List of refrigerants

Chemical refrigerants are assigned an R number which is determined systematically according to molecular structure. Common refrigerants are frequently
referred to as Freon (a registered trademark of Chemours). The following is a list of refrigerants with their Type/Prefix, ASHRAE designated numbers,
IUPAC chemical name, molecular formula, CAS registry number / Blend Name, Atmospheric Lifetime in years, Semi-Empirical Ozone depletion potential, net
Global warming potential over a 100-year time horizon, Occupational exposure limit/Permissible exposure limit in parts per million (volume per volume) over
a time-weighted average (TWA) concentration for a normal eight-hour work day and a 40-hour work week, ASHRAE 34 Safety Group in Toxicity &
Flammability (in Air @ 60 °C & 101.3 kPa) classing, Refrigerant Concentration Limit / Immediately Dangerous to Life or Health in parts per million (volume
per volume) & grams per cubic meter, Molecular mass in Atomic mass units, Normal Boiling Point (or Bubble & Dew Points for the Zeotrope(400)-series)(or
Normal Boiling Point & Azeotropic Temperature for the Azeotrope(500)-series) at 101,325 Pa (1 atmosphere) in degrees Celsius, Critical Temperature in
degrees Celsius and Critical Pressure (absolute) in kiloPascals.

Contents
List
Type and flammability
See also
References
Notes

List
 CAS
T
registry Atmospheric Semi- net p
y ASHRAE Molecular
IUPAC Chemical Name number/ Lifetime Empirical GWP A
p Number Formula
Blend (years) ODP 100-yr
e
Name

PCC R-10 Carbon tetrachloride (Tetrachloromethane) CCl4 56-23-5 26[1][2] 0.73[2] 1,400[3] 1

CFC R-11 Trichlorofluoromethane CCl3F 75-69-4 45[1][2] 1.0[2] 4,660[8]

CFC R-12 Dichlorodifluoromethane CCl2F2 75-71-8 100[1][2] 1.0[2] 10,200[8]

H R-12B1 Bromochlorodifluoromethane CBrClF2 or CF2ClBr 353-59-3 16[1][2] 7.1[2] 1,750[3]

H R-12B2 Dibromodifluoromethane CBr2F2 75-61-6 2.9[2] 1.7[2]

CFC R-13 Chlorotrifluoromethane CClF3 75-72-9 640[1] 1[10] 13,900[8]

H R-13B1 Bromotrifluoromethane CBrF3 or CF3Br 75-63-8 65[1][2] 16[2] 6,290[3]

PFC R-14 Tetrafluoromethane CF4 75-73-0 50,000[1] 0[11] 7,390[1]

HCC R-20 Chloroform (Trichloromethane) CHCl3 67-66-3 0.51[1] 31[1]

HCFC R-21 Dichlorofluoromethane CHFCl2 75-43-4 1.7[2] 0.04[12] 148[3] 1

HCFC R-22 Chlorodifluoromethane CHClF2 75-45-6 12.0[1][2] 0.05[2] 1,760[3]

H R-22B1 Bromodifluoromethane CHBrF2 or CHF2Br 1511-62-2 5.8[2] 0.74[10] 404[2]

HFC R-23 Trifluoromethane (Fluoroform) CHF3 75-46-7 270[1] 0[11] 12,400[3]

HCC R-30 Dichloromethane (Methylene chloride) CH2Cl2 75-09-2 0.38[1] 0[13] 8.7[1] 1

HCFC R-31 Chlorofluoromethane CH2FCl 593-70-4 0.02[12]

HFC R-32[14] Difluoromethane CH2F2 75-10-5 4.9[1] 0[11] 677[3]

HCC R-40 Chloromethane CH3Cl 74-87-3 1.0[1][2] 0.02[2] 13[1] 1

HFC R-41 Fluoromethane CH3F 593-53-3 2.4[1] 0[11] 116[3]

HC R-50 Methane CH4 74-82-8 12 ± 3[1] <0(smog)[17] 28[3]

PCC R-110 Hexachloroethane C2Cl6 67-72-1

CFC R-111 Pentachlorofluoroethane C2FCl5 354-56-3 1[10]

CFC R-112 1,1,2,2-Tetrachloro-1,2-difluoroethane C2F2Cl4 76-12-0 1[10]

CFC R-112a 1,1,1,2-Tetrachloro-2,2-difluoroethane C2F2Cl4 76-11-9 1[a]

CFC R-113 1,1,2-Trichloro-1,2,2-trifluoroethane C2F3Cl3 76-13-1 85[1][2] 1.0[2] 5,820[8]

CFC R-113a 1,1,1-Trichloro-2,2,2-trifluoroethane C2F3Cl3 354-58-5 1[a]

CFC R-114 1,2-Dichlorotetrafluoroethane C2F4Cl2 76-14-2 300[1][2] 1.0[2] 8,590[8]

CFC R-114a 1,1-Dichlorotetrafluoroethane C2F4Cl2 374-07-2 1[a]

H R-114B2 Dibromotetrafluoroethane C2F4Br2 or CF2BrCF2Br 124-73-2 20[1][2] 11.5[2] 1,470[3]

CFC R-115 Chloropentafluoroethane C2F5Cl 76-15-3 1,700[1][2] 0.44[2] 7,670[3]

PFC R-116 Hexafluoroethane C2F6 76-16-4 10,000[1] 0[11] 12,200[1]

HCC R-120 Pentachloroethane C2HCl5 76-01-7

HCFC R-121 1,1,2,2-Tetrachloro-1-fluoroethane C2HFCl4 354-14-3 0.01-0.04[12]

HCFC R-121a 1,1,1,2-Tetrachloro-2-fluoroethane C2HFCl4 354-11-0 0.01-0.04[b]

HCFC R-122 1,1,2-Trichloro-2,2-difluoroethane C2HF2Cl3 354-21-2 0.02-0.08[12]

HCFC R-122a 1,1,2-Trichloro-1,2-difluoroethane C2HF2Cl3 354-15-4 0.02-0.08[b]

HCFC R-122b 1,1,1-Trichloro-2,2-difluoroethane C2HF2Cl3 354-12-1 0.02-0.08[b]

HCFC R-123 2,2-Dichloro-1,1,1-trifluoroethane C2HF3Cl2 306-83-2 1.3[1][2] 0.02[2] 79[3] 5

HCFC R-123a 1,2-Dichloro-1,1,2-trifluoroethane C2HF3Cl2 354-23-4 1.3?[c] 0.02?[b] 77?[c]

HCFC R-123b 1,1-Dichloro-1,2,2-trifluoroethane C2HF3Cl2 812-04-4 1.3?[c] 0.02?[b] 77?[c]

HCFC R-124 1-Chloro-1,2,2,2-tetrafluoroethane C2HF4Cl 2837-89-0 5.8[1][2] 0.022[2] 527[3]

HCFC R-124a 1-Chloro-1,1,2,2-tetrafluoroethane C2HF4Cl 354-25-6 5.8?[c] 0.022?[b] 609?[c]

HFC R-125 Pentafluoroethane C2HF5 354-33-6 29[1] 0[11] 3,170[3]

HFC R-E125 Pentafluorodimethyl ether C2HF5O 3822-68-2 136[1] 0[d] 14,900[1]

HCC R-130 1,1,2,2-Tetrachloroethane C2H2Cl4 79-34-5

HCC R-130a 1,1,1,2-Tetrachloroethane C2H2Cl4 630-20-6

HCFC R-131 1,1,2-Trichloro-2-fluoroethane C2H2FCl3 359-28-4 0.007-0.05[12]

HCFC R-131a 1,1,2-Trichloro-1-fluoroethane C2H2FCl3 811-95-0 0.007-0.05[b]

