Professional Documents
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Epoxy Composites:
Impact Resistance and
Flame Retardancy
Debdatta Ratna
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Item 1
Source of
Macromolecules
original article
33, No.6, 21st March 2000, p.2171-83
Title EFFECT OF THERMAL HISTORY ON THE RHEOLOGICAL
BEHAVIOR OF THERMOPLASTIC POLYURETHANES
Authors and
Pil Joong Yoon; Chang Dae Han affiliation
Akron,University
The effect of thermal history on the rheological behaviour of ester- and ether-
based commercial thermoplastic PUs (Estane 5701, 5707 and 5714 from
B.F.Goodrich) was investigated. It was found that the injection moulding
temp. used for specimen preparation had a marked effect on the variations
of dynamic storage and loss moduli of specimens with time observed
during isothermal annealing. Analysis of FTIR spectra indicated that
variations in hydrogen bonding with time during isothermal annealing very Abstract
much resembled variations of dynamic storage modulus with time during
isothermal annealing. Isochronal dynamic temp. sweep experiments indicated
that the thermoplastic PUs exhibited a hysteresis effect in the heating and
cooling processes. It was concluded that the microphase separation transition
or order-disorder transition in thermoplastic PUs could not be determined
from the isochronal dynamic temp. sweep experiment. The plots of log
dynamic storage modulus versus log loss modulus varied with temp. over
the entire range of temps. (110-190C) investigated. 57 refs. Companies or
GOODRICH B.F. organisations
Location USA mentioned
Accession no.771897
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Epoxy Composites: Impact
Resistance and Flame
Retardancy
Debdatta Ratna
(IPTME, Loughborough University)
ISBN: 978-1-84735-065-7
Epoxy Composites: Impact Resistance and Flame Retardancy
Contents
1. Introduction .................................................................................................................................................3
2. Thermosetting Composites .........................................................................................................................3
3. Epoxy Resins................................................................................................................................................3
3.1 Chemorheology and Curing of Epoxy...............................................................................................5
4. Epoxy Composites.......................................................................................................................................5
4.1 Fracture Testing.................................................................................................................................7
4.2 Fracture Mechanism..........................................................................................................................7
5. Impact Resistant Epoxy Composites............................................................................................................8
6. Modification of Epoxy Matrix.....................................................................................................................8
6.1 Flexibilisation of Epoxy....................................................................................................................8
6.2 Toughening of Epoxy........................................................................................................................9
6.3 Liquid Rubber Toughening................................................................................................................9
6.3.1 Reaction-induced Phase Separation......................................................................................9
6.3.2 Mechanism of Toughening..................................................................................................11
6.3.3 Morphological Parameters..................................................................................................11
6.3.4 Recent Advances ................................................................................................................13
6.4 Toughening by Preformed Particle..................................................................................................15
6.5 Thermoplastic Toughening..............................................................................................................16
6.6 Rigid Particle Toughening...............................................................................................................17
7. Nanoreinforcement of Epoxy.....................................................................................................................17
7.1 Clay Reinforced Epoxy...................................................................................................................17
7.2 CNT-Reinforced Epoxy...................................................................................................................20
8. Simultaneous Nanoreinforcement and Toughening ..................................................................................21
9. Fire Retardant Epoxy Composites.............................................................................................................22
9.1 Flammability and Smoke Tests ...........................................................................................................22
9.1.1 UL-94 Flammability Test....................................................................................................22
9.1.2 Cone Calorimetry................................................................................................................22
9.1.3 LOI Test .............................................................................................................................22
10. Fire Retardant Resin Compositions...........................................................................................................23
10.1 Halogenated Flame Retardants........................................................................................................23
10.2 Phosphorus Containing Flame Retardants .....................................................................................23
10.3 Nanoclay-Based Flame Retardants ................................................................................................24
10.4 Combination of Organoclay and Other Flame Retardants..............................................................26
10.5 Intumescent Fire Retardants . .........................................................................................................26
11. Summary and Outlook ..............................................................................................................................26
12. List of Abbreviation and Acronyms...........................................................................................................27
1
Epoxy Composites: Impact Resistance and Flame Retardancy
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2
Epoxy Composites: Impact Resistance and Flame Retardancy
2 Thermosetting Composites
Over the last three decades, the use of PMC, has
increased tremendously and this dramatic growth is
expected to continue in the future. The composites
possess many useful properties such as high specific
stiffness and strength, dimensional stability, adequate
electrical properties and excellent corrosion resistance.
The implications are easy transportability, high payload
for vehicles, low stress for rotating parts, high ranges
for rockets and missiles, which make them attractive
for both the civil and defense applications (186,
32). The composite industry is currently dominated
by thermosetting resins namely epoxy, vinyl ester,
unsaturated polyester, phenolic, polyimides, cyanate
ester and so on. This is because of their availability,
relative ease of processing, lower cost of capital
equipment for processing and low material cost (a.1).
The thermosetting resins are available in oligomeric
or monomeric low viscosity liquid forms, which
have excellent flow properties to facilitate resin
impregnation of fibre bundles and proper wetting of
the fibre surface by the resin. They are characterised
by a crosslinking reaction or curing, which converts
those into a three-dimensional (3D) network form
(insoluble, infusible). Because of the crosslinked
Figure 1
structure, thermoset composites offer better creep
properties and environmental stress cracking resistance Chemical structures of commonly used amine curing
compared to many thermoplastics e.g., polycarbonate. agents
3
Epoxy Composites: Impact Resistance and Flame Retardancy
Undoubtedly, there exists more publications based on • availability of the resin ranging from low viscous
the basic and applied research on epoxy resins than that liquid to tack free solid, etc. Because of these unique
for any other commercially available thermosetting characteristics and useful properties of network
resins. The broad interest in epoxy resins originates polymers.
from the versatility of epoxy group towards a wide
variety of chemical reactions and the useful properties • epoxy resins are widely used in structural adhesives,
of the network polymers (a.2) such as high strength, surface coatings, engineering composites, and
very low creep, excellent corrosion and weather electrical laminates.
resistance, elevated temperature service capability and
adequate electrical properties. Epoxy resins are unique The most commonly used epoxy resin is diglycidyl
among all the thermosetting resins due to several factors ether of bisphenol-A (DGEBA), which is characterised
(a.1) (115) namely, minimum pressure is needed for by two epoxy groups e.g., LY-556, GY-250 (Ciba
fabrication of products normally used for thermosetting Gigey). Multifunctional epoxies with functionality of
resins: three and four are also available. Chemical structures
of DGEBA and multifunctional epoxies namely
• shrinkage is much lower and hence there is lower epoxy novolac (e.g., Dow DEN 438), tetraglycidyl
residual stress in the cured product than that ether of 4,4́-diamino diphenyl methane (TGDDM)
encountered in the vinyl polymerisation used to (e.g., Araldite MY-720, Ciba Speciality Chemicals),
cure unsaturated polyester resins. triglycidyl p-amino phenol (TGAP), (e.g. Araldite
MY 0510, Ciba Speciality Chemicals), are given in
• use of a wide range of temperature by judicious Figure 2. The chemical nature and the amount used
selection of curing agent with good control over of curing agents or hardeners plays an important role
the degree of crosslinking. in determining thermomechanical properties of the
Figure 2
Chemical structures of difunctional and multifunctional epoxies
4
Epoxy Composites: Impact Resistance and Flame Retardancy
cured networks (243). A wide range of properties can gel point, that is at a < agel, at least part of the polymer
be demonstrated and materials can be developed for is typically not soluble in any solvent and is called a gel.
extreme applications using the same resin, by judicious Kinetically, gelation does not usually inhibit the curing
selection of curing agents. For example, DGEBA, when process so the conversion rate remains unchanged.
cured with an aromatic amine, produces a network with Hence, it cannot be detected by the techniques sensitive
high glass transition temperature (Tg) and is used for only to chemical reaction like differential scanning
high temperature composite applications whereas the calorimetry (DSC) and thermogravimetric analysis
same resin, on curing with Jeffamine (Mn > 800 g/mole) (TGA). There are various methods to determine the gel
generates a flexible/rubbery network, which can be used point. The most sophisticated one is determination by
for vibration damping applications (81). using a rheological experiment. Another process, which
a thermoset resin undergoes during cure, is vitrification.
High Tg epoxy matrices can be made by using an It is defined as the point at which the Tg of the network
aromatic curing agent such as DDM, DDS, DETDA. has become the same as the cure temperature. At this
The advantage of DETDA over others is that it is a point, the material is transformed from a rubbery gel
liquid and offers better processability. The Tg can to a gelled glass.
be further increased by using a higher functionality
resin. Thermally stable high performance resins are Rheological measurement is generally carried out
required for use in composite structure for aerospace with a controlled stress rheometer using a parallel
applications. Polyimides and cyanate ester reins are the plate assembly. The dynamic viscoelastic test makes
leading candidates for exterior structural components. it possible to characterise the gelation and vitrification
Conventional epoxies are generally not suitable for process during curing. Various parameters such as
aerospace applications. However, multifunctional complex viscosity, storage modulus, loss modulus, loss
epoxies cured with a suitable aromatic amine, can offer factor at various frequencies (at a particular temperature)
thermal stability comparable to polyimides. Hence, can be determined as a function of cure time. The point
the conventional epoxy resins, with the combination at which clear increase in G̋ occurs is defined as gel
of a multifunctional component, can satisfy the point and G̋ maximum is defined as the vitrification
thermomechanical properties, specified for aerospace point. The gelation and vitrification are more clearly
application. determined from a loss factor plot as shown in Figure 3
for a trifunctional epoxy system (154).
3.1 Chemorheology and Curing of Epoxy This experiment clearly demonstrates the time required
for curing an epoxy system at a particular temperature
to get a required Tg, which is very important for
From the application point of view, the effective use
development of prepregs. It may be noted that when the
of any thermosetting system requires one to be able to
Tg of the cured system reaches the cure temperature,
predict the cure kinetics of the system to consistently
the curing reaction becomes very slow. That is why
obtain the maximum Tg and also to predict the flow
when a multifunctional epoxy network, without a post
curing treatment at a sufficiently high temperature, is
behaviour of the curing resin, in particular to precisely
locate when the sol-gel transitions occurs. This is
subjected to dynamic mechanical analysis, it shows two
because the polymer can be easily shaped or processed
loss peaks; one is for the partially cured network and
only before the gel point, where it can still flow and
other is for the fully cured network. Hence, it is very
can be easily formed with the stresses applied relaxed
important to give a proper post curing treatment to an
to zero thereafter. Accurate knowledge of the gel point
epoxy system (especially multifunctional epoxy system)
would therefore allow estimation of the optimum
to get a network with the desired Tg.
temperature and time for which the sample should be
heated before being allowed to set in the mould.
5
Epoxy Composites: Impact Resistance and Flame Retardancy
Figure 3
Loss factor versus time plots of toughened trifunctional epoxy at 140 °C using various frequencies
Reprinted with permission from D. Ratna, R. Varley and G.P. Simon, Journal of Applied Polymer Science, 2003,
89, 9, 2339. ©2003, John Wiley and Sons
fibres and by designing the interface. The FRP and safety benefits. However, the main drawback of
composites are used in aerospace, automotive and other RTM is the lower fibre volume fraction due to the
structural applications (222, 225, 232). Epoxy-based low pressure involved in the process. Moreover, the
FRP composites (for general purpose use) are made by property enhancement using 3D woven fabric due to
the wet-lay up technique and followed by compression through-the-thickness reinforcement and limiting crack
moulding. On the other hand, the prepreg route propagation is not achieved in RTM (218), although
(autoclave curing) is the standard production method a similar effect is achieved for wet lay-up with the
within the aerospace sector for manufacturing high fibre autoclave curing route. The reason is thought to be due
volume fraction, void free composite materials with to the 3D weave involved, having a high crimp and low
good mechanical properties (233). Similar laminated compressibility, hence, higher consolidation pressure
composites, produced by a vacuum impregnation resin than the pressure provided by RTM, is required to realise
transfer moulding (RTM), offer cost savings, health the actual advantages of a 3D weave.
6
Epoxy Composites: Impact Resistance and Flame Retardancy
However, the epoxy-based composites are known to be material are a function of testing speed and temperature.
highly susceptible to internal damage caused by a low Furthermore the values may be different under cyclic
velocity impact due to inherent brittleness of the cured load. Therefore application of KIc and GIc in the design
resin, which may lead to severe safety and reliability of service components should be made considering the
problems (226, 237). Thus, for high performance differences that may exist between the test condition
applications the improvement of damage tolerance of and the field condition.
epoxy composites by enhancing their impact strength
is essential and has been the subject of investigation Apart from the fracture toughness analysis, various
throughout the world (280, 285). impact tests are used for quick assessment of the
behaviour of a material under dynamic loading
conditions. The impact tests are used to determine the
4.1 Fracture Testing behaviour of a material subjected to shock loading in
bending, tension and torsion. Mostly, the Charpy and
Izod impact and occasionally tensile impact tests are
Toughness of a material is defined as the energy
used. These Izod/Charpy tests are widely applied in
absorbed by a material before fracture. Toughness is
industries due to the ease of sample preparation and it
a very important property in applications where the
is possible to generate comparative data very quickly.
material has to encounter a lot of mechanical shock
Both the tests are done as per ASTM D256 (a.4). In the
and vibration. Fracture toughness (KIc) is one of the
Charpy test the specimen is supported as a simple beam
most important properties of a material, which is
whereas in Izod test it is supported as a cantilever. The
used to design materials for dynamic applications. It
apparatus consists of a pendulum hammer swinging at a
basically describes the resistance of a material with a
notched sample. The energy transferred to the material
crack to fracture. Since it is almost impossible to make
can be inferred by comparing the difference in height
a material for practical purposes without cracks/defects,
of the hammer before and after the fracture. Depending
fracture toughness analysis is extremely important for
on the instrument, the impact energy (J/m) or the load
design applications. The critical stress intensity factor,
history during the impact event can be recorded. The
KIc and impact energy, GIc are determined using ASTM
test can be carried out using different combinations of
D5045-99 (a.3). The tests were carried out using an
impactor mass and incident impact velocity to generate
Instron machine using a flexure or tensile mode. An
the data on damage tolerance as functions of impact
initial crack was machined in a rectangular specimen,
parameters, which are helpful for design of composite
and tapping on a fresh razor blade placed in the notch
materials for a particular application (177).
generated a natural crack. The parameters can be
expressed mathematically as follows:
Another test, which is used to evaluate epoxy composites,
is the falling dart impact test. In this test a dart is allowed
PQ
K IC = f (x) to fall on a specimen kept in a fixture with an annular
BW 1/2 (1) hole typically ranging from 2.5 to 7.5 cm. The output
of the load transducer can be directly fed into a signal
1− ν2 2 processor and the impact energy or the entire loading
GIC = K IC
E (2) history can be recorded. It can also be coupled with
ultrasonic c-scan (nondestructive inspection technique
Where: ν is Poisson's ratio composites in which a short pulse of ultrasonic energy
PQ is the critical load for crack propagation, is incident on a sample) and microscopic techniques
B and W are the thickness and width of the to study the post failure analysis (258, 260). It may be
specimen, noted that for critical applications, rigorous testing has
to be carried out considering the service conditions, to
E is elastic modulus, and ensure the specified service life (255).
f (x) is a nondimensional shape factor given
by:
7
Epoxy Composites: Impact Resistance and Flame Retardancy
the processing is perfected, the mechanical properties b) introduction of z-directional fibre (stitching) (153,
can be predicted from the known value of mechanical 267), and,
properties of the individual components. The modulus
of a composite material can be approximately calculated c) addition of whiskers or short fibres to the
from simple linear or logarithmic relationships: interlaminar zone (supplementary reinforcement)
(248, 262, 263, 280).
log Ec = log Ee (1-Vr) + log Er (Vr) (4)
Wimolkiatiask and Bell (275) electropolymerised a
Ec = Ee (1-Vr) + Er Vr (5)
high temperature thermoplastic (3-carboxy phenyl
Where: Ec, Ee and Er are the bending moduli of composite, maleimide-styrene copolymer) interphase onto a
epoxy and reinforcement, respectively, and graphite fibre and evaluated the fibre-reinforced epoxy
composites. The improvement in critical strain energy
Vr is the volume fraction of reinforcement in
factor of about 100% and notched impact of about 60%
the composite.
were achieved while maintaining the interlaminar shear
strength at around the same value as for a controlled
Hence, composites show a modulus value, which
composite. Cox and co-workers (257) investigated the
is in between that of an epoxy and a reinforcement.
tensile behaviour of graphite epoxy composites with
Interestingly, the impact strength of an FRP composite
3D woven interlock reinforcement and reported the
does not follow the rule-of-mixture (the average strength
contributions of various mechanism of fracture. The
calculated from individual components) and the value is
impact strength of an epoxy composite with a particular
found to be much higher than the impact strength values
matrix can be improved by using a high strain fibre
of individual components. As for example, the impact
strength of pure epoxy network (DGEBA cured with or fibre hybridisation (228, 231, 239). However, high
TETA) is about 20 J/m and impact strength of glass is strain fibres often show lower modulus and thus cannot
less than that of epoxy, however, the impact strength of satisfy the requirement for dimensional stability in
an epoxy/glass fibre composite is 950 J/m which is about high performance engineering applications (297). This
50 times more. Various models have been proposed to approach is particularly exploited for the application of
explain the toughness of the brittle matrix/brittle fibre composites under high-incident-energy conditions, as
composites (249, 251). The models considers various for example ballistic applications (242, 258). Using a
energy absorbing processes, which occur during the particular reinforcement, low-velocity impact resistance
fracture of composites like fibre pull-out, fibre kinking, (desirable for structural applications) of a particulate
stress redistribution, creation of new surface through or FRP composite can be improved to a great extent
fibre, matrix and the interface, fiber debonding and so by increasing the toughness of the matrix (291) as
on (205, 268, 298, 299). Since fibre pull out and fibre discussed next.
debonding, largely contribute in energy dissipation
during fracture, very high interlaminar shear strength
(ILSS) is detrimental for toughness of composites. Thus,
the interface has to be designed for an optimum ILSS to 6 Modification of Epoxy Matrix
get the best mechanical property and toughness.
8
Epoxy Composites: Impact Resistance and Flame Retardancy
Epoxies are flexibilised by using reactive diluents, is associated with a significant deterioration in thermo-
which are basically mono epoxide compounds or by mechanical properties (especially Tg) whereas for
using long chain hardeners (287). The basic idea is toughening, the same is achieved without significant
to reduce the effective crosslink density (Xc), thereby deterioration in thermomechanical properties.
making the networks less tight. Epoxy resins can also The difference arises due to differences in blend
be chemically modified to extend the chain length morphology. Flexibilisation is associated with single-
between the two epoxy groups leading to the increase phase morphology whereas toughening arises from a
in molecular weight between crosslinks (Mc) and two-phase morphology. Unlike flexibilisation where
development of a tougher (ductile) network (141). A the modifier becomes a part of the epoxy phase, the
general scheme for chemical modification of epoxy modifier forms a separate phase in toughening and
resin is shown in Figure 4. thus the bulk thermomechanical properties of epoxy
matrix, are retained. Depending on the second phase
The major downside of this approach is that the used, epoxy toughening can be grouped into four
modification is associated with a drastic reduction in types: liquid rubber toughening, core-shell particle
Tg, which restricts the use of such materials for high toughening, thermoplastic toughening and rigid particle
temperature applications. This arises due to the typical toughening.
plasticisation phenomena observed in case of compatible
blending of a rigid plastic with a flexible polymer or
low molecular weight plasticiser. This problem can
6.3 Liquid Rubber Toughening
be overcome by using the second phase toughening
technology where the modifier is incorporated as a
separate phase.
6.3.1 Reaction-induced Phase Separation
9
Epoxy Composites: Impact Resistance and Flame Retardancy
(ΔGm) P,T < 0 (6) tremendous increase in viscosity. The final network is
obtained after a heat treatment called post curing. The
Combining the Flory-Huggins equation and the process is shown schematically in Figure 5.
Hildebrand equation, the free energy of mixing can be
expressed as: If (de - dr) is very low, then DGm will be highly negative
and entropy change (during curing) cannot make DGm
ΔGm /V = φe φr (de - dr)2 + RT(φe/Ve . ln φe + φr / Vr . ln φr) equal to - ve, before gelation, leading to the formation
(7) of a single phase morphology. Again if (de - dr) is very
high, then DGm will be positive at curing temperature
where φe, φr are the volume fractions, de, dr are the and rubber will be immiscible at the initial stage
solubility parameters, Ve and Vr are the molar volume itself, leading to a macro level phase separation. As an
of epoxy and rubber, respectively, V is total volume, R example, carboxyl-terminated polybutadiene is not a
is universal gas constant and T is temperature. suitable toughening agent for epoxies as the solubility
parameter of butadiene is much lower than that of epoxy
Since both φe, φr are fractions, the second term is always and it is immiscible with epoxy. However, a carboxyl-
negative. High temperature favours miscibility. For terminated copolymer of butadiene and acrylonitrile
a fixed epoxy/rubber composition, DGm at constant (CTBN) with 20 to 30 wt.% of acrylonitrile (polar
temperature, depends on dr, i.e., the chemical nature acrylonitrile increases the solubility parameter) has a
of rubber and Vr which is dependent on the molecular solubility parameter, which is close to the solubility
weight of the rubber. A toughening agent has to be parameter of the epoxy and is an effective toughening
designed in such a way that the free energy of mixing agent for the epoxy. The copolymers are commercially
is marginally negative at the curing temperature. Then produced by the Goodrich Company and are known
the rubber will be compatible with epoxy before the as Hycar CTBN. The amine-terminated copolymers
curing but with the advancement of curing reaction, Ve of butadiene and acrylonitrile are known as ATBN.
and Vr will increase due to the increase in molecular CTBN or ATBN with a higher acrylonitrile content,
weight of the rubber and the epoxy and at a certain have a better miscibility with the epoxy resin in terms
stage DGm will become positive. At that point rubber of solubility parameter and undergo phase separation
starts undergoing phase separation and it is called the at a later stage of curing and result in lower amount of
cloud point. The process continues until the gelation phase separated rubber. CTBN with an acrylonitrile
point, where the phase separation is arrested due to the content of more than 30 wt.%, results in a single-phase
Figure 5
Description of reaction-induced phase separation in rubber-modified epoxy system
10
Epoxy Composites: Impact Resistance and Flame Retardancy
morphology and the modifier acts as a flexibiliser rather initiating the ductile shear yielding mechanism (269).
than a toughening agent. At the crack tip where the hydrostatic tensile component
is large, the magnitude of the concentrated hydrostatic
The morphology is controlled by the initial cure stress in the vicinity of rubber particles is insufficient to
temperature and the post curing condition (although it promote shear yielding.
affects the final properties), has no role in morphology
development (272). The time from cloud point to The internal cavitations of the rubber particles relieve the
gelation is the effective phase separation time (tps). For plain strain constraint by effectively reducing the bulk
complete phase separation, the tps has to be higher than modulus and then the magnitude of the concentrated
the time required for diffusion of rubber from epoxy deviatoric stress is sufficient for shear yielding. The voids
medium (tdiff). The diffusivity is the controlling factor of left behind by the cavitated rubber particles act further as
phase separation if tdiff is greater than tps. The diffusivity stress concentrators. Li and co-workers (a.7) studied the
of rubber in epoxy medium (Dr) is considered to be fracture behaviour of unmodified and CTBN modified
proportional to the temperature viscosity ratio through epoxies under hydrostatic pressure. They found that when
the Stokes-Einstein equation (a.6): rubber cavitations were suppressed by superimposed
hydrostatic pressure, the fracture toughness of CTBN
Dr = kT/6pRr he (8) modified epoxy was no higher than that of the unmodified
epoxy. This implies that the stress concentration by
Where: k is the Boltzman constant, rubber particles alone will not necessarily induce massive
Rr is the radius of rubber adducts, shear yielding and increase the fracture toughness. Hence,
he is the viscosity of the medium, and, rubber cavitations are very important to the toughening
of rubber modified epoxies; without cavitations these
T is absolute temperature. rubber particles can still cause stress concentration but
they are not effective in toughening.
