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450:1995
UDC 666.971.98:693.5:666.952.2:001.4:658.562
BS EN 450:1995
© BSI 07-1999
Amd. No. Date Comments
Contents
Page
Committees responsible Inside front cover
National foreword ii
Foreword 2
Text of EN 450 3
National annex NA (informative) Comparison between
BS 3892-1 and BS EN 450 8
National annex NB (normative) Requirements permitted
to be specified on a national basis 9
List of references Inside back cover
© BSI 07-1999 i
BS EN 450:1995
National foreword
This British Standard is the English language version of EN 450:1994 Fly ash for
concrete — Definitions, requirements and quality control prepared under the
authority of the European Committee for Standardization (CEN). This standard
has been prepared as part of a package of standards harmonized within the
member countries of CEN to support the essential requirements of the
Construction Products Directive.
The term “fly ash” used in this standard covers pulverized-fuel ash (pfa) which is
the more precise term for fly ashes produced from electricity generating power
stations burning pulverized hard coals and which has been in common use in the
UK for many years.
BS EN 450 does not supersede BS 3892-1 which remains in force and covers a
processed material, as explained in the introduction of this standard.
BS 3892-2:1984 is under revision.
This standard was drafted with the cooperation of the UK which proposed a
requirement for different classes of ash each with specific applications in order to
maintain the successful system of classification and use established under
BS 3892 since 1965. This was not required or accepted by the majority of CEN
member countries. However, the introduction to EN 450 acknowledges that the
UK and Ireland require that ash, for use as a cementitious component in concrete,
be processed in order to restrict variations in quality and to enhance performance
in concrete. It further recognizes that the specific requirements for controlled
properties which allow such processed ash to be used as a special component of
cementitious systems in concrete are not included in EN 450. Pfa conforming to
BS 3892-1 is subject to such processing. BS 5328-1 and BS 8110-1 refer to the use
of other fly ashes that do not conform to BS 3892-1 provided that satisfactory data
on their use are available.
Requirements in both BS EN 450 and BS 3892-1 are specified as characteristic
values and conformity is assessed by means of a statistical procedure for
continuous inspection operated by the ash producer (autocontrol). This includes
the concept of “major defects” which are likely to reduce materially the usability
of the ash for its intended purpose. In this respect both BS EN 450 and
BS 3892-1 are based upon the text on conformity criteria given in the European
Prestandard for cement, ENV 197-1:1992. Subsequent draft revisions of this text
have removed reference to major defects, referring instead to “limit values”
(upper and lower). The sum of the specified characteristic value and the
corresponding major defect is the limit value for the particular property. The
latter term is used throughout National annex NA in which the main differences
between BS EN 450 and BS 3892-1 are summarized.
BS EN 450 makes reference in 3.2, 3.3 and 4.2.2 to certain items which are
permitted to be fixed on a national basis. Normative National annex NB indicates
how these clauses are to be interpreted for the UK.
Most ash produced in the UK would conform to BS EN 450 without further
processing. Rules to allow ash conforming to BS EN 450 to be used in concrete
produced in accordance with EN 206 are, however, still under development. Until
such rules have been developed and agreed, users of ash conforming to BS EN 450
are advised that, for the specific use as part of the cement content in concrete, pfa
is required by BS 5328 and BS 8110 to conform to BS 3892-1. In particular,
BS 5328 requires that, when pfa is combined with a Portland cement in the
concrete mixer to give a combination equivalent to a cement conforming to
BS 6588 or BS 6610, the pfa conforms to BS 3892-1.
ii © BSI 07-1999
BS EN 450:1995
Cross-references
A British Standard does not purport to include all the necessary provisions of a
contract. Users of British Standards are responsible for their correct application.
Compliance with a British Standard does not of itself confer immunity
from legal obligations.
Summary of pages
This document comprises a front cover, an inside front cover, pages i to iv,
the EN title page, pages 2 to 10, an inside back cover and a back cover.
This standard has been updated (see copyright date) and may have had
amendments incorporated. This will be indicated in the amendment table on
the inside front cover.
UDC
666.971.98:693.5:666.952.2:001.4:658.562
Descriptors: Concrete, fly ash, definitions, specifications, chemical properties, physical properties, quality control, certification
English version
CEN
European Committee for Standardization
Comité Européen de Normalisation
Europäisches Komitee für Normung
Central Secretariat: rue de Stassart 36, B-1050 Brussels
Foreword Contents
This European Standard was drawn up by the Page
Technical Committee CEN/TC 104, Concrete, the 0 Introduction 3
Secretariat of which is held by DIN.
