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SAFETY IJATA SHEET
acc. to 91/155IEWGand 2001/58/EG
Date ofPrfnt: 09.05.08
Rev/$ed on: 15.05.2007

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Designation of Product 1
Name of Product: BATTERY (wet, filled with acidt
- Type
- Voltage
AGM,GIS, OGI, OP%S.PzF, PzS
2 Vorts/ 6 Volts 112 Volts
- Electro-Chemlcal
System Lead,sulpl'1uric
acid
(This product does not constitute a substance or a dispensation according to the Lawon Chemicals.)
Application of Product: Industrial batterie or stationary batterie
Manufacturer 1Supplier: Banner GmbH
4020 Linz/ AUSTRIA. SalzburgerStra~ 298 1BannerSIr.1
Tel. +43'732 13888 - 0
Fax +43/732/3888 21299 -
Infonnation Field: Department for Operational Safety
Tel.~3/732 '3888 21209 Fax +43/732'3888 - - - 21299
Department for Transport
Tel.+43'732/3888 - 21327- Fax +43'732'3888 -21398
Emergency Infonnation: Information Center for Poisoning
Tel. +43/1/4064343

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Designation of CA$-No. Contènt EINECS-No- Code R-Rates


Substance <D Letter
rm-%l
Lead 7439-92-1 approx. 231-100-4 T 20/22; 33; 61;62
50
Lead Oxide 1309-60-0 approx. 215-174-5 T;N 20122; 33; 50/53; 61; 62
20
Sulphuric Acid 37 m-% 76493-9 approx. 231-&9-5 C 35
20
POlypropylene -- apP(O;JII;.-- -- --
10
Q) referring to the tot01lweight of the battery

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- When Intact starter batteries ara bandled in a Drocer manner. there are no hazards for people or for the
environment.
- If the casing breaks, sulphuric Bcid may escape danger of chemical burns. -
- Fire hazard.when thereis a shortcircuitof the poles.
- When the reguletions for electrlcal recharging of the batteries are disregarded. there is a hazard through
the formationof hydrogel'l(cs5ingmayburstand dangerof explo~IC'ln).
- Hazardouscorrosionproducts may form If there is a fire (sulphurlc acid).
- It is absolutelv safe ta comcliment !ne electro1'lte levai with Durified (distille<!)water.

Ela""e, GmbH' A,..t020Linz' $ul:!'t>urgm- SI~Be 2!'!B . .


Tel. ..431732' 3B8a-O FIIX +43 1732 1 :)88!!-299
Fax reçu de : 1 16-EJ9-EJ8 EJ8:Z1 Pg: Z

PI'Ig& :?of 7
SAFETY DATA SHEET
acc. to 91/155/8NG and 2001/58/EG
Dat~ or Print:' 09. OS. 08 Revissd on: 15.05.2007

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o1~::"~I~~!'~"O~M~sÜà~~:.:Fp:~'.Ç9HtACTWITH;AJ~ld..
0 GENERAL NOTES
- Immediately remove clothing soiled with acid.
0 AFTER INHALING
- Brlng wounded person out of the danger zone to fresh air, consult s doctor.
- Keepthewoundedperson in a quiet resting position and prevent hypothermia.
- Allow a semi-seated position if shortness of breath occurs.
- Facl1itate the inhalingof Dexamethason-21-isonicotinat (e.9. Auxilo50n-can of aerosol) as soon as
possible:
4 strokes to start with, then two more strokes every five minutes until the firSt package is empty.
ln the following, one stroke every hour.
- For unconscÎousnes5 with continued breathing, tind a secure sideways position.
- Conduct mouth-to-nose resusitation when breattling stops, if this is not possible conduct mouth-to-
mouth resusitation.
Keep respiratory tracts clear.
- ln the evant of œrdlac arrest immediately conduct heart-Iung resusitation.
D AFTER SKIN CONTACT
- Remove moistened clothing as quick as possible, thereby heeding self.protection.
- Rinse main areas affected for ten minutes with running water.
- Dabconcentrated acid with dry cellulose or textile substance beforehand. aS it reads Intensely with
water under strong hest development.
- VVhenpossible, apply a flood-shower after large-scale moistenlng, or rinse otherwlse with large
quantities of water. Then rest the wounded person motionless and warm.
- Consult a doctor.
:J AFTER eYE CONTACT
- Rinse the eye - protecting the unharrned one - for at leas1 ten minutes with running water and with
the eyelids wlde open.
- Direct a m!ld jet of water at the eye in order to remove acid residue as quickly and completaiy as
possible. >

