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DR - HilmiS.Salem ApplicationoftheKozenyCarmanEquation PDF
DR - HilmiS.Salem ApplicationoftheKozenyCarmanEquation PDF
Hilmi S. Salem
To cite this article: Hilmi S. Salem (2001) Application of the Kozeny-Carman Equation to
Permeability Determination for a Glacial Outwash Aquifer, Using Grain-size Analysis, Energy
Sources, 23:5, 461-473, DOI: 10.1080/009083101300058480
Download by: [Professor Prof. Hilmi S. Salem] Date: 21 April 2017, At: 00:52
Energy Sources, 23:461 ± 473, 2001
Copyright # 2001 Taylor & Francis
0090-8312 /01 $12.00 ‡ .00
HILMI S. SALEM
Atlantic Geo-Technology
Halifax, Nova Scotia, Canada
Numerous fresh-water aquifers of glacial origin are present in diŒerent regions of the
world, such as the northern central part of the United States of America, the
southern part of Canada, and the northern part of Europe. Glacial aquifers generally
consist of silts, sands, and gravels, with variable amounts of clays. The sediments of
glacial aquifers have a wide range of grain size, grain shape, and grain type (miner-
alogy). Large quantities of the sands and gravels were deposited as outwash material,
swept out from the melting glaciers by the forces of the melt-water streams and
moraines in front of the glaciers. In their studies on glacial aquifers, McDonald
and Wantland (1961), Frohlich (1973), Kelly (1977), Urish (1981) , and Frohlich
and Kelly (1985) pointed out that glacial aquifers are greatly heterogeneous, laterally
and vertically.
The area of investigation, Segeberger forest, forms about 10% of the total area
of the province of Schleswig-Holstein (S-H), northern Germany. The sediments of
the area are of Pleistocene age, similar to all glacial deposits in northern Europe
(Einsele and Schulz, 1973). The altitude of the area ranges from 25 to 65 m above sea
461
462 H. S. Salem
level. The annual precipitation on the area is about 800 mm/yr, distributed as
follows: 500 mm evaporation, 60 mm runoŒ, and 240 mm in® ltration recharging
the aquifer system. The aquifer ranges in thickness from 30 to 70 m, with a water
table about 5 to 10 m deep and about 20 m underneath the areas of higher altitude.
The aquifer is underlain by an aquiclude composed of boulder clays, known as
``Geschiebemergel.’’
Fluid ¯ ow through porous media may be quantitativel y evaluated by knowledge
of several physical parameters and conditions, as well as several lithological attrib-
utes. These include velocity of ¯ ow; gravity acceleration; pressure drop; hydraulic
gradient; permeability; porosity; speci® c surface area; density, viscosity, and tem-
perature of ¯ uid; pore-water salinity; geometry of pores and pore channels (tortu-
osity); shape and size of pores and pore channels; and size, shape, type, packing,
sorting, distribution, and orientation of grains (anisotropy).
In the present study, emphasis is placed on determination of permeability, with
respect to the porosity and the speci® c surface area, for the grain-size fractions and
the layers of the S-H aquifer and the aeration zone, using grain-size analysis and the
Kozeny-Carman equation.
Theory
For permeability …k† determination, several equations have been theoretically,
experimentally, and empirically developed (e.g., Slichter, 1899; Van Terzaghi,
1923; Krumbein and Monk, 1942; Wyllie and Rose, 1950; Loudon, 1952; Rose,
1957; Harr, 1962; Chilingar et al., 1963; Davis and De Wiest, 1966; Berg, 1970;
Todd, 1980; De Marsily, 1986; Katz and Thompson, 1986; Johnson et al., 1987;
Salem, 1994; Salem and Chilingarian, 1999). Those equations are dependent, one
way or another, on three fundamental equations: Darcy’s equation (Darcy’s law),
Poiseuille’s equation, and the Kozeny-Carman equation.