HCFC R-131b 1,1,1-Trichloro-2-fluoroethane C2H2FCl3 2366-36-1 0.007-0.05[b]

HCFC R-132 Dichlorodifluoroethane C2H2F2Cl2 25915-78-0 0.008-0.05[b]

HCFC R-132a 1,1-Dichloro-2,2-difluoroethane C2H2F2Cl2 471-43-2 0.008-0.05[b]

HCFC R-132b 1,2-Dichloro-1,1-difluoroethane C2H2F2Cl2 1649-08-7 0.008-0.05[12]

HCFC R-132c 1,1-Dichloro-1,2-difluoroethane C2H2F2Cl2 1842-05-3 0.008-0.05[b]

H R-132bB2 1,2-Dibromo-1,1-difluoroethane C2H2Br2F2 75-82-1 0.2-1.5[10]

HCFC R-133 1-Chloro-1,2,2-Trifluoroethane C2H2F3Cl 431-07-2 0.02-0.06[b]

HCFC R-133a 1-Chloro-2,2,2-Trifluoroethane C2H2F3Cl 75-88-7 0.02-0.06[12]

HCFC R-133b 1-Chloro-1,1,2-Trifluoroethane C2H2F3Cl 421-04-5 0.02-0.06[b]

HFC R-134 1,1,2,2-Tetrafluoroethane C2H2F4 359-35-3 9.6[1] 0[11] 1,120[3]

HFC R-134a 1,1,1,2-Tetrafluoroethane C2H2F4 811-97-2 14[1] 0[11][13] 1,300[3]

HFC R-E134 Bis(difluoromethyl)ether C2H2F4O 1691-17-4 26[1] 0[d] 6,320[1]

HCC R-140 1,1,2-Trichloroethane C2H3Cl3 79-00-5

HCC R-140a 1,1,1-Trichloroethane (Methyl chloroform) C2H3Cl3 or CH3CCl3 71-55-6 5.0[1][2] 0.12[2] 160[3]

HCFC R-141 1,2-Dichloro-1-fluoroethane C2H3FCl2 430-57-9 9.3?[c] 0.12?[b] 725?[c]

H R-141B2 1,2-Dibromo-1-fluoroethane C2H3Br2F 358-97-4 0.1-1.7[10]

HCFC R-141a 1,1-Dichloro-2-fluoroethane C2H3FCl2 430-53-5 9.3?[c] 0.12?[b] 725?[c]

HCFC R-141b 1,1-Dichloro-1-fluoroethane C2H3FCl2 1717-00-6 9.3[1][2] 0.12[2] 725[1] 5

HCFC R-142a 1-Chloro-1,2-difluoroethane C2H3F2Cl 25497-29-4 17.9?[c] 0.07?[b] 2,310?[c]

HCFC R-142b 1-Chloro-1,1-difluoroethane C2H3F2Cl 75-68-3 17.9[1][2] 0.07[2] 2,310[1]

HFC R-143 1,1,2-Trifluoroethane C2H3F3 430-66-0 3.5[1] 0[11] 328[3]

HFC R-143a 1,1,1-Trifluoroethane C2H3F3 420-46-2 52[1] 0[11] 4,800[3]

HFC R-143m Methyl trifluoromethyl ether C2H3F3O 421-14-7 0[d]

HFC R-E143a 2,2,2-Trifluoroethyl methyl ether C3H5F3O 460-43-5 4.3[1] 0[d] 756[1]

HCC R-150 1,2-Dichloroethane C2H4Cl2 107-06-2

HCC R-150a 1,1-Dichloroethane C2H4Cl2 75-34-3

HCFC R-151 Chlorofluoroethane C2H4ClF 110587-14-9

HCFC R-151a 1-Chloro-1-fluoroethane C2H4ClF 1615-75-4

HFC R-152 1,2-Difluoroethane C2H4F2 624-72-6 0.60[1] 0[d] 16[3]

HFC R-152a 1,1-Difluoroethane C2H4F2 75-37-6 1.4[1] 0[11][13] 138[3]

HCC R-160 Chloroethane (ethyl chloride) C2H5Cl 75-00-3

HFC R-161 Fluoroethane C2H5F 353-36-6 0.3[1] 0[d] 4[3]

HC R-170 Ethane C2H6 or CH3CH3 74-84-0 12 ± 3[e] < 0(smog)[e] 5.5[1]

HC R-E170 Dimethyl ether CH3OCH3 115-10-6 0.015[1] < 0(smog)[e] 1[1]

CFC R-211 1,1,1,2,2,3,3-Heptachloro-3-fluoropropane C3FCl7 422-78-6 1[10]

CFC R-212 Hexachlorodifluoropropane C3F2Cl6 76546-99-3 1[10]

CFC R-213 1,1,1,3,3-Pentachloro-2,2,3-trifluoropropane C3F3Cl5 2354-06-5 1[10]

CFC R-214 1,2,2,3-Tetrachloro-1,1,3,3-tetrafluoropropane C3F4Cl4 2268-46-4 1[10]

CFC R-215 1,1,1-Trichloro-2,2,3,3,3-pentafluoropropane C3F5Cl3 4259-43-2 1[10]

CFC R-216 1,2-Dichloro-1,1,2,3,3,3-hexafluoropropane C3F6Cl2 661-97-2 1[10]

CFC R-216ca 1,3-Dichloro-1,1,2,2,3,3-hexafluoropropane C3F6Cl2 662-01-1 1[a]

CFC R-217 1-Chloro-1,1,2,2,3,3,3-heptafluoropropane C3F7Cl 422-86-6 1[10]

CFC R-217ba 2-Chloro-1,1,1,2,3,3,3-heptafluoropropane C3F7Cl 76-18-6 1[a]

PFC R-218 Octafluoropropane C3F8 76-19-7 2,600[1] 0[11] 8,830[1]

HCFC R-221 1,1,1,2,2,3-Hexachloro-3-fluoropropane C3HFCl6 422-26-4 0.015-0.07[12]

HCFC R-222 Pentachlorodifluoropropane C3HF2Cl5 134237-36-8 0.01-0.09[b]

HCFC R-222c 1,1,1,3,3-Pentachloro-2,2-difluoropropane C3HF2Cl5 422-49-1 0.01-0.09[12]

HCFC R-223 Tetrachlorotrifluoropropane C3HF3Cl4 134237-37-9 0.01-0.08[b]

HCFC R-223ca 1,1,3,3-Tetrachloro-1,2,2-trifluoropropane C3HF3Cl4 422-52-6 0.01-0.08[12]

HCFC R-223cb 1,1,1,3-Tetrachloro-2,2,3-trifluoropropane C3HF3Cl4 422-50-4 0.01-0.08[b]

HCFC R-224 Trichlorotetrafluoropropane C3HF4Cl3 134237-38-0 0.01-0.09[b]

HCFC R-224ca 1,3,3-Trichloro-1,1,2,2-tetrafluoropropane C3HF4Cl3 422-54-8 0.01-0.09[12]

HCFC R-224cb 1,1,3-Trichloro-1,2,2,3-tetrafluoropropane C3HF4Cl3 422-53-7 0.01-0.09[b]

HCFC R-224cc 1,1,1-Trichloro-2,2,3,3-tetrafluoropropane C3HF4Cl3 422-51-5 0.01-0.09[b]

HCFC R-225 Dichloropentafluoropropane C3HF5Cl2 127564-92-5 0.01-0.05[b]

HCFC R-225aa 2,2-Dichloro-1,1,1,3,3-pentafluoropropane C3HF5Cl2 128903-21-9 0.01-0.05[b]

HCFC R-225ba 2,3-Dichloro-1,1,1,2,3-pentafluoropropane C3HF5Cl2 422-48-0 0.01-0.05[b]