The characteristic time scale for diffusion in two
dimensions is:
Dompas and Groeninckx (264) developed a criterion for
the internal cavitations. The condition has been treated
tdiff = L2 / 2 Dr (9) as an energy balance between the strain energy relieved
by cavitations and the surface energy required to create
A length scale (L) can be assigned from the average two-
a new surface and given by the following equation:
dimensional distance between domain centres obtained
from micrographs of the cured specimen.
Utotal = Ustrain + Usurface
= - p/12 Kr D2 do3 + g p D2/3 do2 < 0 (10)
6.3.2 Mechanism of Toughening
Where: Kr, D, do, g are the rubber bulk modulus, relative
volume strain, rubber particle diameter and
The rubber modified epoxy with two-phase microstructure surface energy per unit area, respectively.
shows improved fracture toughness (178, 272, 279) as
the rubber particles, dispersed and bonded to the epoxy
Accordingly, the cavitation of rubber is dependent
matrix act as the centres for dissipation of mechanical
on the elastic and molecular properties of rubber,
energy. A number of theories have been proposed to
rubber particle size and on the applied volume strain,
explain the toughening effect of rubber particles on the
which again depends on the difference in Poisson’s
brittle epoxy matrix, based on the fractographic features
ratio between the matrix and the rubber. Cavitation
and fracture properties of the rubber toughened epoxy
resistance increases with the decrease in particle size
networks. According to recent theories, the most accepted
and difference in Poisson’s ratio.
mechanism for rubber toughening is rubber cavitation
followed by shear yielding. In rubber modified plastics,
under triaxial tensile stresses, voids can be initiated
inside the rubber particles. Once the rubber particles 6.3.3 Morphological Parameters
are cavitated, the hydrostatic tension in the material is
relieved, with the stress state in the thin ligaments of Rubber toughened epoxy networks display a discrete
the matrix between the voids being converted from a morphology, which consists of spherical particle
triaxial to a more uniaxial tensile stress state. This new dispersed in the epoxy matrix. The morphology is
stress state is favourable for the initiation of shear bands. characterised by polarised optical microscope, scanning
In other words, the role of rubber particles is to cavitate electron microscopy (SEM), atomic force microscopy and
internally, thereby relieving the hydrostatic tension and transmission electron microscopy (TEM). A typical SEM
11
Epoxy Composites: Impact Resistance and Flame Retardancy
microphotograph for rubber toughened epoxy network are listed in Table 2. It is very difficult to study the
is shown in Figure 6. The morphological parameters effect of an individual parameter on toughening effect
dictate the fracture properties of the toughened epoxy as the parameters are interrelated. For example if we
networks (145). Various morphological parameters and want to study the effect of functionality of rubber by
the molecular parameters, which control the morphology, changing the functionality, this changes the solubility
parameter difference and affects the other morphological
parameters.
Figure 7
Effect of acrylate rubber content on impact strength of modified networks
Reprinted with permission from D. Ratna, A.K. Banthia and P.C. Deb, Journal of Applied Polymer Science, 2000,
78, 4, 716. ©John Wiley and Sons
12
Epoxy Composites: Impact Resistance and Flame Retardancy
6.3.3.2 Particle Size and Distribution size corresponding to a lower brittle-tough transition
temperature. However, it has been found in a number
The origin of this size dependence on toughening of systems that there exists a minimum particle size
behaviour arises from the role played by the particles, below, which the brittle-tough transition no longer shifts
which is governed by the size of the process zone. Large to lower temperatures. As a possible explanation for the
rubber particles (> 5 mm) lying outside the process zone peculiar behaviour, it has been suggested that particles
are only able to act as bridging particles, which provide which are too small are not able to cavitate and therefore
only a modest increase in fracture energy. Small rubber do not release the hydrostatic tension in the material to
particles, which lie in the process zone are forced to promote ductile shear yielding.
cavitate by the large hydrostatic stress component that
exists in the process zone and contributes to the increase
in fracture energy. However, very small particles 6.3.3.4 Matrix Particle Adhesion
(< 0.2 mm) cannot cavitate (cavitation resistance
increases with decreasing particle size - see Equation Matrix-rubber particle adhesion is an important
10) and cannot effectively toughen the epoxy matrix. parameter for rubber toughening. For effective rubber
toughening, the rubber particles must be well bonded
to the epoxy matrix. The poor intrinsic adhesion across
6.3.3.3 Matrix ligament thickness the particle-matrix interface causes premature particle
debonding, leading to the catastrophic failure of the
Wu and Mongolina (a.8) proposed that the matrix materials (289, 300). Most of the studies, reported
ligament thickness (MLT) i.e., surface-to-surface, in the literature, have been concerned with reactive
interparticle distance is the more fundamental parameter. groups terminated rubbers (functionality = 2 eq/mole)
For effective toughening, the average matrix ligament as toughening agents for epoxies, which results in
thickness (t) should be less than that of a critical value dispersed rubbery particles having interfacial chemical
(tc) where brittle-tough transition occurs. The tc is bonds as a consequence of chemical reactivity. It was
independent of rubber volume fraction, particle size observed that further increase in functionality of rubber,
and characteristics of the matrix alone at a given test improved the toughening effect up to an optimum value
temperature and rate of deformation. For blends with of functionality (2.3-3 eq/mole). The toughening effect
dispersed spherical particles, the tc can be related to the decreases beyond the optimum value of functionality,
rubber particle size and rubber volume fraction (φr) by due to the formation of a single phase morphology
the following equation: (203).
For a given volume fraction of rubber, the critical In the last two decades a lot of work has been done
MLT is achieved by decreasing the particle size and and various issues in the field have been addressed as
by improving the dispersion. For most systems, this listed in Table 3. The commercially available liquid
concept works very well and a decrease in particle rubber (CTBN, ATBN) toughened epoxy often shows
13
Epoxy Composites: Impact Resistance and Flame Retardancy
outstanding fracture properties and the technology is some limitation in its use due to the possibility of
is exploited in the field of engineering adhesives the presence of traces of free acrylonitrile, which is
(124). However, since the butadiene component of the carcinogenic. Hence, considerable efforts have been
elastomer contains unsaturation, it would appear to be made to develop saturated liquid rubber alternative to
a site for premature thermal and/or oxidative instability CTBN.
and such modified resins are not suitable for application
at high temperatures. One would imagine that excessive Several liquid rubbers have been investigated as
crosslinking could take place with time, which would alternatives to CTBN. The chemical structures of
detract from otherwise desirable improvements some useful toughening agents are shown in Figure 8.
accomplished with these structures. Secondly, there Saturated rubbers namely polyacrylates, polyurethane,
Figure 8
Chemical structures of some useful toughening agents. ESO = epoxidised soybean oil
Table 3 Issues involved in toughening research and addressed in the last two decades
Issue Solution
Toxicity and poor oxidative stability of commercial Use of saturated modifier e.g., polyacrylates,
toughener (CTBN, ATBN) polyurethanes, polysiloxane, etc.
Depression of epoxy Tg Use of high molecular weight rubber and optimum cure
temperature
Processability (high viscosity) Use of hyperbranched polymer based toughening agents
Reduction in modulus Use of liquid crystalline modifiers and nanoreinforcement
14
Epoxy Composites: Impact Resistance and Flame Retardancy
polysiloxane, and epoxidised soybean oil (ESO) cure, is difficult to control and may result in uneven
(142, 220, 230), offer better oxidative stability and particle size distribution. The differences in morphology
better performance of such materials. Complete phase and volume of the separated phase affect the mechanical
separation can be achieved for such liquid rubbers by performance of the product. The factors that affect
increasing the molecular weight of liquid rubber and the fracture toughness of the modified epoxy such
decreasing the cure temperature within the processing as morphology, particle size and composition are
window (the theoretical reason for the effect of these interdependent and hence, it is very difficult to study
two parameters have been discussed in Section 6.3.1). the effect of the individual parameters. These problems
However, beyond a certain molecular weight, the liquid can be minimised by using an insoluble preformed
rubber undergoes phase separation at a very early stage particle directly (265). Since the size, morphology
leading to agglomeration and macrophase separation. and composition, shell thickness and crosslink density
The optimum molecular weight for difunctional of the rubbery cores can be controlled separately by
modifier is reported to be about 7000 g/mole (220). using emulsion polymerisation techniques, the effects
of various parameters on the toughening of epoxies can
The modification of epoxy with linear elastomers, be investigated.
as discussed in previous sections, is associated
with a considerable increase in viscosity, which is The control of the particle parameters by emulsion
disadvantageous as far as processing is concerned. polymerisation has been extensively studied, and
The problem can be overcome by using dendritic various efficient technologies have been developed
hyperbranched polymer (HBP) based toughening agents (283). Monodisperse latex particles with a diameter
(168, 202). Due to the compact 3D structure of dendritic from submicron to micron range can be prepared.
polymers, these molecules mimic the hydrodynamic Cohesive strength, which is influenced by crosslink
volume of spheres in solution or melt and flow easily density of the rubber phase, can be controlled by
past each other under applied stress. This results in a the conversion of polymerisation and the amount of
low melt viscosity, even at high molecular weights, crosslinking agent (a.10). Interfacial architecture can be
due to a lack of restrictive interchain entanglements controlled by changing the following parameters:
(a.5). Indeed, dendritic polymers have been shown to
exhibit melt and solution viscosities that are an order 1. thickness of the shell which depends on the ratio
of magnitude lower than linear analogues of similar of the shell-core materials and polymerisation
molecular weight (a.5) (168). The high density of mechanism,
functional terminal groups on dendritic polymers also
offers the potential for tailoring their compatibility 2. chemical bonding and physical interaction between
either through conversion of dendritic polymer end particles and matrix which can be enhanced by
groups to chemically suitable moieties or through in situ introducing functional groups onto the surface of
reaction to form covalently bound networks. These two the shell,
properties: low viscosity and tailorable compatibility,
make HBP excellent candidates as flow additives that 3. grafting between the shell and core, and,
could act simultaneously as toughening agents. These
polymers are commercially available e.g., Boltron.
4. molecular weight of shell materials.
The fourth issue is reduction in modulus of cured epoxy Various morphologies of the composite such
as a result of incorporation of rubber. It is necessary to as core shell, occluded or multilayer can be
couple a strengthening mechanism with the toughening achieved through two or multiple stage emulsion
process to get really tough and strong materials. The polymerisation (278). The preformed particles are
successful approach is nanoreinforcement which will incorporated into the epoxy matrix by mechanical
be discussed in the following sections. mixing. The dispersibility of the particles can be
improved by:
15
Epoxy Composites: Impact Resistance and Flame Retardancy
6.5 Thermoplastic Toughening the thermoplastic is compatible with the epoxy resin
but as the molecular weight increases due to the curing
Rubber toughening can dramatically increase the reaction, the homogeneous mixture starts undergoing
fracture resistance of cured epoxy castings and phase separate by a spinodal decomposition, resulting
composites. However, the presence of the rubber phase in the development of a two-phase microstructure
does somewhat decrease the modulus and thermal (107). Gorbunova and co-workers (107) reported that
stability of the materials and increase the tendency incorporation of polysulfone into epoxy networks,
of water absorption with an accompanying loss of resulted in a considerable increase in impact strength
properties at elevated temperatures. Moreover, the and cross-breaking strength of epoxy composites.
reactive rubbers have been reported as ineffective
modifiers for a highly crosslinked system based on an In contrast to the liquid rubber modified epoxy systems,
epoxy having a functionality of more than 2 (i.e., 3 or which displays a simple particulate microstructure,
4). This is because the rubber rich particles, as stress the thermoplastic-toughened epoxy networks produce
concentrator, induce the plastic deformation of a highly different morphology/microstructures at different
crosslinked matrix to a far less extent and dissipation modifier concentrations (266). Initially at low
of fracture energy by the enlargement of deformation concentrations of thermoplastic, the thermoplastic
zone can hardly be attained (272). The search for an becomes miscible in the epoxy matrix and generates
alternative method to rubber toughening led to the a single-phase morphology. On subsequent increase
development of thermoplastic toughened epoxy (84, in thermoplastic concentration, the phase separation
125, 256). Because of their high modulus and high Tg occurs leading to the development of a two-phase
of engineering thermoplastics, the modified epoxy resin morphology and the microstructure changes from
will reach or even exceed the corresponding values for particulate to cocontinuous and finally to the phase-
the unmodified resin. Unlike the rubber toughening inverted microstructure. The mechanisms responsible
where significant reduction in stiffness and modulus for the toughening of epoxy by thermoplastics, are
was observed at an ambient temperature, in case of reported to be plastic yielding or drawing and tearing
thermoplastic toughened epoxy, reduction in stiffness of thermoplastic rich phases.
becomes significant only at temperatures near to the Tg
of the thermoplastic moiety. Once the -OH- terminated bis phenol-A (BPA) based
PES was found to be successful for toughening the
The initial studies on thermoplastic toughened epoxy were epoxy matrix, efforts were concentrated on developing
carried out by using unreactive low molecular weight amine-terminated oligomers of PES, which can be
thermoplastics like polyether sulfone) (PES), polyether synthesised by adding a stoichiometric amount of amino
imide. No significant increase in fracture toughness was phenol as the end-capping agent (282). The oligomeric
observed due to such blending of thermoplastic modifier amines can be reacted with epoxy and DDS to give the
with difunctional and multifunctional epoxies (302). It toughened thermoset. Pak and co-workers (274) have
was concluded that the lack of improvement of fracture used PES with pendent amino groups as the modifier
toughness observed in these systems may be due to for epoxy resin. Like amine-terminated PES, they
the fact that cured epoxy resin’s high crosslink density can be used as such or after modification with maleic
inhibited the primary toughening mechanism ‘namely’ anhydride. It has been found that with increase in -NH2
the formation of shear bands. content, the toughness increases initially, passes through
a maximum and then decreases. The initial increase
Hedrick and co-workers (301) considered poor interfacial in fracture toughness with increase in -NH2 content
adhesion to be the main reason for the inability of is due to increase in interfacial adhesion between the
commercial thermoplastics (nonreactive) to improve epoxy matrix and the dispersed PES particles, which
the toughness of epoxy resin. They used phenolic -OH prevents the debonding of particles. The decrease in
ended bisphenol-A based PES and amine-terminated fracture energy above an optimum -NH2 concentration
PES oligomers as toughening agents and claimed can be attributed to the formation of a single-phase
that this approach resulted in remarkable increase in morphology (undesirable for toughening) as a result of
fracture energy. The theory is similar to liquid rubber higher miscibility of the PES, containing higher -NH2
toughening. The thermoplastic modifier having reactive content, with the epoxy resin.
end groups, reacts with the epoxy resin. The presence of
an excess of epoxy resin essentially produces an epoxy Crystalline thermoplastics have also been utilised for
end-capped thermoplastic modifier. The modified and toughening epoxy resins (238). Polyethylene oxide
unmodified epoxy resin further reacts with the curing (PEO) was reported to be an effective toughening
agent and produces the toughened network. Initially agent for epoxy (284). The -OH groups of PEO react
16
Epoxy Composites: Impact Resistance and Flame Retardancy
with epoxy at an elevated temperature and form a (207). An effective exploitation of nanoreinforcement
compatible blend with single-phase morphology or requires an understanding of nonscale structure-
two-phase microstructure depending on the molecular property-processing relationships of nancomposites
weight of PEO and the curing condition. Nichols and to select the right nancomponent and to process
Robertson (a.11) reported a systematic exploration of them properly for the target properties (214). The
the relationship between thermal history, morphology main advantage of the nanocomposite is the property
and mechanical properties of polybutylene terepthalate tradeoffs associated with conventional composites. For
(PBT)/epoxy blends. They found that 5 wt.% of a example, nanomodification can improve the stiffness
thermoplastic PBT was able to increase the fracture without sacrificing toughness, can enhance barrier
energy (GIc) of a brittle anhydride cured epoxy from properties without sacrificing transparency and offer
180 to 2000 J/m2 with proper control of morphology. flame retardency without deteriorating mechanical
The exceptional higher toughening ability of PBT in property and colour (100, 190, 191). Applications
comparison to Nylon 6, can be attributed to phase- of nanocomposites have been proposed for ballistic
transformation of PBT at the crack tip (a.11) as observed armour, capable of withstanding small arms fire
in toughened ceramics. (7.62 mm bullets) (209). If the nanoreinforcement effect
can be synergistically coupled with the effect of other
additives/microfillers, the resultant composite materials
will find wider applications leading to the more and
6.6 Rigid Particle Toughening more replacement of conventional metallic materials
for critical applications (22, 102).
The fourth approach generally taken to improve crack
resistance of an epoxy resin, is the incorporation of Various nanofillers namely, nanosilica (204) and
rigid inorganic fillers such as alumina, silica, glass nano calcium carbonate (33), polyhedral oligomeric
beads, etc., into glassy epoxy matrix (276, 281, 286). silsesquixane (24, 31), have been used to make
The mechanisms proposed for improvement of fracture epoxy-based nanocomposites as described in Table 1.
resistance are shear yielding and crack pinning. Nanocomposites are now no longer only restricted to
However, unlike rubbery filler which can cavitate, the laboratory, they are found in the real world (62).
get stretched and remain bonded due to the chemical Recently, two new polyamide-6 nanocomposites
interaction to sustain the imposed load, the rigid filler (NanoTuff and Nanoseal), have been introduced by the
cannot deform or cavitate and easily get debonded Nylon Corporation of America (21). Two technologies
from the matrix leading to the catastrophic failure namely the technology of polymer/clay and technology
of the material. It is difficult also to achieve a good of polymer/carbon nanotube (CNT) nanocomposites,
dispersion of such materials in the epoxy matrices. The will be discussed briefly in the following sections.
combinations of glass beads and rubbery fillers have
been tried out (253, 273, 276) and it was reported that
the fracture energies displayed a strong improvement
and a synergistic effect due to the presence of both kinds 7.1 Clay Reinforced Epoxy
of particles in the hybrid composites (270, 271).
Polymer-clay nanocomposite (PCN) is one among very
few areas in the field of polymer technology which has
drawn considerable interest in recent years (42, 146,
151, 152). The main attractions of PCN are the low cost
7 Nanoreinforcement of Epoxy of clay and the well developed intercalation chemistry,
which makes it possible to achieve a nanostructure
Nanoreinforced composites or nanocomposites offer from a micron size filler. Thus, PCN technology can
a great potential for novel properties because the avoid the potential health hazards involved in other
distinct inorganic organic component properties can nanomaterials technology.
be combined in a single material with a uniformity
of dispersion at the nano level. Such reinforcement The clays are made up of a crystal lattice (0.95 nm
often offers synergistic improvement in properties thick layer) stacked together. A layer consists of two
when the component sizes approach the nano scale tetrahedral sheets fused to one octahedral sheet of either
(77). The concept of nanoreinforcement arises from aluminum or magnesium hydroxide (2:1 layer). These
the knowledge that control of structure/interactions 2:1 layers are not electrostatically neutral. The excess
at the smallest scales and the systematic nanometer layer charge, caused by isomorphous substitutions
by nanometer construction of composites provide of Si4+ for Al3+ in the tetrahedral lattice and Al3+ for
the best chance to control the macroscopic properties Mg2+ in the octahedral sheet, is balanced by interlayer
17
Epoxy Composites: Impact Resistance and Flame Retardancy
cations, which are commonly Na+, Ca2+ or Mg2+ ions. the mechanical properties of a wide range of commodity
The strong hydrophilic nature of the clay surface results and engineering thermoplastics plus thermosets (37).
in a high interfacial tension with organic materials, The process is called ‘Nano Med’, which is intended to
making the layered silicate difficult to intercalate and be used in medical devices such as catheters. Techmer
disperse homogeneously in an epoxy matrix. That is Lehvoss company, USA commercialised nanocomposite
why in situ polymerisation of epoxy with clay leads products since 2003 (111). It is estimated that global
to a conventional microcomposite with particle size of polymer nanocomposite market will exceed 211 million
about 5 to 15 mm as shown in Figure 9. US Dollars by 2008. According to a report published
by Business Communications Inc., USA in 2004, the
That is why it is necessary to modify the montmorillonite polymer nanocomposite market is forecast to grow by
or bentonite clays with alkyl ammonium cation, which 18.4% (136).
can be carried out by a simple ion exchange method (133).
The introduction of an alkyl chain into the galleries, The organo-modified clay materials can easily be
serves two purposes: firstly it introduces hydrophobic dispersed in liquid thermosetting resins like epoxy
character into the gallery and it expands the spacing resin by simple techniques like mechanical mixing,
between the clay layers. Both these factors facilitate shear mixing or sonication (17, 53). Curing such nano
the penetration of polymer molecules into the galleries, filled resin mixtures makes epoxy/clay nanocomposites.
leading to the formation of a nanocomposite (158, 166). The fundamental principle behind the formation
Toyota Central R&D Laboratories Inc., Japan is the of layered silicate/thermoset nanocomposites is
first company to exploit Nylon 6/clay composite for that both the resin and curing agent molecules are
automotive applications. Subsequently, the organoclay able to intercalate into and react within the silicate
for various polymer systems were commercialised by layer galleries. The organic modification of clay
Nanocore Inc., USA and Southern Clay Ltd., and various encourages such intercalation leading to the formation
polymer nancomposites were developed (201, 244, of a nanocomposite after curing. The nanocomposite
246). The RTP Company has introduced a polyamide 6 structures formed after curing can be broadly divided
nanocomposite film for extruded film/sheet applications into two types: intercalated nanocomposite in which
and Bayer has commercialised a LPDU 601 grade, the silicate is well dispersed in a polymer matrix with
which is transparent with barrier properties. The TNO polymer chains inserted into silicate layers that retain
group has successfully made polyamide, polyethylene, their lateral order, and exfoliated nanocomposites
polypropylene, polystyrene, polymethyl methacrylate where the silicate platelets become fully separated or
and polyurethane using planomer technology, which is delaminated, essentially individually dispersed in the
based on the concept of modifying the clay with a block epoxy matrix as schematically shown in Figure 10.
copolymer (219). PCN offer better dimensional stability, However, the real morphology falls somewhere
thermal stability and flame retardency (211). Recently, between these two extremes and the synthesis of true
Foster Corporation (USA) has commercialised a exfoliated nanocomposite, where the greatest property
patented nanocomposite technology, which enhanced improvement takes place, still remains a challenge.
Figure 9
Formation of epoxy/clay microcomposites
18
Epoxy Composites: Impact Resistance and Flame Retardancy
l = 2d sinθ (12)
Figure 11
XRD Plots of TgDDM nanocomposites containing 7.5% organoclay, cured at different temperature profile
Reprinted with permission from O. Becker, Y.B. Cheng, R.J. Varley and G.P. Simon, Macromolecules, 2003, 36, 5,
1616. ©2003, American Chemical Society
19
Epoxy Composites: Impact Resistance and Flame Retardancy
20
Epoxy Composites: Impact Resistance and Flame Retardancy
to the matrix and the efficiency of stress transfer in turn effect has been reported for polymer nanocomposites
dictates the mechanical properties of the composites. (35, 130). Increasing tether rigidity improves thermal
Thus the current interest in using CNT and anticipated stability and elastic modulus but decreases the fracture
potential applications for CNT-reinforced polymer toughness, which is extremely important for engineering
composites, demands a better understanding of CNT- applications. Brittle polymers can be toughened by
matrix interfacial characteristics. Since the magnitude of incorporating a rubbery phase as discussed before
CNT strength is very high (almost 10 times higher than (in Section 6.2) for epoxy resin. However, rubber
typical carbon fibre) very high interfacial shear strength modification is accompanied with a substantial decrease
may be required for more efficient strengthening of in modulus. Hence, the conventional toughening strategy
polymers with CNT. can be coupled with the nanoreinforcement strategy to
make really a strong and tough material. The ternary
When treated with inorganic acid, the outer shells of blending strategy (simultaneous nanoreinforcement
CNT were damaged to some extent and carboxylic acid and toughening) is schematically represented in
groups were formed on the surface. Such functionalised Figure 13.
CNT can easily be dispersed in epoxy resin by
mechanical mixing, magnetic agitation or high-energy Ternary blends consisting of rubber, clay and various
sonication (39, 78). Epoxy/CNT composites can be polymer matrices have been investigated and show
made by curing the modified resin with a suitable considerable promise (20, 28, 34, 67). However, it was
curing agent. The carboxyl groups of CNT, react
with the epoxy groups resulting in higher
interfacial interactions. Such composites
show mechanical strength, several times
higher compared to carbon fibre-reinforced
composites (78, 131).