The temporal rate of change of the position of a ¯ uid particle is represented by
means of the particle velocity. Fluid velocity is one of the major factors in the
mechanism of ¯ uid ¯ ow through a medium because it is aŒected by the dynamic
and kinematic relationships among the ¯ uid, medium and ¯ ow. The apparent veloc-
ity of ¯ uid ¯ ow …¾ap †, in cm/s, also known as ® lter (microscopic) velocity, is de® ned
as the mean velocity of a ¯ uid, ¯ owing with a rate q, in cm3 /s, through the entire
space of a porous medium, having a cross-sectional area A, in cm2 , and permeability
k, in cm/s, i.e.,
q
¾ap ˆ …1†
A
Equation (1) is one of the simplest forms of Darcy’s law. The actual velocity of
¯ uid …¾ac †, in cm/s, also known as distance (macroscopic) velocity is obtained by
dividing ¾ap by the fractional porosity …¿† of the medium. For a ¯ uid with viscosity ·
(in cP) ¯ owing with a rate q (in cm3 /s) under a pressure gradient ¢P (in atm/cm),
normal to cross-sectional area A (in cm2 ) of a medium with permeability k (in
Darcy), the apparent velocity …¾ap †, in cm/s, is (Darcy’s law):
³ ´
q k
¾ap ˆ ˆ ¢P …2†
A ·
The Kozeny-Carman Equation to Permeability Determination 463
Using the same units given in Equation (2), k (in Darcy) for the same medium,
having length L (in cm), is
q·L
kˆ …3†
A¢P
For a ¯ uid with viscosity · (in Poise) ¯ owing through a number of capillary
tubes nc , each with capillary length Lc and capillary radius rc (both in cm), where ¢P
is in dyne/cm 2 , the general form of the Poiseuille’s equation for capillary ¯ ow is
!³ ´
nc ºr4c ¢P
qˆ …4†
8· Lc
For linear ¯ ow and capillary ¯ ow, the Darcy’s law and the Poiseuille’ s equation
are quite similar (Tiab and Donaldson, 1996). Using the same units given in Equa-
tions (2)± (4), q of a ¯ uid passing through capillary tubes with a total cross-sectional
area At (in cm 2 ) is
³ ´³ ´
kAt ¢P
qˆ …5†
· Lc
¢Pg¿3
¾ap ˆ …6†
Kcc s2s ·Lc
where
¾ap 5 apparent velocity of ¯ uid ¯ ow (cm/s);
¢P 5 pressure gradient in the direction of ¯ uid ¯ ow (g/cm2 );
g 5 gravity acceleration (ˆ 981 cm/s 2 );
¿ 5 porosity (fractional);
Kcc 5 Kozeny-Carman coe cient (dimensionless);
ss 5 speci® c surface area (cm ¡1 );
· 5 viscosity of ¯ uid (Poise ˆ g/cm.s);
Lc 5 length of capillary tubes (cm).
Substituting · by f¸»g, where ¸ is ¯ uid’s kinematic viscosity (in cm2 /s) and » is
¯ uid’s density (in g/cm3 ), and then substituting f¢P=»Lc g by the hydraulic gradient,
I, dimensionless, Equation (6) is
Ig¿3
¾ap ˆ …7†
¸Kcc s2s
It is important to mention that the symbol I is used for the hydraulic gradient
instead of i because i is used later for the grain-size fractions. Substituting f¿ap =Ig by
k, then k (in cm/s) is
464 H. S. Salem
g¿3
kˆ …8†
¸Kcc s2s
¿
kˆ …10†
Kcc s2s
The Kozeny-Carman coe cient, Kcc , is de® ned as the product of tortuosity …½†
and shape factor …Shf †, both are dimensionless, i.e., fKcc ˆ ½Shf g. The shape factor is
a measure of the shape of the grains, pores, and pore channels in a porous medium.
The tortuosity and shape factor re¯ ect the geometry of the cross-sectional area of the
pore channels normal to the ¯ ow direction. For unconsolidated sediments, Carman
(1937, 1938) assigned a value of 2.0 for ½ and a value of 2.5 for Shf , which both
results in a value of 5.0 for Kcc .
The speci® c surface area, ss , is variably de® ned as the interstitial surface area of
the pores and pore channels for each unit of bulk volume, grain volume, pore
volume, in cm2 /cm 3 (ˆ cm¡1 ), or for a unit of weight of a material, in cm2 /g. For
a medium, with grain diameter D, in cm, and porosity ¿, in fraction, Carman (1937)
gave the following equation for ss :
6…1 ¡ ¿†
ss ˆ …11†
D
If porosity and grain size are known, then Equation (11) can be used to obtain
the speci® c surface area of fractions of sediments …ssf , in cm¡1 †. For a layer con-
sisting of diŒerent fractions (X i to X n), with various grain sizes and various speci® c
surface areas, the speci® c surface area of all sediment fractions in that layer (ssl , in
cm ¡1 ) can be obtained as (Loudon, 1952)
( )
n
X
ssl ˆ L X i ssi …12†
iˆ1
where
L 5 dimensionless coe cient ranging from 1.1 (for rounded grains) to 1.4 (for
angular grains);
ssi 5 speci® c surface area of fraction i, in cm¡1 (ˆ 6=Dmi †;
Dmi 5 mean diameter of the grains in fraction i (in cm).
