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,..0.!~Jt-1!!.~J.__3...

_
~..- .,- ......·-----·-···-··----- ........-•-·-····---· ...··-..··-·
NG"U . 2 O 18 .•.
; -·---·---···-··-··•..·••·....
i ( Non metallic enture base materials
''
i
I• Aery Ic res!,!J s material of choice as they have required esthetic quality, cheap & are e asy to

I
l,, •
pro<ess..
R ~rements for ideal denture base:-
'-·1 - Non toxic, non irritant . ~
.....--· -

I' c~ 0 ('-,:.:,J1 Jt--


2· Insoluble, non-absorbent.
~- Good esthetl9 {Should b~transprg.n:)ftransluce~~aslly pigrnenudlJ

4- Adequate mechanical properties:-


~
\
C.:.__;,,,. ~ --:.

..._JJ
-
G·'\ <:
Q,

1
a11' Modulus of e;g5fic1ty lfigiol ➔ to decrease bone resorption & us<!d as thin section.
b) 1' proporrto·nal limit ➔ 19 •~ permanent deformation when stressed.

\1 t J 1' Strengtli ➔ to resin high stre»es and Ira


0--. - JI v"l..,.;.., I ...;
d) If'!' Res,Jience-to,resist:~ ~11!\t'l!A< d eformation. -;- -\ 0
~
ure.
olrc vr.,~ t:,:,\I\C
~
,0
<C".S(2,• • "'

I el~ Impact st (impact st [no fracture


,. if denture dropped]. .
I..J>..fa (,i._,__, _
I fl H'ar<l"'I' abrasion r esistance.

g) '1' fat fgue strength ~ to resist cyclic loading -U'c;. ~ I, i;;



S- Adequate"pt\yskal, properties:_.
a- Thermal eKpansion match that of artificial teeth. - lo (!.U o\ J Cro c_,¥('
b- The softening temp> !1qu1d. food !11 the mouth.
c- Low density [light weight) ➔ for retention.
d - 1' Thermal conductivity (to stimulate underlying tissue, activate its blood

circulation). \- ....---·
Z_eo - J
6- Dimensional stable [no expansion, contr~n, warpage) .
..._.-- L- i.------
7- Easy to repair, clean.

- .... \ I 8• Radio-opaque to be seen i~~ [if p~rt of denture ~ I- G,V\d.5 W a \J.o~d


4 ! rr.e:
-------- -
1

. . ----- '
.
~ - No denture base material fulfills all these requirem~

'
.i:
l V1t.;i..'J{:,.11:v .:,.1. ,vv.,,11 J'(j. l
: •••,................ ,·OOOO-•······•·•··· ....................._ ..,,...............................,.............. 0000·····•••·-••••---···· ········..••HOaO ♦O·OO·O•OOO ...............,--··••-• 00
..~.;!•!.!..~!f..~~f..~...J................................................i!':'.{i.'j,J.,,, ..•• ,.. ,..•••••••••••••••• ••••••••••••••••• •••••••••• .. '..J ( I ) N
•••••••u u ♦ o of'/, 11• •• •:. ,,,ou

\J~,- \ (""y~ ) lfveii,J


{ Al- Heat cured rosin:- )

Powder:- c "l::',.,,.,
/ ) • •
I'.\ JJ H/\
1 , , I
v.J.,,O, ,•
(~ I\
. . '))r' 11,,,m,. or gr.111111, ... of (poly methyl m,·1h,1uyl,1tl'). I,) () tt'( Yf"n./) t1 \A .I J
~ '-( , ' · 'j, ,'), iov <: h1 ,•., 'f"•,;, ~Y
\} r .,~~ b- Initiator (b~ yl J'll~ <.lc 0 .'i l .!>%). • , I\"
C Pigment •, 1% lo Kl111• 1111• 11,1t111,1I tl•,•,,u, like• ,11>lll'M,1111,•

• , . "' d· Pla,tlclzcr,; (dlhutyl phthalat1•) ➔ to r,:lvt• mor(re~lllcnt & •,ofter polymer.


