Para temp.

Ambiente = 25°C

Tabla de Datos Experimentales

Tiempo (s) Volumen de Na2S2O3 CH2O2 dCa dt Caprom
0 0 0.145 0.01 3 0.14
3 0.1 0.135 0.01 7 0.13
10 0.2 0.125 0.01 37 0.12
47 0.3 0.115 0.01 25 0.11
72 0.4 0.105 0.01 13 0.1
85 0.5 0.095 0.01 20 0.09
105 0.6 0.085 0.01 15 0.08
120 0.7 0.075 0.01 22 0.07
142 0.8 0.065 0.01 11 0.06
153 0.9 0.055 0.055 -153 0.0275

T ambiente
0
-3.8 -3.6 -3.4 -3.2 -3 -2.8 -2.6 -2.4 -2.2 -2 -1.8
-1
y=Ln(dCa/dt) (Mol/L)(seg^-1)

-2
-3
-4
-5
-6
-7
f(x) = 0.650656179294329 x − 5.69795700653143
R² = 0.177117539561965 -8
-9
x=Ln(Caprom) (Mol/L)

Para Temp. fría = 1°C

Tabla de Datos Experimentales

Tiempo (s) Volumen de Na2S2O3 CH2O2 dCa dt Caprom
0 0 0.1069 0.0002 7 0.107
7 0.1 0.1071 0.1072 43 0.1607
50 0.2 0.2143 0.1071 10 0.26785
60 0.3 0.3214 0.1072 13 0.375
73 0.4 0.4286 0.1071 12 0.48215
85 0.5 0.5357 0.1072 11 0.5893
96 0.6 0.6429 0.1071 14 0.69645
110 0.7 0.75 0.1071 13 0.80355
123 0.8 0.8571 0.1072 12 0.9107
 135 0.9 0.9643 -0.9643 -135 0.48215

y=Ln (dCa/dt) (M ol/L) (seg^-1 )

T fria
0
-2.5 -2 -1.5 -1 -0.5 0
k= e^-3.6887
-2

-4
f(x) = 1.94902734757746 x − 3.68870459982735
R² = 0.570827705258722
-6

-8

-10

-12
x=Ln(Caprom) (Mol/L)

Ca vs Tiempo
1.2

0.8
CH2O2

T
0.6 ambiente
T fría
0.4

0.2

0
0 20 40 60 80 100 120 140 160 180
t (s)

K T(K) x= 1/T y= Ln(K)

0.0033526 298 0.0033557 -5.69801911
0.007306 274 0.00364964 -4.91905935

0
0.8 1 f(x) =1.2 1.4 1.6
4.92270898564554
− 5.70137481946508 1.8 2 2.2
4.92635862068204
x + 5.70473052416307
R² = 1
-1

T ambiente
-2
K)

Linear (T ambiente)
 1

0
0.8 1 f(x) =1.2 1.4 1.6
4.92270898564554
− 5.70137481946508 1.8 2 2.2
4.92635862068204
x + 5.70473052416307
R² = 1
-1

T ambiente
-2

y= Ln(K)
Linear (T ambiente)
T Fria
-3 Linear (T Fria)

-4

-5

-6
x= 1/T
x=Ln(Caprom) y=Ln(dCa/dt) Tiempo (s) CH2O2
-1.96611286 -5.703782475 0 0.145
-2.04022083 -6.551080335 3 0.135
-2.12026354 -8.216088099 10 0.125
-2.20727491 -7.824046011 47 0.115
-2.30258509 -7.170119543 72 0.105
-2.40794561 -7.60090246 85 0.095
-2.52572864 -7.313220387 105 0.085
-2.65926004 -7.696212639 120 0.075
-2.81341072 -7.003065459 142 0.065
-3.59356927 -7.930860015 153 0.055

n=0.6507
k=e^-5.698
k=3.3526x10^-3

x=Ln(Caprom) y=Ln(dCa/dt) Tiempo (s) CH2O2

-2.23492644 -10.46310334 0 0.1069
-1.82821601 -5.994259146 7 0.1071
-1.31732816 -4.536577395 50 0.2143
-0.98082925 -4.798008388 60 0.3214
-0.72950001 -4.718898951 73 0.4286
-0.52881989 -4.630954303 85 0.5357
-0.36175928 -4.873049631 96 0.6429
-0.21871587 -4.798941659 110 0.75
-0.09354174 -4.71796568 123 0.8571
-0.72950001 -4.941627608 135 0.9643

n=1.949
k= e^-3.6887
k=0.502228542

Tamb = 25ºC +273 = 298K

Tfria = 1ºC+273 = 274 K

In K = In(A) -

y=b-mx….... (3)
A=eb ………. (4)
Sustituyendo valores en 3 y 4
E=-(-1408)(1.987cal/mol*K) = 2798 cal/mol

A=eb=e-2.6456 = 0.07096 (mol/l) seg-1