8 Simultaneous
Nanoreinforcement and
Toughening
Polymer composites with well-dispersed,
layered silicate often offer improved thermal
stability and elastic modulus at the expense
Figure 13
of fracture toughness. A similar trend
was observed for CNT based and other Schematic representations of simultaneous nanoreinforcement
nanocomposites, though the toughening and toughening
21
Epoxy Composites: Impact Resistance and Flame Retardancy
observed (144) that for epoxies, addition of nanofiller ignition is noted if polymer dripping ensues; dripping
affects the microstructure generated as a result of is permissible if no cotton ignites. Then the second
reaction-induced phase separation. Thus, control of ignition is performed for the same sample and the self
nanostructure and microstructure poses a real challenge extinguishing time and dripping characteristic recorded.
for development ternary polymer blends based high If the plastic self extinguishes in less than 10 seconds
performance composites. after each ignition with no dripping, it is classified as
V-0. If it self extinguishes in less than 30 seconds after
each ignition with no dripping, it is classified as V-1
and if the cotton ignites then it is classified as V-2.
If the sample does not self extinguish before burning
9 Fire Retardant Epoxy Composites completely, it is classified as failed (F).
The second limitation of epoxy composites (polymer
composites in general) is the poor fire resistance. This
problem is a major concern in applications, where fire 9.1.2 Cone Calorimetry
can occur, namely, aircraft cabin, ships, submarines,
offshore drilling platforms and rail carriages. The Cone calorimeter experiments were performed at an
subject of fire retardant composites became a source incident heat flask of 50 kW/m. Combustion behavior
of interest (160). Several studies have examined the was assessed according to ASTM E1354-92 (a.13).
effect of high temperature or fire on the load bearing During the test the materials were subjected to irradiated
properties of polymer laminates and sandwich structures heat plus the feedback heat from the flame starting
(66) (a.12). These studies have shown that thermal from the ignition of the volatile products. The aim
softening of the polymer matrix and reinforcement, is to simulate the conditions likely to occur in a real
creep and decomposition of polymer matrix, deteriorate fire. The data were collected for first 250 seconds, this
the tension properties, whereas matrix softening and being regarded as representative of the initial stage
delamination cracking are responsible for the reduction of fire when it can still be stopped before becoming
of compression properties. Hence, it is necessary to uncontrollable after flashover. The heat released was
make the composite materials-based end products calculated from the consumption of oxygen due to
flame retardant to ensure reliability and human safety. combustion (72). Various parameters like peak heat
Before discussing the development of flame retardant release rate, mass loss rate, specific extinction area,
composites, it necessary to know about flammability ignition time (t ign), carbon dioxide yield, carbon
and smoke tests. monoxide yield and specific heat of combustion data are
calculated (119, 120). The results obtained from cone
calorimeter, are considered reproducible to within 10%
error when measured at 50 kW/m2. The average heat
9.1 Flammability and Smoke Tests release rate is correlated to the heat released in a room
where the flammable materials are not ignited in the
There are many standards and governing regulatory same time. The data should be reported for a minimum
bodies controlling the level of flame retardency required of three replicated instruments.
for various applications as described in earlier issue
of Rapra review reports (128). Three most commonly
used flame tests, namely, Underwriters laboratory test
9.1.3 LOI Test
(UL-94), Cone calorimetry and limiting oxygen index
(LOI) test, are very briefly described here.
LOI test is one of the oldest flammability tests - ASTM
D2863 (a.14) and frequently used to compare the flame
retardant properties of polymer samples. The method
9.1.1 UL-94 Flammability Test of operation is to select the desired initial concentration
of oxygen based on the past experience with a similar
The UL-94 test is performed on a plastic sample material (43). The gas is allowed to flow for 30 seconds
(125 mm by 13 mm with various thickness up to to purge the system. The specimen is ignited so that
13 mm) suspended vertically above a cotton patch. The entire tip is burning. The relative flammability is
plastic is subjected to a flame exposure for 10 seconds determined by adjusting the concentration of oxygen,
with a calibrated flame in a unit, which is free from which will permit the specimen to burn. LOI is
the effect of external currents (158). After the first calculated from the following formula:
10 seconds exposure, the flame is removed and the time
for the sample to self extinguish is recorded. Cotton
22
Epoxy Composites: Impact Resistance and Flame Retardancy
23
Epoxy Composites: Impact Resistance and Flame Retardancy
phosphorus containing curing agents (amine, acid or difficulties, and the often severe degradation of the
anhydride) and/or phosphorus containing epoxy resins thermomechanical properties of the base resin.
(240). The reactive types of flame retardant exhibit
much better flame retardancy and overcome several Very recently, Braun and co-workers (68) have reported
drawbacks associated with physical blends of the epoxy a novel phosphorus modified polysulfone acting as a
and the flame retardants (128). By the judicious selection flame retardant and as an impact modifier for epoxy
of curing agent of the epoxy, the fire-retardant property systems at the same time. Incorporating the modifier in
can be manipulated taking advantage of phosphorus- an amine-cured difunctional epoxy they could enhance
nitrogen synergism. Note that the synergistic property both the toughness and the flame retardancy without a
probably occurs due to the formation of the P-N bonded significant sacrifice in thermomechanical properties.
intermediates, which are better phosphorylating agents Also it was possible to generate a network of higher
than those of the related phosphorus compounds without Tg under certain curing condition due to the formation
nitrogen (180). However, introduction of phosphorus in of an interlocked epoxy-thermoplastic network. In
the resin backbone or in the curing agents may affect order to explain the fire property, the decomposition
the curing behaviour and thermomechanical properties behavior has been investigated (68). The possible
of the cured resin. decomposition pathway for DGEBA/DDS network is
shown in Figure 14 (68). The analysis of decomposed
Hergenrother and co-workers (112) synthesised the product indicates formation of gases such as SO2, CO,
epoxy and the diamine curing agents containing CH4 and so on. The phosphorus-containing polysulfone
phosphorus and evaluated the resins for composite interacts with the epoxy as shown in Figure 15 during
applications. The optimised formulations showed decomposition and favoured the middle pathway
excellent flame retardation with phosphorus content (68).
as low as 1.5 wt.%. The flame retardancy is achieved
without any sacrifice in the properties due to
incorporation of phosphorus. Braun and co-workers
(18) investigated the influence of the oxidation 10.3 Nanoclay-Based Flame Retardants
state of phosphorus on the decomposition and fire
behavior of epoxy-based composites highlighting Incorporation of a small amount of modified
the potential for optimising flame retardancy while (organophilic) layered silicates, into a polymer matrix,
maintaining the mechanical properties of epoxy/ has been reported to reduce the heat release and mass
carbon fibre composites. They have used phosphene loss rate as measured by cone calorimetry (170, 182,
oxide, phosphinate, phosphonate, and phosphates 192, 236). The improvement in flame retardancy
(phosphorus content about 2.6 wt.%) and found that has been investigated using both thermoplastic and
by increasing the oxidation state of the phosphorus, thermosetting resins. Evidence was found for a common
additional charring is observed. So, the thermally stable mechanism of thermal stability and flammability
residue increases whereas the flame inhibition, which reduction, and it was found that addition of organoclays
plays an important role for the fire performance of the can substantially aid flame retardancy by encouraging
composites, decreases. The study of the decomposition the formation of a carbonaceous char in the condensed
behaviour indicates that phosphorus-containing groups phase (137, 170, 174). The nanoscale dispersed lamellae
influence the decomposition of the epoxy, resulting of clay, either intercalated or exfoliated in polymer
in a clear multi-step decomposition with mass losses matrix, all enhance the formation of charring upon
between approximately 15 to 20 wt.% in subsequent burning (212). After pyrolysis the nanocomposite
processes after the main decomposition step. The mass forms a char with a multilayered carbonaceous silicate
loss of the main decomposition process is reduced as structure (121, 139). The exfoliated clay layers
a result of incorporation of phosphorus. firstly collapse into an intercalated structure which is
transformed into a multilayered carbonaceous-silicate
Recently the use of 9,10 dihydro-9-oxa-10- structure later (30, 193, 199). The carbonaceous char
phosphaphenanthrene-10-oxide based compounds builds up on the surface during burning and insulates
have been shown (13, 155) to induce a significant the underlying materials. This limits the passage of
improvement in the flame retardancy of epoxies, while degradation products from the matrix which supports
at the same time avoiding many disadvantages such as the continuous fueling of the fire (38, 127). The
poor compatibity, migration of compound and release of advantages of organoclay over conventional flame
toxic gases upon burning as compared to conventional retardants are manifolds: no generation of toxic gases
flame retardants. The beauty of this system is that (truly green flame retardant) and no discoloration (175,
the flame retardancy can be improved at phosphorus 176, 198). Use of organoclay improves the mechanical
content as low as 3 wt.%, thereby limiting processing properties unlike conventional flame retardants which
24
Epoxy Composites: Impact Resistance and Flame Retardancy
Figure 14
Part of possible decomposition pathway for DGEBA-DDS epoxy material. Verified decomposition products are
shown in grey and charring/crosslinking is indicated by zigzag line.
Reprinted with permission from U. Braun, U. Knoll, B. Schartel, T. Hoffmann, D. Pospiech, J. Artner, M.
Ciesielski, M. Döring, R.P. Graterol, J.K.W. Sandler and V. Altstädt, Macromolecular Chemistry and Physics,
2006, 207, 16, 1501. ©2006, Wiley-VCH Verlag GmbH & Co KgaA
Figure 15
Proposed interaction of phosphorus-containing FR and epoxy
Reprinted with permission from from U. Braun, U. Knoll, B. Schartel, T. Hoffmann, D. Pospiech, J. Artner, M.
Ciesielski, M. Döring, R.P. Graterol, J.K.W. Sandler and V. Altstädt, Macromolecular Chemistry and Physics,
2006, 207, 16, 1501. ©2006, Wiley-VCH Verlag GmbH & Co KgaA
usually cause a deterioration in the thermomechanical to extinction time (19, 49). The failure is attributed to
properties (224, 227, 229). the adsorbed onium salt present in the clay (making
it organophilic), which increases the early ignition.
However, it is usually found that such clay additions Also at high temperature the onium ions present in the
are not themselves sufficiently effective to be classified galleries of the clay undergo decomposition destroying
as a flame retardant. The clay modified polymer the nanocomposite structure (19). Moreover, a major
compositions perform poorly when tested by the limitation of organoclay is that they work in ‘condensed
industrially significant UL-94 standard with respect phase’ and do not work in the vapour phase (49, 52).
25
Epoxy Composites: Impact Resistance and Flame Retardancy
10.4 Combination of Organoclay and Other heat flux and thus protects the structure. The final state
Flame Retardants consists of a carbonaceous residue which contains
polyaromatic and phosphorus oxides. IFR consists
Recent studies on the combined effects of organoclay of three main components: the acid source, carbon
and flame-retardants on polymer blends system source and gas source. Polyphosphates-pentaerytritol-
reveal that the presence of an organoclay increases melamine system has been successfully used to develop
the compatibilisation of the blend (61). The results intumescent coating and additive for thermoplastics
have been attributed to the barrier effect or specific and thermosetting polymers (165, 216, 217). It was
interaction of both the polymer with the clay which reported that amine cured epoxy-based intumescent
resulted in change in free energy of mixing. The compositions can be developed using a ammonium
modern flame retardants are basically organic molecules polyphosphate, calcium borate and phenanthrene
with halogen or phosphorus groups, and are not dehydropolycondensation product containing chromium
well dispersed in polymer system. Hence, it can be and nickel, as additives (160). The composites based
postulated that the presence of clay might enhance the on intumescent epoxy formulation and fire retardant
compatibility between the polymer and the fire retardant cellulose fibres have been studied (160). Physical and
resulting in improvement in fire properties (184, 188). chemical interactions of the three components lead
Thus, by using a small amount of clay, it is possible to synergistic effect resulting in an enhanced char
to significantly reduce the amount of conventional formation.
fire retardant additives, required for optimum flame
retardant properties. The conventional flame retardants
always have some detrimental effects on the mechanical
properties of the polymer system, hence by using
nanoclay, such detrimental effects can be minimised
11. Summary and Outlook
and compensated for. The synergistic effect of nanoclay
and conventional fire retardant (decabromodiphenyl The limitations of conventional epoxy-based FRP
oxide plus antimony trioxide) for polypropylene-g- composites for high performance applications are
maleic anhydride system was investigated (189). The poor damage tolerance and fire resistance. The damage
synergy between the brominated fire retardant and tolerance can be improved by using a tough resin, high
antimony trioxide was found in nanocomposite system strain fibres and by manipulation of the interfaces.
whereas no synergy was observed in the virgin polymer The most successful method for improvement of
matrix. Synergistic effects of inorganic flame retardants impact strength of an epoxy composite for structural
(aluminum trihydrate) and phosphorus-based flame applications, is the toughening of epoxy resin. Liquid
retardants with nanoclay, were reported for epoxy (52, rubber toughening is recommended for a difunctional
94, 188) and other polymer systems like vinyl ester epoxy and thermoplastic toughening is the most
(88, 98), ethylene vinyl acetate (43), polystyrene (147), suitable for a multifunctional epoxy network. The
polypropylene (189) and silicone rubber (41). TEM toughening strategy can be coupled with a suitable
and pyrolysis gas chromatography-mass spectrometry nanoreinforcement by using a nanofiller like nanoclay
measurements of serially burned samples indicate that and CNT, to produce strong and tough composites.
the clays play various roles on quenching the flame, The control of both microstructures and nanostructures
such as promoting the char formation, improving the is required for achieving optimum properties. Since
dispersion of fire-retardants and catalysing the chain the magnitude of CNT strength is very high (almost
reaction for dissociation of halogenated compounds. 10 times higher than that of a typical carbon fibre),
very high interfacial shear strength may be required
for a more efficient strengthening of polymers with
CNT. Recent strategy of using functionalised CNT,
10.5 Intumescent Fire Retardants shows a considerable promise and the chemical means
to improve interfacial adhesion between CNT and the
Intumescent fire retardants (IFR) are a new class of polymer matrix, is likely to be a major focus in near
flame retardants which develop a carbonaceous shield future.
under heat flux (216). The solid first begins to melt
and dissipates thermal energy in the process. A state In recent years, a lot of studies have been carried out to
of viscoelastic material is achieved which can trap predict the composite properties in fire and to develop
the evolving gases. This material starts to expand and efficient fire-retardant composites. Though various
grow, i.e., to intumesce. The intumescent coating so methods can be adopted to improve the performance
formed no longer traps the evolving gases when the of composites in fire, the use of flame retardant resins,
internal pressure increases and it degrades under the is inevitable. Phosphorus-containing flame retardants
26
Epoxy Composites: Impact Resistance and Flame Retardancy
27
Epoxy Composites: Impact Resistance and Flame Retardancy
28
References and Abstracts
oxygen index and effective thermal conductivity. The and structure of the composites. In the case of the direct
distribution of nanoparticles in the acrylic nanocomposite addition of epoxy, the composite had an intercalated
was characterised by transmission electron microscopy. structure, whereas when the epoxy was used to pre-treat
The flame-retarding efficiency of the intumescent the composite, it demonstrated an exfoliated structure in
nanocomposite coating was improved by the presence of which the modified montmorillonite was well-dispersed
1.5% of well-distributed nanoclay particles. However, the at the nano-scale. Cone calorimetry experiments showed
addition of 3% of nanoclay had a negative effect on the that the intercalated structure was a little more effective
fire performance of the coating. The fire-retardant property than the exfoliated one in terms of flame retardancy, due
of a conventional intumescent coating is destroyed by to the char formation following pyrolysis. Composites
ageing, whereas nanocomposite coatings modified with with an exfoliated structure exhibited a solid-like response
1.5% of nanoclay showed good resistance to ageing and and had a higher storage modulus and viscosity in the low
fire. 16 refs. frequency zone than those with an intercalated structure.
CHINA 29 refs.
Accession no.984623 CHINA
Accession no.983443
Item 16
Polymer Engineering and Science Item 18
46, No.12, 2006, p.1667-1673 Polymer
NANOREINFORCEMENT OF FLEXIBLE EPOXY 47, No.26, 2006, p.8495-8508
USING LAYERED SILICATE INFLUENCE OF THE OXIDATION STATE OF
Ratna D; Chakraborty B C; Dutta H; Banthia A K PHOSPHORUS ON THE DECOMPOSITION AND
India,Naval Materials Research Laboratory; Indian FIRE BEHAVIOUR OF FLAME-RETARDED
Institute of Technology EPOXY RESIN COMPOSITES
Braun U; Balabanovich A I; Schartel B; Knoll U;
Flexible epoxy matrices, having a good vibration damping
Artner J; Ciesielski M; Doring M; Perez R;
capability, were nanoreinforced using an organoclay. The
Sandler J K W; Altstadt V; Hoffmann T; Pospiech D
nanocomposites were characterized by X-ray diffraction
Germany,Federal Institute for Materials
(XRD) and transmission electron microscopy (TEM)
analysis. The effect of matrix flexibility on the reinforcing
Research & Testing; Karlsruhe,Forschungszent
rum; Bayreuth,University; Leibniz-Institut fuer
effect was investigated. It was found that the reinforcing
effect increased with an increase in flexibility of the matrix.
Polymerforschung Dresden EV
The reinforcement is achieved without any sacrifice in A systematic and comparative evaluation of the pyrolysis
flexibility and Tg. In addition, a reduction in solvent of halogen-free flame-retarded epoxy resins containing
diffusion and flammability has been demonstrated. DMA phosphine oxide, phosphinate, phosphonate, and
study indicates that the height of the loss peak, decreases phosphate (phosphorus contents around 2.6wt.%) and
with incorporation of the clay because of the intercalation. the fire behaviour of their carbon fibre composites is
Nevertheless, the nanocomposite samples having up to 10 presented. Decomposition pathways are proposed based
wt% of the clay show a high damping capability as evident on the thermal analysis (TG), TG coupled with evolved gas
from the tan deltamax values. 38 refs. analysis (TG-FTIR), kinetics and analysis of the residue
INDIA with FTIR and XPS. All organophosphorus-modified
Accession no.984691 hardeners containing phenoxy groups lead to a reduced
decomposition temperature and mass loss step for the main
decomposition of the cured epoxy resin. With increasing
Item 17 oxidation state of the phosphorus the thermally stable
Polymers and Polymer Composites residue increases, whereas the release of phosphorus-
14, No.8, 2006, p.805-812 containing volatiles decreases. The flammability of the
EFFECT OF EPOXY MODIFIER ON FLAME composites was investigated with LOI and UL 94 and the
RETARDANCY AND RHEOLOGICAL fire behaviour for forced-flaming conditions with cone
BEHAVIOUR OF ABS/MONTMORILLONITE calorimeter tests performed using different irradiations.
COMPOSITES The flame retardancy mechanisms are discussed. With
Bo Liu; Chaoying Wan; Yong Zhang; Yinxi Zhang; increasing oxidation state of the phosphorus additional
Yu Su; Jiliang Ji charring is observed, whereas the flame inhibition, which
Shanghai,Jiao Tong University plays the more important role for the performance of the
The effect is studied of an epoxy modifier on the composites, decreases. The processing and the mechanical
morphology, flame retardancy and rheology of an performance (delamination resistance, flexural properties
organically modified montmorillonite-reinforced ABS. and interlaminar bonding strength) of the fibre-reinforced
It was shown that the processing condition of epoxy composites containing phosphorus were maintained at a
modification had a significant influence on the morphology high level and, in some cases, even improved. The potential
for optimising flame retardancy while maintaining nano-scale deformation processes in melt-compounded
mechanical properties is highlighted in this study. 44 refs. nylon 66/organoclay/SEBS-g-MA ternary nanocomposites
Copyright (c) 2006 Elsevier Ltd. prepared by different blending sequences. In addition,
EUROPEAN COMMUNITY; EUROPEAN UNION; GERMANY; the deformation processes of the ternary nanocomposites
WESTERN EUROPE were compared to the binary nanocomposites (nylon 66/
Accession no.983496 organoclay and nylon 66/SEBS-g-MA) and neat nylon
66. The incorporation of SEBS-g-MA particles toughened
nylon 66 markedly; but the flexural modulus and strength
Item 19
were both reduced. Conversely, the use of organoclay
Polymers for Advanced Technologies
increased the modulus but decreased the fracture toughness
17, No.9-10, Sept.-Oct.2006, p.772-777
of nylon 66. Nylon 66/SEBS-g-MA/organoclay ternary
SOME COMMENTS ON THE MAIN FIRE
nanocomposites exhibited balanced elastic stiffness
RETARDANCY MECHANISMS IN POLYMER
and toughness. Stress-whitening studies of the fracture
NANOCOMPOSITES
surfaces in terms of gray level were also performed and
Schartel B; Bartholmai M; Knoll U
an attempt was made to correlate the optical reflectivity
Germany,Federal Institute for Materials Research &
characteristics with fracture toughness. It was concluded
Testing
that the capability of SEBS-g-MA particles to cavitate was
The two main general fire retardancy mechanisms for decreased by the presence of organoclay in the SEBS-g-
polymer nanocomposites, i.e. barrier formation and MA phase, resulting in reduced toughening efficiency. The
increasing the melt viscosity, were examined. These best micro-structure for toughness and other mechanical
mechanisms resulted in specific effects on fire properties properties is thus to maximize the amount of exfoliated
that then caused varying flame retardancy efficiency in organoclay in the nylon 66 matrix rather than to have it
different fire tests. The barrier formation mainly retarded embedded in the finely dispersed SEBS-g-MA particles.
flame spread (peak of heat release rate) in developing fires, 66 refs. Copyright (c) 2006 Elsevier Ltd.
but did not reduce fire load (total heat evolved), ignitability AUSTRALIA; CHINA
or flammability (limiting oxygen index). This flame Accession no.981505
retardancy effect also increased with increasing irradiation
and disappeared with decreasing irradiation. The increased
melt viscosity prevented dripping, which was beneficial or Item 21
disadvantageous depending on the fire test used. In some High Performance Plastics
tests, it became the dominant influence, transforming Aug.2006, p.6
self-extinguishing samples into flammable materials NANOCLAY-REINFORCED PA FOR FUEL TANK
or causing wicking. Advantages and disadvantages for ”NanoTuff” and “NanoSeal” are two new polyamide-6
exploiting the main general fire retardancy mechanisms of nanocomposites which have been recently introduced by
polymer nanocomposites were compared. It was concluded Nylon Corp. of America (Nycoa). The grades reportedly
that barrier formation and changing the melt viscosity in offer novel combinations of stiffness, toughness, and
nanocomposites were not sufficient for most applications, barrier properties. Brief details are provided in this concise
but should be accompanied by additional mechanisms article.
in special systems or in combination with other flame
Nylon Corp.of America; Nycoa
retardants. 29 refs. (8th International Symposium on USA
Polymers for Advanced Technologies 2005, Budapest,
Accession no.982079
Hungary, Sept.2005)
EUROPEAN COMMUNITY; EUROPEAN UNION; GERMANY;
WESTERN EUROPE Item 22
Accession no.984240 Medical Device Technology
17, No.7, Sept.2006, p.10-12
Item 20 NEXT GENERATION POLYMER
Composites Science and Technology NANOCOMPOSITES
66, No.16, 2006, p.3097-3114 Heijkants R G J C; Batenburg L F
MICRO- AND NANO-SCALE DEFORMATION TNO Science and Industry
BEHAVIOR OF NYLON 66-BASED BINARY AND It is explained here that developments in nanocomposite
TERNARY NANOCOMPOSITES technology are now offering designers a much wider
Dasari A; Zhong-Zhen Yu; Mingshu Yang; set of combinations of materials and properties to use.
Qing-Xin Zhang; Xiao-Lin Xie; Yiu-Wing Mai This in turn will result in medical devices with improved
Sydney,University; Chinese Academy of Sciences; mechanical properties and enhanced integration of
Huazhong,University of Science & Technology different functions. This detailed article describes some
The primary aim of this paper is to provide an insight on of the possibilities. Section headings include: definitions,
the effect of the location of organoclay on the micro- and commercialisation, next-generation possibilities, and,
expanding design combinations. 2 refs. Yao Xueli; Ma Xiaoyan; Zhu Yahong; Wang Jinhua
General Motors; Hybrid Plastics Corp.; Foster Corp. Xian,Northwestern Polytechnical University
A review is presented on flame retardants (including
EUROPEAN COMMUNITY; EUROPEAN UNION;
NETHERLANDS; WESTERN EUROPE; WORLD
phosphorus-, halogen- and silicon-containing compounds,
Accession no.982114 metal hydrates and oxides and nanocomposites) for
PP fibres. Properties and methods of enhancing flame
Item 23 retardant efficiency are covered. 24 refs.