HCFC R-225bb 1,2-Dichloro-1,1,2,3,3-pentafluoropropane C3HF5Cl2 422-44-6 0.01-0.05[b]

HCFC R-225ca 3,3-Dichloro-1,1,1,2,2-pentafluoropropane C3HF5Cl2 422-56-0 1.9[1][2] 0.02[2] 127[3]

HCFC R-225cb 1,3-Dichloro-1,1,2,2,3-pentafluoropropane C3HF5Cl2 507-55-1 5.8[1][2] 0.03[2] 525[3]

HCFC R-225cc 1,1-Dichloro-1,2,2,3,3-pentafluoropropane C3HF5Cl2 13474-88-9 0.01-0.05[b]

HCFC R-225da 1,2-Dichloro-1,1,3,3,3-pentafluoropropane C3HF5Cl2 431-86-7 0.01-0.05[b]

HCFC R-225ea 1,3-Dichloro-1,1,2,3,3-pentafluoropropane C3HF5Cl2 136013-79-1 0.01-0.05[b]

HCFC R-225eb 1,1-Dichloro-1,2,3,3,3-pentafluoropropane C3HF5Cl2 111512-56-2 0.01-0.05[b]

HCFC R-226 Chlorohexafluoropropane C3HF6Cl 134308-72-8 0.02-0.1[b]

HCFC R-226ba 2-Chloro-1,1,1,2,3,3-hexafluoropropane C3HF6Cl 51346-64-6 0.02-0.1[b]

HCFC R-226ca 3-Chloro-1,1,1,2,2,3-hexafluoropropane C3HF6Cl 422-57-1 0.02-0.1[b]

HCFC R-226cb 1-Chloro-1,1,2,2,3,3-hexafluoropropane C3HF6Cl 422-55-9 0.02-0.1[b]

HCFC R-226da 2-Chloro-1,1,1,3,3,3-hexafluoropropane C3HF6Cl 431-87-8 0.02-0.1[12]

HCFC R-226ea 1-Chloro-1,1,2,3,3,3-hexafluoropropane C3HF6Cl 359-58-0 0.02-0.1[b]

HFC R-227ca 1,1,2,2,3,3,3-Heptafluoropropane C3HF7 2252-84-8 0[d]

HFC R-227ca2 Trifluoromethyl 1,1,2,2-tetrafluoroethyl ether C3HF7O 2356-61-8 0[d]

HFC R-227ea 1,1,1,2,3,3,3-Heptafluoropropane C3HF7 431-89-0 34.2[1] 0[11][13] 3,350[3]

HFC R-227me Trifluoromethyl 1,2,2,2-tetrafluoroethyl ether C3HF7O 2356-62-9 11[2] 0[d] 1,540[2]

HCFC R-231 Pentachlorofluoropropane C3H2FCl5 134190-48-0 0.05-0.09[12]

HCFC R-232 Tetrachlorodifluoropropane C3H2F2Cl4 134237-39-1 0.008-0.1[12]

HCFC R-232ca 1,1,3,3-Tetrachloro-2,2-difluoropropane C3H2F2Cl4 1112-14-7 0.008-0.1[b]

HCFC R-232cb 1,1,1,3-Tetrachloro-2,2-difluoropropane C3H2F2Cl4 677-54-3 0.008-0.1[b]

HCFC R-233 Trichlorotrifluoropropane C3H2F3Cl3 134237-40-4 0.007-0.23[12]

HCFC R-233ca 1,1,3-Trichloro-2,2,3-trifluoropropane C3H2F3Cl3 131221-36-8 0.007-0.23[b]

HCFC R-233cb 1,1,3-Trichloro-1,2,2-trifluoropropane C3H2F3Cl3 421-99-8 0.007-0.23[b]

HCFC R-233cc 1,1,1-Trichloro-2,2,3-trifluoropropane C3H2F3Cl3 131211-71-7 0.007-0.23[b]

HCFC R-234 Dichlorotetrafluoropropane C3H2F4Cl2 127564-83-4 0.01-0.28[b]

HCFC R-234aa 2,2-Dichloro-1,1,3,3-tetrafluoropropane C3H2F4Cl2 17705-30-5 0.01-0.28[b]

HCFC R-234ab 2,2-Dichloro-1,1,1,3-tetrafluoropropane C3H2F4Cl2 149329-24-8 0.01-0.28[b]

HCFC R-234ba 1,2-Dichloro-1,2,3,3-tetrafluoropropane C3H2F4Cl2 425-94-5 0.01-0.28[12]

HCFC R-234bb 2,3-Dichloro-1,1,1,2-tetrafluoropropane C3H2F4Cl2 149329-25-9 0.01-0.28[b]

HCFC R-234bc 1,2-Dichloro-1,1,2,3-tetrafluoropropane C3H2F4Cl2 149329-26-0 0.01-0.28[b]

HCFC R-234ca 1,3-Dichloro-1,2,2,3-tetrafluoropropane C3H2F4Cl2 70341-81-0 0.01-0.28[b]

HCFC R-234cb 1,1-Dichloro-2,2,3,3-tetrafluoropropane C3H2F4Cl2 4071-01-6 0.01-0.28[b]

HCFC R-234cc 1,3-Dichloro-1,1,2,2-tetrafluoropropane C3H2F4Cl2 422-00-5 0.01-0.28[b]

HCFC R-234cd 1,1-Dichloro-1,2,2,3-tetrafluoropropane C3H2F4Cl2 70192-63-1 0.01-0.28[b]

HCFC R-234da 2,3-Dichloro-1,1,1,3-tetrafluoropropane C3H2F4Cl2 146916-90-7 0.01-0.28[b]

HCFC R-234fa 1,3-Dichloro-1,1,3,3-tetrafluoropropane C3H2F4Cl2 76140-39-1 0.01-0.28[b]

HCFC R-234fb 1,1-Dichloro-1,3,3,3-tetrafluoropropane C3H2F4Cl2 64712-27-2 0.01-0.28[b]

HCFC R-235 Chloropentafluoropropane C3H2F5Cl 134237-41-5 0.03-0.52[12]

HCFC R-235ca 1-Chloro-1,2,2,3,3-pentafluoropropane C3H2F5Cl 28103-66-4 0.03-0.52[b]

HCFC R-235cb 3-Chloro-1,1,1,2,3-pentafluoropropane C3H2F5Cl 422-02-6 0.03-0.52[b]

HCFC R-235cc 1-Chloro-1,1,2,2,3-pentafluoropropane C3H2F5Cl 679-99-2 0.03-0.52[b]

HCFC R-235da 2-Chloro-1,1,1,3,3-pentafluoropropane C3H2F5Cl 134251-06-2 0.03-0.52[b]

HCFC R-235fa 1-Chloro-1,1,3,3,3-pentafluoropropane C3H2F5Cl 677-55-4 0.03-0.52[b]

HFC R-236cb 1,1,1,2,2,3-Hexafluoropropane C3H2F6 677-56-5 13.6[1] 0[d] 1,210[3]

HFC R-236ea 1,1,1,2,3,3-Hexafluoropropane C3H2F6 431-63-0 10.7[1] 0[11] 1,330[3]

HFC R-236fa 1,1,1,3,3,3-Hexafluoropropane C3H2F6 690-39-1 240[1] 0[11] 8,060[3]

HFC R-236me 1,2,2,2-Tetrafluoroethyl difluoromethyl ether C3H2F6O 57041-67-5 5.8[2] 0[d] 989[2]

HFC R-FE-36 Hexafluoropropane C3H2F6 359-58-0 0[d]

HCFC R-241 Tetrachlorofluoropropane C3H3FCl4 134190-49-1 0.004-0.09[12]

