Understanding Naphtha and Ethane Cracking Processes

By: Frank Caprio | On: June 6, 2017

Let’s investigate naphtha and ethane cracking.

Ethylene – because its molecules have very distinctive and useful chemical properties – is
manufactured in greater amounts than any other chemical. The majority of ethylene is produced
using a process called “steam cracking”, a thermal process where hydrocarbons are broken
down, or “cracked” into smaller molecules that are then used to manufacture more useful (and
valuable) chemicals. In the petrochemical industry, two of the main feedstocks for steam crackers
are naphtha and ethane.

Naphtha is primarily derived from crude oil, while ethane is more prevalent in natural gas
and natural gas liquids (aka NGLs, a mixture of various hydrocarbons often co-produced along
with natural gas). Steam cracking these hydrocarbons is accomplished by first mixing them with
steam, then running them through tubes in a cracking furnace where the feedstock is briefly
heated to very high temperatures. The cracked feedstock is then rapidly quenched (cooled) to
stop the hydrocarbon molecules from being completely consumed. The resulting product streams
are separated and purified, leaving valuable compounds called “olefins”: ethylene, propylene, and
others. These olefins, or monomers, are then processed so they form chains of molecules called
polymers – plastics with varying properties and uses. Olefins are a group
of petrochemicals, because they are derived from petroleum and/or natural gas.

Before hydraulic fracturing revolutionized the way we produce natural gas and NGLs in the U.S.,
most steam cracking furnaces used naphtha as the primary feedstock. Because oil prices were
much lower overseas, many U.S.-based steam cracking plants were forced to close, as they were
simply not competitive on a global scale. This all changed when hydraulic fracturing shale
formations provided inexpensive and plentiful supplies of natural gas and NGLs, which are rich in
ethane. American petrochemical manufacturers are now very competitive globally and are
expanding ethane cracking capacity.

Steam cracking furnaces for ethane are similar to those using naphtha. In fact, many U.S. steam
crackers are designed to run either feedstock. However, the actual cracking reaction must be
carefully tailored depending on the composition of the feedstock as well as the desired end
product. The temperature in the cracking furnace, the residence time of the feedstock, and the
quenching process used all affect the quality of the produced hydrocarbon stream. Once the
feedstock has been cracked, the product stream must be purified and separated, using various
processes depending on the feedstock. These furnaces must occasionally be de-coked, which
requires injecting flammable gas into the furnace in order to burn residue (coke) off of the tubes
carrying the hydrocarbon feedstock.

Regardless of the feedstock (naphtha, ethane, propane, butanes, kerosene, et al), steam
cracking requires vast amounts of energy. In fact, it is the single most energy-consuming process
in the chemical industry. Most of this energy is used to create the steam and the heat in the
cracking furnaces, but energy is also required for pumps, quenching towers, heat exchangers,
compressors, condensers, cold boxes, distillation towers, decoking operations, and many other
processes. Because of the sequential heating and cooling of all of the different process streams,
there is quite a bit of thermal expansion and contraction in the piping systems that connect this
equipment.

These piping systems must have a way to prevent the stresses that are created from thermal
expansion from being applied to the piping system. If these stresses acted on the piping system,
then cracks could develop, allowing dangerous product leaks. A metal expansion joint is perfectly
suited to accommodate these thermal movements, thus preventing the associated stresses from
acting on the piping system. But the expansion joint must also be properly applied into a well-
designed piping system, where pipe anchors and guides are used to control the stresses being
applied to the expansion joint. One fire in an ethane cracking facility in Japan was the result of a
pipe guide that malfunctioned, which did not allow the pipe to expand properly. The pipe then
cracked, leaking ethylene into the furnace, resulting in a huge fire.

Expansion joint salespeople must not only be familiar with the products they supply, but also with
how those products work along with the rest of the components in a properly designed piping
system. Accordingly, we spend a lot of time discussing piping system components such as
anchors, guides, supports, and hangers in Hose Master University. Any expansion joint must be
installed in a properly anchored and guided piping system in order to perform as designed. Still
not sure about the performance requirements of the intended application? That’s why we’re here.
Contact us today if we can help you to survey the piping layout. Call us at 1-800-221-2319 or
through our website at hosemaster.com today. Let’s get cracking!

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