Journal of Applied Polymer Science CHINA
98, No.6, 15th Dec.2005, p.2563-71 Accession no.955300
MECHANICAL AND FLAME-RETARDING
PROPERTIES OF STYRENE-BUTADIENE
RUBBER FILLED WITH NANO-CACO3 AS A Item 26
FILLER AND LINSEED OIL AS AN EXTENDER Polymers and Polymer Composites
Mishra S; Shimpi N G 13, No.8, 2005, p.835-8
North Maharashtra,University THE CURE AND THERMAL BEHAVIOUR
OF MG(OH)2/EPOXY RESIN/DEEA
A nanosized calcium carbonate filler is synthesised and NANOCOMPOSITES PREPARED BY A NOVEL
incorporated into styrene-butadiene rubber (SBR) with METHOD. BRIEF COMMUNICATION
2% linseed oil as an extender. The SBR/nano-CaCO3 Cheng Yiyun; He Pingsheng; Cui Ronghui
composite is compounded and moulded for analysis. China,University of Science & Technology
Properties such as specific gravity, swelling index,
hardness, tensile strength, abrasion resistance, modulus Magnesium hydroxide is a smoke-reducing and non-toxic
at 300% elongation, flame retardancy and elongation at additive that has been extensively used in halogen-free
break are measured. The strong rubber-filler interactions flame retardant polymeric materials. However, it’s low
increase the physical, mechanical and thermal properties flame retardant efficiency and the very high loadings
of the composites. 20 refs. that are consequently required when used in its ordinary
INDIA
form, lower the mechanical properties of a flame-retarded
polymeric composition. It has been reported that nanosized
Accession no.953695 magnesium hydroxide/polymeric compositions have the
potential to solve such problems due to the mechanically
Item 24 reinforcing and flame retardant functions of nanosized
Macromolecular Chemistry and Physics composite materials. This study reports on the cure
206, No.20, 24th Oct.2005, p.2075-83 and thermal behaviour of these epoxy resin/magnesium
EPOXY RESIN CONTAINING hydroxide composites. The results of tests indicate
OCTAMALEIMIDOPHENYL POLYHEDRAL enhanced thermal stability. This is claimed to be partly
OLIGOMERIC SILSESQUIOXANE attributable to the prevention of out-diffusion of the
Ni Y; Zheng S volatile gas from the thermally decomposed particles,
Shanghai,Jiao Tong University because magnesium hydroxide nanoparticles, when well-
dispersed in epoxy networks, act as gas barriers, reducing
The synthesis of octamaleimidophenyl polyhedral oligomeric
the permeability of the volatile gas. 10 refs.
silsesquioxane (POSS) by imidisation of octaaminophenyl
CHINA
POSS and maleic anhydride, and its characterisation
by FTIR and proton, carbon-13 and silicon-29 NMR, is Accession no.956569
described. The synthesis of nanocomposites of epoxy
resin with various proportions of octamaleimidophenyl Item 27
POSS and their characterisation by TEM, DSC and TGA International Polymer Science and Technology
was investigated and the flame retardant properties of the 32, No.10, 2005, p. T/61-3
products are discussed. 46 refs. NEW FLAME-RETARDANT MODIFIERS FOR
CHINA EPOXY RESINS
Accession no.953809 Salakhov M S; Agadzhanov R G; Umaeva V S
Azerbaijan,Academy of Sciences
Item 25 This article describes the synthesis of N-
China Synthetic Fiber Industry trichloromethylolimides of polychlorinated polycyclic
28, No.5, Oct.2005, p.39-42 dicarboxylic acids and their use as fire retardant modifiers
Chinese of epoxy resins. Tabulated test results are included of
RESEARCH PROGRESS OF APPLICATION OF physicomechanical and dielectric properties of modified
FLAME RETARDANTS FOR POLYPROPYLENE epoxy composites. The test results show that these
FIBER properties are improved by comparison to unmodified
show the nanostructured composites to possess higher MORPHOLOGY, THERMAL AND MECHANICAL
Tgs. Nanoreinforcement of PPSQ domains enhances the BEHAVIOR OF POLYPROPYLENE
dynamic storage modulus. The composites also display NANOCOMPOSITES TOUGHENED WITH
improved thermal stability and flame retardancy. 51 POLY(ETHYLENE-CO-OCTENE)
refs. Jian Wei Lim; Hassan A; Rahmat A R; Wahit M U
CHINA Malaysia,Universiti Teknologi
Accession no.960248 Rubber-toughened PP(RTPP) nanocomposites containing
organophilic layered silicates were prepared by means
Item 32 of melt extrusion at 230C using a co-rotating twin-
Offshore screw extruder in order to examine the influence of
66, No.2, Feb.2006, p.94 the organoclay and the addition of PP grafted with
COMPOSITE MATERIALS CONTINUE THEIR maleic anhydride(PPgMAH) as a compatibiliser on
MOVE OFFSHORE the morphological, mechanical and thermal properties.
From tensile and flexural tests, the optimum loading of
The trend of replacing more conventional metal alloys organoclay in RTPP was found to be 6 wt %. The optimum
with non-metallic, composite materials of construction loading of PPgMAH, based on the tensile and flexural
continues in the building of shelters and storage units. properties, was also 6 wt %. The increase in the organoclay
Offshore rigs rely on resilient and long-lasting shelters and PPgMAH content resulted in a severe embrittlement,
and storage containers to protect equipment, inventories manifested by a drop in the impact strength and tensile
and personnel from harsh environmental factors of wind, EB. X-ray diffraction studies revealed that intercalated
rain, ocean waves and temperature extremes. Alkan RTPP nanocomposites were successfully prepared where
Shelter’s alternative to metallic alloys is based on fibre- the macromolecular PP segments were intercalated into
reinforced epoxy composites. Alkan reports success with the interlayer space of the organoclay. In addition, the
carbon fibres as a reinforcement material, pointing to their organoclay was dispersed more evenly in the RTPP
high level of specific stiffness and very high tensile and nanocomposites as the PPgMAH content increased. TGA
compression strength as being ideally suited for use in results revealed that the thermal stability of the RTPP
performance structures. The company’s Non-Expandable nanocomposites improved significantly with the addition
ISO containers provide 8x8x20 cu ft of well-insulated, of a small amount of organoclay. 50 refs.
corrosion and fatigue resistant cargo space, and can be MALAYSIA
stacked nine-high.
Accession no.961205
Alkan Shelter LLC
USA
Accession no.960325 Item 35
POLYOLEFINS 2005. Proceedings of a conference held
Houston, Tx., 27th. Feb. - 2nd. March 2005.
Item 33 Brookfield, Ct., SPE, 2005, Paper 6, pp.7, CD-ROM, 012
Polymer Plastics Technology and Engineering TOUGHENING MECHANISM OF NANOCLAY-
44, No.3, 2005, p.463-73 FILLED POLYPROPYLENE
COMPARATIVE STUDY ON IMPROVEMENT
IN MECHANICAL AND FLAME RETARDING Jin Zhao; Hoang Pham; Fibiger R; Garcia-Meitin E; Lizhi
PROPERTIES OF EPOXY-CaCO3 NANO AND Liu; Juarez V; Bouchard K; Matthews W; Esparza G
COMMERCIAL COMPOSITES Dow Chemical Co.
Mishra S; Sonawane S; Chitodkar V (SPE,South Texas Section; SPE,Thermoplastic
North Maharashtra,University Materials & Foams Div.; SPE,Polymer Modifiers &
The physical, mechanical and flame retardant properties
Additives Div.; Society of Plastics Engineers)
of nanocomposites and commercial composites of epoxy Materials science guidelines that determine the toughness
resin filled with different contents of calcium carbonate of PP-clay nanocomposites are described by means of
nanoparticles or microparticles respectively were an understanding of the failure mechanism transitions
investigated by XRD, tensile and impact testing, and rate based on temperature and rate of deformation, including
of burning. The results are discussed in terms of exfoliation quantification of the ductile-to-brittle transition temperature.
in the nanocomposites. 11 refs. Increased stiffness is usually associated with a decrease
INDIA in toughness. Studies have shown that toughening took
Accession no.960365 place at low clay loading where exfoliation was optimised
by use of a completely maleated PP matrix polymer, but
that loss of impact performance was found with above
Item 34 5 wt% organoclay content. An investigation is reported
Polymer International into the key factors that influence the stiffness-toughness
55, No.2, Feb.2006, p.204-15 balance for PP nanocomposites with between 1 and 10
than that of NMH whereas the mechanical properties of and nanoclay products are compared and tested in terms
EVA containing NMH were better than those of EVA of properties, filler levels, processability, dimensional
containing NHT. 27 refs. stability, and colour. 6 refs.
CHINA USA
Accession no.964049 Accession no.965244
Item 41 Item 43
Journal of Applied Polymer Science Macromolecular Symposia
99, No.6, 15th March 2006, p.3275-80 No.233, 2006, p.180-90
MORPHOLOGY, THERMAL, AND POLYMER NANOCOMPOSITES: HOW TO
MECHANICAL PROPERTIES OF FLAME- REACH LOW FLAMMABILITY?
RETARDANT SILICONE RUBBER/ Bourbigot S; Duquesne S; Jama C
MONTMORILLONITE NANOCOMPOSITES ENSCL
Ling Yang; Yuan Hu; Hongdian Lu; Lei Song
The flammability properties of nanocomposites of
China,University of Science & Technology
polymers such as ethylene-vinyl acetate copolymer,
Morphology, mechanical properties, thermal stability polystyrene and poly(ether-b-amide) block copolymer, with
and flammability of composites of silicone rubber and montmorillonite clay, organically modified montmorillonite
montmorillonite, with magnesium hydroxide and red clay, polyhedral oligomeric silsesquioxanes and carbon
phosphorus as synergistic flame retardant additives, were nanotubes are reviewed in terms of heat release rate, UL-94
examined using X-ray diffraction, environmental scanning testing and limiting oxygen index. The characterisation of
electron microscopy, tensile testing, thermogravimetric dispersion of nanoparticles by solid-state NMR and TEM,
analysis and limiting oxygen index measurements. Addition and the synergistic effects of combining nanoparticles
of 1 percent montmorillonite clay lifted the decomposition with flame-retardants or plasma treatment are discussed.
temperature above that of the base silicone rubber. Good 54 refs.
flame retardant properties with higher thermal stability EUROPEAN COMMUNITY; EUROPEAN UNION; FRANCE;
were observed in the nanocomposites. 17 refs WESTERN EUROPE
CHINA Accession no.966495
Accession no.964509
Item 44
Item 42 Journal of Materials Science
SPE Automotive TPO Global Conference 2005. 41, No.2, Jan.2006, p.363-7
Proceedings of a conference held Sterling Heights, Mi., MAGNESIUM HYDROXIDE SULFATE
10th.-12th. Oct. 2005. HYDRATE WHISKER FLAME RETARDANT
Brookfield, Ct., SPE, 2005, Paper 15, pp.11, CD-ROM, POLYETHYLENE/MONTMORILLONITE
012 NANOCOMPOSITES
THE DEVELOPMENT AND EXPANSION OF Hongdian Lu; Yuan Hu; Junfeng Xiao;
TPO NANOCOMPOSITE MATERIALS IN Zhengzhou Wang; Zuyao Chen; Weicheng Fan
AUTOMOTIVE APPLICATIONS China,university of Science & Technology
Rodgers W R; Fasulo P D; Balow M J; Bolthouse C L Exfoliated nanocomposites were fabricated from maleated
General Motors; Basell Advanced Polyolefins PE, magnesium hydroxide sulphate hydrate (MHSH)
(SPE,Detroit Section) whiskers and organomodified montmorillonite by direct
The practical implementation of thermoplastic polyolefin melt intercalation. The morphology, combustion behaviour
(TPO) composites in the automotive industry has been and heat stability of the nanocomposites were investigated
challenging, it is stated. Initial applications were where by X-ray diffraction, TEM, cone calorimetry and TGA
overall part quality and thermal properties were considered and the effects of MHSH and modified montmorillonite
more important than maximising the mechanical properties. on nanocomposite properties evaluated. A synergistic
More recently, there has been an impetus to improve the flame retardant effect was observed in the nanocomposites
property profile, and the maximisation of exfoliation is containing both MHSH and modified montmorillonite.
known to be the key to reaching these objectives. This This effect was attributed to the release of water from
paper, therefore, reviews the current state of the effort MHSH, which accelerated the transportation of silicate
to improve the physical properties of thermoplastic layers to accumulate over the substrate. 16 refs.
polyolefin nanocomposite materials for use in automotive CHINA
applications. Improvements in platelet exfoliation have Accession no.966763
been made by chemical modification of the organoclay
and also by the refining of compounding techniques. Such
techniques are examined and TPOs based on recent talc
Item 45 Item 47
High Performance Fillers 2006: 2nd International Polymer Engineering and Science
Conference on Fillers for Polymers. Proceedings of a 46, No.5, 2006, p.670-9
conference held Cologne, Germany, 21st-22nd March STRUCTURE AND PROPERTIES OF
2006. MULTIWALLED CARBON NANOTUBES/
Shawbury, Rapra Technology Ltd., 2006, Paper 16, CYANATE ESTER COMPOSITES
pp.6, 29 cm, 012 Zhengping Fang; Jianguo Wang; Aijuan Gu
POSS AS PROMISING FIRE RETARDANTS IN Zhejiang,University
POLYMER NANOCOMPOSITES
Two types of multiwalled carbon nanotubes (MW-
Gamino G; Fina A; Tabuani D
CNTs) with different structure and morphology were
Torino,Politecnico
used to fabricate cyanate ester (CE) matrix composites.
(Rapra Technology Ltd.)
Mechanical, thermal, and transmission electron microscopy
The organic-inorganic chemical structure of polyhedral tests were performed to evaluate the different effects of the
oligomeric silsesquioxanes (POSS) makes them suitable two types of MW-CNTs on the structure and properties
for use as versatile nanofillers for flame retarded polymer of MW-CNT/CE composites. Results showed that the
nanocomposites. The thermal stability of the organic Si- bundled MW-CNTs were easier to be dispersed in CE
O structure is combined with good dispersibility due to matrix than single MW-CNTs, and could improve the
the compatibility of POSS organic substituents. In this toughness and stiffness of CE material more significantly.
work, nanocomposites were prepared by melt processing Functionalisation of the two types of MW-CNTs, which
POSS in polypropylene nylon-6 and PBTP. The thermal was achieved by grafting triethylenetetramine groups onto
and combustion properties of the nanocomposites the surface of MW-CNTs, was helpful in improving the
were evaluated. It was found that POSS-polymer dispersion of the MW-CNTs in CE, and thus in fabricating
nanocomposites produced a thermally stable ceramic layer MW-CNT/CE composites with improved mechanical and
during the early stage of thermal decomposition which thermal properties. 27 refs. Copyright 2006 Society of
protected the underlying material from oxygen, reduced Plastics Engineers
diffusion of volatile degradation products and limited CHINA
heat transfer. This combined physical action reduced the Accession no.967583
rate of heat release during combustion. Cone calorimetry
was used to investigate the fire performance of the POSS
nanocomposites. 13 refs. Item 48
EUROPEAN COMMUNITY; EUROPEAN UNION; ITALY;
Journal of Materials Chemistry
WESTERN EUROPE 16, No.16, 28th April 2006, p.1549-54
Accession no.967313 STRUCTURAL CHARACTERIZATION AND
THERMAL OXIDATION PROPERTIES OF
LLDPE/MgAl-LDH NANOCOMPOSITES
Item 46 Du L; Qu B
London, Interscience Communications Ltd., 2006, 30 Hefei,University of Science & Technology
papers, pp.xii, 283, ISBN 0954121678, 24cm, 012
FLAME RETARDANTS 2006. Proceedings of The synthesis of nanocomposites of linear low density
a conference held London, 14th-15th polyethylene with various proportions of magnesium-
Feb.2006 aluminium layered double hydroxide by melt intercalation,
(BPF; Interscience Communications Ltd.; Plastics and their characterisation by FTIR, XRD, TEM, DSC and
Europe; European Flame Retardant Assn.) TGA, is described. The thermal properties of the products
are discussed in terms of potential applications as flame-
Thirty papers are presented following the twelfth retardants for polymeric materials. 26 refs.
International Flame Retardants conference series. This CHINA
series concentrates on the practical applications of
Accession no.967693
flame retardants and polymers and brings together the
manufacturers and users with legislators, fire test experts
and fire scientists. Papers include fire safety, smoke toxicity Item 49
and acidity, ignition of solids - what have we learned in Polymers for Advanced Technologies
a half-century of research, progress with nanocomposites 17, No.4, April 2006, p.206-17
and new nanostructured FRs, mechanisms of phosphorus FLAME RETARDED POLYMER LAYERED
flame retardants, acceptable fire safety, the need for full SILICATE NANOCOMPOSITES: A REVIEW
scale fire testing of sandwich panels. OF COMMERCIAL AND OPEN LITERATURE
EUROPE-GENERAL; EUROPEAN COMMUNITY; EUROPEAN SYSTEMS
UNION; UK; USA; WESTERN EUROPE Morgan A B
Accession no.967538 Dow Chemical Co.
A review is presented of polymer nanocomposites used ratios. The nanocomposite structure was examined using
for flame retardancy applications, including commercial X-ray diffraction, TEM and high resolution electron
materials and open literature examples. Where possible, microscopy. This study showed that the presence of maleic
details of the way in which the nanocomposite and flame anhydride-modified PP and the ratio of surfactant to MMT
retardant work together are discussed. The key lesson from both influenced the dispersion of MMT in the hybrids.
this review is that, while the polymer nanocomposite can The thermal stability and flame retardant properties were
be considered to be flame retarded (or a flame retardant) investigated. The synergistic effect between MMT and an
by definition, these materials by themselves are unable to intumescent flame retardant (ammonium polyphosphate/
pass regulatory fire safety tests such as UL-94V. Additional pentaerythritol) and the flame retardant mechanism are
flame retardants are, therefore, needed in combination discussed. 23 refs.
with the polymer nanocomposite to pass these tests. In CHINA
multiple examples, the nanocomposite works with other Accession no.969165
flame retardants in a synergistic or cooperative manner
to lower the polymer flammability (heat release rate).
Finally, a discussion on research needs and the outlook Item 52
for polymer nanocomposite flammability research is Polymers for Advanced Technologies
included. 68 refs. 17, No.4, April 2006, p.281-93
USA
PHOSPHONIUM-MODIFIED LAYERED
SILICATE EPOXY RESINS NANOCOMPOSITES
Accession no.969162 AND THEIR COMBINATIONS WITH ATH AND
ORGANO-PHOSPHORUS FIRE RETARDANTS
Item 50 Schartel B; Knoll U; Hartwig A; Puetz D
Polymers for Advanced Technologies BAM Federal Institute for Materials Research &
17, No.4, April 2006, p.218-25 Testing; Fraunhofer-Institut fuer Fertigungstechnik und
FLAME RETARDANCY OF NANOCOMPOSITES Ang.Materialforschung
BASED ON ORGANOCLAYS AND CARBON
Phosphonium-modified layered silicate epoxy resin
NANOTUBES WITH ALUMINIUM TRIHYDRATE
nanocomposites were evaluated by testing the thermal/
Beyer G
thermomechanical properties (DSC, TGA, torsion
pendulum, Sharpy toughness), flammability (limiting
Kabelwerk Eupen AG
The addition of aluminium trihydrate as a microfiller oxygen index) and fire behaviour (cone calorimeter with
to organoclays or carbon nanotubes is shown to be different irradiations). The morphology of the composites
essential to generate EVA nanocomposites with adequate was determined using SEM and TEM. The drying
flame retardant properties, as required by industry. conditions of phosphonium-modified layered silicate
Cables containing a combination of organoclays or were varied in order to improve nanocomposite formation
carbon nanotubes and aluminium trihydrate are used to and properties. The results were compared with those
demonstrate the applications of these nanocomposites as obtained by using a commercial ammonium-modified
a new concept for flame retardancy. Small-scale fire tests montmorillonite. Enhanced nanocomposite formation
with Bunsen burner flames attacking the wire insulation was found for the commercial systems due to the amount
show that the char is strengthened by the long L/D ratio of excess surfactant, but this effect was overcompensated
of the multi-walled carbon nanotubes. The improved through the advanced morphology of the phosphonium-
char results in better flame retardant performances of the modified systems. Several fire retardancy mechanisms and
wires. 36 refs. their specific effect on various fire properties are discussed.
BELGIUM; EU; EUROPEAN COMMUNITY; EUROPEAN UNION; The main mechanism of layered silicate is a barrier
WESTERN EUROPE; WESTERN EUROPE-GENERAL formation influencing the flame spread in developing fires.
Accession no.969163 Several minor mechanisms are significant, but important
fire properties such as flammability or fire load are hardly
influenced. Combinations with aluminium hydroxide
Item 51
and organo-phosphorus flame retardants were, therefore,
Polymers for Advanced Technologies
evaluated and the combination with aluminium hydroxide
17, No.4, April 2006, p.235-45
was shown to be a promising approach. 42 refs.
POLY(PROPYLENE)/CLAY NANOCOMPOSITES
EUROPEAN COMMUNITY; EUROPEAN UNION; GERMANY;
AND THEIR APPLICATION IN FLAME WESTERN EUROPE
RETARDANCY
Accession no.969170
Yuan Hu; Yong Tang; Lei Song
China,University of Science & Technology
Item 53
PP/clay and PP/clay/calcium carbonate nanocomposites
Polymers for Advanced Technologies
were prepared by a one-step method, using pristine
17, No.4, April 2006, p.294-303
montmorillonite(MMT) with surfactant loading at different
FLAME-RETARDANT UNSATURATED
showed an increase in Tg for the nanocomposites. Tensile gel process provided promising opportunities for the
properties and impact strength of nanocomposites were preparation of a variety of organic-inorganic hybrid
better than those of conventional composites. Water barrier materials at the molecular level, and was used in this study
properties of nanocomposites were also better than those to improve the flame retardance and thermal stability. A
of conventional composites. 23 refs. coupling agent was used to form the covalent bonding
INDIA between organic and inorganic phases to promote the
Accession no.972169 miscibility of the hybrid creamers. Thermal properties
were investigated by thermogravimetric analysis. The
char yields of the hybrids increased with increasing
Item 57 tetraethoxysilane content. Limiting oxygen Index and
Composites Technologies for 2020. Proceedings of the UL-94 tests revealed that the hybrid ceramer possessed
Fourth Asian-Australasian Conference on Composite excellent flame resistance. 31 refs
Materials (AACM-4), held Sydney, Australia, 6th-9th CHINA
July 2004.
Cambridge, Woodhead Publishing, 2004, p.742-747, Accession no.972324
ISBN 1855738317, 25 cm, 012
PREPARATION AND PROPERTIES OF Item 59
TOUGHENED NOVOLAC TYPE PHENOLIC/ European Polymer Journal
SILICON DIOXIDE FLAME RETARDANT 42, No.6, 2006, p.1362-1369
NANOCOMPOSITE THERMAL STABILITY AND FLAME
Chen-hi Ma; Hsin Tai; Chin-Lung Chiang; RETARDANT EFFECTS OF HALLOYSITE
Hsu-Chiang Kuan; Jen-Chang Yang; Chia-Wen Hsu NANOTUBES ON POLY(PROPYLENE)
Taiwan,National Tsing Hua University; Hung- Mingliang Du; Baochun Guo; Demin Jia
Kuang,University; Chung Shan,Institute of Science South China,University of Technology
(Asian-Australasian Association for Composite
Naturally occurred halloysite nanotubes (HNTs) with
Materials)
hollow nanotubular structures were used as a new type
I n t h i s s t u d y, h y d r o x y l g r o u p t e r m i n a t e d filler for poly(propylene) (PP). Nanocomposites based on
polydimethylsiloxanes were used to toughen 3-glycidox PP and HNTs were prepared by melt blending. Scanning
ypropyltrimethoxysilane-modified novolac-type phenolic electronic microscopy (SEM) results suggested HNTs were
resins reinforced with silicon dioxide in an organic/ dispersed in PP matrix evenly at nanoscale after facile
inorganic nanocomposite via the sol-gel method. The modification. Thermal stability of the nanocomposites
properties of the hybrid nanocomposites are investigated, was found remarkably enhanced by the incorporation of
and improvements in impact strength, flexural strength and HNTs. Cone calorimetric data also showed the decrease
modulus and toughness are discussed. 8 refs. of flammability of the nanocomposites. Entrapment
CHINA mechanism of the decomposition products in HNTs was
Accession no.972323 proposed to explain the enhancement of thermal stability
of the nanocomposites. The barriers for heat and mass
transport, the presence of iron in HNTs, are all responsible
Item 58 for the improvement in thermal stability and decrease in
Composites Technologies for 2020. Proceedings of the flammability. Those results suggested potential promising
Fourth Asian-Australasian Conference on Composite flame retardant application of HNTs in PP. 18 refs.