- Consult aldoctor.
0 AFTER SWALlOWING
- Rinse mouth. spit out the liquid,
- Immediatelyprovide1 or 2 glasses of water (milk or tea) for drlnking.
~ Do not try to neutralize with leaches 1do not apply A-coa!!
- Do not facilitate vomitting.
- Cali the EMT to the site of the accident.
- Shouldthe personaffectedspontaneouslyvomit, hold the person's head low to the stomach, in
order ta prevent vomit from entering the wlndpipe.
Absolutèly ensure rapld medical care.
0 NOTES FOR THE DaCTOR
~ Informthe doctor about substance f product and conducted measures.
- Dangerof stomachperforation.

Benne.GmbH' A-4020Linz . SBlzbU1'O~'


Slral!.o3
2'38 . Tel.+4311321:1888-0
. Fa\(+43/73~13888-;;199
Fax reçu de : 1 16-1:19-1:18 1:18:21 Pg: 3

Page 30f7
SAFETY DATASHEET
acc. to 91/155/EWG and 2001/58/EG
Dafe of Prim: Qg. D5, 08 Revlsed on: 15.05,2007

, ~.M!ASiJRÉS :F~:R:F1:~~JiFI~H'11NG ;':

-
- Alicommon fire-fightingsubstances Bresuitable,
Preferably foam. carbon dioxide, and fire-fightlngpowder.
- Adàpt fire-fightlngmeasures to the surroundings,
- Beware of acids escaping fram boxes which have caught tire.
- Possibilityof hazardous corrosion products (sulphur trioxide)forrning,

0,.'6.;. "';Mr~iASlsRES
'r:OR' ÜNI:NtENTIONAL'RELt:ASE '

ln order to remove the hazardous situation, the danger zone may only be acoessed with approprlate
protective measures,
CJ lEAD 1LEADOXIDE
- Absorb mecl'lanicallyand avoid dust.
- Collect absorbed substance in container.
- Do not bum waste containing leM oxide.
- Absorb the spread substance with moisture immediatelyand do not carry It into other rooms.
- prevent penetration of underground or bodies of water.
CJ SULPHURIC ACID
- Do not allow it to enter thé sewage system or bodies of water.
- Dilute wit/1water and than neutraliZè it with, e.g, sodium hydroxide. sodium carbonate, or calcium
carbonate (Caution! Strong fonnation of C02 wt1enapplying carbDnates)
Altematives:
- Absorb with calcium or water.free soda and store in closed arrangement until disposaI.
- Immediately cleanse moistened surfaces wlth large amounts of water.
Q POLYPROPYLENE
none

':,
0,'

O'1.'0~~~'pltNG:'AN()'~TORAGE'.
CJ HANDLING
- Do not throw or tilt batterie,
- Effectively prevent a short-circuit of the battery poles.
- Heed the loading regulations of the battery manufacturer when loadlng batteries.
- 8eware of the guidelines when installing it inta vehicles (polarityl)
CJ STORAGE
- No specifie storagé requrrements for up-and-funning batteries.

Bann(ar
GMbI-I. A.41120
Un:r. g!ll"burgêr
Stl'tl~2gB' Tg!.+4~173213880-0. Fax+43/7321JBaB-299
Fax reçu de : 1 16-1)9-1)8 1)8:21 Pg: 4

Pag$40f7
SAFETY DATA SHEET
acc. to 91/155/8NG and 2001/58/EG
Date of Print.' 09.05.08 Revl:.edon: 15.05.2007

...' à "L~Mlt4TI()N ~c>~ .~)(~~~t1~E... A~t)P.ERSONÂ~:.~~q~~*IY~{~~A.:~.: . ...

0 LIMITATIONOF EXPOSURE
not applicable
0 PERSONAL PROTECTIVE GEAR FOR HANDLING BATTERY ACID
- HAND PROTECTION
. Use protective gJoves.
.. The material of the gloves must be sufficientlyresistant to the applied substance.

.
. Ch~k tightness before use.
Heed skln protection.
Pre-Rlnse wom gloves before removing them; store them in a well-ventilated manner.
~ Prevent skin contact.
- EYE PROTECTION
. Use WÎcker-goggles.
0 GENERAL PROTECTIONAND MEASURESOF HYGENE
- The common cautionary guidelines for handling chemicals are to be abided.
- Prevent skin f eye f clothing contact.
- Prevent breathing in vapOr!~L
- Wash hands before breaks and at the end of work.
- Consuit a doctor when experiencing health concerns.