'.u. ' . t}J
CV r ,
I ,,,.'
I > fJ,;:f. Opaclflcr ➔ to RIVC'(adlo• opaclty.j)
1:::---
r ~ '

( .J c_; l~J~. Dyed organic fiber,; ➔ t.o •,1rnul.1t" II V_ Cv, ' , J ~ ~~ \') )
1
uauld;- .;__ Hft, ' \ .'-;ho~\ ~Jf.A:>
'- ·_ , ~I Monomc!)mc~ mcthac,ylatc). ,:,,.p V-, J • :,·
\,-_.> 1.- 7: ' ./'
'- C" 21,._ln~btoyihydroqulononc I (0,006%) ➔ to 1nh1b1t polymn11,1t 1on <in ·.tor,1P,<'
i_ S'-' ;-..- &, Cr oss- llnkln~)clycol dlmathacrylatf') ➔ 1 mcch p ro p, I, r r .,ck

hJ ~ \d) Plasticizers J
( 8)- Ch; mlcal cure (cold cure• s~lf cure)::) c; ((\-'\/'
\,..)'-"A \ e
rv'..,,J 7)
,(' / =
• The same composition but nctlvator
- - - -;:::=:called ➔
. . .___ _.:~--===:...-.
Pol merizatlon reaction:
IN, dlhydroxy ethyl para tolu,dinef '.
~ --
~

1 Hc_at ewe : _ L·f\v-.: ~ ·


r0-v , ~ lymeJ + peroxide..rltlatorr monomer ~hlbtor)➔ Polymer + heat
(Pow der) (Liquid I

2 Self cur.!n_g :
Polym er + peroxide initiator + monomer + ~ Polymer+ heat

(Pow der]

• The polymerization process is ➔ exothermic & actomeanied by shrinkage.

f C Residual monomer emalns its a~ ount Is ercater 1n self-cu~esln .

1 v---o V-"i' < eo. c) (l ~,). w-r) (\ o ~ ~ f 5


j 'j)'/t:A.'l l.'M 'l 'V .~ . 'JU\f.'A'Jl 'l'(i, 'J ()/l/ •794 ·724 7
:..........................................................,.......,........................................................................................................
l • DCOPOcJlQOIOC,
I. ri 1:., m 1 ,. , ,,,, .,, •,h\ 2 ~ 11 , m••'v.~ll\
. / f""'1 r4 lfli" , ~•.uffltt,.nt "'"ttln,i ,,f prnirltir\

/ / If , •"', ~ '!.,.'.)irinl,:'.!!:1 I!, ptJro ,IIV '

/ 7 ~.;-
• 8y St ',to,<?I ~patula. . -

( 3• Sandy ',laRt \
• St•l" of mix;.
~ StotkY ~UV))\
r ,~Stlft ,u,~.}
-
-r
"3 Siiiadlor. m!dh.un,. lvAlum •filo•~
• All-t,<ttt'r'it' .,..,-.t....rl t ►'F"fl,1 ·J ~-Mt,;,. } ,11r.t,.1f fl(':-trw(J11Jfih· /r ,. fjtf"_, ,, rf1,~J

• 8'1ll.c \,, '91p,J I ,, j "4

l· Prevent pll~ of H,o Imm ur,-,u~ It> r'l~ln{uu-.; u~1mv.!)

J. I, 110_,cwtv ~

4- f ~<Jlrt-111,
-
<,,.,~,~""" of fla~k\

• Auyh, par.Md into dw11h •,tav,':.

\ 5kr·,n\<O~- (
I :n,,, ·. t \

-----Too !ftt 4tlmd;;


l "" / •,r ,.,..v•;-f,o!., r,,tit ..tfirJ m!!kif , ,,r,fJYt 1
-
· ...~---- -- -- --':M=G'U
,a•m:J.,.;W;::;~- . !!..-.- - -- - - -....-- --.2~0~1~ 8~-
- ,,0•1ck'< ev.r;ILj ~ '\' Rei'.> ;ot,...J
s- Proces,sina JCuring\:
\ • Heat in water bath. ) ,- . : NI,
- o\J~( \...,...,:(~ ➔ jffl ;(\q r ofo.S,
r.AOV\C~; n, '
-
• Cu ring cycle: 1 ....)
\ "-'l
-_Lol'I&cvde: 74 •c for Sh ~ rt cycle : [74 °c for 11ththen 1' temp to 100 °c for lhJ .
~ neflask 1ng. finishing,
Premature opening before cooling may cause warpage.
r,.---
Rapid cooling will increase internal stresses (thermal stresses) in the denture.