Materials (AACM-4), held Sydney, Australia, 6th-9th Copyright (c) 2006 Elsevier Ltd.
July 2004. CHINA
Cambridge, Woodhead Publishing, 2004, p.748-753,
ISBN 1855738317, 25 cm, 012 Accession no.972489
SYNTHESIS, THERMAL PROPERTIES AND
FLAME RETARDANCE OF NOVEL PHENOLIC Item 60
RESIN/SILICA NANOCOMPOSITES Polymer Degradation and Stability
Chin-Lung Chiang; Chen-Chi Ma; Hey Rey Chang; 91, No.9, 2006, p.1937-1947
Shiu-Chun Lu EFFECT OF ACRYLIC POLYMER AND
Hung-Kuang,University; Taiwan,National Tsing NANOCOMPOSITE WITH NANO-SIO”2
Hua University; Ming Hsin,University of Science & ON THERMAL DEGRADATION AND FIRE
Technology RESISTANCE OF APP-DPER-MEL COATING
(Asian-Australasian Association for Composite Wang Z; Han E; Ke W
Materials) Shenyang,Institute of Metal Research
Novel phenolic/silica hybrid ceramers were synthesised Acrylic nanocomposite and flame retardant coatings with
by the sol-gel process and FTIR and NMR were used different acrylic polymers were prepared. The effect of
to characterise the structure of the hybrids. The sol- molecular structure and molecular weight of acrylic resins
and nanocomposite with nano-SiO2 on the interaction developments in nanoclay materials now available for use
and char formation of ammonium polyphosphate- in applications from automotive to agricultural, materials
dipentaerythritol-melamine (APP-DPER-MEL) coating handling, and electrical wire and cable jacketing. It
was investigated using differential thermal analysis (DTA), demonstrates how these new nanoclay blends are lowering
thermogravimetry (TG), Limiting Oxygen Index (LOI), costs and raising performance.
scanning electron microscopy (SEM), X-ray photoelectron Co-Op Chemical Co.; DDG Cryogenics; Degussa Corp.;
spectroscopy (XPS) and fire protection test. The interaction Dieter Scientific; Dyneon LLC; Elam El Industries;
of APP, DPER, MEL and 3F-1 acrylic resin led to the Elementis Specialties Inc.; Executive Conference
formation of intumescent coherent char at 300-450 deg.C. Management; Naturalnano Inc.; NanoSperse LLC;
Owing to low molecular weight and lack of benzene rings, PolyOne Corp.; Premix Thermoplastics; Putsch
F-963 acrylic resin decomposed at lower temperature than Kunststoffe GmbH; Pyrograph Products Inc.;
APP, and hence their endothermic interaction was destroyed. Sachtleben Chemie GmbH; Sud-Chemie; Ube America
The well-distributed nano-SiO2 particles in acrylic Inc.; DMS Xplore; Geoflow; Toro Co.; Delphi Corp.;
nanocomposite could modify char formation and anti- Audi; Volkswagen; Kabelwerk Eupen; Nexans; Draka
oxidation of char structure at high temperature. It is noted Cable; Toyota Corp.; US,Air Force; Wright-Patterson
that the fire protection properties of nanocoating with acrylic AFB; Dayton,University; Boeing
nanocomposite were better than those of flame retardant BELGIUM; EU; EUROPE-GENERAL; EUROPEAN COMMUNITY;
coatings with conventional acrylic resins. 36 refs. EUROPEAN UNION; FRANCE; GERMANY; ISRAEL; JAPAN;
NETHERLANDS; NORTH AMERICA; USA; WESTERN EUROPE;
CHINA
WESTERN EUROPE-GENERAL
Accession no.972527 Accession no.973225
Item 61 Item 63
Macromolecules Flame Retardants 2006, Proceedings of a conference
39, No.14, 11th July 2006 p.4793-4801 held London, 14th -15th Feb.2006..
COMPATIBILIZING BULK POLYMER BLENDS London, Interscience Communications Ltd., 2006,
BY USING ORGANOCLAYS p.123-133, ISBN 0954121678, 24CM, 012
Si M; Araki T; Ade H; Kilcoyne A L D; Fisher R; PROGRESS WITH NANOCOMPOSITES AND
Sokolov J C; Rafailovich M H NEW NANOSTRUCTURED FRs
New York,State University; North Carolina,State Beyer G
University; Lawrence Berkeley Laboratory; Kabelwerk Eupen AG
Uniondale,Hebrew Academy (BPF)
The compatibilising effects of addition of two commercial This study explores the use of organoclays as flame
Cloisite organoclays on blends of polymers including retardants for thermoplastic polyurethanes and plasticised
polystyrene/polymethyl methacrylate; polycarbonate/ PVC, and also reports on the flame retardant properties
styrene acrylonitrile copolymer or polymethyl methacrylate/ of nanostructured fillers, sepiolite and carbon nanofibres.
ethylene vinyl acetate copolymer were studied transmission When modified layered silicates as fillers were dispersed
electron microscopy, X-ray microscopy, differential at a nm-level within a thermoplastic polyurethane matrix,
scanning calorimetry and dynamic mechanical analysis. thermal stability and peak of heat release rates were
In all cases, in comparison to blends without clay, large improved, but time to ignition of the nanocomposite were
reductions in domain size were observed with localisation reduced. PVC with organoclays showed a fast HCl release
of clay platelets along polymer interfaces. Increases in by an accelerated chain-stripping reaction of the polymer
modulus and in some cases unification of glass transition catalysed by the ammonium compound of the organoclays.
temperatures were observed. System models were Synthesis routes based on EVA or TPU masterbatches of
proposed indicating in-situ grafting of polymers to clay organoclays were found to avoid the darkening of PVC
platelets, and the technology may be of value in recycling compounds. Test using a cone calorimeter did not show
of mixed polymers. 32 refs. any remarkable improvement in the flame retardancy of
USA
PVC filled with organoclays. The use of modified sepiolite
Accession no.972942 and also carbon nanofibres were found to be effective
nanostructured flame retardants in EVA. 14 refs.
Item 62 BELGIUM; EU; EUROPEAN COMMUNITY; EUROPEAN UNION;
WESTERN EUROPE; WESTERN EUROPE-GENERAL
Plastics Technology
52, No.2, Feb.2006, p.56/68 Accession no.974428
NANOCOMPOSITES DO MORE WITH LESS
Schut J H
Nanocomposites are at last out of the laboratory and
into the real world! This detailed article highlights new
polymers, poly(oxyphenylene-sulphonylphenylene- burn test. The tensile and compression properties of the
oxydiphenyl phenylene phosphine oxide), 2,5-dihydroxy- flame retarded composites were also investigated. The
1-biphenylene-phosphine oxide-based polysulphone, flame retardant readily mixed with the resins and provided
poly(sulphonyl-diphenylphenylene phosphonate) and cast materials with a V-O UL94 rating. 5 refs.
bisphenol A-based polysulphone was studied using TGA. USA
The pyrolysis and fire retardancy properties of blends Accession no.977528
of the polymers with epoxy resin were investigated by
limiting oxygen index and cone calorimetry measurements
and the results are discussed in terms of the heat release Item 71
rate, char formation and flame inhibition. 45 refs. SAMPE ‘06: Creating New Opportunities for The World
EUROPEAN COMMUNITY; EUROPEAN UNION; GERMANY;
Economy: Volume 51. Proceedings of a conference held
WESTERN EUROPE Long Beach, Ca., 30th April-4th May 2006.
Accession no.977226 Covina, Ca., SAMPE International Business Office,
2006, Paper 74, pp.11, CD-ROM, 012
FLAME RETARDED POLYUREA
Item 69 NANOCOMPOSITES FOR EXPLOSION
SAMPE ‘05: New Horizons for Materials and RESISTANT COATINGS
Processing Technologies. Proceedings of a conference Zammarano M; Gilman J W
held Long Beach, Ca., 1st-5th May 2005. NIST
Covina, Ca., ACS, SAMPE International Business (SAMPE)
Office, 2005, paper 125, pp.11, CD-ROM, 012
NAVY R & D PROGRAMS: MATERIALS The flammability of polyurea explosion-resistant
TECHNOLOGY FOR FIRE SAFETY OF coatings containing a combination of conventional flame
COMPOSITE STRUCTURES retardants (ammonium polyphosphate or melamine
Sorathia U; Perez I polyphosphate) and nanofillers (layered double hydroxides,
US,Naval Surface Warfare Center; US,Office of Naval polyhedral oligosilsesquioxane and carbon nanofibres)
Research was investigated by means of the modified horizontal
(SAMPE) radiant panel test and cone calorimetry. The effect of
partially replacing the conventional flame retardants
Current research by, or funded by, the naval authorities with the nanofillers on the flammability of the coatings
in fire retardant structural systems for use in marine was examined. The results obtained indicated that partial
applications is discussed. Resin systems based on replacement of the flame retardants with layered double
brominated polyvinyl ester resins with nanoclay additives hydroxides or polyhedral oligosilsesquioxanes could
and phosphate fire retardants, phthalonitrile resins, provide a significant improvement in flammability and
polyhedral oligomeric silsesquioxane resin systems and toughness and possibly anti-blast properties. 13 refs.
bisphenol-C resins were compared. New core materials
USA
such as carbon foam and phenolic foam were compared
Accession no.977531
to balsa wood and other thermoplastic foam cores such as
polyvinyl chloride and polymethacrylamide. 10 refs.
USA Item 72
SAMPE ‘06: Creating New Opportunities for The World
Accession no.977357
Economy: Volume 51. Proceedings of a conference held
Long Beach, Ca., 30th April-4th May 2006.
Item 70 Covina, Ca., SAMPE International Business Office,
SAMPE ‘06: Creating New Opportunities for The World 2006, Paper 79, pp.13, CD-ROM, 012
Economy: Volume 51. Proceedings of a conference held EARLY IGNITION OF FLAME RETARDED
Long Beach, Ca., 30th April-4th May 2006. PLASTICS AS MEASURED BY CONE
Covina, Ca., SAMPE International Business Office, CALORIMETER
2006, Paper 70, pp.7, CD-ROM, 012 Morgan A B; Bundy M
A NEW FLAME RETARDANT ADDITIVE FOR Dayton,University,Research Institute; NIST
POLYMERIC COMPOSITES (SAMPE)
Rogers M; Small A; Amos T; Johnson A; Sterner L
Luna Innovations The results are reported of flame retardancy studies
(SAMPE) carried out on a range of flame retarded polymers and
nanocomposites, including high-impact PS, polycarbonate,
A novel flame retardant composed of superabsorbent polycarbonate/ABS blend and PS and PP nanocomposites,
polyacrylamide microspheres containing an inorganic using the UL-94V test procedure and cone calorimeter. The
phosphate was prepared and evaluated in vinyl ester and phenomenon of early ignition in some of these materials is
epoxy matrix resins for glass fibre-reinforced composite addressed and the relationship between UL-94V and cone
systems using the horizontal burn test and UL94 vertical calorimeter is examined. 44 refs.
GROWTH OF GLASS PARTICLE AND FIBER The compression strength suffers significant reductions
REINFORCED EPOXIES WITH STRONG with water absorbed (28%) and impact (maximum 42%).
AND WEAK BONDING CONDITIONS. II. The least sensitive to impact damage are wet samples
MICROSCOPIC STUDY ON TOUGHENING of interlaminated composite. The experimental results
MECHANISM of residual compression strength are compared with
Kawaguchi T; Pearson R A predictions based on a simple, empirical model. 26 refs.
Lehigh,University EASTERN EUROPE; EU; EUROPEAN COMMUNITY;
EUROPEAN UNION; FRANCE; POLAND; WESTERN EUROPE;
The toughening mechanisms in three types of glass- WESTERN EUROPE-GENERAL
filled epoxy composites subject to fatigue loading are Accession no.931405
studied by several different microscopy techniques. The
observed toughening mechanisms are then related to the
macroscopic fatigue crack propagation behaviour. The Item 88
role of matrix-reinforcement adhesion is systematically Journal of Fire Sciences
investigated. Scanning electron microscopy (SEM) and 23, No.1, Jan.2005, p.75-87
transmission optical microscopy (OM) studies reveal that FLAME RETARDANCY OF NANOCOMPOSITES
toughening mechanisms such as microcracking, crack - FROM RESEARCH TO TECHNICAL
pinning, shear yielding, fibre bridging, and fibre debonding PRODUCTS
and pull-out are dependent on the surface treatment of the Beyer G
reinforcements as well as the shape of reinforcements. Kabelwerk Eupen AG
The nature of the toughening mechanisms observed agree Flame-retardant nanocomposites were synthesised by
with the fatigue crack propagation behaviour predicted melt-blending EVA with modified layered silicates as
by crack tip shielding concepts. Interestingly, matrix nanofillers. TGA performed in air demonstrated a clear
shear yielding turns out to be the prevalent toughening increase in the thermal stability of the layered silicate-
mechanism in those mechanisms subjected to moisture based nanocomposites. The cone calorimeter was
exposure. In dry as-moulded composites, a careful used to investigate fire hazards. The nanocomposites
investigation involving SEM, OM, fluorescent microscopy caused a large decrease in the peak of heat release rates.
and atomic force microscopy indicate that the particular Char formation was the main important factor for the
micromechanisms observed are indeed microcracks, and improvement of flame retardancy and its function was
not micro-shear bands as has been suggested by other examined. Further improvements of the flame retardancy
researchers. 39 refs. by using combinations of nanofillers and traditional flame
USA retardant additives based on metal hydroxides were also
Accession no.931385 studied. The nanocomposites based on nanofillers and
aluminium trihydrate could be used as efficient systems for
Item 87 flame-retardant cables. The corresponding results obtained
Composites Science and Technology for a coaxial cable complying with the UL 1666 riser test
64, Nos.13-4, 2004, p.2271-8 are presented. 17 refs.
BELGIUM; EU; EUROPEAN COMMUNITY; EUROPEAN UNION;
EFFECT OF WATER IMMERSION AGEING
WESTERN EUROPE; WESTERN EUROPE-GENERAL
ON LOW-VELOCITY IMPACT BEHAVIOUR
OF WOVEN ARAMID-GLASS FIBRE-EPOXY Accession no.932175
COMPOSITES
Imielinska K; Guillaumat L Item 89
Gdansk,University; ENSAM Polymer Degradation and Stability
Two different woven glass-aramid-fibre/epoxy laminates 86, No.3, 2004, p.535-40
are subjected to water immersion ageing followed by PREPARATION AND PROPERTIES OF
instrumented low velocity impact testing. The hybrid HALOGEN-FREE FLAME-RETARDED
aramid-glass reinforcement consists of ten plies of woven POLYAMIDE 6/ORGANOCLAY
aramid-glass-fibre fabric or alternatively aramid-fibre NANOCOMPOSITE
fabric with glass-fibre fabric interlayers. The impacted Lei Song; Yuan Hu; Zhihua Lin; Shangyong Xuan;
plates are re-tested statically in compression to determine Shaofeng Wang; Zuyao Chen; Weicheng Fan
residual strength for assessment of damage tolerance. The China,University of Science & Technology
maximum water absorption (4.1-4.4%) and water diffusion Halogen-free flame retarded nylon-6/organoclay (PA6/
coefficients are found to be only slightly dependent on OMT) nanocomposite was prepared by using magnesium
reinforcement configuration. The delamination threshold hydroxide (MH) and red phosphorus (RP) as a flame
load and impact energy absorption are not significantly retardant and organoclay (OMT) as synergist, via a melt
affected by the absorbed water. Due to low fibre-matrix blend technique. The morphology was characterised by
adhesion, the prevailing failure modes at low impact X-ray diffraction and transmission electron microscopy.
energy are fibre/matrix debonding and interfacial cracking.
The effects of the organoclay on the mechanical properties polyamide or EVA and various flame retardants. It was
and the flammability of the flame retarded nylon-6 were concluded that the introduction of MMT into a polymer
investigated. The addition of OMT is shown to improve may improve the flame retardancy even without interface
the mechanical properties of the composite, and cone modification via a viscosity increasing effect. Surface
calorimetry tests showed that a synergistic effect occurred treatment of MMT with a cationic surfactant of higher heat
as MH-RP and OMT were added to nylon-6. The flame resistance increased the mechanical properties while the
retardant property of PA6 containing MH-RP and OMT flame retardancy was increased of decreased, depending
was better than PA6 containing MH-RP or OMT. 27 on the type of flame retardant system used. Well-dispersed
refs. MMT combined with charring flame retardants showed a
CHINA char stabilising effect. MMT had a catalytic effect on the
Accession no.932283 charring process which could be increased by replacing
its surface ions. Depending on its surface layer, MMT
could promote or hinder the migration of flame retardants
Item 90 to the surface. Expandable MMT, formed by intercalation
Journal of Polymer Science: Polymer Chemistry with a well-designed synergist, was the most rapid way
Edition of delivering the nanolayers and flame retardants to the
42, No.23, 1st Dec.2004, p.6163-6173 surface. 10 refs.
POLYPROPYLENE/MONTMORILLONITE EASTERN EUROPE; HUNGARY
NANOCOMPOSITES AND INTUMESCENT,
Accession no.934474
FLAME-RETARDANT MONTMORILLONITE
SYNERGISM IN POLYPROPYLENE
NANOCOMPOSITES Item 92
Yong Tang; Yuan Hu; Baoguang Li; Lei Liu; ACS Polymeric Materials: Science and Engineering.
Zhengzhou Wang; Zuyao Chen Fall Meeting 2004. Volume 91. Proceedings of a
Hefei,University Of Science & Technology conference held Philadelphia, Pa., 22nd-26th Aug.2004.
Washington, D.C., ACS, Division of Polymeric
Polypropylene (PP)-montmorillonite (MMT)
Materials: Science & Engineering, 2004, p.34-5, CD-
nanocomposites were prepared by melt intercalation
with pristine MMT, PP and maleic acid-modified PP, using
ROM, 012
EFFECT OF LAYERED SILICATE
the cationic surfactant hexadecyltrimethylammonium
NANOCOMPOSITES ON BURNING BEHAVIOUR
bromide. The dispersibility of MMT in the PP matrix was
OF CONVENTIONALLY FLAME-RETARDED
studied by X-ray diffraction, TEM and high-resolution
electron microscopy. An intumescent flame retardant (IFR)
UNSATURATED POLYESTERS
was added to the nanocomposites and the flammability
Kandola B K; Nazare S; Horrocks A R
Bolton Institute
properties were studied by cone calorimetry. Increasing
(ACS,Div.of Polymeric Materials Science & Engng.)
the surfactant or compatibiliser concentration improved
the dispersion of MMT and SCT-DFT theory predicted that Unsaturated polyester-organically modified montmorillonite
this reduces the free energy of the system. An optimum (5% w/w) nanocomposites incorporating a flame retardant
value for the synergistic effect between MMT and IFR was (ammonium polyphosphate, 20% with respect to resin-
found and the mechanism of synergism was discussed. clay mixture) were prepared by in-situ intercalative
32 refs. polymerisation. Thermal analysis of these materials was
CHINA compared with that of resin-organoclay nanocomposites
Accession no.933197 and resin-flame retardant samples. The results showed
that in unsaturated polyester resins, nanoclays on their
own were nor effective as char promoters although
Item 91 significant reduction of heat release values occurred.
ACS Polymeric Materials: Science and Engineering. When conventional flame retardants were added to the
Fall Meeting 2004. Volume 91. Proceedings of a nanocomposites, char formation was enhanced and the
conference held Philadelphia, Pa., 22nd-26th Aug.2004. peak heat release rate was reduced. The results were
Washington, D.C., ACS, Division of Polymeric discussed. 3 refs.
Materials: Science & Engineering, 2004, p.29, CD- EU; EUROPEAN COMMUNITY; EUROPEAN UNION; UK;
ROM, 012 WESTERN EUROPE; WESTERN EUROPE-GENERAL
EFFECT OF INTERFACES IN FLAME Accession no.934477
RETARDED NANOCOMPOSITES
Marosi G; Anna P; Szabo A
Budapest,University of Technology & Economics Item 93
(ACS,Div.of Polymeric Materials Science & Engng.) ACS Polymeric Materials: Science and Engineering.
Fall Meeting 2004. Volume 91. Proceedings of a
A 5% concentration of layered silicate (montmorillonite, conference held Philadelphia, Pa., 22nd-26th Aug.2004.
MMT) was introduced into systems containing PP, Washington, D.C., ACS, Division of Polymeric
resin, which was thought to be due to the high viscosity of Nanocomposites incorporating modified layered silicates
tetrafunctional epoxy resin. The blending of tetrafunctional as fillers dispersed at the nm-level within a polymer
epoxy resin with low viscosity trifunctional epoxy resin matrix are examined with respect to their inherent flame
resulted in a marked improvement in mechanical properties retardancy. The flame retardancy mechanism is reported
of composites due to reduction in viscosity. The results to be based on the char formation and its structure. The
were explained in terms of interlaminar shear strength char insulates the polymer from heat and acts as a barrier,
analysis of the composites. 21 refs. reducing the escape of volatile gases from the polymer
INDIA combustion. In addition, the combination of organoclays
Accession no.946316 with traditional flame retardants is shown to be a means
of further improving the flame retardant properties of
polymers. The cone calorimeter is used as a tool for the
Item 116 investigation of flame retardancy. 9 refs.
Polymer Materials Science and Engineering BELGIUM; EU; EUROPEAN COMMUNITY; EUROPEAN UNION;
21, No.3, May 2005, p.1-5 WESTERN EUROPE; WESTERN EUROPE-GENERAL
Chinese Accession no.950361
THE LATEST DEVELOPMENT OF NON-
HALOGEN FLAME-RETARDED PA
Yu-Xiang Ou Item 119
Beijing,Institute of Technology Fire and Materials
29, No.5, Sept.-Oct.2005, p.283-94
The latest developments in non-halogen flame retarded CONE CALORIMETRIC AND
polyamides, including those treated with melamine THERMOGRAVIMETRIC ANALYSIS
derivatives and reactive phosphorus compounds and EVALUATION OF HALOGEN-CONTAINING
inorganic nanocomposites. Flame retardant mechanisms POLYMER NANOCOMPOSITES
and the future of non-halogen flame retarded polyamides Wang D; Echols K; Wilkie C A
are also considered. 36 refs. Marquette,University
CHINA
The morphology and fire retardancy of nanocomposites
Accession no.948085
of bromine-containing polymers, such as copolymers of
styrene and dibromostyrene, with various proportions of
Item 117 montmorillonite clay, organically modified with a fluorine-
ACS Polymeric Materials: Science and Engineering. containing quaternary ammonium salt, were investigated
Fall Meeting 2004. Volume 91. Proceedings of a by XRD, TGA and cone calorimetry studies. The effects of
conference held Philadelphia, Pa., 22nd-26th Aug.2004. bromine content and method of preparation on the results
Washington, D.C., ACS, Division of Polymeric are discussed. 15 refs.
