Materials Science and Engineering (CHMT 2016/CHEM2007) 2.) _ Describe the equilibrium cooling process by using a table format of the following Ti-Ni alloys as they slowly cool from 1400 °C to room temperature. List the: temperature, the reaction occurring, the phases present, the amount of the phases, the chemical composition of the phases. Sketch the expected microstructure at each temperature: a). Ti-33 wt% Ni [1400, 960, 942, 765°C) Top, Prone Compe, Ante 100. L 33 ut Ni 100% L_ ww L 30 8 38533. 85. cash Lee ~ Thi 38 Bese 7 eer RS BL - 9) \ 4y24AT OL 24 ThNi ae “4y2-at T,Ni 38 [ars | B IBEW Liq, > TaNi+ B H5+aT TiN c eudecto’ % Ono sat A> bid | . = By. 50 at.% Ni [TSIO, 900, 630°C] (3104 AT ee 50 tet Ni eee A eee Coy Ne 630 +4T “ Z igNi p> 28-88 = Bs 61% 1i cao-at TiaNi 84 ae Bese = i BTM eukectoid TiNi, 78 SB = UI TG Nig : 2. TINi > Tigi + TIN: oteeso iS are bare g - of < . TN a EG Ni EB B- ms OTN 76-328 42 TiNig 35 aanMaterials Science and Engineering (CHMT 2016/CHEM2007) 3) Fillin the table below listing all the INVARIANT points on the Ti-Ni phase diagram. For each point, list the composition and temperature of the invariant point, what kind of invariant itis (e.g. eutectic), and the reaction equation ON HEATING. show + label your points ON the phase diagram on pg. 3] no Temperature RMN) Kind of reaction Reaction on heating ( 1bto ° Pare. metal melas Tits) > Tile) 2 8, ° eo eae eee |e Tome ails 3 FOS” AS | Ectectoid Ti+TaNi > AT 4 942 2 Erdeectin. bi+TaNi2> L S| 94 | 34 | Rritectis Ti Ni -> be Tins G 630 50 Ekectoidl TieNi + TiNis > t 1310 50 Conaruente mp. | TN > Le S (US bl Eidectin TINI+ TiNig > L 4 (380 FS Congruent> mp. | TNis > Lb fom Mrs ioeem Exdocticn TiNig (Wi) > L (| 1455 | 100 | Pare metal mp.) Ni m> Ly:Materials Science and Engineering (CHMT 2016/CHEM2007) Student number: °C Temperature, Atomic percent nickel 30 40 50 60 70 80 90 100 Weight percent nickelMaterials Science and Engineering (CHMT 2016/CHEM2007) PHASE DIAGRAM ASSIGNMENT Student number: 1) Analloy of Ag - 60wt% Pd (i.e. 40wt% Ag & 60wt% Pd) is slowly heated from 900 °C. (NOTE: "Slowly heated" = "heated slowly enough to maintain thermodynamic equilibrium”.) a) At what temperature does the first liquid form? (320°C b) What is the composition ofthe first liquid to form? 42.5 wth fol c) At what temperature does the alloy completely melt? 1380. {4} What is the composition of the last solid to melt? 7 Sot PA pS; NB Describe the freezing process of a Pd-10wt%Ag alloy as it slowly cools from 1500°C to 900°C. TOURS Temp Phase Composition — Avouat= Tar IS10 atrAls L Aut Pol oohL orig 8 “Bo-aT SAG uth bl > GL > oN ChgyPl) Ae ot POL 86 ——— ML = 28 2 © S00 L . -—-%6 %L. Bow B= 88 (4 dt) —492 ——~—— w-« -4& _ _ . _ tree 6 © WeoraT Le 2% ——%L = 205-90 a) — st 9S 82 (s, yo4 a ee OS-82— 4S0-AT (Rl) 2%, al Too % (hg, PA) =. or 10" alMaterials Science and Engineering (CHMT 2016/CHEM2007) 3) What is the maximum amount of Ag that can be dissolved in liquid Pd at 1300 °C while maintaining a single phase? v43.5Pd, . % bg. 2565 4). What is the equivalent atomic percent (at.%) of the following Ag-Pd alloys: a). 25wt%Pd 26 at.% Pe b).65wthPd Go [NB. Show your working out] Ag-Pd Atomic Percent Palladium 8 w 2 , 9 4 0 60 , 7 9 9 100 1600. + 1500 Z £ 2 200 I : f 00 t E t 000 sees: E a we 70 Ag Weight Percent Palladium Pd