometime.
• Likely: Not Surprised that it will happen.
• Certain: Most Likely to happen.
Page 249 of 249

Rev.No .A
RISK ACTION TO BE TAKEN

RATING
SCORE
Up to 20 Risk is low: Acceptable: Additional control measures may be

considered to reduce the Risk, although low priority Time, effort
and cost should be proportional to the Risk
21-50 Risk is medium: Unacceptable: Additional Control measures
required soon to control. Interim measure may be necessary in the
short term.
51-100 Risk is high: Unacceptable: Additional Control measures required
urgently to control Risk. Interim measure required in the short
term. Significant effort, time, etc. may have to be control the Risk.
100+ Risk totally unacceptable.

MSRA For Chemical Cleaning Fuel Gas Line at UEN - Monophase - Rev A

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MSRA For Chemical Cleaning Fuel Gas Line at UEN - Monophase - Rev A

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Page 1 of 249

A 02.05.2021 Karthikeyan Issued for approval

Aweer Power Station ‘H’ Phase

Date Name Document Title: Scale:

Complete sections 1,2,3,4 – Method Statement √

Civil Electrical Mechanical √ Other (Please specify)

Location of UEN at phase 4

Brief Description of Work (Purpose / Scope):

• Piping Material Specification, No: 3761800008-U-31-M-T-40012

MSDS of all chemicals attached (Attachment No.: 02.2)

5. GENERAL SAFETY PRECAUTIONS

Dosing will be on the chemical mixing / circulation tank.

Degreasing Phase Parameters:

6.6 Acid phase

6.6.8 Maintain the pH value in between 2.0 – 3.0.

Inhibitor steel wool : No visible hydrogen gas (Every 30 Min.)

pH Value : 2.0 – 3.0

Iron concentration : stabilized for 2 measurements (with a maximum of 15g/l).

Residual Nitrite : > 1500 ppm

Visual Appearance :- Visual Check with Torch in Accessible Area of Pipes.

6.8.5 Refer to attachment 1 - inspection and test plan (ITP) / Section 7.

8. Waste Water Disposal:

 Waste will be collected in Corodex provided 40 ft. containers.

 Neutralization of the waste water to pH

 Disposal permit to be requested through DM portal.

9.0 Operational details:

Permit To Work Activity Type and Special Needs:

√ Plant/Equipment Dangerous Goods Others:

Using of Hazardous substances

Temporary Services Required:

A. Man-Power (on site):

Project Manager No. 01

APPROX. DIMENSION (LXWXH)

10.2- TESTING EQUIPMENT

11. Complete the Risk Assessment Form:

List of Attachments : (Drawings, Photo, Certificates, Safety Data Sheet, etc.)

1. Fuel Gas General Arrangement drawing 3.

Construction Site Manager

Name Signature Date

Construction Site Manager

Fuel Gas Line Chemical Cleaning - Reference Table

Deminarlized or ERGITOL NP-10 Surfactant /

A- Temporary Equipment Arrangement Location Per

Waste Tank Waste Tank Waste Tank

Chemical Storage Container

Chemical Storage Container

CHEMICAL STORAGE AREA

Steam Boiler Lab Container

CHEMICAL CLEANING AREA

Waste storage tank Photo

40 feet waste storage tank – 60 m3/Tank.

DIESEL PUMP – 900 m3/Hr.

5 TONS STEAM BOILER

Disposal Company Detail

Emergency Response Plan

Doc. No. CMS/DEWA/ERP Rev. 00

EMERGENCY RESPONSE PLAN

Page 100 of 294

Doc. No. CMS/DEWA/ERP Rev. 00

1. Emergency Response Plan

1.2 Designated Positions and Responsibilities

1.3 Emergency Response Action Leader (on-site)

1.4 Emergency Response Priorities