Materials: Science & Engineering, 2004, p.738-9, CD- USA
ROM, 012 Accession no.950949
THERMAL PROPERTIES AND FLAME
RETARDANCE OF NANOCOMPOSITES
OF POLYVINYL CHLORIDE AND Item 120
NANOHYDROTALCITE Journal of Applied Polymer Science
Wang X 97, No.6, 15th Sept.2005, p.2375-81
Beijing,University of Chemical Technology TENSILE AND FLAMMABILITY PROPERTIES
(ACS,Div.of Polymeric Materials Science & Engng.) OF POLYPROPYLENE-BASED RTPO/CLAY
NANOCOMPOSITES FOR CABLE INSULATING
Details are given of the preparation of PVC modified with MATERIAL
hydrotalcite as a heat stabiliser. The thermal degradation of Hong C H; Lee Y B; Bae J W; Jho J Y; Nam B U;
the nanocomposite was investigated. Characterisation was Nam G J; Lee K J
also undertaken using TEM, TGA and FTIR. 9 refs. Seoul,National University; Korea,University of
CHINA Technology & Education; LG Cable Ltd.
Accession no.949897
Nanocomposites were prepared by blending polypropylene-
based reactor thermoplastic polyolefin, maleic anhydride-
Item 118 grafted polypropylene oligomer compatibiliser, organically-
Polymers and Polymer Composites modified montmorillonite clay and magnesium hydroxide
13, No.5, 2005,p.529-38 flame retardant. The tensile strength increased, whilst
FLAME RETARDANCY OF NANOCOMPOSITES the elongation at break decreased, with increasing clay
- FROM RESEARCH TO REALITY. REVIEW content. From consideration of the tensile properties, it
Beyer G was concluded that the nanocomposites containing 10
Kabelwerk Eupen AG wt% clay were candidate materials for cable applications.
The nanocomposites exhibited heat release rates which retardant properties. Reasons for these observations were
were significantly less than that of the neat polymer, discussed. 18 refs.
combining was very high char yields. Although the clay EU; EUROPEAN COMMUNITY; EUROPEAN UNION; FRANCE;
enhanced the flame retardant properties, it was considered SENEGAL; WESTERN EUROPE; WESTERN EUROPE-GENERAL
that a conventional flame retardant, such as magnesium Accession no.951264
hydroxide, was necessary to provide adequate flame
retardant properties for cable applications. 32 refs.
Item 123
KOREA
Addcon World 2005. Proceedings of the 11th
Accession no.951085 International Plastics Additives and Modifiers
Conference, held Hamburg, 21st-22nd Sept.2005.
Item 121 Shawbury, Rapra Technology Ltd., 2005, Paper 11,
IRC 2005: Creating Value throughout the Supply Chain. pp.8, 29cm, 012
Proceedings of the North European International Rubber PROGRESS WITH NANOSTRUCTURED FLAME
Conference held Maastricht, The Netherlands, 7th-9th RETARDANTS
June 2005. Beyer G
London, IOM Communications, 2005, p.327-37, 21cm, Kabelwerk Eupen AG
012 (Rapra Technology Ltd.)
NANOCOMPOSITES AS A NEW CONCEPT FOR A brief report is presented on work carried out to
FLAME RETARDANCY OF POLYMERS improve the fire performance of polymers and cables
Beyer G using nanostructured materials. Results are reported for
Kabelwerk Eupen AG thermoplastic PU cables containing organoclays, PE and
(UK,Institute of Materials,Minerals & Mining) LDPE filled with polyhedral oligomeric silsesquioxanes,
Nanocomposites were fabricated from EVA and dimeth EVA filled with sepiolite and EVA flame retarded with
yldistearylammonium cation-modified montmorillonite a masterbatch of carbon nanofibres in EVA as carrier
as nanofiller with or without alumina trihydrate as matrix. 8 refs.
flame retardant and their morphological properties, heat BELGIUM; EU; EUROPEAN COMMUNITY; EUROPEAN UNION;
stability, flammability and thermal degradation behaviour WESTERN EUROPE; WESTERN EUROPE-GENERAL
The interlaminar shear strength(ILSS) of a composite examined in a nitrogen atmosphere, and the residues
composed of glass rovings in a polycarbonate-toughened were analysed thermogravimetrically and by transmission
epoxy resin matrix was studied. The variation of ILSS electron microscopy and X-ray diffraction. Up to 80% by
with the contents of glass rovings and of polycarbonate mass of the blackened residues consisted of clay particles
was investigated. For a given content of polycarbonate in and the remainder was thermally stable organic components
the matrix, the ILSS increased with volume fraction of with a possible graphitic structure. Clay particles were
glass rovings. For a given content of rovings, the ILSS stacked in the carbonaceous floccule residues and the
decreased with increasing polycarbonate content. The d-spacing of the clay platelets was 1.3-1.4 nm compared
ILSS of the composites with epoxy resin alone as the with the well exfoliated original sample. There are two
matrix was, however, found to be higher than that of the possible mechanisms that explain the accumulation of
epoxy resin/polycarbonate blend and this was attributed the initially well-dispersed clay particles in the sample
to better adhesion between epoxy resin and reinforcement on burning or gasifying the sample surface: recession of
than that between epoxy resin/polycarbonate blend and the polymer resin from the surface by pyrolysis to leave
reinforcement. This was further confirmed by SEM of with the de-wetted clay particles; and transportation of
ILSS fractured samples. 13 refs. clay particles by rising bubbles of degradation products
CHINA; INDIA and the associated convection flow in the melt from the
Accession no.904275 interior of the sample toward the surface. Neither PA6/clay
nanocomposite sample produced a sufficient amount of
protective floccules to cover the entire sample surface, and
Item 126 vigorous bubbling was observed over the sample surface
Composite Structures that was not covered by protective floccules. 30 refs.
62, No.3-4, Nov.-Dec.2003, p.391-5 USA
PREPARATION AND CHARACTERIZATION
Accession no.905576
OF Mg(OH)2 NANOPARTICLES AND
FLAME-RETARDANT PROPERTY OF ITS
NANOCOMPOSITES WITH EVA Item 128
Longzhen Qiu; Rongcai Xie; Peng Ding; Baojun Qu Shawbury, Rapra Technology Ltd., 2003, pp.138, 29
China,University of Science & Technology cm. Rapra Review Report 168,. vol. 14, no. 12, 2003.
NALOAN
Magnesium hydroxide nanocrystalline particles with
PLASTIC FLAME RETARDANTS:
needle- or lamella-like morphologies were synthesised
TECHNOLOGY AND CURRENT
by a surfactant-mediated solution method. The structures
DEVELOPMENTS
and morphologies of magnesium hydroxide nanoparticles
Innes J; Innes A
were characterised by X-ray diffraction, TEM and FTIR
Edited by: Humphreys S
spectroscopy. Magnesium hydroxide/EVA nanocomposite
(Rapra Technology Ltd.)
was also prepared and was shown to have a limiting oxygen
Rapra Review Report No.168
index value of 38.3. The high-resolution TEM picture
showed that the magnesium hydroxide nanoparticles A comprehensive review is presented of flame retardants
dispersed homogeneously in EVA matrix and the SEM for plastics, with particular reference to US and European
images indicated that the char formed after combustion of legislation, test methods and product developments. A
the nanocomposite was very compact. 21 refs. market overview is included with indications of market
CHINA drivers, major end-use applications, and safety standards.
Accession no.904327 Particular emphasis is given to flammability and smoke
tests. Flame retardants are considered under the headings
of halogen flame retardants; metal hydrate flame retardants;
Item 127 phosphorous flame retardants, smoke suppressants,
Polymer and other flame retardants, including recent technology
45, No.3, 1 Feb. 2004, p.881-91 advances, including nanotechnology. 434 refs.
FLAME RETARDANT MECHANISM OF EUROPE-GENERAL; USA
POLYAMIDE 6-CLAY NANOCOMPOSITES
Accession no.907057
Kashiwagi T; Harris R H; Xin Zhang; Briber R M;
Cipriano B H; Raghavan S R; Awad W H; Shields J R
NIST,Building & Fire Research Laboratory; Item 129
Maryland,University Journal of Materials Science. Materials in Electronics
The thermal and flammability properties of polyamide-
15, No.3, March 2004, p.175-82
FLAME RESISTANT GLASS-EPOXY PRINTED
6/clay nanocomposites containing 2 and 5% by mass of
clay were measured to determine their flame retardant
WIRING BOARDS WITH NO HALOGEN OR
PHOSPHORUS COMPOUNDS
performance. The gasification of the nanocomposite
samples at an external radiant flux of 50 kW/sq m was
Iji M; Kiuchi Y
build materials by the repetitive addition of thin layers. TEM analysis. The mechanical and dynamic mechanical
The mixture of epoxidised soybean oil and epoxy resin properties were evaluated and compared with the
is modified with di-, tri- or polyethylene amine gelling corresponding matrix. Improvements in impact properties
agent to solidify the materials until curing occurs. The high was explained in terms of fracture surface analysis by
strength and stiffness composites are formed through fibre SEM. 37 refs.
reinforcement. E-glass, carbon and mineral fibres are used AUSTRALIA; INDIA
in the formulations. The type of fibre affects the properties Accession no.902029
of the composites. It is found that a combination of two
types of fibres can be used to achieve higher strength and
stiffness parts than can be obtained from single fibre type. Item 145
In addition, the effects of curing temperature, curing time Journal of Applied Polymer Science
and fibre concentration on mechanical properties of are 90, No.8, 21st Nov.2003, p.2268-75
studied and reported. 9 refs. INFLUENCE OF ELASTOMER DISTRIBUTION
USA
ON THE CRYOGENIC MICROCRACKING OF
CARBON FIBRE/EPOXY COMPOSITES
Accession no.917942 Nobelen M; Hayes B S; Seferis J C
Washington,University
Carbon fibre-reinforced epoxy composites were toughened
Item 143
Polymer
with preformed rubber particles, core-shell rubber and
45, No.15, 2004, p.5163-70
solid carboxyl-functional rubber and the effect of these
THERMOPHYSICAL AND IMPACT
toughening agents on the microcracking response of the
PROPERTIES OF EPOXY NANOCOMPOSITES
composites upon exposure to cryogenic cycling investigated.
REINFORCED BY SINGLE-WALL CARBON
The effect of these toughening agents on the mode I and
NANOTUBES
mode II fracture toughness and interlaminar shear strength
Miyagawa H; Drzal L T
of the composites was also studied and scanning electron
Michigan,State University
microscopy was employed to analyse the fracture surfaces of
Dynamic mechanical analysis, thermogravimetric the rubber-modified composites. The modifiers were found
analysis and Izod impact testing were used to examine to significantly reduce microcrack density of the composites
thermophysical properties and impact strength of subjected to cryogenic cycling. 47 refs.
nanocomposites prepared using small volumetric amounts USA
of fluorinated single wall carbon nanotubes (FSWCNT) Accession no.899821
in epoxy resins based on the diglycidyl ether of bisphenol
A. Dispersion of FSWCNT in epoxy resin was achieved
using a sonication method, and large improvements Item 146
in modulus were achieved with a reduction in glass Shawbury, Rapra Technology Ltd., 2003, pp.166, 29 cm,
transition temperature due to the fluorine affecting the Rapra Review Rept. No. 163, vol.14, No.7, 2003
curing chemistry. Stoichiometric amounts of curing agent POLYMER/LAYERED SILICATE
required were determined using dynamic mechanical NANOCOMPOSITES
analysis. Large improvements in storage modulus were Okamoto M
observed with only slight reductions in Izod impact Toyota Technical Institute
strength up to filler levels of 0.3 percent. 35 refs. Edited by: Humphreys S
USA
(Rapra Technology Ltd.)
Rapra Review Report No. 163
Accession no.921579
Advantages of the use of polymer/layered silicate (PLS)
composites are discussed. The main reasons for improved
Item 144
properties is the interfacial interaction between the
polymer matrix and organically modified layered silicate,
Polymer
44, No.24, Nov.2003, p.7449-57
the latter having layer thicknesses in the order of 1 nm, and
NANOCOMPOSITES BASED ON A COMBINATION
very high aspect ratios. This review highlights the major
OF EPOXY RESIN, HYPERBRANCHED EPOXY
developments in this area during the last ten years, and
AND A LAYERED SILICATE
focuses on the different techniques used to prepare PLS
Ratna D; Becker O; Krishnamurthy R; Simon G P;
nanocomposites, their physicochemical characterisation,
Varley R J
and the improved material properties that those materials
Monash,University; CSIRO; India,Naval Materials
can provide. Processing and typical applications of PLS
Research Laboratory
composites are reported in detail. 484 refs.
Details are given of the preparation of epoxy resin/clay EUROPEAN COMMUNITY; EUROPEAN UNION; JAPAN; UK;
nanocomposites. The formation of the nanocomposites WESTERN EUROPE
was confirmed by wide angle X-ray diffraction and Accession no.898802
of thermo-oxidative degradation of modified epoxy vertical position. SAXS and mu-TA methods are used for
nanocomposites and pure epoxy is utilised by thermal determining the structure of this material. 29 refs.
analysis. The thermal stability of modified epoxy EASTERN EUROPE; HUNGARY
nanocomposites is not superior to that of the pure epoxy Accession no.882565
at low temperature, however the char yield of modified
epoxy nanocomposites is higher that that of the pure
epoxy at 800 deg.C in air atmosphere. The modified Item 166
epoxy nanocomposites possess better thermal stability at Polimery
high temperature range. The values of the limiting oxygen 48, No.2, 2003, p.85-90
index of pure epoxy and modified epoxy nanocomposites Polish
are 24 and 32, respectively. This indicates that modified POLYMER NANOCOMPOSITES.
epoxy nanocomposites possess better flame retardance. By II. NANOCOMPOSITES BASED ON
the Kissinger’s method, the activation energies of termo- THERMOPLASTIC POLYMERS AND LAYERED
oxidative degradation for epoxy nanocomposites are less SILICATES
than that of thermo-oxidative degradation for pure epoxy Kacperski M
in first stage of thermo-oxidative degradation. However, Szczecin,Polytechnic
the activation energies of thermo-oxidative degradation A review is presented of the literature published in 2000
for epoxy nanocomposites are more than those of thermo- and 2001 of the methods of synthesis and properties
oxidative degradation for pure epoxy in the second stage of nanocomposites containing layered silicates and
of thermo-oxidative degradation. 29 refs. thermoplastic polymers such as polyamides, polyolefins
TAIWAN (PP, PE), PS and styrene copolymers, PETP and PMMA.
Accession no.882703 Preparation methods such as mixing of the components
in the melt or swelling of montmorillonite(MMT) in the
monomers (substrates in the case of PETP) are discussed,
as well as methods of MMT modification. Particular
Item 165
Polymers for Advanced Technologies
attention is paid to the advantageous properties of
nanocomposites such as flexural strength, stress at break,
13, No.10-12, Oct.-Dec.2002, p.1103-11
flexural modulus, impact strength and heat resistance.
FLAME-RETARDED POLYOLEFIN SYSTEMS
OF CONTROLLED INTERPHASE
47 refs.
Narosi G; Anna P; Marton A; Bertalan G; Bota A;
EASTERN EUROPE; POLAND
Toth A; Mohai M; Racz I
Budapest,University of Technology & Economics; Accession no.882164
Hungarian Academy of Sciences; Zoltan Bay Applied
Research Foundation Item 167
The principle of multiplayer interphases has previously Shawbury, Rapra Technology Ltd., 2003, pp. xii, 558,
been proposed for modifying the mechanical properties 25cm, 627
and UV stability of various multi-component polymer HANDBOOK OF POLYMER BLENDS AND
systems. Emphasis is placed on the applicability COMPOSITES, VOLUME 1
of this principle for improving the performance of Petru Poni,Institute of Macromolecular Chemistry;
intumescent flame retardant systems using melamine- Indian Petrochemical Corp.Ltd.
treated ammonium polyphosphate, silicone-modified Edited by: Vasile C; Kulshreshtha A K
polyol + ammonium polyphosphate, and silicone modified This handbook is the first part of a four volume publication
nanoparticles in PP. The structure-property relationship of ‘Handbook of Polymer Blends and Composites’ which
the formed systems is studied. A melamine layer of 1.45 gives an overview of the theory and application of polymer
mm thickness is formed around ammonium polyphosphate blends and composites. It comprises of a collection of
in order in order to improve the hygrothermal stability, monographs written by professionals from academia
but this layer is not shear resistant enough. An interphase and industry. This volume is concerned with composite
formed using a special silicone additive is more stable development, characteristics of particulate fillers,
and acts with the intumescent flame retardant system fibre reinforcements and interface, main procedures of
synergistically. The advantageous interfacial structure is composites manufacture and their applications. Chapters
quite complex in this case: polyphosphate particles are cover the following topics: the history of composites;
surrounded with a macromolecular layer formed from particulate fillers and fibre reinforcements; composites
polyol, silicone and reactive surfactant in order to ensure in Asia; composites technology in Korea; advances in
good stability, efficiency and compatibility. AFM, XPS and wood-based composites in China; an overview of the
cone calorimetry are used for determining the structure use of composites Worldwide; the interface in polymer
and flame retardancy of these systems. Nanocomposites composites; novel multifunctional epoxy resins; flame
combined with silicone-containing intumescent system retardant polyesters; cure kinetics of vinyl ester resins;
are developed in order to avoid dipping at ignition in the curing monitoring; curing and bonding of composites
thereof. Tests showed that flame retardant modifiers III, Accession no.872695
IV or blend thereof provided the composites with a self-
extinguishing capacity, adhesion, high dielectric indices,
and crack resistance. Best ratios are suggested. 2 refs.
(Article translated from Plasticheskie Massy, No.2, 2002,
reference to the example of the cab for the UGN Mercedes nanofillers and traditional FR additives on the basis of
multi-purpose 4 wheel drive vehicle. The different stages metal hydroxides are also studied. 15 refs.
of manufacture are described: RTM moulding under BELGIUM; EUROPEAN COMMUNITY; EUROPEAN UNION;
vacuum, trimming, attachment of inserts by bonding and WESTERN EUROPE
riveting, and assembly of composite cab components by Accession no.852891
bonding. This is followed by a discussion of the different
improvements that in the short and medium terms will
Item 189
bring gains in both productivity and reduction of material
Chemistry of Materials
costs.
14, No.1, Jan.2002, p.189-93
EUROPEAN COMMUNITY; EUROPEAN UNION; FRANCE; UK;
WESTERN EUROPE
FIRE RETARDANT HALOGEN-ANTIMONY-
CLAY SYNERGISM IN POLYPROPYLENE
Accession no.853961 LAYERED SILICATE NANOCOMPOSITES
Zanetti M; Camino G; Canavese D; Morgan A B;
Item 187 Lamelas F J; Wilkie C A
Journal of Polymer Science: Polymer Chemistry Torino,Universita; US,National Institute of Standards &
Edition Technology; Marquette,University
The flammability of nanocomposites of PP-graft-maleic
40, No.10, 15th May 2002, p.1498-503
anhydride with organically modified clays was studied with
SILICON-METHOXIDE-MODIFIED CLAYS AND
THEIR POLYSTYRENE NANOCOMPOSITES
and without the presence of both decabromodiphenyl oxide
and antimony trioxide fire retardants. The combustion
Zhu J; Start P; Mauritz K A; Wilkie C A
Marquette,University; Southern Mississippi,University
behaviour was evaluated using oxygen consumption
Clays, organically modified by reaction with ammonium cone calorimetry. Synergy was observed between the
salts containing a silicon methoxide linkage, were nanocomposite and the fire retardants, which did not occur
dispersed with AIBN in styrene and heated to 60 when antimony oxide and the brominated fire retardant
C to obtain polystyrene-clay nanocomposites. The were added to the virgin polymer. 28 refs.
nanocomposites were characterised by X-ray diffraction, EUROPEAN COMMUNITY; EUROPEAN UNION; ITALY; USA;
and transmission electron and atomic force microscopies. WESTERN EUROPE
Thermal stability and flame retardance were determined Accession no.848147
by thermogravimetric analysis and cone calorimetry. It
is proposed that the linkage which occurred between the
Item 190
silicon and the clay did not occur in the nanocomposite
Polymer Preprints. Volume 42. Number 2. Fall 2001.
as the distance between the reactive sites was increased
Proceedings of a conference held Chicago, Il., 26th-30th
by the polystyrene. 18 refs.
August 2002.
USA
Washington, D.C., ACS,Div.of Polymer Chemistry,
Accession no.853231 2001, p.48-9
POSS NANOSTRUCTURED CHEMICALS: TRUE
Item 188 MULTIFUNCTIONAL POLYMER ADDITIVES
Fire and Materials Schwab J J; Reinerth W A; Lichtenhan J D; An Y-Z;
25, No.5, Sept./Oct.2001, p.193-7 Phillips S H; Lee A
FLAME RETARDANT PROPERTIES OF EVA- Hybrid Plastics; US,Edwards Air Force Base;
NANOCOMPOSITES AND IMPROVEMENTS Michigan,State University
BY COMBINATION OF NANOFILLERS WITH (ACS,Div.of Polymer Chemistry)
ALUMINIUM TRIHYDRATE Continuing demand for advancements in the performance
Beyer G of polymeric materials has driven the search for new
Kabelwerk Eupen AG additive technologies to upgrade the properties of existing
Flame retardant nanocomposites are synthesised by plastics. One of the primary goals has been to reinforce
melt-blending EVA with modified layered silicates polymeric chains and segments at the molecular level
(montmorillonites). Thermogravimetric analysis performed in much the same way that traditional fillers reinforce
under different atmospheres (nitrogen and air) demonstrates plastics on the macroscopic level. This would prevent
a clear increase in the thermal stability of the layered polymers and their corresponding composites from being
silicate-based nanocomposites. Use of cone calorimetry subject to thermal limitations imposed by coil-coil and
to investigate the fire properties of the materials indicates segment-segment interactions. Significant opportunity
that the nanocomposites cause a large decrease in heat exists for new additive technologies that are compatible
release. Char formation is the main factor important with existing polymer/filler systems yet provide unique
for improvement and its function is outlined. Further value that is not attained from conventional technological
improvements in flame retardancy by combinations of approaches. Nanostructured Chemicals represent a merger
between chemical and filler technologies acting as true silicate based on montmorillonite modified with dimethyl-
multifunctional polymer additives. The chemical diversity distearylammonium cations). The effect of incorporating a
of POSS Nanostructured Chemicals is vast and parallels flame retardant (aluminium trihydrate) on the flammability
that of traditional organic systems, yet incorporates it onto of cable sheaths made from EVA nanocomposites is also
a robust and precisely defined inorganic (silicon-oxygen) demonstrated. Investigative techniques employed included
nanostructure. POSS Molecular Silicas can be utilised in TEM, X-ray diffraction, TGA and flammability testing in
the same manner as traditional polymer additives in both a cone calorimeter. 15 refs.
melt and solution compounding. Molecular Silicas are BELGIUM; EUROPEAN COMMUNITY; EUROPEAN UNION;
capable of alloying polymer chains at the molecular level UK; WESTERN EUROPE
to improve the physical properties of virtually all plastics. Accession no.845175
Loading levels for Molecular Silicas can be varied in
accordance to the degree and level of enhancement desired.
Item 193
POSS Nanostructured Chemicals have the unique ability to
Polymer Degradation and Stability
act as multifunctional polymer additives by simultaneously
75, No.2, 2002, p.397-402
acting as molecular level reinforcements, processing aids
FLAMMABILITY OF POLYAMIDE-6/CLAY
and flame retardants. 3 refs.
HYBRID NANOCOMPOSITE TEXTILES
USA
Bourbigot S; Devaux E; Flambard X
Accession no.847964 Gemtex; Ecole Nationale Superieure des Arts & Ind.
Text.
Item 191 Flammability of polyamide-6/clay nanocomposites as
European Plastics News textile fabrics was studied. The samples were prepared
29, No.3, March 2002, p.14 by melt blending and shown to have an exfoliated
SMALLER IS BETTER structure. These were processed into multifilament yarns
Sall K by melt spinning. The textiles were evaluated as knitted
The automotive industry is driving the commercialisation fabrics and showed promise as relatively low cost flame
of nanocomposite grades. Last year, General Motors retarding materials with long term laundry resistance. Cone
announced that it had worked with Basell and Southern calorimetry showed a heat release with the textile of 40
Clay to successfully commercialise an advanced percent less than that for pure PA-6. 10 refs.
thermoplastic olefin nanocomposite which is now used EUROPEAN COMMUNITY; EUROPEAN UNION; FRANCE;
to make the step assist for two of its vans. Ford’s target WESTERN EUROPE
Item 195 cyclic impact strength tests. Results indicated that in the
London, Interscience Communications Ltd., 2002, region of average values of stresses of the cycle of 10-90
pp.xii,273, 24cm, 012 Mpa, a thermal fluctuation mechanism of failure of the
FLAME RETARDANTS 2002. Proceedings composite is realised. With an increase in the stresses, there
of a conference held London, 5th-6th is a transition in the mechanism of failure from thermal
Feb. 2002 fluctuation to athermal. 4 refs. (Article translated from
APME; European Flame Retardant Assn.; Fire Plasticheskie Massy, No.1, 2001, pp.15-16).
