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U 4
U 4
Dry steam,
Flash
Binary cycle
Advantages
operate at low temperature cathode. Combining the anode and cathode
have fast startup times (50% rated reactions, the overall cell reactions are:
power at ambient temperature)
have high efficiency (1) H2 + 2OH–→ 2H2O + 2e–
need little or no expensive platinum (2) ½O2 + H2O + 2e–→ 2OH–
catalyst
have minimal corrosion Thus, the fuel cell produces water that either
have relative ease of operation evaporates into the source hydrogen stream
have low weight and volume (in an immobile system) or is flushed out of
the cells along with the electrolyte (in a
mobile system). This water must be
Disadvantages continually removed to facilitate further
The disadvantages are that they are reaction.
extremely intolerant to CO2 (about
Solar Power Plants
350 ppm maximum) and somewhat
intolerant of CO. This is a serious Parabolic Trough
disadvantage and limits both the type
Parabolic trough-shaped mirror reflectors
of oxidant and fuel that can be used
are used to concentrate sunlight on to
in an alkaline fuel cell. The oxidant
thermally efficient receiver tubes placed in
must be either pure oxygen or air that
the trough focal line. In these tubes a
has been scrubbed free of carbon
thermal transfer fluid is circulated, such as
dioxide. The fuel must be pure
synthetic thermal oil. Heated to
hydrogen due to the presence of
approximately 400°C by the concentrated
carbon oxides in reformate.
sun’s rays, this oil is then pumped through a
have a liquid electrolyte, introducing
series of heat exchangers to produce
liquid handling problems
superheated steam. The steam is converted
require complex water management
to electrical energy in a conventional steam
have a relatively short lifetime
turbine generator, which can either be part
Reaction of a conventional steam cycle or integrated
into a combined steam and gas turbine
Alkaline fuel cells must operate using pure cycle.
hydrogen free of carbon oxides.
Parabolic Dish