HCFC R-242 Trichlorodifluoropropane C3H3F2Cl3 134237-42-6 0.005-0.13[12]

HCFC R-243 Dichlorotrifluoropropane C3H3F3Cl2 134237-43-7 0.007-0.12[12]

HCFC R-243ca 1,3-Dichloro-1,2,2-trifluoropropane C3H3F3Cl2 67406-68-2 0.007-0.12[b]

HCFC R-243cb 1,1-Dichloro-2,2,3-trifluoropropane C3H3F3Cl2 70192-70-0 0.007-0.12[b]

HCFC R-243cc 1,1-Dichloro-1,2,2-trifluoropropane C3H3F3Cl2 7125-99-7 0.007-0.12[b]

HCFC R-243da 2,3-Dichloro-1,1,1-trifluoropropane C3H3F3Cl2 338-75-0 0.007-0.12[b]

HCFC R-243ea 1,3-Dichloro-1,2,3-trifluoropropane C3H3F3Cl2 151771-08-3 0.007-0.12[b]

HCFC R-243ec 1,3-Dichloro-1,1,2-trifluoropropane C3H3F3Cl2 149329-27-1 0.007-0.12[b]

HCFC R-244 Chlorotetrafluoropropane C3H3F4Cl 134190-50-4 0.009-0.14[12]

HCFC R-244ba 2-Chloro-1,2,3,3-tetrafluoropropane C3H3F4Cl 0.009-0.14[b]

HCFC R-244bb 2-Chloro-1,1,1,2-tetrafluoropropane C3H3F4Cl 421-73-8 0.009-0.14[b]

HCFC R-244ca 3-Chloro-1,1,2,2-tetrafluoropropane C3H3F4Cl 679-85-6 0.009-0.14[b]

HCFC R-244cb 1-Chloro-1,2,2,3-tetrafluoropropane C3H3F4Cl 67406-66-0 0.009-0.14[b]

HCFC R-244cc 1-Chloro-1,1,2,2-tetrafluoropropane C3H3F4Cl 421-75-0 0.009-0.14[b]

HCFC R-244da 2-Chloro-1,1,3,3-tetrafluoropropane C3H3F4Cl 19041-02-2 0.009-0.14[b]

HCFC R-244db 2-Chloro-1,1,1,3-tetrafluoropropane C3H3F4Cl 117970-90-8 0.009-0.14[b]

HCFC R-244ea 3-Chloro-1,1,2,3-tetrafluoropropane C3H3F4Cl 0.009-0.14[b]

HCFC R-244eb 3-Chloro-1,1,1,2-tetrafluoropropane C3H3F4Cl 0.009-0.14[b]

HCFC R-244ec 1-Chloro-1,1,2,3-tetrafluoropropane C3H3F4Cl 0.009-0.14[b]

HCFC R-244fa 3-Chloro-1,1,1,3-tetrafluoropropane C3H3F4Cl 0.009-0.14[b]

HCFC R-244fb 1-Chloro-1,1,3,3-tetrafluoropropane C3H3F4Cl 2730-64-5 0.009-0.14[b]

HFC R-245ca 1,1,2,2,3-Pentafluoropropane C3H3F5 679-86-7 6.2[1] 0[11] 716[3]

HFC R-245cb Pentafluoropropane C3H3F5 1814-88-6 0[d]

HFC R-245ea 1,1,2,3,3-Pentafluoropropane C3H3F5 24270-66-4 0[d]

HFC R-245eb 1,1,1,2,3-Pentafluoropropane C3H3F5 431-31-2 0[d]

HFC R-245fa 1,1,1,3,3-Pentafluoropropane C3H3F5 460-73-1 7.6[1] 0[11][13] 858[3] 3

HFC R-245mc Methyl pentafluoroethyl ether C3H3F5O 22410-44-2 0[d]

HFC R-245mf Difluoromethyl 2,2,2-trifluoroethyl ether C3H3F5O 1885-48-9 2.2[2] 0[d] 286[2]

HFC R-245qc Difluoromethyl 1,1,2-trifluoroethyl ether C3H3F5O 69948-24-9 0[d]

HCFC R-251 Trichlorofluoropropane C3H4FCl3 134190-51-5 0.001-0.01[12]

HCFC R-252 Dichlorodifluoropropane C3H4F2Cl2 134190-52-6 0.005-0.04[12]

HCFC R-252ca 1,3-Dichloro-2,2-difluoropropane C3H4F2Cl2 1112-36-3 0.005-0.04[b]

HCFC R-252cb 1,1-Dichloro-2,2-difluoropropane C3H4F2Cl2 1112-01-2 0.005-0.04[b]

HCFC R-252dc 1,2-Dichloro-1,1-difluoropropane C3H4F2Cl2 0.005-0.04[b]

HCFC R-252ec 1,1-Dichloro-1,2-difluoropropane C3H4F2Cl2 0.005-0.04[b]

HCFC R-253 Chlorotrifluoropropane C3H4F3Cl 134237-44-8 0.003-0.03[12]

HCFC R-253ba 2-Chloro-1,2,3-trifluoropropane C3H4F3Cl 0.003-0.03[b]

HCFC R-253bb 2-Chloro-1,1,2-trifluoropropane C3H4F3Cl 0.003-0.03[b]

HCFC R-253ca 1-Chloro-2,2,3-trifluoropropane C3H4F3Cl 56758-54-4 0.003-0.03[b]

HCFC R-253cb 1-Chloro-1,2,2-trifluoropropane C3H4F3Cl 70192-76-6 0.003-0.03[b]

HCFC R-253ea 3-Chloro-1,1,2-trifluoropropane C3H4F3Cl 0.003-0.03[b]

HCFC R-253eb 1-Chloro-1,2,3-trifluoropropane C3H4F3Cl 0.003-0.03[b]

HCFC R-253ec 1-Chloro-1,1,2-trifluoropropane C3H4F3Cl 0.003-0.03[b]

HCFC R-253fa 3-Chloro-1,3,3-trifluoropropane C3H4F3Cl 0.003-0.03[b]

HCFC R-253fb 3-Chloro-1,1,1-trifluoropropane C3H4F3Cl 460-35-5 0.003-0.03[b]

HCFC R-253fc 1-Chloro-1,1,3-trifluoropropane C3H4F3Cl 0.003-0.03[b]

HFC R-254cb 1,1,2,2-Tetrafluoropropane C3H4F4 40723-63-5 0[d]

HFC R-254pc Methyl 1,1,2,2-tetrafluoroethyl ether C3H4F4O 425-88-7 2.6[1] 0[d] 359[1]

HCFC R-261 Dichlorofluoropropane C3H5FCl2 134237-45-9 0.002-0.02[b]

HCFC R-261ba 1,2-Dichloro-2-fluoropropane C3H5FCl2 420-97-3 0.002-0.02[12]

HCFC R-262 Chlorodifluoropropane C3H5F2Cl 134190-53-7 0.002-0.02[12]

HCFC R-262ca 1-Chloro-2,2-difluoropropane C3H5F2Cl 420-99-5 0.002-0.02[b]

HCFC R-262fa 3-Chloro-1,1-difluoropropane C3H5F2Cl 0.002-0.02[b]

HCFC R-262fb 1-Chloro-1,3-difluoropropane C3H5F2Cl 0.002-0.02[b]

HFC R-263 Trifluoropropane C3H5F3 0[d]

HCFC R-271 Chlorofluoropropane C3H6FCl 134190-54-8 0.001-0.03[12]

HCFC R-271b 2-Chloro-2-fluoropropane C3H6FCl 420-44-0 0.001-0.03[b]

HCFC R-271d 2-Chloro-1-fluoropropane C3H6FCl 0.001-0.03[b]