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pf{Q~~RrJÊ$.
Closed caslng for code-substance with connecting peles
0 ADDITIONAL PHYSICALANDCHEMICALPROPERllES
not applicable
0 OTHER FEATURES
Electrlcity storage (\loltage. capacity)

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, 1o.~~t~~rL:i,tf;ÀND;REACfh/:Î:Tv:: ..

0 HEED THE ElECTRIC LOADING AND MOUNTING GUIDELINES OF THE BATTERY MANUFACTURER

0 PLASTIC CASING
- Melting point of the plastic casing: approx. 160~C
- Point of inflammabilityof the plasticcasing: approx. 380.C
I:J SULPHURICACIOIBATTERYACID
- Corrosionof sulphuricacid above33S.C.
- Sulphuric acid corrosion products: sulphur trioxide.
Q LEADJLEADOXIDE
- Corrosionof leadoxideabove300°C under seperation of oxygen.
- Corrosion products: oxygen.

S3nnerGmbH' M02C1linz . $aI~bu'ger Stml!è 2ge .


Tel. +43/ 732/ ~e8e-o . F8X"~ J 732/ 38811-299
Fax reçu de : 1 16-B9-B8 B8:21 Pg: 5

Page50(7
SAFETY DATA SHEET
acc, to 91/155/EWG and 2001/58/EG
DatfJ of Print D9.OS.DB Revised on: 15, ()5. 2QQ7

11,:.1"OXj#()~O(jy
>IJATA.'

No toxie agents will be released during proper use and when abidjng the guidelines of the battery
manufacturer.
[J SULPHURIC ACIOI BATTERY ACID
Acute Toxicity
- LDILC50values relevantto rating:Oral LD50 2.140 mg.kg.'(rat)
1

- Irritatingand caustic effecton mucousmembraneandskin.


1

-
Dangerof severeeye andlungdamage.
Dangerofperforating
~ oesophagusand stomachwhen swallowed.
CJ LEAD1LEADOXIDE
~cute IOxiCi!ï
- Gastro~lnte5tinalmalfunction
- ZNS malfunction.
- Harmto blood.
- Signs of intoxication through inhaling or oral întake:
sweet-metalic taste, flow of saliva, vomitting.
Q POLYPROPYLENE
net applicable
Also reterto informationunderparagraph2,

',"
'1'2.'eb6i6GY"OATA:

No ecologicalagents will be releasedduling proper use and when abiding the guidelines of the battery
manufacturer.

I:J LEAD 1LEAD OXIDE (surrounded by sulphurlc acld 1battèty acid)


- Highly poisonous to water organisms; can have a harmful èffect on bodies of water over a long
period of Ume.
- WGK 111:high hazard to water.
CI POL YPROPYLENE
Not applicable

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0 PRODUCT
- Do not dispose product along with household refuse.
- Transfer to licensed disposai company,
- Afteruse, the product must be forwarded to recycling.
- Numbers of the keys for disposai: ÙNORM S 2100 Key Number 35322
LAGA-Code35322
EWC-Code 160601

a~ronerGmbH. A-4020Linz . S31:tburger


Slml!&298 . iet.1-43/732, ~!l88-0. ~RX"'~'732f 388S-:2r19
Fax reçu de : 1 16-69-68 68:21 Pg: 6

~
Page (jOf 7
SAFETY DATA SHEET
acc. to 91/155/EWG and 2001158/EG
Dete Df Prin(: 09.05.08 Revlsed on: 1!3.05.2007

,~4~r~~à~~~tA1(ON
'G9k1~L.N~~:"
Used batteries which are to be retumed or transportedto disposai, must be thoroughly inspectedfor
damage and transport-sptitude. in order to ensure the integrity of each battery and its suitability for
transportation.
0 ADRIRIC(AC ROSSBORDERSJ DOMESTIC)
LANDTRANSPORTATION
ADR/RID Grade: 8
Classification code: C11
Kemler Number. 80
UN Number: 2794
Hazard Notice: 8
PaC:kaglng Group: none
Designation of Goods: BATTERIES (ACCUMULA TORS), WET.
FILLED WlTH ACID, electric collector
Special Regulations: 295 and 598