The Kozeny-Carman Equation to Permeability Determination 465
Methodology
The permeability, k, was determined for the grain-size fractions and the layers of the
S-H aquifer and its aeration zone with respect to the porosity, ¿, and the speci® c
surface area, ss . That was achieved by using grain-size analysis (GSA) of the sedi-
ments obtained from 6 wells at depth (Z) ranging from 1 to 32 m and by applying the
Kozeny-Carman equation.
The fractions of silts, ® ne, medium, and coarse sands and gravels, as well as a
small amount of clays were recognized at various depths. The weight percentage
(WP) and the grain-size distribution (GSD), both obtained from GSA, were plotted
on semi-log paper to construct the accumulative curves that represent the various
fractions of the sediments. The accumulative curves were then used to obtain the
grain size (Gs , in mm) as D10 , D50 , and D90 , which are, respectively, de® ned as the size
of the grains (in terms of diameter D) regressed at WP of 10, 50, and 90% . The
uniformity coe cient …Uc †, dimensionless, was obtained as the ratio of D regressed
at 90% to D regressed at 10% , i.e., fUc ˆ D90 =D10 g.
For each accumulative curve, the values of Uc and D50 (in mm) were introduced
in the following empirical equations, given by Urish (1981) for similar heterogeneous
glacial aquifers, to obtain the porosity, in % , as maximum …¿max † and minimum
…¿min †, from which the average porosity …¿av † was obtained as f…¿max ‡ ¿min †=2g
The speci® c surface area of the grain-size predominant fractions of the grain
sizes of the sediments in each layer (ssf , in cm ¡1 ) was obtained in accord with
Equation (11). The speci® c surface area of all the fractions in each layer (ssl , in
cm ¡1 ) was obtained in accord with Equation (12). For this purpose, one requires
Gs regressed at D10 , D50 , and D90 and the corresponding WP (both read from the
accumulative curves), as well as a value for L, which was assumed as 1.3, because of
the variations in the grain shape of the sediments.
The values of porosity and speci® c surface area were then used in the Kozeny-
Carman equation (Equation 9) to determine the permeability …kf † and …k1 †, in cm/s,
for the fractions and the layers, respectively. A value of 0.01 cm 2 /s was used for ¸ and
a value of 5.0 (dimensionless) was used for Kcc .
The values of D10 , D50 , and D90 (in mm), U c (dimensionless), ¿av (in % ), ssf and
ssl (in cm ¡1 ), kf and k1 (in m/s), corresponding to the various layers penetrated by the
six wells at diŒerent depths …Z†, are given in Table 1. Empirical equations [Equations
(15)± (32)], along with their coe cients of correlation …Rc †, ranging from 0.65 to 1.0,
are given in Table 2. These 18 equations represent relationships correlating among
the various parameters determined in this study. Examples of the relationships are
given in Figures 1± 4.
466
2.85 £ 10¡4 4.02 £ 10¡6
77 80 440 2,600 32.5 35.2 89 190 1.36 £ 10¡2 2.98 £ 10¡3
C 5.5± 6.5 12 110 575 47.9 45.0 300 2,878 1.78 £ 10¡3 1.94 £ 10¡5
710.5 215 800 17,500 81.4 29.6 53 158 2.96 £ 10¡3 3.30 £ 10¡3
D 1± 6 16 220 1,550 96.9 39.5 166 1,896 4.71 £ 10¡3 3.57 £ 10¡5
78 145 1,800 4,600 31.7 28.1 24 284 1.33 £ 10¡1 9.49 £ 10¡4
714 180 3,500 4,400 24.4 25.0 13 173 3.93 £ 10¡1 2.18 £ 10¡3
722 130 600 4,600 35.4 33.7 67 575 2.27 £ 10¡2 3.02 £ 10¡4
E 1± 6 230 600 3,800 16.5 35.1 65 226 2.52 £ 10¡2 2.08 £ 10¡3
712.5 160 380 1,400 8.8 38.6 97 153 1.31 £ 10¡2 5.27 £ 10¡3
F 1± 9 85 440 6,750 79.4 33.5 91 153 1.20 £ 10¡2 4.22 £ 10¡3
710 20 925 30,000 1,500 26.0 48 1,133 3.00 £ 10¡2 5.37 £ 10¡5
719 102 390 2,200 21.6 36.6 98 212 1.19 £ 10¡2 2.53 £ 10¡3
721 83 290 775 9.3 39.9 125 431 8.42 £ 10¡3 7.02 £ 10¡4
732 95 500 7,000 73.7 33.1 81 148 1.51 £ 10¡2 4.44 £ 10¡3
The Kozeny-Carman Equation to Permeability Determination 467
Table 2
Empirical equations [Equations (15)± (32); listed as indicated in the text] with
coe cients of correlation (Rc , ranging from 0.65 to 1.0) correlating among grain size
of sediments (diameter of grains; D10 , D50 , and D90 ), in mm, regressed at weight of 10,