1 Scope 3
The preparatory work was carried out by WG 4 of
2 Normative references 3
CEN/TC 104 since June 1988 in which the following
countries participated: Austria, Belgium, Denmark, 3 Definitions 3
France, Germany, Ireland, Italy, Netherlands, 3.1 type II addition 3
Norway, Portugal, Sweden and United Kingdom. 3.2 fly ash 3
This European Standard has been prepared under a 3.3 reference cement 4
mandate given to CEN by the European
Commission and the European Free Trade 3.4 particle density 4
Association, and supports essential requirements of 3.5 activity index 4
EC Directive(s). 3.6 autocontrol 4
This European Standard shall be given the status of 4 Requirements 4
a national standard, either by publication of an 4.1 General 4
identical text or by endorsement, at the latest by
March 1995, and conflicting national standards 4.2 Chemical requirements 4
shall be withdrawn at the latest by March 1995. 4.2.1 General 4
It is supported by standards of the series EN 451 for 4.2.2 Loss on ignition 4
test methods for determination of free calcium oxide 4.2.3 Chloride 4
content and of the fineness by sieve residue. No 4.2.4 Sulfuric anhydride 4
existing European Standard is superseded.
4.2.5 Free calcium oxide 4
According to the CEN/CENELEC Internal
Regulations, the following countries are bound to 4.3 Physical requirements 4
implement this European Standard: Austria, 4.3.1 Fineness 4
Belgium, Denmark, Finland, France, Germany, 4.3.2 Activity index 5
Greece, Iceland, Ireland, Italy, Luxembourg, 4.3.3 Soundness 5
Netherlands, Norway, Portugal, Spain, Sweden,
Switzerland, United Kingdom. 4.3.4 Particle density 5
5 Packaging and marking 5
6 Quality control 5
6.1 Conformity criteria 5
6.2 Autocontrol 5
6.2.1 General 5
6.2.2 Sampling 5
6.2.3 Frequency of sampling and testing 6
Annex A (informative) Sampling plans 7
A.0 Introduction 7
A.1 Inspection of variables 7
A.2 Inspection by attributes 7
Table 1 — Major defects 6
Table 2 — Sampling and testing frequency 6
Table 3 — Acceptability constant
kA (Pa = 10 %) 7
Table 4 — Acceptable number of defects ca 7
2 © BSI 07-1999
EN 450:1994
1 Scope 3.1
type II addition
This European Standard specifies requirements for
finely divided inorganic, pozzolanic or latent
the properties of fly ash for use as a type II addition
hydraulic material that may be added to concrete in
in cast-in-situ or prefabricated structural concrete
order to improve certain properties or to achieve
conforming to ENV 206.
special properties (see ENV 206)
Fly ash for use in the manufacture of cements
according to ENV 197-1 is outside the scope of this 3.2
standard. fly ash
Provisions governing the practical application of fly fine powder of mainly spherical, glassy particles,
ash in the production of concrete, i.e. requirements derived from burning of pulverized coal, which has
concerning composition, mixing, placing, curing etc. pozzolanic properties and consists essentially of
of concrete containing fly ash are not part of this SiO2 and Al2O3, the content of reactive SiO2,
standard. As regards such provisions, reference defined and determined as described in ENV 197-1,
should be made to ENV 206 or national standards being at least 25 % by mass
for concrete.
© BSI 07-1999 3
EN 450:1994
4 © BSI 07-1999
EN 450:1994
The maximum value of the fineness shall not 6.1 Conformity criteria
exceed 40 %. The fineness shall not vary by more The conformity criteria and conformity procedures
than ± 10 percentage points from the average value specified in ENV 197-1 for the physical and
which shall be calculated from the number of tests chemical properties of cement shall apply in this
within a given production period as described in 6.2. standard. The characteristic values specified in
Upon request, the average value and the period over clause 4 shall correspond to the 10 % fractile (upper
which it has been calculated shall be declared by the or lower as appropriate) while the probability of
producer. acceptance (consumer’s risk) shall be 5 % for all the
4.3.2 Activity index properties dealt with in this standard. In addition,
major defects, as defined in ENV 197-1, exceeding
Preparation of standard mortar bars and the values listed in Table 1 shall not be accepted for
determination of the compressive strength shall be any of the properties.
carried out in accordance with the method described
in EN 196-1. 6.2 Autocontrol
The activity index at 28 days and at 90 days shall be 6.2.1 General
not less than 75 % and 85 %, respectively. A system of autocontrol shall be operated by the
NOTE The result of the activity index tests gives no direct producer or his agent at every single fly ash
information on the strength contribution of fly ash in concrete, generating facility to ensure conformity to the
nor is the use of the fly ash limited to the mixing ratio used in
these tests. requirements specified in clause 4. The continuous
statistical quality control shall be based on
4.3.3 Soundness inspection by attributes or by variables of the
The expansion, as determined on a 50 % fly ash producer’s or his agent’s choice using single spot
plus 50 % reference cement by mass reference samples. A minimum of 10 samples shall be used for
cement paste by the method designated the Le assessing the conformity and shall represent a
Chatelier test and described in EN 196-3, shall not production period of not more than 12 months, nor
be greater than 10 mm. less than 1 month.
