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9701 CHEMISTRY
9701/43 Paper 4 (A2 Structured Questions), maximum raw mark 100
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners’ meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2012 series for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level components and some Ordinary Level
components.
Page 2 Mark Scheme Syllabus Paper
GCE A LEVEL – October/November 2012 9701 43
total n(Cl–) = 3.08 or 3.09 or 3.1 × 10–2 mol [2 or more sig. figs.] allow ecf
(iii) moles sampled for the titration = 3.09 × 10–2 × 10/1000 = 3.09 × 10–4 mol ecf [1]
this equals n(Ag+), so vol of AgNO3 = 3.09 × 10–4 × 1000/0.02 = 15.5 cm3 ecf [1]
[Total: 5]
(c) (i) bonds broken are C–H and I–I = 410 + 151 = 561 kJ mol–1 (all bonds = 5731 kJ mol–
1
)
bonds formed are C–I and H–I = 240 + 299 = 539 kJ mol–1 (all bonds = 5709 kJ mol–1)
∆H = +22 kJ mol–1 [2]
[Total: 4]
[TOTAL: 14]
2 (a) catalyst: any two from the following three bullets for [1] mark:
• speeds up/increases (NOT alters or changes) the rate of a reaction
• lowers energy barrier/Eact or offers a lower energy pathway
• is not used up or remains unchanged or does not alter its mass/concentration
or does not appear in stoichiometric equation or is regenerated [1]
[Total: 2]
(b) (i) e.g. car exhausts/engines or aeroplanes or lightning or burning fuels or power stations
[1]
[Total: 5]
(c)
[Total: 3]
[TOTAL: 10]
[Total: 1]
(b) (i) electron / orbitals near ligands are at a higher energy [1]
due to repulsion from ligand lone pairs [1]
(ii) when an electron moves to higher orbital / energy level or is promoted [1]
it absorbs a photon or light (mention of light being emitted negates this mark) [1]
(iii) (different ligands produce) different (sizes of) energy gap or ∆E [1]
[Total: 5]
(c)
V
salt
bridge
Pt
Cu
Fe3+ + Fe2+
Cu2+
[Total: 5]
[Total: 4]
[Total: 3]
[Total: 2]
[TOTAL: 20]
[Total: 2]
(b) (i) (allow structural, displayed or skeletal formulae in (b), (c) and (e))
OH O
OH OH OH
H3CO
HO2C CO2H NC CN
HO
B C D
[1] + [1] + [1]
[Total: 4]
(c) (i) reduction/redox (allow nucleophilic addition or hydrogenation, as appropriate from (ii)) [1]
(iii)
HO2C CO2H
O O
A
[1]
[Total: 3]
[Total: 2]
(e)
O O
H3CO OCH3
HO OH
curcumin
allow
[Total: 2]
[TOTAL: 13]
5 (a) (i) contains a lone pair on N (that can react with H+) [1]
(iii) the lone pair (on N) in phenylamine overlaps with ring or is delocalised [1]
electron density of N is reduced or N becomes more positive or lone pair is less
available [1]
(iv)
N Cl-
H CH3
N
Cl-
H
[1] + [1]
[7 max 6]
(b) (i) NaNO2 + HCl/H+ or HNO2 (HNO3 or NO3– negates this mark) [1]
–10 oC < T Y 10 oC or 'less than 10 oC' [1]
CO2H
N N
or
N N
but NOT N2
[1] + [1]
methyl orange:
(iii) makes the molecule (more) hydrophilic/soluble in water (due to H-bonding or ionic
solvation)
or increases its melting point [1]
[Total: 7]
[TOTAL: 13]
6 (a) It has no chiral centre/asymmetric carbon/optical isomers or is not optically active [1]
[Total: 1]
van der Waals’ ala, gly, leu, ile, val, pro, phe, try, met
hydrogen bond asn, asp, arg, gln, glu, his, lys, ser, thr, try, tyr
[1] + [1] [1 ] + [1]
(candidates can identify amino acids by name, three-letter abbreviation, formula of sidechain
or formula of whole amino acid)
[Total: 6]
[Total: 1]
[Total: 5]
[TOTAL: 13]
7 (a) (i) No. of carbon atoms present in J is 100 × 1.3 = 5 carbons (must show working) [1]
1.1 x 23.5
(NMR spectrum shows) 10 H (atoms present) (no reasoning need be shown) [1]
[Total: 5]
(b) (i)
technique physical method
(ii) 4 [1]
(iii)
X
correct spot circled [1]
(iv) 3 [1]
[Total: 5]
[TOTAL: 10]
Condensation [1]
[max 5]
(b) (i) Need a statement from both columns for [1] mark.
(a) (b)
[Total: 2]
[TOTAL: 7]