50, and 90% ; average porosity …¿av †, in% ; speci® c surface area of the predominant
grain-size fractions of sediments in a layer …ssf †, in cm¡1 ; speci® c surface area of all
grain-size fractions of sediments in a layer …ssl †, in cm¡1 ; permeability of grain-size
fractions …kf †, in m/s; and permeability of layers …k1 †, in m/s. These equations are
based on grain-size analysis for samples obtained from 6 wells at depth (Z) ranging
from 1 to 32 m, penetrating the aeration zone and the aquifer (S-H northern
Germany). The equations represent grain size ranging from µ 63 mm to
¶ 2 £ 104 mm, which correspond to clays and silts (µ 63), ® ne sands (63± 200),
medium sands (200± 630), coarse sands (630± 2000), ® ne gravels (2000± 6300), medium
gravels …6:3 £ 103 –2 £ 104 †, and coarse gravels …¶ 2 £ 104 †. Equations (21), (26),
(28) and (32) correspond, respectively, to Figures 1± 4
sediments. The D10 (Table 1) covers a Gs range of 10± 600 mm (median ˆ 100 mm),
corresponding to silts, ® ne and medium sands, and the small clay portion. The D50
(Table 1) covers a Gs range of 35± 3500 mm (median ˆ 500 mm), corresponding to silts,
® ne, medium, and coarse sands, and ® ne gravels. The D90 (Table 1) covers a Gs range
from 182 to 3 £ 104 mm (median ˆ 3800 mm), corresponding to ® ne, medium, and
468 H. S. Salem
coarse-grained sands and gravels. The median values (100, 500, and 3800 mm) corre-
spond, respectively, to ® ne sands, medium sands, and ® ne gravels. The sediments
within the aquifer exhibit a general range of Gs from 100 to 6300 mm, corresponding
to ® ne, medium, and coarse sands, as well as ® ne gravels. The Gs range of the aquifer
coincides with the median values of Gs (100, 500, 3800). These results indicate that
the values of Gs (regressed at D10 , D50 , and D90 ) cover together the whole range of the
size of the grains present in the aquifer and the aeration zone.
The obtained physical parameters (Table 1) have the following ranges and median
values (given in brackets): ¿av ˆ 25± 51% (35.1% ), corresponding to a range of ¿max of
33± 55% and a range of ¿min of 16± 42% ; ssf 5 13± 844 cm¡1 (81 cm¡1 ); ssl ˆ 49±
7100 cm¡1 (218 cm¡1 ); kf ˆ 2:85 £ 10¡4 –4:6 £ 10¡1 m/s (1:15 £ 10¡2 m/s); k1 ˆ 4:02£
10¡6 –3:35 £ 10¡2 m/s (2:18 £ 10¡3 m/s). The wide ranges of these parameters can be
contributed to the high degree of lateral and vertical heterogeneitie s characterizing
the sediments of the aquifer and the aeration zone.
It is important to mention that the median values are used instead of the mean
values, because the median values are more representative of the wide variations of
the parameters obtained than the mean values. In addition, a median value (repre-
senting the value of the middle variable of a class of data and corresponding to the
50% point on an accumulative frequency range of values) is not sensitive to extreme
values, as in the case of the mean value. Regarding the porosity in particular, the
diŒerence between the mean value (35.3% ) and the median value (35.1% ) is negli-
gible because ¿ has no extreme values, similar to the other parameters.
The interrelationships among the various parameters determined for the frac-
tions and the layers [Table 2; Equations (15)± (32); Figures 1± 4] show the presence of
a strong interconnection between Gs (represented by D10 , D50 , and D90 ), ¿, ss , and k.
Table 2 shows that an increase in ¿ is associated with a decrease in Gs [Equations
(15)± (17)]; an increase in ss is associated with a decrease in Gs (Equations (18)± (20)
and with an increase in ¿ [Equations (21)± (22); Figure 1]; and an increase in k is
associated with an increase in Gs [Equations (23)± (25)] and with a decrease in ¿
[Equation (26); Figure 2], as well as with a decrease in ss [Equations (27)± (30);
Figure 1. Average porosity …¿av †, in % , versus speci® c surface area of the predominant grain-
size fractions of sediments in a layer …ssf †, in cm¡1 ; 19 readings representing 6 wells penetrating
the aeration zone and the aquifer (S-H, northern Germany).