HCFC R-271fb 1-Chloro-1-fluoropropane C3H6FCl 0.001-0.03[b]

HFC R-272 Difluoropropane C3H6F2 0[d]

HFC R-281 Fluoropropane C3H7F 0[d]

HC R-290 Propane C3H8 or CH3CH2CH3 74-98-6 12 ± 3[e] < 0(smog)[e] 3.3[1]

74.6 ± 3(E),114.1 0.40(E), 4,160(E),

CFC R-C316 Dichlorohexafluorocyclobutane C4Cl2F6 356-18-3
± 10 (Z)[20] 0.49(Z)[20] 5,400(Z)[20]

CFC R-C317 Chloroheptafluorocyclobutane C4ClF7 377-41-3

PFC R-C318 Octafluorocyclobutane (Perfluorocyclobutane) C4F8 or -(CF2)4- 115-25-3 3,200[1] 0[11] 10,300[1]

PFC R-3-1-10 Decafluorobutane (Perfluorobutane) C4F10 355-25-9 2,600[1] 0[11] 8,860[1]

HFC R-329ccb 1,1,1,2,2,3,3,4,4-Nonafluorobutane C4HF9 375-17-7 0[d]

HFC R-338eea 1,1,1,2,3,4,4,4-Octafluorobutane C4H2F8 75995-72-1 0[d]

HFC R-347ccd 1,1,1,2,2,3,3-Heptafluorobutane C4H3F7 662-00-0 0[d]

HFC R-347mcc Perfluoropropyl methyl ether C4H3F7O 375-03-1 5.2[1] 0[d] 575[1]

HFC R-347mmy Perfluoroisopropyl methyl ether C4H3F7O 22052-84-2 3.4[2] 0[d] 343[2]

HFC R-365mfc 1,1,1,3,3-Pentafluorobutane C4H5F5 406-58-6 8.6[1] 0[11][13] 804[1]

PFC R-4-1-12 Dodecafluoropentane (Perfluoropentane) C5F12 678-26-2 4,100[1] 0[11] 9,160[1]

PFC R-5-1-14 Tetradecafluorohexane (Perfluorohexane) C6F14 355-42-0 3,200[1] 0[11] 9,300[1]

50% CCl2F2 ·
R-12/114(50/50 wt%) OR 50% C2F4Cl2 OR 200[note 1] OR 10,450[note 1]
CFC R-400 1.0[note 2]
(60/40)(must be specified) 60% CCl2F2 · 180[note 1] 10,540[note 1]
40% C2F4Cl2

53±2% CHClF2 ·
HCFC R-401A R-22/152a/124 (53±2/13+.5,-1.5/34±1) 13+.5,-1.5% C2H4F2 · MP-39[7][22] 8.514[note 1] 0.03398[note 2] 1,182[note 1]
34±1% C2HF4Cl

61±2% CHClF2 ·
HCFC R-401B R-22/152a/124 (61±2/11+.5,-1.5/28±1) 11+.5,-1.5% C2H4F2 · MP-66[7][22] 9.098[note 1] 0.03666[note 2] 1,288[note 1]
28±1% C2HF4Cl

33±2% CHClF2 ·
HCFC R-401C R-22/152a/124 (33±2/15+.5,-1.5/52±1) 15+.5,-1.5% C2H4F2 · MP-52[22] 7.186[note 1] 0.02794[note 2] 933[note 1]
52±1% C2HF4Cl

60±2% C2HF5 ·
HCFC R-402A R-125/290/22 (60±2/2±1/38±2) 2±1% C3H8 · HP-80[7][22] 22.2?[note 1] 0.019[note 2] 2,788[note 1]
38±2% CHClF2

38±2% C2HF5 ·
HCFC R-402B R-125/290/22 (38±2/2±1/60±2) 2±1% C3H8 · HP-81[7][22] 18.46?[note 1] 0.03[note 2] 2,416[note 1]
60±2% CHClF2

5+.2,-2% C3H8 ·
ISCEON 69-
HCFC R-403A R-290/22/218 (5+.2,-2/75±2/20±0) 75±2% CHClF2 · 529.6?[note 1] 0.0375[note 2] 3,124[note 1]
S[7]
20±0% C3F8

5+.2,-2% C3H8 ·
ISCEON 69-
HCFC R-403B R-290/22/218 (5+.2,-2/56±2/39±0) 56±2% CHClF2 · 1,021.32?[note 1] 0.028[note 2] 4,457[note 1]
L[7]
39±0% C3F8

HFC R-404A R-125/143a/134a (44±2/52±1/4±2) 44±2% C2HF5 · HP-62,[7][22] 40.36[note 1] 0[note 2] 3,922[note 1]
52±1% C2H3F3 · FX-70[7][22]
 4±2% C2H2F4

45±0% CHClF2 ·
7±1% C2H4F2 · GREENCOOL
HCFC R-405A R-22/152a/142b/C318 (45±0/7±1/5.5±1/42.5±2) 1,366.4825[note 1] 0.02635[note 2] 5,328[note 1] 1
5.5±1% C2H3F2Cl · G2015[7]
42.5±2% C4F8

55±2% CHClF2 ·
HCFC R-406A R-22/600a/142b (55±2/4±1/41±0) 4±1% C4H10 · GHG[7][22] 14.419?[note 1] 0.0562[note 2] 1,943[note 1]
41±0% C2H3F2Cl

65±2% CHClF2 ·
HCFC R-406B R-22/600a/142b (65±2/4±1/31±0) 4±1% C4H10 · GHG-HP[7] 13.829?[note 1] 0.0542[note 2] 1,893[note 1] 1
31±0% C2H3F2Cl

20±2% CH2F2 ·
HFC R-407A R-32/125/134a (20±2/40±2/40±2) 40±2% C2HF5 · Klea 60[7][22] 18.18[note 1] 0[note 2] 2,107[note 1]
40±2% C2H2F4

10±2% CH2F2 ·
HFC R-407B R-32/125/134a (10±2/70±2/20±2) 70±2% C2HF5 · Klea 61[7] 23.59[note 1] 0[note 2] 2,804[note 1]
20±2% C2H2F4

23±2% CH2F2 ·
Klea 66,[7]
HFC R-407C R-32/125/134a (23±2/25±2/52±2) 25±2% C2HF5 · 15.657[note 1] 0[note 2] 1,774[note 1]
52±2% C2H2F4 AC9000[22]

15±2% CH2F2 ·
HFC R-407D R-32/125/134a (15±2/15±2/70±2) 15±2% C2HF5 · 14.885[note 1] 0[note 2] 1,627[note 1]
70±2% C2H2F4

25±2% CH2F2 ·
HFC R-407E R-32/125/134a (25±2/15±2/60±2) 15±2% C2HF5 · 13.975[note 1] 0[note 2] 1,552[note 1]
60±2% C2H2F4

30±2% CH2F2 · Genetron

HFC R-407F R-32/125/134a (30±2/30±2/40±2) 30±2% C2HF5 · Performax 15.77[note 1] 0[note 2] 1,825[note 1]
40±2% C2H2F4 LT[22]

7±2% C2HF5 ·
HCFC R-408A R-125/143a/22 (7±2/46±1/47±2) 46±1% C2H3F3 · FX-10[7][22] 31.59[note 1] 0.0235[note 2] 3,152[note 1]
47±2% CHClF2

60±2% CHClF2 ·
HCFC R-409A R-22/124/142b (60±2/25±2/15±1) 25±2% C2HF4Cl · FX-56[7][22] 11.335[note 1] 0.046[note 2] 1,585[note 1]
15±1% C2H3F2Cl

65±2% CHClF2 ·
HCFC R-409B R-22/124/142b (65±2/25±2/10±1) 25±2% C2HF4Cl · FX-57[7] 11.04[note 1] 0.045[note 2] 1,560[note 1]
10±1% C2H3F2Cl