Retardant Chemicals Assn. RUSSIA
(BPF; Interscience Communications Ltd.) Accession no.836561
Twenty-seven papers are presented following the tenth
conference in the ‘Flame Retardant’ series. The conference Item 198
concentrates on the practical appliactions of flame International Polymer Science and Technology
retardants and polymers, exchanging ideas on what is 28, No.10, 2001, p.T/1-5
needed and what is possible and practicable in the control NANOCOMPOSITES. 2. A NEW FLAME
of fire in polymeric materials. PROTECTION SYSTEM FOR POLYMERS
EUROPEAN COMMUNITY; EUROPEAN UNION; UK; WESTERN Beyer G
EUROPE
Kabelwerk Eupen AG
Accession no.841688
Disadvantages are discussed of traditional methods of
achieving flame retardancy in polymers, and advantages
Item 196 provided by the use of nanocomposites are examined.
Speciality Chemicals Details are given of the thermal improvements and
21, No.9, Nov.2001, p.24-5 flame retardant properties of nanocomposites, and their
TECHNOLOGIES GROW FLAME RETARDANTS ability to provide improved thermal stability and flame
MARKET protection with relatively small amounts of nanofillers.
Rosen M R These improvements are attributed to the formation of a
Interactive Consulting Inc. thermally insulating char which is poorly permeable to
A significant reduction in the risk of fire-related deaths decomposition products on exposure to high temperatures
and injuries is expected from the development of new or flames. Cone calorimetry is used to measure these
performance standards for upholstered furniture. The US effects. 14 refs. (Article translated from Gummi Fasern
Consumer Product Safety Commission has been conducting Kunststoffe, No.5, 2001, p.321)
extractability and migration studies in order to evaluate EUROPEAN COMMUNITY; EUROPEAN UNION; GERMANY;
potential health risks from flame retardant fabric treatments.
WESTERN EUROPE
Item 203
Item 201
Polymer
Plastiques Flash
42, No.18, 2001, p.7739-47
No.316, Feb./March 2001, p.49
MECHANICAL CHARACTERIZATION AND
French
MORPHOLOGY OF CARBOXYL RANDOMIZED
WHAT ARE NANOCOMPOSITES?
POLY(2-ETHYL HEXYL ACRYLATE) LIQUID
An examination is made of the properties, processing and RUBBER TOUGHENED EPOXY RESINS
applications of nanocomposites in which submicron silicate Ratna D; Simon G P
particles are dispersed in a polymer matrix. Developments India,Naval Materials Research Laboratory;
by a number of companies in polyamide, polyolefin and Monash,University
polyacetal matrix nanocomposites are reviewed, and
reference is made to the imminent appearance of the first
Carboxyl randomised poly(2-ethylhexyl acrylate) liquid
rubbers (2-ethylhexyl acrylate-acrylic acid copolymers)
nanocomposites based on PETP. Trends in the world
market for such materials are also briefly considered.
with different carboxyl functionality were synthesised by
solution polymerisation. These were used as toughening
TOYOTA; UBE; ALLIEDSIGNAL; GENERAL agents for an epoxy resin. The effects of the functionality
ELECTRIC; HONEYWELL INC.; BAYER AG; of the liquid rubbers and the ductility of the epoxy matrix
BASELL; MONTELL; GENERAL MOTORS CORP.; on the mechanical properties of the modified networks
SHOWA DENKO was studied. The results were discussed with reference
to the morphology of the modified network. There was
EUROPEAN COMMUNITY; EUROPEAN UNION; GERMANY;
JAPAN; USA; WESTERN EUROPE; WORLD
an optimum functionality which gave the best impact
Accession no.828693
performance. 50 refs.
AUSTRALIA; INDIA
Item 202 Accession no.822054
Composites Science and Technology
61, No.5, 2001, p.787-95
REVIEW OF DENDRITIC HYPERBRANCHED Item 204
POLYMER AS MODIFIERS IN EPOXY Materials Today
COMPOSITES 3, No.3, 2000, p.8
Mezzenga R; Boogh L; Manson J A E TOUGHENING AT NANOSCALE MAKES
Lausanne,Ecole Polytechnique Federale PLASTICS SUITABLE FOR AIRCRAFT USE
Dendritic hyperbranched polymers have been shown to We are told in this short article that researchers at Ohio
be able to double the interlaminar fracture resistance of State University have patented a method of mixing plastic
epoxy-based composites and reduce the internal stress with tiny silica particles, to create a material which is three
level by as much as 80%, with only 10 phr of modifier. to four times tougher than the plastic alone. Brief details
These property improvements were obtained affecting are provided of the properties of the new nanocomposite
the viscosity, and thus the processability, nor the glass material, which is suitable for use in aircraft.
transition temperature of the epoxy resin. Both fully soluble OHIO,STATE UNIVERSITY
product of emulsion polymerisation or obtained from during the combustion of polymers and methods to reduce
recycled products containing significant amounts of their flammability are briefly described. Combustion of
polyvinyl chloride. The additive can be used in an amount polymer materials is characterised by a complex coupling
of from 1 to 75% by weight, based on the amount of between condensed phase and gas phase phenomena.
inorganic filler present in the formulation. Characteristics of the critical role in each phase are
USA outlined. 46 refs.
Accession no.801264 RUSSIA; USA
Accession no.795748
Item 214
Plastics Additives and Compounding Item 216
2, No.5, May 2000, p.30-2 Cambridge, UK, Royal Society of Chemistry, 1998,
NANOCOMPOSITES - IT’S A QUESTION OF pp.xvii,466. 69.50. 8/2/99. 54F
PICKING THE WINNERS FIRE RETARDANCY OF POLYMERS: THE USE
Murphy J OF INTUMESCENCE
Ecole Nationale Superieure de Chimie de Lille;
Trends in the development of nanocomposites are
Torino,Universita; CREPIM
reviewed and discussed. Claims of improved mechanical
Edited by: Le Bras M; Camino G; Bourbigot S;
properties, stiffness, high barrier properties and inherent
flame retardancy are examined. Out of all the potential
Delobel R
prospects for nanocomposites, it is argued that only This book, based upon papers presented at the sixth
around five are practicable and perhaps only two will be European meeting on fire retardancy of polymeric
fully commercialised. Recent developments have seen materials, provides a comprehensive overview of the
the commercialisation of a nylon film with high barrier subject. Main headings include strategies, intumescence
properties from nanoparticles, and a nylon moulding - mechanism studies, new intumescent polymeric
compound with optimised mechanical properties. materials, flame retardant intumescent textiles and
GM is reported to have been working with Montell finally, an examination of whether intumescence is an
on a thermoplastic olefin elastomer with 5% smectite environmentally friendly process.
clay which gives stiffness equivalent to a 23-35% talc Accession no.793775
reinforcement. Research is reported into methods for the
incorporation of ultra-fine fillers, the production of nano-
sized carbon and fullerene tubes, and the use of conductive Item 217
reinforcements in automotive bodywork panels which can Fire and Materials
be electrostatically painted. 24, No.4, July/Aug.2000, p.201-8
PA-6 CLAY NANOCOMPOSITE HYBRID AS
Accession no.798275 CHAR FORMING AGENT INTUMESCENT
FORMULATIONS
Item 215 Bourbigot S; Le Bras M; Dabrowski F; Gilman J W;
Fire Retardancy of Polymers. Kashiwagi T
Cambridge, UK, Royal Society of Chemistry, 1998, 54F, ENSAIT; Ecole Nationale Superieure de Chimie de
p.175-202 Lille; US,National Institute of Standards & Technology
New flame retardant (FR) intumescent formulations for
POLYMER COMBUSTION AND NEW FLAME
RETARDANTS
EVA using charring polymers polyamide 6 (PA-6) and
Kashiwagi T; Gilman J W; Nyden M R; Lomakin S M
polyamide-6 clay nanocomposite hybrid (PA-6 nano)
US,National Institute of Standards & Technology;
as carbonisation agents are reported. Use of PA-6 nano
Russian Academy of Sciences
improves both mechanical and fire properties of FR
Edited by: Le Bras M; Camino G; Bourbigot S;
EVA-based materials. The part played by the clay in the
Delobel R
improvement of the FR performance is studied using FTIR
(Ecole Nationale Superieure de Chimie de Lille;
and solid state NMR. It is shown that the clay allows the
Torino,Universita; CREPIM)
thermal stabilisation of a phosphorocarbonaceous structure
The majority of polymer-containing end products in the intumescent char which increases the efficiency of
(e.g. cables, carpets, furniture) must pass some type of the shield and, in addition, the formation of a ‘ceramic’
regulatory fire test to help assure public safety. Thus, it which can act as a protective barrier. 44 refs.
is important to understand how polymers burn and how EUROPEAN COMMUNITY; EUROPEAN UNION; FRANCE;
to best modify materials to make them less flammable USA; WESTERN EUROPE
in order to pass such tests without compromising their Accession no.790159
uniquely valuable physical properties and also significantly
increasing the cost of end products. Chemical and physical
processes occurring in the gas and condensed phases
composition comprising a thermosetting resin (I) and a data shows that the peak heat release rate is reduced by
hardener (II) having the following components III and IV 63% in a nylon-6 clay-nanocomposite containing a clay
incorporated therein. The semiconductor device is thus mass fraction of only 5%. In addition, physical properties
provided with a high heat resistance at infrared reflow are not degraded by the clay additive, but moreover, greatly
step and a high flame retardance, showing a drastically improved. Furthermore, the nanocomposite structure is
enhanced reliability. (III) a metal hydroxide of formula (1): claimed to appear to enhance the performance of the char
n(MaOb).cH2O (1), where M is a metallic element; a, b through reinforcement of the char layer. 18 refs.
and c each = a positive number; and n is a positive number USA
of 1 or more, with the proviso that when MaOb is repeated, Accession no.693137
the plurality of M’s may be the same or different and that
a and b may be the same or different; and (IV) a metal
Item 237
oxide of formula (2): n’(QdQe) (2), where Q is a metallic
Antec ‘98. Volume II. Conference proceedings.
element belonging to the group selected from Groups IVa,
Atlanta, Ga., 26th-30th April 1998, p.2316-20. 012
Va, VIa, VIIa, VIII, Ib and IIb in the Periodic Table; d and
ASPECTS OF THE TENSILE RESPONSE OF
e each represents a positive number; and n’ = a positive
RANDOM CONTINUOUS GLASS/EPOXY
number of 1 or more, with the proviso that when QdQe is
COMPOSITES
repeated, the plurality of Q’s may be the same or different
Okoli O I; Smith G F
and that d and e may be the same or different.
Warwick,University
JAPAN
(SPE)
Accession no.695736
The impact properties of a material represent its capacity
to absorb and dissipate energies under impact shock
Item 235 loading. If a material is strain rate sensitive, its static
Composites Plastiques Renforces Fibres de Verre mechanical properties cannot be used in designing
Textile against impact failure. In addition, the failure modes in
No.21, May/June 1997, p.82-4 dynamic conditions can be quite different from those
RESIN TRANSFER MOULDING OF FIRE- observed in static tests. The effect of strain rate on failure
RETARDED COMPOSITES FOR RAILWAY mechanisms is investigated by viewing fractured surfaces
APPLICATIONS of tensile specimens using scanning electron microscopy.
Woodward M G; Brown N The relationship between the energy dissipated and fibre
Ashland Composite Polymers Ltd.; Martinswerk GmbH content is also evaluated. Tensile tests are conducted on
Formulations for the resin transfer moulding of glass fibre- a random continuous glass/epoxy laminate at increasing
reinforced composite components for railway rolling stock rates of strain. A second laminate (with random continuous
are described. These consist of Modar 835 S modified glass reinforcement) is tested in tension at varying fibre
acrylic resin (Ashland), Martinal ON-904 aluminium volume fractions in order to ascertain the relationship
hydroxide flame retardant (Martinswerk), BYK-W 996 between fibre content and energy dissipated. 8 refs.
wetting and dispersing agent (BYK-Chemie), and random EUROPEAN COMMUNITY; EUROPEAN UNION; UK; WESTERN
glass mat. The flammability characteristics and mechanical EUROPE
FATIGUE OF HYBRID EPOXY COMPOSITES: model for future deck replacement projects. The contract
EPOXIES CONTAINING RUBBER AND is to develop and install six experimental fibre-reinforced
HOLLOW GLASS SPHERES composite deck panels in the lift span of the bridge, which
Azimi H R; Pearson R A; Hertzberg R W will then be subjected to rigorous testing to ensure it will
Lehigh,University perform as predicted with a 25 year service life.
A diglycidyl ether of bisphenol A epoxy resin was modified CALTRANS
USA
by incorporation of varying concentrations of hollow glass
spheres (HGS) and/or reactive liquid rubber. The fatigue Accession no.607094
crack propagation (FCP) behaviour and mechanisms
of such materials were studied in detail. A synergistic Item 256
phenomenon reported for static fracture toughness was Reactive and Functional Polymers
also observed in the FCP resistance of such composites. 30, Nos.1-3, June 1996, p.85-91
Optical microscopy studies revealed that the interactions PREPARATION OF POLYIMIDE-EPOXY
between the stress fields of the crack-tip process zone and COMPOSITES
HGS cause plastic-zone branching, which in turn gave rise Gaw K; Kikei M; Kakimoto M; Imai Y
to synergistic toughening. It is also shown that process Tokyo,Institute of Technology
zone second phase particle interactions cause a transition
in FCP behaviour of rubber-modified epoxy polymers, Epoxy resin was cured with polyamic acid (from
similar to that observed in metal alloys. Consequently, pyromellitic dianhydride and 4,4’-oxydianiline) instead
the process zone toughening mechanisms are active only of traditional amino-group-containing hardening agents.
above a certain stress intensity range. Conversely, FCP The cure behaviour and potential reaction mechanisms of
resistance of both modified and unmodified epoxies were Epon 828/polyamic acid mixtures were evaluated by DSC
the same below the transition. 48 refs. and TGA. Thermal analysis showed a complex reaction
USA
sequence taking place in the mixture and also determined
the extent of reaction of the polyamic acid with itself and
Accession no.615671 the competitive reaction of the polyamic acid with the
epoxy. The compositions of the mixtures were varied to
Item 254 see all the dependence of the cure behaviour on component
Patent Number: EP 742266 A2 19961113 concentrations. Solutions of the two components did not
EPOXY RESIN COMPOSITIONS FOR FIBRE- phase separate and also phase separation was not apparent
REINFORCED COMPOSITE MATERIALS, either optically or microscopically in the cured samples.
PREPREGS AND FIBRE-REINFORCED This phase behaviour was attributed to a unique in situ
COMPOSITE MATERIALS reaction. A novel solvent system for the polyamic acid
Oosedo H; Noda S precursor was also used. The thermal stability of the epoxy
Toray Industries Inc. cured with polyamic acid was superior to that of epoxy
cured with standard diamines, but inferior to that of the
These compositions comprise at least the constituents
polyimide. 3 refs.
(A) an epoxy resin comprising 70 pbw or more, per 100
JAPAN
pbw of the epoxy resin, of a bifunctional epoxy resin, (B)
fine particles comprising a rubber phase and substantially Accession no.599707
insoluble in epoxy resins and (C) a curing agent.
Composites made therefrom have high impact resistance Item 257
and heat resistance. Composites Part A: Applied Science and
JAPAN Manufacturing
Accession no.610227 27A, No.6, 1996, p.447-58
TENSILE FAILURE OF 3D WOVEN
COMPOSITES
Item 255
Cox B N; Dadkhah M S; Morris W L
Composites and Adhesives Newsletter
Rockwell Science Center
13, No.1, Oct-Dec.1996, p.5
RFQ/RFP ISSUED FOR CALTRANS COMPOSITE Tensile tests are reported for some graphite-epoxy
BRIDGE DECK PROGRAM; MODIFICATIONS composites with three-dimensional woven interlock
DELAY PROPOSALS - NOW DUE OCT.10 reinforcement. Rough estimates are made of various
contributions to the work of fracture. 27 refs.
Details are given of the Caltrans composite deck
USA
programme in which a failing steel open-grated deck on
the Schuyler-Heim Bridge will be replaced with composite Accession no.590659
materials. This programme is important for the composites
industry, since Caltrans intends to use the project as a
Low velocity impact tests were carried out on T300/976 Accession no.541551
graphite/epoxy composites with and without FM300
thermoset interleaves, on T800/3900-2 graphite/epoxy Item 262
composite with thermoplastic interface coatings, and Composites
on graphite/PEEK thermoplastic matrix composites. 26, No.2, 1995, p.115-24
Numerical calculations were also done. The results showed CHARACTERISATION OF INTERLAMINAR
that interface toughening can improve significantly the FRACTURE BEHAVIOUR OF WOVEN FABRIC
impact resistance of laminated composites to low velocity REINFORCED POLYMERIC COMPOSITES
impact. 7 refs. Youjiang Wang; Dongming Zhao
USA Georgia,Institute of Technology
Accession no.543693 An experimental study was conducted to characterise
the interlaminar fracture behaviour of two-dimensional
Item 260 woven fabric reinforced epoxy composites under mode
Journal of Composites Technology and Research I loading using double cantilever beam tests. A large
17, No.1, Jan.1995, p.11-6 displacement, small strain non-linear beam model was
EFFECT OF TEMPERATURE AND MOISTURE used to calculate the interlaminar fracture toughness.
ON THE IMPACT BEHAVIOUR OF GRAPHITE/ The fabrics used included glass fibre and Kevlar woven
EPOXY COMPOSITES. II. IMPACT DAMAGE structures with different weave patterns. An attempt was
Karasek M L; Strait L H; Amateau M F; Runt J P made to enhance the composite interlaminar toughness
Pennsylvania,State University by adding different types of microfibres into the matrix.
Toughening mechanisms of the composites were analysed
Following the study in part I (ibid, p.3-10) in which dropped
using SEM. It was found that the weave patterns of fabrics
weight impact testing was used to evaluate the effect of
exhibited a strong influence on the interlaminar fracture
temp. and moisture (sea water) on the impact resistance
behaviour, and that the addition of the microfibres to the
epoxy matrix could improve the interlaminar fracture properties of an epoxy resin. Morphological properties
toughness significantly. 11 refs. were also determined. 14 refs.
USA EUROPEAN COMMUNITY; EUROPEAN UNION; FRANCE;
WESTERN EUROPE
Accession no.539409
Accession no.519872
Item 263
Composites Science and Technology Item 266
52, No.3, 1994, p.439-48 Journal of Applied Polymer Science
MODE II DELAMINATION TOUGHNESS OF 52, No.12, 20th June 1994, p.1775-83
CARBON FIBRE/EPOXY COMPOSITES WITH RUBBER- AND THERMOPLASTIC-
CHOPPED KEVLAR FIBRE REINFORCEMENT TOUGHENED EPOXY ADHESIVE FILM
Sohn M-S; Hu X-Z Romano A M; Garbassi F; Braglia R
Western Australia,University Istituto Guido Donegani SpA; EniChem
Chopped Kevlar fibres were spread between continuous Epoxy resins were toughened using two components, a liquid
fibre layers of a carbon fibre-reinforced epoxy resin to rubber (Hycar CTBN 1300x13, a butadiene-acrylonitrile
determine how the mode II delamination toughness is carboxyl-terminated rubber) and a thermoplastic polymer
affected by the Kevlar fibres lying within the fracture (Phenoxy PKHH, a polyhydroxyether). Unsupported
plane. 28 refs. adhesive films were obtained from the blends. The effect of
AUSTRALIA different curing cycles on morphology, fracture behaviour
and adhesive strength was studied and phase separation
Accession no.537543
was monitored by dynamic mechanical analysis. The
combination of the two moieties was shown to be a very
Item 264 efficient toughening agent when a slow curing cycle was
Polymer adopted. 23 refs.
35, No.22, 1994, p.4743-9 UNION CARBIDE CORP.; GOODRICH B.F.,CO.
TOUGHENING BEHAVIOUR OF RUBBER- EUROPEAN COMMUNITY; ITALY; USA; WESTERN EUROPE
MODIFIED THERMOPLASTIC POLYMERS Accession no.515906
INVOLVING VERY SMALL RUBBER
PARTICLES. I. A CRITERION FOR INTERNAL
RUBBER CAVITATION Item 267
Dompas D; Groeninckx G Composites
Leuven,Catholic University 25, No.4, April 1994, p.251-62
INFLUENCE OF WEAVE STRUCTURE ON PIN-
The criteria for internal cavitation of rubber particles were LOADED STRENGTH OF ORTHOGONAL 3D
evaluated. It was shown that internal rubber cavitation COMPOSITES
could be considered as an energy balance between the Chen J C; Lu C K; Chiu C H; Chin H
strain energy relieved by cavitation and the surface energy Feng Chia,University; Chung-Shan,Institute of Science
associated with the generation of a new surface. The model & Technology
predicted that there existed a critical particle size for
cavitation. Very small particles (100-200 nm) were not able Orthogonal three-dimensional(3D) carbon fibre fabrics
to cavitate. This critical particle size concept explained with different weave structures were obtained by varying
the decrease in toughening efficiency in different rubber- the yarn spacing and number of carbon filaments per tow
modified systems involving very small particles. 35 refs. in the x-, y- and z-directions during weaving. These weave
BELGIUM; EUROPEAN COMMUNITY; EUROPEAN UNION; structures were impregnated with epoxy resin to produce
WESTERN EUROPE orthogonal 3D carbon/epoxy composites. In addition,
Accession no.533326 one-dimensional (0 and 90 degree unidirectional) and
two-dimensional (cross-ply and plain fabric) laminates
were prepared from the same carbon fibres and epoxy
Item 265 resin. Single-hole pin-loaded specimens of each material
Polymer Bulletin were tested in tension and the effects of reinforcement
33, No.1, June 1994, p.67-74 type, weave structure, specimen width-to-hole diameter
TOUGHENING OF EPOXY NETWORKS USING ratio and edge distance-to-hole diameter ratio evaluated.
PRE-FORMED CORE-SHELL PARTICLES OR Various modes of failure were observed in the specimens.
REACTIVE RUBBERS The effect of in-plane and out-of-plane fibres on the pin-
Maazouz A; Sautereau H; Gerard J F loaded strength of orthogonal 3D composites is discussed.
CNRS 26 refs.
The influence of liquid reactive rubbers or core-shell TAIWAN
particles were studied on the thermal and mechanical Accession no.508830
Item 292
Item 289 42nd Annual Conference & Expo ‘87;Proceedings.
Composites Science and Technology Cincinnati,Ohio,2-6 Feb.1987,Session 20-B,pp.6. 627
34,No.3,1989,p.267-83 EFFECTS OF A CONTROLLED MODULUS
FAILURE MECHANISMS IN GLASSY-METAL- INTERLAYER UPON THE PROPERTIES OF
REINFORCED EPOXY COMPOSITES GRAPHITE/EPOXY COMPOSITES
Low I M;Hewitt G;Mai Y W;Foley C Chang J;Bell J P;Joseph R
AUCKLAND,UNIVERSITY; CSIRO,DIV.OF CONNECTICUT,UNIVERSITY
APPLIED PHYSICS; SYDNEY,UNIVERSITY (SPI,Reinforced Plastics/Composites Institute)
Epoxy composites containing both rubbery particles and The results are reported of a study of the effect of a high
short or continuous glassy metal ribbons were investigated. molec.wt. polymeric interlayer between the graphite
Considerable improvement in the fracture toughness fibres and epoxy matrix of a graphite-epoxy composite
was obtained, particularly in composites containing on composite mechanical properties. Thickness, modulus
aligned short ribbons. As the volume fraction of the of the interlayer and bonding between the interlayer and
ribbon was increased, so was the fracture toughness. The epoxy matrix were the three major parameters examined. A
micromechanisms of toughening and failure processes uniform thickness acrylonitrile/methyl acrylate copolymer
were also identified and discussed in the light of the coating, applied onto the graphite fibre surface through
microstructures. 23 refs. a batch electro-copolymerisation technique, was used
AUSTRALIA; NEW ZEALAND as the interlayer. Interlaminar shear strength and impact
Accession no.378252 resistance data of the composites are tabulated. 19 refs.
