NH3 pNH3 s log(s)

5 2.54919E-08 -7.593597794
4 2.54919E-07 -6.593597794
3 2.54919E-06 -5.593597794
2 2.54919E-05 -4.593597794 pNH3 vs l
1 0.000254919 -3.593597794
0
0.5 1 1.5 2 2.5 3 3.
-1

pNH3 log(s) -2
5 -7.5936 -3

log(s)
4 -6.5936 -4
3 -5.5936
-5
2 -4.5936
-6
1 -3.5936
-7
-8
pNH3
 pNH3 vs log(s)
0.5 1 1.5 2 2.5 3 3.5 4 4.5 5 5.5

log(s)

pNH3
Ci u gamma Pb2+ gamma Cl- Ksp, activity s
0.01 0.015 0.82819059059388 0.95202777205 1.340383E-05 0.023754339
0.1 0.15 0.6766210996668 0.89869202776 1.033726E-05 0.021783874
1 1 0.57056144745081 0.85216347766 7.04364E-06 0.019168982
0.001 0.0721 0.72588354477597 0.91746039137 1.132148E-05 0.02245438

[KNO3] = 0.001M
Iteration [KNO3] /M [Pb2+] /M [Cl-] /M Ionic strength gamma Pb2+ gamma Cl-
0 0.001 0.01916898244319 0.03833796489 0.0585069473 0.740129538 0.9226085
1 0.001 0.02204265315715 0.04408530631 0.0671279595 0.730757707 0.9192351
2 0.001 0.02189568424795 0.0437913685 0.0666870527 0.731207245 0.9193981
3 0.001 0.02190276164014 0.04380552328 0.0667082849 0.731185529 0.9193903

[KNO3] = 0.01M
Iteration [KNO3] /M [Pb2+] /M [Cl-] /M Ionic strength gamma Pb2+ gamma Cl-
0 0.01 0.01916898244319 0.03833796489 0.0675069473 0.730373649 0.9190958
1 0.01 0.02188963552298 0.04377927105 0.0756689066 0.722589135 0.9162528
2 0.01 0.02176658720528 0.04353317441 0.0752997616 0.722922519 0.9163753
3 0.01 0.02177187447339 0.04354374895 0.0753156234 0.72290816 0.9163701

[KNO3] = 0.1M
Iteration [KNO3] /M [Pb2+] /M [Cl-] /M Ionic strength gamma Pb2+ gamma Cl-
0 0.1 0.01916898244319 0.03833796489 0.1575069473 0.673428724 0.8974204
1 0.1 0.02096898864022 0.04193797728 0.1629069659 0.671234724 0.8965424
2 0.1 0.02093252672949 0.04186505346 0.1627975802 0.671278362 0.8965599
3 0.1 0.0209332526897 0.04186650538 0.1627997581 0.671277493 0.8965595

[KNO3] = 1M
Iteration [KNO3] /M [Pb2+] /M [Cl-] /M Ionic strength gamma Pb2+ gamma Cl-
0 1 0.01916898244319 0.03833796489 1.0575069473 0.568112931 0.8509715
1 1 0.01995296942199 0.03990593884 1.0598589083 0.568016505 0.8509245
2 1 0.01995296942199 0.03990593884 1.0598589083 0.568016505 0.8509245
3 1 0.01995296942199 0.03990593884 1.0598589083 0.568016505 0.8509245

Variation of solubility with ionic s

Ionic strength Solubility / M
0.0225
0.0667 0.0219
0.0220
0.0753 0.0218 0.0215
0.1628 0.0209
Molar solubility /M

0.0210
1.0599 0.0191 0.0205
0.0200
0.0195
0.0190
0.0185
0.0180
0.0175
0.0000 0.2000 0.4000 0.6000 0.80
Ionic strength
 0.0200

Molar solu
0.0195
0.0190
0.0185
0.0180
0.0175
0.0000 0.2000 0.4000 0.6000 0.80
Ionic strength
 s
0.022043
0.021896
0.021903
0.021902

s
0.02189
0.021767
0.021772
0.021772

s
0.020969
0.020933
0.020933
0.020933

s
0.019124
0.019122
0.019122
0.019122

n of solubility with ionic strength

00 0.4000 0.6000 0.8000 1.0000 1.2000

Ionic strength
00 0.4000 0.6000 0.8000 1.0000 1.2000
Ionic strength