NOTE This test is required only if the free calcium oxide NOTE Examples of some convenient sampling plans for
content of the fly ash exceeds 1,0 % by mass, see clause 4.2.5. inspection by variables and by attributes are shown in Annex A.
4.3.4 Particle density 6.2.2 Sampling
The particle density, determined by the method Spot samples, equally distributed over the
described in EN 196-6, shall not deviate by more production period, shall be taken in connection with
than ± 150 kg/m3 from the average value as loading or discharging fly ash to or from a storage
declared by the producer or his agent. silo into packages or into a bulk-delivery vehicle or
ship, or, alternatively, directly from packages or
5 Packaging and marking bulk-delivery vehicles or ships, using the equipment
NOTE Fly ash may be delivered in suitable packages, such as and principles described in EN 196-7.
bags or drums, and in bulk-delivery vehicles or ships. For the purpose of carrying out all the analyses and
Packages shall be marked or labelled and delivery tests needed to show compliance or non-compliance
notes (or invoices) relating to bulk delivery shall be with the requirements set out in 4.2 and 4.3 a
marked with the following particulars: representative laboratory sample of dry fly ash of at
a) the type of the material, i.e. fly ash; least 1 kg is required. This sample is obtained by
subdividing, such as quartering, a spot or composite
b) the name, trade mark or other means of
sample of at least 4 kg. The laboratory sample shall
identification of the supplier;
be dried in a well-ventilated oven at (105± 5) °C to
c) the name and location of the facility from which constant weight and then cooled in a dry
the fly ash is dispatched; atmosphere.
d) the number and year of this European
Standard (or of the national standard which
implements this standard);
e) certification mark (if necessary).
6 Quality control
NOTE This clause comprises general rules for conformity
criteria and autocontrol. Rules for acceptance inspection at
delivery and for certification are outside the scope of the
standard.
© BSI 07-1999 5
EN 450:1994
6 © BSI 07-1999
EN 450:1994
© BSI 07-1999 7
BS EN 450:1995
8 © BSI 07-1999
BS EN 450:1995
h) Both BS EN 450 and BS 3892-1 contain a requirement that a combination of ash and Portland cement
has an expansion of not more than 10 mm in the Le Chatelier soundness test. The BS EN 450 test is
carried out on a combination containing 50 % ash whilst the BS 3892-1 test is carried out on a
combination containing 30 % ash.
i) BS EN 450 has no autocontrol limit for particle
density but specifies that the value shall not
deviate by more than ± 150 kg/m3 from the
supplier’s declared average value. The variations
thus permitted may become significant with the
wide range of sieve residues permitted by BS
EN 450.
BS 3892-1 specifies an autocontrol minimum of 2
000 kg/m3 with a lower limit value of 1 950 kg/
m3. No limit on variation is specified but the
strict control on fineness ensures that density
variations are minimized.
j) Unlike BS 3892-1, BS EN 450 has no requirements for moisture content, water requirement or initial
setting time. As a result of the absence of a specification for water requirement and the wide tolerance
on fineness, the water demand of concrete may be increased and/or made more variable by the inclusion
of ash conforming to BS EN 450. This is in contrast to ash conforming to BS 3892-1 which, by virtue of
conformance to the specifications for water requirement and controlled fineness, can produce a
consistent reduction in concrete water demand.
k) BS EN 450 specifically excludes rules for acceptance inspection at delivery whereas the limit values
are treated by BS 3892-1 as acceptance inspection limits.
l) BS EN 450 specifically excludes rules for certification and contains no requirement for information to
be provided on a test certificate. BS 3892-1 makes provision for results of tests for every requirement of
the standard as well as additional information to be included in a test certificate if requested by the
purchaser.
m) BS EN 450 makes no reference to control of ash colour. Although colour consistency is not a
requirement of BS 3892-1:1993, A.7 of that standard recognizes that an indication of colour consistency
may be given by any test mutually agreed between producer and purchaser and recommends a suitable
method of test for this purpose.
© BSI 07-1999 9
10 blank
BS EN 450:1995
List of references
© BSI 07-1999
BS EN
450:1995
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