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German Andres Diaz Gelves 1*, Hector Rivera Alarcón Uriel 2*,
Julio Isaac Maldonado Maldonado 3*
1
Pamplona University, Department of Environmental Engineering, Pamplona, Norte de Santander,
Colombia
2
Pamplona University, Department of Environmental Engineering, Pamplona, Norte de Santander,
Colombia
3
Pamplona University, Department of Environmental Engineering, Pamplona, Norte de Santander,
Colombia
Abstract
The carbon footprint is useful to estimate the environmental impact of any production system on
climate change, specifically in the emission fixing net greenhouse gas (GHG) medium. This study
aimed to quantify the carbon footprint for production processes in drinking water treatment plants
Water (DWTP) El Portico and Carmen de Tonchala for the years 2016 and 2017 through the ISO
14064 methodologies and GHG Protocol. This was required for the rates of the different inputs, flows
and machinery used in the process. Using the methodology of life-cycle assessment (LCA) the
amount of CO2 eq / m3 / year produced by each plant SMCs methodologies 2001, IPCC 2007, IPCC
2013 and was estimated RECIPE Midpoint. Starting from this, observed that the units are more impact
Coagulation and rapid mixing, desanders, flocculation-sedimentation and filtration give similar
values of CO2 eq kg / m3 in both PTAP for year study (2016-2017), the water flow which gives more
contribution to this impact because it is used for cleaning the same units. Mitigation lies in the sludge
treatment can be performed on each floor, so look clarify the water and separating the solid material.
Keywords: Carbon footprint, life-cycle assessment, environmental impact, Drinking Water Treatment
Plant.
2016 2017
materials Unity Value based on Value based on ecoinvent
UF UF
Power Kwh /
0.007203493 0.005563266 Electricty Mix // [BR]
consumption m3
Aluminum
kg / m3 0.002106122 - Aluminum hydroxide // [GLO]
chlorohydrate
AK-23 kg / m3 0.014077994 0.006139172 Aluminum hydroxide // [GLO]
Gaseous chlorine kg / m3 0.001921479 0.001656483 Chlor-alkali Electrolysis [ROW]
Aluminum Sulfate Aluminum sulfate mix
kg / m3 0.002005805 0.000104951
Type B (production market +) [ROW]
Polifloc Q-2000 kg / m3 0.000059519 0.000063557 Paraffin [GLO]
Superfloc C-576 kg / m3 0.000111343 0.000014281 Polyacrylamide // [GLO]
Activated carbon kg / m3 0.000053201 0.000024748 Activated carbon [GLO]
Floquat FL-2665 kg / m3 0.000032246 0.000032246 Polyacrylamide // [GLO]
Table 2 Inventory primary and secondary sources for DWTP Carmen de Tonchala
2016 2017
materials unity Value based on Value based on Ecoinvent name
UF UF
Power
Kwh / m3 0.044102861 0.081918574 Electricty Mix // [BR]
consumption
Aluminum
kg / m3 0.001017892 0.012189391 aluminum hydroxide // [GLO]
chlorohydrate
Gaseous chlorine kg / m3 0.001499895 0.001214565 Chlor-alkali Electrolysis [ROW]
Aluminum Sulfate aluminum sulfate mix (production
kg / m3 0.004824277 0.009554252
Type B market +) [ROW]
Polifloc kg / m3 0.000023006 0.00005727 Paraffin [GLO]
Superfloc C-576 kg / m3 0.000073671 0.000028581 polyacrylamide // [GLO]
Floquat FL-2665 kg / m3 - 0.000051325 polyacrylamide // [GLO]
2.2.3. Impact Assessment b. Operational control: When the company
For impact assessment "Global Warming (kg has full authority to include and
CO2 eq.)" Indicator was used with CML2001 incorporate its operational policies in the
methodologies, IPCC 2007, IPCC 2013 and
operation.
ReCiPe Midpoint (H) considering the database
Ecoinvent version 3.1 for inventory data of the
The criteria used has been "Operational
processes involved in the study. Finally, the
Control", since the organization has full
last phase of LCA is the interpretation, for the
authority to introduce and implement its
analysis of results and discussion.
operating policies at the operation.
2.3. Carbon footprint
2.3.1.2. Operational limits
The carbon footprint can be determined using Scope 1: Direct GHG emissions
different methodologies, but for this case
study, is calculated by "Guide to the In the first range direct emissions from
calculation and reporting Corporate Carbon
footprint" developed by the District sources that are owned or controlled by the
Department of Environment (DDE), the which company are included. In this sense, it
it is based on the GHG Protocol (greenhouse
defined as follows:
gas Protocol), or GHG Protocol, the NTC ISO
14064-1: 2006 and the matrix defined under
o Inputs and flows
the project " Emission Factors considered in
the calculation tool of corporate carbon Scope 2: Indirect emissions associated
footprint" of Environmental Business with electricity
Corporation (ENBC) and Foundation Natura
Colombia, with support from other agencies. In the second range indirect emissions
2.3.1. Defining Bounds related to electricity that is consumed by
There are two types of limits defined in the company are included.
determining the carbon footprint, which are:
o Electricity
2.3.1.1. Organizational limits
2.3.2. Choice of base year
In this first part can use 2 different approaches
in order to consolidate GHG emissions which A significant and consistent comparison of
are: emissions over time requires setting a
performance basis for comparing current
Shareholding approach: Emissions are emissions; This is called base year emissions.
registered in the proportion that the
company has on different ownership For the choice of base year should consider the
structures. following:
Approach Control: This control can be: The information required for the
a. Financial control: When the company measurement of GHG that year must be
has power to govern its financial and complete.
operatic policies in order to monetize their
activities.