AZ-20,[7]
50+.5,–1.5% CH2F2 ·
HFC R-410A R-32/125 (50+.5,–1.5/50+1.5,–.5)
50+1.5,–.5% C2HF5 Puron,[7] Suva 16.95[note 1] 0[note 2] 2,088[note 1]
9100[7]
45±1% CH2F2 ·
HFC R-410B R-32/125 (45±1/55±1) AC9100[22] 18.155[note 1] 0[note 2] 2,229[note 1] 1
55±1% C2HF5

1.5+0,–1% C3H6 ·
GREENCOOL
HCFO R-411A R-1270/22/152a (1.5+0,–1/87.5+2,–0/11+0,–1) 87.5+2,–0% CHClF2 · 10.834[note 1] 0.04375[note 2] 1,597[note 1] 9
G2018a[7]
11+0,–1% C2H4F2

3+0,–1% C3H6 · 94+2,–

GREENCOOL
HCFO R-411B R-1270/22/152a (3+0,–1/94+2,–0/3+0,–1) 0% CHClF2 · 3+0,– 11.682[note 1] 0.047[note 2] 1,705[note 1] 9
G2018b[7]
1% C2H4F2

3+0,–1% C3H6 ·
GREENCOOL
HCFO R-411C R-1270/22/152a (3+0,–1/95.5+2,–0/1.5+0,–1) 95.5+2,–0% CHClF2 · 11.841[note 1] 0.04775[note 2] 1,730[note 1]
G2018c[7]
1.5+0,–1% C2H4F2

70±2% CHClF2 ·
Arcton
HCFC R-412A R-22/218/142b (70±2/5±2/25±1) 5±2% C3F8 · 142.875[note 1] 0.0525[note 2] 2,286[note 1]
TP5R[7]
25±1% C2H3F2Cl

9±1% C3F8 ·
HFC R-413A R-218/134a/600a (9±1/88±2/3+0,–1) 88±2% C2H2F4 · 3+0,– ISCEON 49[7] 246.68?[note 1] 0[note 2] 2,053[note 1]
1% C4H10

51±2% CHClF2 ·
GHG-X4,[7]
R-22/124/600a/142b 28.5±2% C2HF4Cl ·
HCFC R-414A Autofrost,[7] 11.2065?[note 1] 0.04332[note 2] 1,478[note 1]
(51±2/28.5±2/4±.5/16.5+.5,–1) 4±.5% C4H10 ·
16.5+.5,–1% C2H3F2Cl Chill-It[7]

50±2% CHClF2 ·
Hot
R-22/124/600a/142b (50±2/39±2/1.5±.5/9.5+.5,– 39±2% C2HF4Cl ·
HCFC R-414B Shot,[7][22] 10.1425?[note 1] 0.04023[note 2] 1,362[note 1]
1) 1.5±.5% C4H10 ·
Kar Kool[7]
9.5+.5,–1% C2H3F2Cl

82±1% CHClF2 ·
HCFC R-415A R-22/152a (82±1/18±1) 10.092[note 1] 0.041[note 2] 1,507[note 1]
18±1% C2H4F2

25±1% CHClF2 ·
HCFC R-415B R-22/152a (25±1/75±1) 4.05[note 1] 0.0125[note 2] 546[note 1]
75±1% C2H4F2

59+.5,-1% C2H2F4 ·
R-134a/124/600 (59+.5,– FRIGC (FR-
HCFC R-416A 39.5+1,–.5% C2HF4Cl · 10.731?[note 1] 0.00869[note 2] 1,084[note 1]
1/39.5+1,–.5/1.5+1,–.2) 12)[7]
1.5+1,–.2% C4H10

HFC R-417A R-125/134a/600 (46.6±1.1/50±1/3.4+.1,–.4) 46.6±1.1% C2HF5 · ISCEON 59,[7] 20.922?[note 1] 0[note 2] 2,346[note 1]
50±1% C2H2F4 · NU-22[7]
3.4+.1,–.4% C4H10
 79±1% C2HF5 ·
HFC R-417B R-125/134a/600 (79±1/18.3±1/2.7+.1,–.5) 18.3±1% C2H2F4 · 25.796?[note 1] 0[note 2] 3,027[note 1]
2.7+.1,–.5% C4H10

1.5±.5% C3H8 ·
HCFC R-418A R-290/22/152a (1.5±.5/96±1/2.5±.5) 96±1% CHClF2 · 11.735?[note 1] 0.048[note 2] 1,741[note 1]
2.5±.5% C2H4F2

77±1% C2HF5 ·
HFC R-419A R-125/134a/E170 (77±1/19±1/4±1) 19±1% C2H2F4 · 24.9906[note 1] 0[note 2] 2,967[note 1]
4±1% C2H6O

88+1,–0% C2H2F4 · Choice

HCFC R-420A R-134a/142b (88+1,–0/12+0,–1) 14.468[note 1] 0.0084[note 2] 1,548[note 1]
12+0,–1% C2H3F2Cl Refrigerant[22]

58±1% C2HF5 · Choice

HFC R-421A R-125/134a (58±1/42±1) 22.7[note 1] 0[note 2] 2,631[note 1]
42±1% C2H2F4 R421A[22]

85±1% C2HF5 · Choice

HFC R-421B R-125/134a (85±1/15±1) 26.75[note 1] 0[note 2] 3,190[note 1]
15±1% C2H2F4 421B[22]

85.1±1% C2HF5 ·
ISCEON
HFC R-422A R-125/134a/600a (85.1±1/11.5±1/3.4+.1,–.4) 11.5±1% C2H2F4 · 26.697?[note 1] 0[note 2] 3,143[note 1]
79[22]
3.4+.1,–.4% C4H10

55±1% C2HF5 ·
ICOR
HFC R-422B R-125/134a/600a (55±1/42±1/3+.1,–.5) 42±1% C2H2F4 · 22.19?[note 1] 0[note 2] 2,526[note 1]
XAC1[22]
3+.1,–.5% C4H10

82±1% C2HF5 ·
ICOR
HFC R-422C R-125/134a/600a (82±1/15±1/3+.1,–.5) 15±1% C2H2F4 · 26.24?[note 1] 0[note 2] 3,085[note 1]
XLT1[22]
3+.1,–.5% C4H10

65.1+.9,–1.1% C2HF5 ·
R-125/134a/600a (65.1+.9,– ISCEON
HFC R-422D 31.5±1% C2H2F4 · 23.697?[note 1] 0[note 2] 2,729[note 1]
1.1/31.5±1/3.4+.1,–.4) MO29[22]
3.4+.1,–.4% C4H10

52.5±1% C2H2F4 ·
HFC R-423A R-134a/227ea (52.5±1/47.5±1) 23.595[note 1] 0[note 2] 2,280[note 1]
47.5±1% C3HF7

50.5±1% C2HF5 ·
R-125/134a/600a/600/601a 47±1% C2H2F4 · RS-44 (new
HFC R-424A 21.525?[note 1] 0[note 2] 2,440?[note 1] 9
(50.5±1/47±1/.9+.1,–.2/1+.1,+.2/.6+.1,–.2) 1.9+.3,–.1% C4H10 · comp.)[22]
.6+.1,–.2% C5H12

18.5±.5% CH2F2 ·
HFC R-425A R-32/134a/227ea (18.5±.5/69.5±.5/12±.5) 69.5±.5% C2H2F4 · 14.7405[note 1] 0[note 2] 1,505[note 1]
12±.5% C3HF7