0 SEA.VESSELTRANSPORTATIONIMDG
- IMDG Grade: 8
- UN Number: 2794
- Packaging Group: none
- Marine pol1utantstatus: no
- EMS Number: F-A. 5--8
- MFAG: 700
- Proper
Tec;hnÎœl
Name: BATTERIES, WET, FILLED WlTHACrD,elec1ricstorage
- Special Regulatiol"ls: 295
r:I AIR TRANSPORTATIONICAO-TI ANDIATA-DGR
- ICAO/IATAGrade: 8
- UN/IDNumber: 2794
- PackaglngGroup: "one
- ProperTechnicalName: BATTERIES.WET, FllLED WlTH ACID, electric storBge

0
.
'~5~:t~~:~~~~:O~~I~;U~~~~~~~~~~~),
HAZARD $YMBOLS AND HAZARD DESIGNATION

C Caustic:
Il
E Danger of Explosion

DETERMININGCOMPONENTS OF HAZARDS FOR LABELLING


- Lead J lead oxideand sulphuricacid 37m-%f batteryacid
R-RATES
.

. .
T Poisonous N Environmental Ha4i:ard

- R20122 Health hazard when int1aled Or swallowed.


- R33 Dangèr of cumulating effect.
- R35 Causes severe chemical bums.
- R50/53 Highly poisonous to water organisms, can have damaging long-term effects on bodies of
water.
- R61 May cause harm to children in the womb.
- R62 May be detrimental to the ability to reproduce.

B!lM'"C..."bH. A-40::!o
Linz . SaIZDutOe1 StI'tlBe 2êB .
T"I. +4317:32 /3BàB-O .
Fax +431732/3881\.,299
Fax reçu de : 1 16-B9-B8 B8:Z2 Pg: 7

Page 7 of 7
SAFETY DATA SHEET
acc:. to 91/155/E\NG and 2001f58/EG
Date of Print.: 09.05.08 Rf/visec! on: 15.Q5.20Q7

CJ S~RATES
- 8D1/02 Sealed s.orage and keep ovt of the reachof cl'1ildren.
- 826 After eye contact, immedlately rinse with water thoroughly and consult a doctor.
- S35 Waste and containers must be disposed of in a securemanner.
- 845 ln case of an accident or of health concems, îmmediately cali upon a dacter (present this
label if possible).
- 553 Avoid exposure - obtain specifie instructions before use,
- S60 This product alol"lgwithits containermust be dlsposedofas ha%ardouswaste-
- 861
Prevent release into the environment. Obtain specifie instructions 1 consult the safety data
sheet,
1:1 NATIONAL REGULATIONS
- The classifiC<ltion aCCOrding to the Austrian ChemG BGBLNo- 153/1996 and
ta the ChemV BGBL. 1196/1994 are equal to the classification of thé EU guidelines.
a CLASSIFICATION ACCORDING TO VbF
does not apply
Heed officiai reaulations for storaae and handlino.

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0 RELEVANT R-RATES
- R20/22 Health l'1azardwhen inl'1aledor swallowed.
- R33 Danger of cumulating effect,
- R35 Causesseverechemicalbums.
-
R50/53 Higl'1lypoisol'1ous to waterorganisms,can havé damaginglong-termeffectsonbodies of
water.
- R61 Maycause hann te chîldreninttlewomb.
- R82 May bedetrlmental te the abîlityto reproduœ.
0 REGULATIONSFOR SAFE HANCLINGOF BATTERIES
-
to be displayed by exhibitor.
0 DATASHEET ISSUING
- Department for Safety Bnd EnvironmentalTechnology of the Banner GmbH company.
CJ CONTACTPERSON1INFORMATION AGENT
-
DepartmentforOperationalSafety Mr.lng. Gleissner Tel, "'43/732/3888 21209 -
- Departmentfor Transport Mr. Klammer Tel, +43 1732/3886 - 21327
The classification equals the current EC guJdelines, however, it is supplemented by remarks from
professionallitera'ure and by company detaîls.

, i;
.:Th~,d~t~~I~~:nd'~~~~~:1~~a~;;:~~~~~~~::~~:t~~~~e:~t~;;~1~~~~'t~':~~rGstu~~ .'.

8annar GmbH . A-40~O U!1:!' . galzbu'lIGr SII'9Bo 298 .


Tel. +4~ /732/3838-0 . "''''' ""3/732138a!l-:2~9

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