It must be reliable without any alteration 6. Graphics: Definition graphics
display.
that may cause discrepancies with
reality. Using LCA-Manager software analyzed the
following results were obtained for each plant
The selected base year was 2016, since it is the in the respective year
most complete information on previous years
and the most reliable and accurate information Figure 1 Results environmental impact DWTP El
that could be obtained. Pórtico 2016 (Kg CO2-eq)
2.3.3. Identification and Quantification of
Emissions
Results environmental impact DWTP El
This step was previously developed in the life-
Portico 2016 (Kg CO2-eq)
cycle assessment, therefore, once all emission
sources in each scope, emissions in the same 1,60E-01
1,40E-01
category to know what the scope with joined
1,20E-01
were ranked the highest source of 1,00E-01
contamination. 8,00E-02
6,00E-02
4,00E-02
2,00E-02
3. Results and Discussion
0,00E+00
Filtration
Sedimentation
Catchment
Desander
Coagulation and
Disinfection
Flocculation-
Rapid mix
To obtain results in the LCA were supported
software that facilitates this process of
quantification. The tool used in the
environmental assessment is the LCA-
Manager version 1.7, software that allows CML 2001 - Global Warming (kg CO2 eq.)
environmental assessment methodology based IPCC 2007 -Global Warming (kg CO2 eq.)
on life-cycle assessment for industrial IPCC 2013 - Global Warming (kg CO2 eq.)
products and processes. (Simpple, 2010) ReCiPe Midpoint (H) - Climate change (kg CO2 eq.)
Catchment
Filtration
Desander
Sedimentation
Coagulation and
Disinfection
Flocculation-
Filtration
Pumping Station
Break Camera
Sedimentation
Coagulation and
Disinfection
Flocculation-
Rapid mix
Rapid mix
Break Camera
Sedimentation
Coagulation and
Disinfection
Flocculation-
Figure 5 Comparison between inputs and flows DWTP El Portico 2016 vs 2017
Polifloc Q-2000
AK-23
electricity
water
Floquat FL-2565
Sulfloc NR-13
SuperFloc C-576
Activated carbon
Gaseous chlorine
Liquid Aluminum
Aluminum Sulfate
Hydrochloride
Type B
electricity
SuperFloc C-576
FLoquat FL-2565
Gaseous chlorine
Polifloc Q-2000
Liquid Aluminum
Figure 6 shows the contribution of each input camera units breaking, coagulation and rapid
and flow generated in the DWTP of Carmen mixing, flocculation-sedimentation and
de Tonchala for the years 2016 and 2017 is filtration, other inputs provide 1.88% 2016
displayed; in said graph it is seen that the 3.20% and 2017, among which electricity
element with the highest percentage of hydroxychloride liquid aluminum, type B,
contribution is the water flow with 98.12% for Superfloc C-576, Q-2000 Polifloc, Floquat
2016 and 96.80% in 2017. The high impact by FL-2565 aluminum sulfate and chlorine gas.
this element is that is used for washing and
cleaning
Figure 8 Comparison between DWTP by applied methodologies
A graphic comparison was made between of CO2 eq / year also demarcates the
DWTP “El Pórtico” and “Carmen de methodology with the lowest values is the
Tonchala” for year study (2016-2017) was IPCC 2013, being for the 2 plants in the lower
performed, considering the four years of study.
methodologies used to quantify kg CO2 eq;
Globally, the methodologies IPCC 2007 and
reflecting the overall performance indicator
2013 gave results CML in which their values
global warming in Figure 8. In each of the
are minutely different in some inputs or flows
methodologies shows that plant Carmen de
at different stages; RECIPE Midpoint
Tonchala in the year 2016 is the one with the
methodology is slightly lower than the
pinnacle of contamination values above 29
previous two, but still within the range of the
million kg of CO2 eq / yr in 2007 IPCC,
same, giving a symmetry in the results of these
Midpoint CML RECIPE 2001 m, this
methodologies have already named.
methodology because of the large volumes of
water used in washing units over 24 million kg
Figure 9 Scope for DWTP
As seen in Figure 9, the environmental impact According to the above, it should be noted that
is generated from the Scope 1 where inputs companies are able to offset emissions
and flows used in the purification process is; generated by projects that promote emission
much of this impact is due to the use of water reductions; but as such compensation does not
for cleaning and washing units; Scope 2 only reduce the carbon footprint if denotes the
is the flow of electric power company individual commitment that the company has
consumed for operating machines (pumps, with the impact on society and the
electric motors, metering, among others.) that environment seeking to contribute to the
facilitate processes in the DWTP and this global commitment to combat climate change.
reaches less relevant due to poor impact (Spanish Office of Climate Change, Ministry
generated over the first Scope. of Agriculture, Food and Environment., 2015)