The Kozeny-Carman Equation to Permeability Determination 469
Figure 3]. The speci® c surface area of the predominant grain-size fractions …ssf † and
that of all the fractions together in a layer …ssl † show a progressive increase with each
other [Equation 31]. Also, the permeability of fractions …kf † and that of layers …k1 †
increase progressively with each other [Equation (32); Figure 4]. The fact that
ssf < ssl and kf > k1 (Table 1) suggests that an increase in the number of fractions
in a layer, particularly those of a ® ner grain size, leads to an increase in the speci® c
surface area of the sediments, which results in a lower permeability of that layer. The
uniformity coe cient …Uc ˆ D90 =D10 † does not show strong correlations with the
various parameters obtained because it re¯ ects a wide range of grain sizes, indicating
lack of uniformity of the sediments. The range of Uc [º 9–97, with a single reading of
1500 (median ˆ 32.5); Table 1] agrees well with the ranges of heterogeneous glacial
deposits given by other researchers.
470 H. S. Salem
Conclusions
Permeability of aquifers can be determined empirically, theoretically or experiment-
ally from laboratory measurements, tracer tests, or pump tests. For the glacial
aquifer in S-H (northern Germany), the permeability, along with the speci® c surface
area and the porosity, was determined from grain-size analysis using the Kozeny-
Carman equation. The aquifer is composed of unconsolidated, heterogeneous sedi-
ments that consist of a variety of grain sizes and diŒerent mineralogical composi-
tions. Variations of the parameters that control the hydraulic ¯ ow through the
aquifer are strongly aŒected by the grain-size distribution of the sediments. The
nature of the relationships between the various parameters is primarily dependent
on the grain-size distribution and variations of the grain size. A decrease in the grain
size leads to an increase in the speci® c surface area, which results in a decrease in the
The Kozeny-Carman Equation to Permeability Determination 471
permeability. The high degree of heterogeneity of the aquifer contributes to the wide
variations of the physical properties of the sediments, re¯ ected in the water-¯ ow
nonuniformity. The results obtained agree well with those obtained experimentally
for the same aquifer or other aquifers composed of glacial deposits. The obtained
empirical equations, correlating among several parameters, can be successfully
applied to similar deposits.
Nomenclature
A Cross-sectional area of a porous medium, normal to ¯ uid ¯ ow (cm2 )
At Total cross-sectional area of capillary tubes in a porous medium (cm2 )
D Diameter of grains (cm, mm, mm)
Dm Mean diameter of grains (cm, mm, mm)
D10 Size of grains regressed at 10% of weight (cm, mm, mm)
D50 Size of grains regressed at 50% of weight (cm, mm, mm)
D90 Size of grains regressed at 90% of weight (cm, mm, mm)
Gs Grain size (cm, mm, mm)
I Hydraulic gradient (dimensionless)
Kcc Kozeny-Carman coe cient (dimensionless)
L Length of medium (cm)
Lc Length of capillary (cm)
Rc Correlation coe cient (dimensionless)
Shf Shape factor of grains, pores, and pore channels (dimensionless)
Uc Uniformity coe cient (dimensionless)
X i¡n Weight percentage of grain-size fractions (i± n) in a layer (% )
X Variable of the X-axis in the empirical equations of Figures 1± 4 (various
dimensions)
Y Variable of the Y-axis in the empirical equations of Figures 1± 4 (various
dimensions)
Z Depth (m)
a Empirical-equation coe cient in Figure 1 (dimensionless)
g Gravity acceleration (ˆ 981 cm/s2 )
k Permeability (cm/s, m/s, mD, Darcy, cm2 )
kf Permeability of the predominant grain-size fractions in a layer (m/s)
kl Permeability of a layer (m/s)
nc Number of capillaries in a medium
q Rate of ¯ uid ¯ ow (cm3 /s)
rc Radius of capillary (cm)
ss Speci® c surface area (cm¡1 , cm 2 /g)
ssi–n Speci® c surface area of grain-size fractions (i± n) in a layer (cm ¡1 )
ssf Speci® c surface area of the predominant grain-size fractions in a layer (cm ¡1 )
ssl Speci® c surface area of all grain-size fractions of sediments in a layer (cm ¡1 )
L Coe cient of roundness and angularity of grains (dimensionless)
· Viscosity of ¯ uid (Centipoise ``cP,’’ Poise, g/cm.s)
¸ Kinematic viscosity of ¯ uid (cm2 /s)
¿ Porosity (fraction or % )
¿av Average porosity (% )
¿max Maximum porosity (% )
¿min Minimum porosity (% )
472 H. S. Salem
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