IProperties]

l· polymeritatlon shrinkage:-
•~ lymerization shrinkage 21vut ideal mix .J, that 1~
• ResiClual monomer:,
• 0.2 - 0.5% of monomer remain, rereased from dentllre, irritate oral tiss~
• .J, mechanical prop, 1' surface oorosity. ~ -t o
- ·
3- Water sorption:• .
➔ denture absorbme

4· solu6ilitv:,
After processing

-
- water. .....-
Drying cause shrinkage, so dentures should kept wet when not in service. - ,..--
,,----_
• Not soluble i,¼ral fluids>
S- MecFianlcal properties:-

a• Tensile s\,50 B~pa. ~-r:\\\ ~


b- Elastic modulus 2.8 x 10 Mpa. ✓
3

c- Transever st 92 Mpa. ,
d- 1' Impact st {resist fracture on drop] . ..----
e• ,,I, Hardness [scratched easily). ·.---

•••••.. •••••••••••n••••••••••••••·••••••••••H.... •••••••• .. •.. •••••••••••·•••••••••••••••••·••••• OUHOOOH .. •.. ••••••••• ....·••••••..•• ..uou,oo•> U•- ♦-• • ••••••••• •• ••••"•
-~-
t4.~t!.'f!:!J..l!S ,.J_ _,,_tt••·-·---·-·2!.!i"'1J'------♦4♦♦-··-·····--·•·H-••-•·•••·... ~1§__,
6- Thermal properities;-
a- Thermal conductivity (very low).

1'• Heat during processing can't escape lead to 1' temp,


• Oen ture isolates oral tissue from an sensation with temp.

b· Coefficient of thermal expansion 1' 1' so contraction & expansion loss of porcelain

~ l,
0
teeth in denture. ci._,,~ _ ' IL) \ ,.. 1..:.......~.:, y

7~ )'
a- . ~ ;urface porosity" :-

'•
Irregular voids on the surface)

Due to:·
I· Under packing, '°'-t
v~,-- J: O
f} ,· ft-e J
II- Packiri.g ea_rty at sticky stage. eo.. ~ f'G'C. I:,.' .2J
111- Excessive monomer. 1 t ~l,\,; °'
I IV-No separting medium..

I b- Gaseous porosity (internal):-


. Fine uniform bubbles i~icker)part of the denture. /

- - - - -'---fI I E' f\-

Ii . due to ➔ over curing 'V-.A \ \ ~-

l.+ -r,,o.--o ~r v,J,\\ h ~


~

l -\ c, \ oo .3 ~ d\ CoQ~<'l
i'j a) mechanical stress:•
-\ o ~
j Repeated drying, wetting causin~ltemate contraction & expansion .)
!
~
\.,.,
•-
Jr-~') .-
I
., . .- v----
\., b) Solvent actio"i EX:- wh~n denture repaired, use monomer ~
-
j c) St ress due to difference in coefficient of thermal' expansion. - - -

! d) CleaniJ!E denture by bleachin~ alcohol. ,__..,,,-


I e) No sepa,iing_medium ➔ water passes from gypsum to acrylic.

'
!
:
I
-----
v1t:,1JIJ'1'[ 1J .:M . 'R.:-\fJ\'B 1'(i. , •>11 1-;94,7~4 7
:.....................................................................................................................................................................................
Modified denturebaseresin
1-_e.Q11r.tYPll nu:lo;,..,
• Compo\lllon \lmil,H 10 " '" 1urt111!\ln hu1.

