Di

isobutyl Aluminium
Hydride
6 . DIBAL H -

IDIBALIDIBAH
Electrophilic Reducing Agent
cb
Highly selective R.A .

④ Temp selective to
mini reg -78°C
High Temp
.

,
t
Reactivity
structure
Ci Bu )z
-

H -

Al -

f) Tt
H -

Al monomer

OH y> n "
"
H
Al
Ae

''
I Dn Ole
l
ly TL Dimer
Al

\
X
/
Tri Iso
butyl -
-
-

TIBALITIBALITIBAH
Solved
Hexane
, xylene ,THf , Benzene
 Mech :
TL
-%
: :

H Ae + ri
-

R -
-
o -

Lewes Lgd *

Acid I
Greaten
.

IBU

H -
Alb
to
1
iBy
415

£10 -

R
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t
fit
.

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-

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Ae
'
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Lewis
rid
Riggio - R
' r

In
is
T
in
H

a- OF
④ "

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d R' o_O t r -
- H + -

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fat
*
Bath .me, # and
only Rto -

H
He

In
'' ' '
 Functional conversion
group
Reaction conditions

:/ I
conversioneguiofDIBAL-HTemfr.ci
- H →
High) Raton
OHM
1 RT

R
-
% -

p
'
→
R - c' H -

R
'
I HTIRT

:÷÷::::÷÷ .
: :Ia:
R -
¥ -
OH → R -
di -
H
z LTI-78°C

R -
% - o -

R
'
→ R -
% -
H 2 LTI -782
°

LTI -78C
'
R EN-
→
R - d te Le

.cm/
-

R - CIN → R -

UIzNHz 2 LITRE
± no .

I:*:S: : .

Ester →
allylic 2
LTI -781
alcohol
a- I are
,
-9 -

um ,
Y
in Toluene

+708

E H
DEAF
②
q-cH=oH
- -

-170°C

¥
ffH
③

Burns DEATH ¥
easily
by "'

II:
watch # AID
H
O

camphor
⑥ -
Coon BACH

+60°C

⑤ CHEF -0-9133 BACH

f 110°C in Hexane

⑥
IE -
on

- 70°C
H

⑦
JEo -

ab
-70C
H

o o

⑧ BATH 4th on

-78°C
a
#
xylene
 →¥CiB% Aetius
Tg HR

ate -

t
f
Cl

f
is:O:

O
o

Ith HH
I
(
o_O
Hzo④
TH ←
ax

⑨ Whoa 2¥BAlH
-79°C
Toluene

⑥
#Ioet → we

Toluene

,tg¥" as::÷÷e
'
'
④ as
-
⇐ n air
.

,iB4
2g
DIBAL Al 's ,oByHz0④
④
NI
.

→
CEN →
atzatz
ay
-

-9134
+80°C Ae gets
1,934 Utz

Lotta
 Replace -

CN with -

CHO

UY it
'

BACH
EX 2g
-
.
DI

⑤ \ .gl -78°C

Aromatic at
N leg
DIBAL
④
.

-
- →
1-
↳ - H Toluene
-76°C
Ctb

at
④
BA '
⇐ -76°C

Benzene
 7 .
seoz (selenium dioxide)

No
Grp range
0 0

oxygen family
.

s
-2 to -16
Se

Te
Po
⑨
Highly specific oxidising agent ④
⑨ Electrophilic o .
Ao

Addition
cyclic
Cd , its
Allylic oxidation
495
Allylic Hydroxylation
ii. is
dehydrating agent
is
catalyst
preparation : set 02 → sees

Burnin Bwse flame e

fo
-
off
solvents weak acids

optimum
around pro
Temp
-
c
① oxidation
of at group .

Cama )
" "

RILEY OXIDATION

r -
% -

ab
# R -
'
d -
e
- H
A- colt 11
0
too -

140°C

Mechanism

:p
r-I-iqif.se
H
=
:L
E'
ki
.

⇐ .

o
④ -

H ④ o¥µoAo I
fill '

discusses
" + H⑦
R
Shou
-

' - ← ,
c .

HAHA Se
replace

_Hgekdm@
AMU with o
f o

1130+0
,

ix#oH→R-k
o
O

d
'
r -

'
Il
H o

Secombe
①
FI Eats
-

¥1
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too e

⑨
Ii:: . :*
( hoc )
Dimethylnote
make

see
③ ,

1202

Sells

⑨
¥I* .

camphor

⑤
98°C