5.1±1% C2HF5 ·
R-125/134a/600/601a 93±1% C2H2F4 · RS-24 (new
HFC R-426A 14.727?[note 1] 0[note 2] 1,508?[note 1] 9
(5.1±1/93±1/1.3+.1,–.2/.6+.1,–.2) 1.3+.1,–.2% C4H10 · comp.)[22]
.6+.1,–.2% C5H12

15±2% CH2F2 ·
25±2% C2HF5 · Forane
HFC R-427A R-32/125/143a/134a (15±2/25±2/10±2/50±2) 20.185[note 1] 0[note 2] 2,138[note 1]
10±2% C2H3F3 · 427A[22]
50±2% C2H2F4

77.5±1% C2HF5 ·
R-125/143a/290/600a 20±1% C2H3F3 ·
HFC R-428A RS-52[22] 33.175?[note 1] <0(smog)[note 2] 3,607[note 1]
(77.5±1/20±1/.6+.1,–.2/1.9+.1,–.2) .6+.1,–.2% C3H8 ·
1.9+.1,–.2% C4H10

60±1% C2H6O ·
HFC R-429A R-E170/152a/600a (60±1/10±1/30±1) 10±1% C2H4F2 · 3.749?[note 1] <0(smog)[note 2] 13.9[note 1]
30±1% C4H10

76±1% C2H4F2 ·
HFC R-430A R-152a/600a (76±1/24±1) 3.944?[note 1] 0[note 2] 95[note 1]
24±1% C4H10

71±1% C3H8 ·
HFC R-431A R-290/152a (71±1/29±1) 8.926?[note 1] <0(smog)[note 2] 38.3[note 1]
29±1% C2H4F2

80±1% C3H6 ·
HO R-432A R-1270/E170 (80±1/20±1) 9.603?[note 1] <0(smog)[note 2] 1.64[note 1] 7
20±1% C2H6O

30±1% C3H6 ·
HO R-433A R-1270/290 (30±1/70±1) 12 ± 3[e] < 0(smog)[e] 2.85[note 1] 8
70±1% C3H8

5±1% C3H6 ·
HO R-433B R-1270/290 (5±1/95±1) 12 ± 3[e] < 0(smog)[e] 3.23[note 1]
95±1% C3H8

25±1% C3H6 ·
HO R-433C R-1270/290 (25±1/75±1) 12 ± 3[e] < 0(smog)[e] 2.93[note 1]
75±1% C3H8

63.2±1% C2HF5 ·
R-125/143a/134a/600a 18±1% C2H3F3 ·
HFC R-434A RS-45[22] 30.264?[note 1] 0[note 2] 3,245[note 1]
(63.2±1/18±1/16±1/2.8+.1,–.2) 16±1% C2H2F4 ·
2.8+.1,–.2% C4H10

80±1% C2H6O ·
HFC R-435A R-E170/152a (80±1/20±1) 0.292[note 1] <0(smog)[note 2] 25.6[note 1]
20±1% C2H4F2

56±1% C3H8 ·
HC R-436A R-290/600a (56±1/44±1) 12 ± 3[e] <0(smog)[note 2] 3.17[note 1]
44±1% C4H10

52±1% C3H8 ·
HC R-436B R-290/600a (52±1/48±1) 12 ± 3[e] <0(smog)[note 2] 3.16[note 1]
48±1% C4H10
HFC R-437A R-125/134a/600/601 (19.5+.5,– 19.5+.5,–1.8% C2HF5 · 16.885?[note 1] 0[note 2] 1,805?[note 1] 9
1.8/78.5+1.5,–.7/1.4+.1,–.2/.6+.1,–.2) 78.5+1.5,–.7% C2H2F4 ·
1.4+.1,–.2% C4H10 ·
.6+.1,–.2% C5H12

8.5+.5,-1.5% CH2F2 ·
45±1.5% C2HF5 · KDD5,[22]
R-32/125/134a/600/601a
HFC R-438A 44.2±1.5% C2H2F4 · ISCEON 19.9305?[note 1] 0[note 2] 2,265?[note 1]
(8.5+.5,-1.5/45±1.5/44.2±1.5/1.7+.1,-.2/.6+.1,-.2)
1.7+.1,-.2% C4H10 · MO99[22]
.6+.1,-.2% C5H12

50±1% CH2F2 ·
HFC R-439A R-32/125/600a (50±1/47±1/3±.5) 47±1% C2HF5 · 16.44?[note 1] 0[note 2] 1,983[note 1]
3±.5% C4H10

.6±.1% C3H8 ·
HFC R-440A R-290/134a/152a (.6±.1/1.6±.6/97.8±.5) 1.6±.6% C2H2F4 · 1.6652?[note 1] <0(smog)[note 2] 144[note 1]
97.8±.5% C2H4F2

3.1±.3% C2H6 ·
R-170/290/600a/600
HC R-441A 54.8±2% C3H8 · HCR-188C[22] 12 ± 3[e] <0(smog)[note 2] 3.6[note 1]
(3.1±.3/54.8±2/6±.6/36.1±2)
42.1±2.6% C4H10

75.5% C3H2F4 · 21.5%

HFO R-455A R-1234yf/32/744 (75.5%/21.5%/3%) 146[29]
CH2F2 · 3% CO2

20.5% C2F2 · 4.0%

R-32/125/134a/227ea/236fa C2HF5 · 61.4%
HFC R-458A 1,650[30]
(20.5%/4.0%/61.4%/13.5%/0.6%) C2H3F3 · 13.5%
C3HF7 · 0.6% C3H2F6

73.8% CCl2F2 ·
HCFC R-500 R-12/152a (73.8/26.2) Carrene #7[7] 74.1668[note 1] 0.738[note 2] 8,077[note 1]
26.2% C2H4F2

75% CHClF2 ·
HCFC R-501 R-22/12 (75/25) 34[note 1] 0.2875[note 2] 4,083[note 1]
25% CCl2F2

48.8% CHClF2 ·
HCFC R-502 R-22/115 (48.8/51.2) 876.256[note 1] 0.24968[note 2] 4,657[note 1]
51.2% C2F5Cl

40.1% CHF3 ·
HCFC R-503 R-23/13 (40.1/59.9) 491.63[note 1] 0.599[note 2] 14,560[note 1] 1
59.9% CClF3

48.2% CH2F2 ·
HCFC R-504 R-32/115 (48.2/51.8) 882.9618[note 1] 0.22792[note 2] 4,143[note 1] 1
51.8% C2F5Cl

78% CCl2F2 ·
HCFC R-505 R-12/31 (78/22) 78.0836+[note 1] 0.7844[note 2] 8,504+[note 1]
22% CH2FCl

55.1% CH2FCl ·
HCFC R-506 R-31/114 (55.1/44.9) 134.90938+[note 1] 0.46002[note 2] 4,495+[note 1]
44.9% C2F4Cl2

50% C2HF5 ·
HFC R-507[A] R-125/143a (50/50) AZ-50[7][22] 40.5[note 1] 0[note 2] 3,985[note 1]
50% C2H3F3

Klea
HFC R-508[A] R-23/116 (39/61) 39% CHF3 · 61% C2F6 6,205.3[note 1] 0[note 2] 13,214[note 1]
5R3[7][22]

HFC R-508B R-23/116 (46/54) 46% CHF3 · 54% C2F6 Suva 95[7][22] 5,524.2[note 1] 0[note 2] 13,396[note 1]

44% CHClF2 · Arcton

HCFC R-509[A] R-22/218 (44/56) 1,461.28[note 1] 0.022[note 2] 5,741[note 1]
56% C3F8 TP5R2[7]

88±.5% C2H6O ·
HC R-510[A] R-E170/600a (88±.5/12±.5) 1.4532?[note 1] <0(smog)[note 2] 1.24[note 1]
12±.5% C4H10