• 'Mic ot 1101vmor hr11~orv ,mall!r ~ Klva(vci!.Y fluid ml~: )


• \~ - exc11llant rt!pruduttlon of d1il nlh.
-
'2· tJtab 1mo11ct.,t,rcsJni::
(
• Slmll•r to hciat cum but.
a• ~clnforcod with butadlenn \tyllrt1nt' rubbrr.
- 1'
•(;d.j· Impact \ t.

3~flapfd heat 00JvmerJ1ed ro)To-


• P,91Ymcrlrnd In boillnK water Immediately aftN packlnR for J.Omin.

•(!.f· (rapid polymerliatlon without poro1liy.)


4- M•icrowave cured rcsJn;·
• Need \pr.clal fla~k.

•&v:• 1' ~peed. ...,,.--


5· VlsJb!e Jlght cured rvsJn;~
• Recent.
t5J Mix appleied [premixed sheets), adap~~ . "W cast, light curlnf!.

6· Gel form acrvHc resin; ·


•' S.1mr. ,ompositlon but P,l mixed a~ gel.<only heat
= cure>
.-

.,,,,·. ,,
•IJ'/<. 'll'//'M'/ '/ 1 .'M, /l)\ / ,\'H " "' ,Q,J ·,1.J7
..........................,.·········.. .................................................................. ...............................................................
, , ' ...
.;..,:.. --
, f'.~D]!.:.: :!:'AL!;a5'._,J,l-:::::-::±
) =.~
====:--"-Mi!iu?~
-...;·=L:::::::·,.,._________2!!;q!L,
Tissue condition rs resilient linin for denture \
• They ar~ Polymers soft at mouth temp.{low G.T.T) d1~.) ~ ro,-1\_S µ' G>\ __-\ ('.-M p
..___f ~:,_;JI ~ I e.,;l/°
1 -
. 11ssue conditioner: -

Solt polymer applies temporarily for fitting .s of the denture.


- .

! 1· rrtat irritated mucosa undetthedenture. / 2-Stabilization of ,mmed,~te dMtures. /

! 3. tJsed as Functional imp mat. .......---


'i
1 • Com position: •
l • Powoe.t)- Polyethyl methacrylate~ d u e to it has low G.T.T
\ ..-. (!5luid'"- Ethyl Alcohol [solvent) .tt.r,omatic e;ter as a plaS1icizer. /.,,....__,(_,
l - ~ ::....:--.::::::=-:=:'~ .....---'C::,, , -
\ N.8 :~ot irritant [no monom~ used tempora::;, must be repl~ced every 3 days as ➔
a lcohol

; evaporate & plaS1icizer leache~out so it ➔ Hardens. ....- ~.:_,


- - c.J~
2- Resilient lining::
Soft polymer, permanent to denture)

c<§ ~
1- Very sensitive mucosa.
3- Improve fit of old denture
2· For Pt's comfort with old denture.
4- For pt diffic•Jlt to wears denture.
-
• Types:- ---
a) 'Self or mouth cured •
. ..
,tiator.
---..._
Powder( PEMS
I
i Liquid:• MMA +activator+ plasticizer.

IV b ) Heat cured or self cured silicone.

Limitations: •
v-;:..,-f w,_- ~ ~ ~_.r-.:sv I
r

j l · Become rough leads to food stagnation. f!,Jl 2- Peel away from denture.
[ 2- Change in color (staining). ~ ( 4- Become hard if touch !.aliva

l ·n11-.:-1:n:~11:v .:,1.
1
·1v'\J.'A'B a<<.. ni,J).:~Ci- ;
• • ·· 0 0 0 0 0 , ,. .0 0 0 0 0 OO• • • H 0·000 UO O O OH000•00 0 0 00·0 00 • • 0 • • • . . . . 0 0 · • 00•• 0 0 • • . . . . ·-··•••~oo--•••-•,,.,_,......_,,,,
<---- n; n :-Q.: •7:!.Ji
oOO•OOH O - - - - -. . . . n - o . . . .. ._ H - ·- . ., • • • • • 00 0 •

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