95±1% C3H8 ·
HC R-511[A] R-290/E170 (95±1/5±1) 11.40075?[note 1] < 0(smog)[e] 3.19[note 1]
5±1% C2H6O

56% C3H2F4 · 44%

HFO R-513A R-1234yf/134a (56%/44%) 0[31] 573[31]
C2H2F2

C4H10 or
HC R-600 Butane 106-97-8 12 ± 3[e] 0[13] 4.0[1]
CH3CH2CH2CH3

HC R-600a Isobutane C4H10 or CH(CH3)2CH3 75-28-5 12 ± 3[32][e] 0[13][33] 3[33]

C5H12 or
HC R-601 Pentane 109-66-0 12 ± 3[e] 0[13] 4 ± 2[f] 60
CH3CH2CH2CH2CH3

C5H12 or
HC R-601a Isopentane 78-78-4 12 ± 3[e] 0[13] 4 ± 2[f] 6
(CH3)2CHCH2CH3

HC R-610 Ethoxyethane (Diethyl ether) CH3CH2OCH2CH3 60-29-7 12 ± 3[e] < 0(smog)[e] 4 ± 2[f] 4

HC R-611 Methyl formate HCOOCH3 107-31-3 12 ± 3[e] 0[13][33] < 25[13][33] 1

R-630 Methylamine CH3NH2 74-89-5

R-631 Ethylamine CH3CH2(NH2) 75-04-7

R-702 Hydrogen H2 1333-74-0 5.8[1]

R-704 Helium He 7440-59-7 Unlimited[g] 0[g] 0[g] 9

R-717 Ammonia NH3 7664-41-7 < 0.019165[34] 0[34] 0[34] 25

R-718 Water/Steam H2O 7732-18-5 0.026 0[36] 0.2 ± 0.2[1]

R-720 Neon Ne 7440-01-9 Unlimited[g] 0[g] 0[g] 9
 R-728 Nitrogen N2 7727-37-9 Unlimited[g] 0[g] 0[g]
78.082% N2 ·
R-729 Air N2/O2/Ar (78.082/20.945/.934 vol%) Unlimited[g] 0[36][g] 0.00054+[1]
20.945% O2 · .934% Ar

R-732 Oxygen O2 7782-44-7 Unlimited[g] < 0[g] 0[g]

R-740 Argon Ar 7440-37-1 Unlimited[g] 0[g] 0[g] 9

R-744 Carbon dioxide CO2 124-38-9 29,300-36,100[37] 0[13] 1[1]

R-744A Nitrous oxide N2O 10024-97-2 114[1] 0.017[17] 265[3]

R-764 Sulfur dioxide SO2 7446-09-5 5

R-784 Krypton Kr 7439-90-9 Unlimited[g] 0[g] 0[g] 9

CFO R-1112a 1,1-Dichloro-2,2-difluoroethylene C2Cl2F2 79-35-6

CFO R-1113 Chlorotrifluoroethylene C2ClF3 79-38-9

PFO R-1114 Tetrafluoroethylene C2F4 116-14-3 0[d]

HCO R-1120 Trichloroethylene (trielene) C2HCl3 79-01-6

HCO R-1130 cis-1,2-Dichloroethylene C2H2Cl2 156-59-2 0[13] < 25[13]

HFO R-1132a 1,1-Difluoroethylene C2H2F2 75-38-7 0[d]

HCO R-1140 Chloroethylene (vinyl chloride) C2H3Cl 75-01-4 1

HFO R-1141 Fluoroethylene (vinyl fluoride) C2H3F 75-02-5 0[d]

HO R-1150 Ethene (Ethylene) CH2=CH2 74-85-1 12 ± 3[e] < 0(smog)[e] 3.7[1] 2

PFO R-1216 Hexafluoropropylene C3F6 116-15-4 1,000+[1][2] 0[d] 17,340+[1]

PFO R-1218 Hexafluoropropene trimer (C3F6)3 6792-31-0 0[d]

HCFO R-1233zd 1-Chloro-3,3,3-trifluoropropene C3H2ClF3 2730-43-0 0.0712328[40] 0[40] 1[40]

HFO R-1234yf 2,3,3,3-Tetrafluoropropene C3H2F4 754-12-1 0.030116[41] 0[33] 4[33][41]

HFO R-1234ze 1,3,3,3-Tetrafluoropropene C3H2F4 1645-83-6 0[33] 6[33]

HO R-1270 Propene (Propylene) C3H6 or CH3CH=CH2 115-07-1 12 ± 3[e] < 0(smog)[e] 1.8[1] 5
CAS
registry Atmospheric Semi- net p
ASHRAE Molecular
Type IUPAC Chemical Name number/ Lifetime Empirical GWP A
Number Formula
Blend (years) ODP 100-yr
Name

Type and flammability

Legends

Types / Prefixes[44] Safety Classification of Refrigerants[45]

Type Meaning Atoms in the Molecule Flammability in Air @ 60 °C & 101.3 kPa ASHRAE 34 Safety group
CFC Chlorofluorocarbon Higher Flammability
Cl, F, C LFL or ETFL60 = 100 g/m3 OR HOC = 19 A3 B3
CFO Chlorofluoroolefin
MJ/kg[46]
HCFC Hydrochlorofluorocarbon
H, Cl, F, C Lower Flammability
HCFO Hydrochlorofluoroolefin LFL or ETFL60 > 100 g/m3 & HOC < 19 A2 B2
MJ/kg[46]
HFC Hydrofluorocarbon
H, F, C Lower Flammability
HFO Hydrofluoroolefin
LFL or ETFL60 > 100 g/m3 & HOC < 19
A2L B2L
HCC Hydrochlorocarbon MJ/kg[46]
H, Cl, C with a maximum burning velocity of = 10 cm/s
HCO Hydrochloroolefin
No flame Propagation A1 B1
HC Hydrocarbon
H, C Lower Toxicity Higher Toxicity
HO Hydroolefin (Alkene) Flammability in Air @ 60 °C & 101.3 kPa OEL OEL
PFC Perfluorocarbon ≥ 400 ppm[25] < 400 ppm[25]
F, C
PFO Perfluoroolefin
LFL = Lower Flammability Limit
PCC Perchlorocarbon ETFL60 = Elevated Temperature Flame Limit @ 60 °C
Cl, C
PCO Perchloroolefin HOC = Heat Of Combustion
Br, Cl (in some but not all), F, H (in some but
H Halon/Haloalkane
not all), C

Compounds used as refrigerants may be described using either the appropriate prefix above or with the prefixes "R-" or "Refrigerant." Thus, CFC-12 may also
be written as R-12 or Refrigerant 12.
An alkene, olefin, or olefine is an unsaturated chemical compound containing at least one carbon-to-carbon double bond.[47]

Educated Estimates
a. Some CFCs are assumed to be similar in terms of Semi-Empirical
ODP being one.[2][10]
b. Some HCFCs are assumed to be similar in terms of Semi-Empirical
ODP.[2][12]
c. Some HCFCs are assumed to be similar in terms of Atmospheric
Lifetime[1][2] & net GWP over a 100-year time horizon.[1][2]
d. All HFCs, HFOs, PFCs & PFOs are assumed to be similar in terms
of Semi-Empirical ODP being zero.[11][13]
See also
Haloalkane
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Notes
1. Blend Calculation using the following information: (a) Hydrocarbons
are assumed to be similar to Methane in terms of Atmospheric
Lifetime being 12 ± 3 years, (b) Pentane & Isopentane is assumed
to have a net GWP over 100-yr to be 4 ± 2
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47. Wade, Leroy G. Jr. (2006). Organic Chemistry (Sixth ed.). Upper
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2. Blend Calculation using the following information:[2][10][12][11][13][21]