USA
thermosetting polymers was investigated. Asbestos fibres RESIN ON CARBON FIBRE BY IN SITU
were pretreated with polyhexamethylene adipamide and POLYMERISATION
used afterwards as filler reinforcement in a bisphenol- Kodama M;Karino I;Kobayashi J
A-based epoxy resin matrix. Two alternative processes MITSUBISHI ELECTRIC CORP.
of fibre pretreatment were used. Thermal expansion Carbon fibre was coated with polyimide resin in an attempt
coefficients and Tgs for the asbestos-nylon-epoxy resin to improve the reinforcement/matrix interaction and the
composites were experimentally determined. Results were properties of epoxy composites reinforced with the coated
qualitatively explained by theoretical models in which the fibres investigated. Comparisons with untreated carbon
concept of the boundary interphase was considered. The fibre composites were made. Properties investigated
effects of asbestos and nylon content as well as of type included dynamic viscoelastic properties, tensile properties
of pretreatment and adhesion between the phases were and T-peel strength. Fourier-transform IR spectroscopy
investigated. 32 refs. was employed to investigate the molecular interaction
GREECE between the epoxy resin and polyimide resin. 16 refs.
Accession no.356410 JAPAN
Accession no.336353
Item 294
Plastics and Rubber International Item 297
13,No.2,April 1988,p.26/31 SAMPE Journal
NEW MATRIX RESINS FOR STRUCTURAL 22,No.6,Nov/Dec.1986,p.10-6
COMPOSITES STATIC AND IMPACT PERFORMANCE OF
Pritchard G POLYETHYLENE FIBRE/GRAPHITE FIBRE
HYBRID COMPOSITES
This detailed article discusses new matrix resins used in
Adams D F;Zimmerman R S
structural composites. It describes the different structures
of fibre reinforcement, the process of mixing these fibres,
WYOMING,UNIVERSITY
and discusses the development of polyesters, vinyl esters A study was carried out to determine the benefits of using
and epoxy composites. Data and properties are presented Spectra 900, high strength, high modulus PE fibres in
for the matrix resins. 7 refs. graphite/epoxy composites to improve impact resistance of
UK the resulting hybrid. The feasibility of using a small amount
Accession no.355519 of graphite fibre in a Spectra laminate to enhance stiffness
properties while maintaining high impact performance was
also evaluated. Data are provided on drop weight impact,
Item 295 tensile properties, compression properties, in-plane shear
Plastics Technology properties and thermal expansion of the various material
34,No.1,Jan.1988,p.13 combinations. 8 refs.
TERPOLYMER TOUGHENS EPOXIES USA
Subject Index
COATED FABRIC, 172 147 148 150 156 157 158 160 CURING RATE, 154 159
COATED FIBRE, 275 285 163 169 170 172 182 184 188 CURING REACTION, 256
COATED FILLER, 207 276 189 192 193 198 199 200 211 CURING TEMPERATURE, 107
COATING, 15 42 45 60 62 71 82 235 236 159
186 259 292 295 296 CONTACT ANGLE, 114 CYANATE, 8
COBALT OXIDE, 234 CONTACT FORCE, 177 CYANATE ESTER RESIN, 47
COEXTRUSION, 62 CONTINUOUS FIBRE, 280 289 CYCLE TIME, 62 186 277
COEXTRUSION BLOW COOLING RATE, 55 CYCLIC LOADING, 197 205 253
MOULDING, 191 COPPER OXIDE, 234
COKING, 200 CORE-SHELL, 145 278
COLD RESISTANCE, 173 CORROSION RESISTANCE, 32 D
COLOUR, 22 185 COTTON, 172 DAMPING, 16 81
COLOUR CONCENTRATE, 111 COUPLING AGENT, 57 60 73 84 DEBONDING, 35 285
COLOUR DEVELOPING, 42 97 162 171 178 223 247 276 DECABROMODIPHENYL
COLOUR STABILITY, 185 298 300 ETHER, 49
COMBUSTIBILITY, 1 45 76 189 CRACK DENSITY, 145 169 DECABROMODIPHENYL
COMBUSTION, 7 36 44 63 76 94 CRACK GROWTH, 226 OXIDE, 110 175 189
97 108 121 126 140 158 161 CRACK INITIATION, 226 DECOMPOSITION, 1 3 4 30 38
163 171 182 185 189 255 CRACK LENGTH, 226 248 275 45 54 68 128 130 175 180 198
COMBUSTION PRODUCT, 185 CRACK PROPAGATION, 197 218 201 235
235 226 253 276 DECOMPOSITION PRODUCT,
COMMERCIAL INFORMATION, CRACK RESISTANCE, 226 1 36
100 102 111 149 176 196 CRACK TIP, 253 DECOMPOSITION RATE, 1
COMPATIBILISATION, 62 120 CRACKING, 86 145 204 221 262 DECOMPOSITION
201 CRAZE RESISTANCE, 35 TEMPERATURE, 1 54 77 185
COMPATIBILISER, 6 29 34 35 61 CRAZING, 35 DEFORMATION, 20 268 272 273
77 90 120 196 CREEP, 300 276 286 298 299
COMPATIBILITY, 35 42 201 219 CRITICAL STRESS INTENSITY DEFORMATION
COMPOSITION, 1 54 80 81 91 93 FACTOR, 271 TEMPERATURE, 55 102 130
94 95 96 112 122 130 152 159 CROSS-BREAKING STRENGTH, 146
178 187 206 222 224 228 245 107 DEGRADATION, 4 11 15 18 54 62
254 CROSS-PLY, 267 84 87 101 110 122 146 160 164
COMPOUNDING, 42 46 79 93 111 CROSSLINK DENSITY, 5 75 143 169 175 188 221
132 175 201 CROSSLINKED COPOLYMER, DEGRADATION PRODUCT, 1
COMPRESSION MODULUS, 276 11 18 96
286 CROSSLINKED POLYMER, 5 DEGRADATION RATE, 1
COMPRESSION MOLDING, 7 28 CROSSLINKING, 5 27 37 122 130 DEGRADATION RESISTANCE, 4
COMPRESSION MOULDING, 7 175 212 216 235 284 302 11 54 194
28 CROSSLINKING PHENOMENA, DEGRADATION
COMPRESSION PROPERTIES, 5 TEMPERATURE, 1 4 11 26 54
70 177 208 239 268 281 297 CRYSTAL STRUCTURE, 20 67 92 110 122
COMPRESSION STRENGTH, 268 CRYSTALLINITY, 20 22 35 54 DEGREE OF CONVERSION, 107
COMPRESSION STRESS, 268 238 DEGREE OF CROSSLINKING, 5
COMPUTER SIMULATION, 215 CRYSTALLISATION, 20 28 54 DEGREE OF DISPERSION, 11 20
CONCENTRATION 55 80 34 47 51 53 54 59 126 156
DEPENDENCE, 54 CRYSTALLISATION RATE, 20 DEGREE OF POLYMERISATION,
CONCRETE, 232 CRYSTALLIZABILITY, 20 107
CONDENSATION POLYMER, CURE RATE, 154 159 DEGREE OF SWELLING, 75
146 CURE TEMPERATURE, 8 142 203 DEHYDRATION, 185
CONDENSED PHASE, 108 215 CURE TIME, 235 266 DELAMINATION, 30 42 66 77
CONDUCTIVE FILLER, 214 CURING, 4 8 26 27 39 78 83 107 118 153 237 239 258 259 263
CONDUCTIVE POLYMER, 111 115 130 154 155 159 167 168 290 291
162 214 180 203 220 235 241 266 301 DELAMINATION RESISTANCE,
CONE CALORIMETER, 6 9 12 302 18
13 17 18 29 38 40 44 45 49 52 CURING AGENT, 8 18 39 75 81 DENDRIMER, 202
53 63 65 67 68 71 72 73 76 85 94 107 112 130 142 154 168 DENTAL APPLICATION, 22
88 89 90 92 94 98 103 104 109 180 203 220 230 234 235 243 DERIVATIVE
110 113 118 119 122 138 140 245 254 272 276 287 THERMOGRAVIMETRY, 3
FLUORESCENCE SPECTRA, 74 GAS PERMEABILITY, 133 207 113 117 119 122 134 135 138
FLUOROMICA, 77 GAS PHASE THERMOLYSIS, 12 143 147 156 164 184 187 221
FLUOROPOLYMER, 62 63 111 GAS-PHASE, 108 185 210 215 235 GROWTH RATE, 128 162
175 207 GASES, 108 235
FOAM, 69 100 106 146 185 210 GASIFICATION, 96 217 227
240 269 277 GEARS, 111 H
FOAMING AGENT, 100 GEL CHROMATOGRAPHY, 170 HACKLEMARK, 258
FOOD PACKAGING, 22 62 219 220 HALIDE, 27
FORMULATION, 27 71 93 105 GEL PERMEATION HALLOYSITE, 59
149 210 213 CHROMATOGRAPHY, 170 HALOGEN, 30 110 128 175 185
FOURIER TRANSFORM 220 301 195
INFRARED SPECTROSCOPY, GEL TIME, 154 168 235 HALOGEN COMPOUND, 25 49
3 8 14 18 24 31 48 58 75 114 GELATION, 26 106 161 241
117 126 138 147 151 155 217 GELLING, 26 274 HALOGEN-FREE, 18 26 62 73 89
227 296 301 GELLING AGENT, 142 110 116 129 179 185 194 198
FRACTOGRAPHY, 86 270 GELS, 215 235 240
FRACTURE, 5 20 124 144 153 205 GLASS, 149 HARDENER, 39 180 203 234 243
226 257 258 262 263 265 266 GLASS BEAD, 271 272 273 276 245
268 270 272 273 276 282 283 286 298 300 HARDNESS, 23 80 287
285 286 289 298 299 301 302 GLASS CONTENT, 235 277 HAZE, 64 246
FRACTURE ENERGY, 271 272 GLASS FABRIC, 249 HEALTH HAZARDS, 46 69 128
276 298 GLASS FIBRE, 62 69 74 233 132 134 161 163 175 179 185
FRACTURE MECHANICS, 276 GLASS FIBRE-REINFORCED 196 216 235
FRACTURE MORPHOLOGY, 5 9 PLASTICS, 62 66 70 74 86 87 HEAT ABSORPTION, 128 235
11 14 17 20 29 31 34 40 41 44 100 114 115 125 129 131 141 HEAT AGEING, 277
47 51 52 54 55 59 64 67 75 76 142 148 160 178 185 186 207 HEAT CURING, 295
77 78 79 80 85 89 91 94 95 96 225 232 233 235 237 243 249 HEAT DEFLECTION
102 117 119 121 122 124 126 250 252 262 277 280 287 303 TEMPERATURE, 21 219 244
130 138 142 151 154 163 168 GLASS MAT, 235 277 246
182 192 239 GLASS ROVING, 125 HEAT DEGRADATION, 1 4 18
FRACTURE PROCESS GLASS SPHERE, 253 44 54 55 59 64 66 67 77 92 117
ANALYSIS, 20 GLASS TRANSITION 121 122 151 156 160 161 164
FRACTURE RESISTANCE, 226 TEMPERATURE, 4 5 8 12 16 170 184 193 198 211 216 217
FRACTURE SURFACE, 5 39 40 31 52 56 66 67 75 81 107 115 221 252
78 141 145 249 258 271 273 130 155 193 203 211 228 229 HEAT DISTORTION, 55 102 130
276 235 261 265 274 278 282 284 146 196
FRACTURE TOUGHNESS, 5 8 13 293 HEAT DISTORTION
20 86 145 226 248 259 262 273 GLYCIDOXY ALKYL TEMPERATURE, 55 102 130
282 285 289 ALKOXYSILANE, 57 155 146 196 227
FRAGMENTATION, 205 GLYCIDOXYPROPYLTRIMETH HEAT FLOW, 30 227
FRICTIONAL PROPERTIES, 257 OXYSILANE, 57 155 HEAT FLUX, 18 148 198
FRIEDEL-CRAFTS REACTION, GOLD OXIDE, 234 HEAT INSULATION, 32 185 198
212 GRAFT COPOLYMER, 6 20 34 236
FUEL TANK, 21 191 122 151 189 HEAT OF COMBUSTION, 236
FULLERENE, 214 247 GRAFT POLYMERISATION, 151 HEAT RELEASE, 1 67 109 110
FUNCTIONAL GROUP, 53 145 GRANULATION, 269 137 148 156 169 174 184 188
203 GRAPHITE, 128 226 193 215 216 227
FUNCTIONALISATION, 47 154 GRAPHITE FIBRE, 275 291 HEAT RELEASE RATE, 1 7 9 12
159 168 GRAPHITE FIBRE- 17 18 19 30 36 38 43 45 49 50
FUNCTIONALITY, 159 203 220 REINFORCED PLASTIC, 226 51 53 63 65 67 68 69 73 76 88
254 242 252 257 258 259 260 261 89 90 92 94 104 120 140 156
FURNITURE, 46 132 185 275 290 292 297 303 157 158 189 236 246 247
GRAPHITE OXIDE, 140 HEAT STABILITY, 1 3 4 44 59 121
GRAVIMETRIC ANALYSIS, 2 3 8 137 162 171 180 187 192 224
G 9 13 15 16 18 24 26 28 29 31 34 HEAT TRANSFER, 215 216
GAS BARRIER, 26 246 38 40 41 44 45 48 50 51 52 53 HEAT-RESISTANT, 1
GAS CHROMATOGRAPHY, 161 56 58 63 64 65 68 75 77 79 85 HELIUM, 175
GAS EMISSION, 235 88 92 94 95 96 97 103 109 110 HEMP, 100
POLYIMIDE, 4 256 296 POLYPHOSPHINE OXIDE, 274 PREPREG, 218 221 222 254 277
POLYISOCYANURATE, 75 POLYPHOSPHONATE, 240 281
POLYLACTONE, 238 POLYPROPENE, 3 14 19 22 25 30 PRESSURE, 100
POLYLAUROLACTAM, 224 34 35 37 42 45 49 51 59 62 72 PRETREATMENT, 17 293
POLYLAURYLLACTAM, 224 90 91 93 100 102 106 120 135 PRINTED CIRCUIT, 129
POLYMERIC COMPATIBILISER, 138 149 150 162 166 175 185 PRINTED CIRCUIT BOARD, 246
120 189 190 191 207 210 214 219 PRINTED WIRING BOARD, 129
POLYMERIC CURING AGENT, 227 228 231 244 246 PROCESSABILITY, 22 73 110 198
81 256 POLYPROPYLENE, 3 14 19 22 25 PROCESSING, 17 18 21 22 37 62
POLYMERIC FLAME 30 34 35 37 42 45 49 51 59 62 63 82 146 149 172 184 201 210
RETARDANT, 67 213 217 240 72 90 91 93 100 102 106 120 239 243 294
POLYMERIC IMPACT 135 138 149 150 162 166 175 PROCESSING AID, 162 190
MODIFIER, 145 253 275 289 185 189 190 191 207 210 214 PROCESSING CONDITIONS, 6
295 219 227 228 231 244 246 20 122
POLYMERIC MODIFIER, 17 76 POLYSILICONE, 41 57 110 118 PRODUCT DEVELOPMENT, 82
77 107 215 227 102 176 191 194 196 246
POLYMERIC PRECURSOR, 256 POLYSILOXANE, 41 57 110 118 PRODUCTION, 21 62
POLYMERIC PROPERTY 165 215 227 PRODUCTION CAPACITY, 246
MODIFIER, 266 275 276 POLYSILSESQUIOXANE, 45 PRODUCTION COST, 42 186
POLYMERIC SHRINK POLYSTYRENE, 19 30 43 46 49 PROPENE, 210
RESISTANCE AGENT, 277 61 62 72 79 95 100 103 104 106 PROPENE COPOLYMER, 6 34 51
POLYMERIC TOUGHENING 110 128 132 161 162 166 170 122 189
AGENT, 34 125 238 256 274 185 187 212 219 227 244 278 PROPENE POLYMER, 14 59 90
POLYMERISATION, 4 21 62 92 POLYSULFONE, 13 68 107 301 91 93 100 102 106 120 138 228
94 100 103 110 118 133 146 POLYUREA, 71 PROPERTY MODIFIER, 275 276
147 155 175 182 187 213 219 POLYURETHANE, 9 37 62 63 65 PROPYLENE, 210
220 227 230 275 75 85 106 123 162 172 185 186 PROPYLENE COPOLYMER, 6 34
POLYMERISATION INITIATOR, 210 219 240 241 269 277 51 122 189
278 POLYURETHANE-ACRYLATE, PROPYLENE POLYMER, 14 59
POLYMERISATION 235 90 91 93 100 102 106 120 138
MECHANISM, 151 221 POLYURETHANE- 228
POLYMERISATION RATE, 278 METHACRYLATE, 235 PROPYLENE-ETHYLENE
POLYMERISATION POLYVINYL ALCOHOL, 163 285 COPOLYMER, 35 54
TEMPERATURE, 278 POLYVINYL CHLORIDE, 9 37 PROTECTIVE COATING, 45
POLYMETHACRYLAMIDE, 69 62 63 69 117 128 162 175 185 PROTON MAGNETIC
POLYMETHACRYLATE, 227 194 213 RESONANCE, 24
POLYMETHYL POLYVINYL ESTER, 62 70 113 PROTOTYPE, 255
METHACRYLATE, 12 19 35 167 294 PULTRUSION, 66 252
61 95 96 100 104 110 118 166 POLYVINYL HALIDE, 9 69 117 PULVERISATION, 129
215 219 278 POLYVINYLBENZENE, 30 43 46 PUNCTURE RESISTANCE, 100
POLYOL, 75 210 235 61 95 100 103 104 106 110 128 PURIFICATION, 78
POLYOLEFIN, 19 22 34 42 49 51 132 187 244 PYROLYSIS, 13 18 30 68 128 163
62 73 100 102 136 146 165 166 POLYVINYLIDENE FLUORIDE, 221
176 179 191 195 201 210 246 62 PYROLYSIS MASS
POLYOLEFIN ELASTOMER, 120 POROSITY, 222 SPECTROMETRY, 227
POLYORGANOSILOXANE, 41 57 POST CURING, 221
110 118 215 227 POWDER, 100 148 213 Q
POLYOXYDIPHENYLENE POWDER COATING, 186
PYROMELLITIMIDE, 256 PPE, 100 QUALITY CONTROL, 62
POLYOXYETHYLENE, 227 PPO, 62 68 100 QUARTZ, 197
POLYOXYETHYLENE GROUP, PRE-TREATMENT, 17 QUATERNARY AMMONIUM
152 PRECISION, 62 COMPOUND, 9 30
POLYPHENYLENE ETHER, 62 PREFORM, 225 277 QUATERNARY AMMONIUM
68 100 PREFORMING, 145 SALT, 42 119
POLYPHENYLENE OXIDE, 62 PREHEATING, 191
68 100 PREPARATION, 92 126 130
POLYPHENYLSILSESQUIOXA PREPOLYMER, 131 286
R
NE, 31 PREPOLYMERISATION, 230 R-CURVE, 226
SMOKE, 46 128 132 148 175 179 100 142 149 152 183 191 196 114 144 151 155
185 216 235 201 214 219 232 276 297 303 SURFACE REACTION, 5
SMOKE EMISSION, 36 63 69 185 STIFFNESS MODULUS, 232 SURFACE STRUCTURE, 47
235 STORAGE CONTAINER, 32 SURFACE TENSION, 247
SMOKE GENERATION, 52 53 73 STORAGE MODULUS, 4 5 17 31 SURFACE TREATMENT, 5 21 42
236 241 76 130 224 271 47 74 91 102 114 172 178 207
SMOKE SUPPRESSANT, 128 185 STRAIN, 205 262 268 244 276 296 300
235 STRAIN ENERGY, 264 275 SURFACTANT, 51 52 62 90 91
SMOKE SUPPRESSION, 118 STRAIN ENERGY RELEASE 100 102 152
SMOKE TOXICITY, 69 RATE, 275 SWELLING, 16 75 166 214 278
SNOWBOARD, 21 STRAIN RATE, 237 SWELLING AGENT, 214
SODIUM MONTMORILLONITE, STRENGTH, 32 37 75 142 146 176 SWELLING INDEX, 23
36 152 175 197 207 219 232 267 288 303 SYNTHESIS, 4 8 9 24 27 38 48 53
SOFTENING TEMPERATURE, 66 STRESS CONCENTRATION, 268 58 60 63 75 80 110 118 133 140
SOL-GEL, 82 155 STRESS INTENSITY FACTOR, 166 173 182 194 200
SOL-GEL FORMATION, 155 276 286 298 SYNTHETIC FIBRE-
SOL-GEL POLYMERISATION, STRESS TRANSFER, 205 REINFORCED PLASTIC, 87
155 STRESS WHITENING, 20 231 248 250 263 285 297
SOL-GEL REACTION, 57 58 155 STRESS-STRAIN PROPERTIES, SYNTHETIC RUBBER, 102 107
SOLDER RESISTANCE, 129 5 8 152 197 223 257 268 133
SOLUTION POLYMERISATION, STRESSES, 202 268 299
220 STRUCTURAL ANALYSIS, 75
SOLVENT, 16 75 110 175 182 STRUCTURE-PROPERTY T
SOLVENT ACTIVITY, 118 RELATIONSHIP, 20 TACKINESS, 222
SOLVENT EVAPORATION, 79 STYRENE, 103 TACTOID, 152
SOLVENT RESISTANCE, 22 STYRENE COPOLYMER, 49 60 TALC, 42 46 62 100 132
SONICATION, 143 106 119 140 166 275 TALLOW AMINE, 156
SOYBEAN OIL, 75 142 STYRENE POLYMER, 30 43 46 TANTALUM OXIDE, 234
SPECIFIC GRAVITY, 14 23 62 176 61 95 100 103 104 106 110 128 TECHNETIUM OXIDE, 234
SPECIFIC HEAT, 66 132 187 244 278 TELECOMMUNICATION
SPECTROSCOPY, 3 8 12 14 18 STYRENE-ACRYLONITRILE APPLICATION, 179
24 31 40 48 58 60 62 75 91 114 COPOLYMER, 61 TELEVISION, 185
117 135 138 165 216 227 302 STYRENE-BUTADIENE TEMPERATURE, 21 22 62 81 100
SPIN-SPIN RELAXATION, 7 RUBBER, 23 171 203 204 235 260 261 276
SPINNING, 193 231 STYRENE-ETHYLENE TEMPERATURE DEPENDENCE,
SPORTS APPLICATION, 21 BUTYLENE-STYRENE 4 66 67 107 159
SPORTS EQUIPMENT, 21 102 BLOCK COPOLYMER, 20 TEMPERATURE MODULATED
SPORTS GOODS, 21 102 STYRENE- DIFFERENTIAL SCANNING
SPRAY DRYING, 52 ETHYLENEBUTYLENE- CALORIMETRY, 13
SPRAYING, 131 214 STYRENE BLOCK TENSILE MODULUS, 56 84 152
STABILISERS, 117 162 171 COPOLYMER, 20 235
STABILITY, 1 2 4 8 9 11 17 22 26 SULFONE COPOLYMER, 274 TENSILE PROPERTIES, 4 5 8 10
28 29 30 31 34 38 45 47 51 54 SULFONE POLYMER, 13 68 107 16 22 23 28 33 34 39 40 41 55
55 56 59 63 65 67 75 76 88 92 SULFUR, 30 56 67 70 73 75 78 80 84 85 97
95 96 104 107 109 110 111 118 SUPERCRITICAL FLUID, 191 120 130 133 146 148 152 159
122 127 130 133 146 147 152 SURFACE ACTIVE AGENT, 51 52 203 208 223 225 235 237 246
156 160 164 171 175 182 184 62 90 91 100 102 152 235 249 251 257 267 296 297
185 187 188 193 196 198 210 SURFACE ANALYSIS, 114 TENSILE STRENGTH, 5 10 22 23
211 216 219 221 224 227 229 SURFACE AREA, 73 75 78 80 120 130 203 223 225
236 SURFACE ATTACHMENT, 47 235
STACKING SEQUENCE, 258 SURFACE CHEMISTRY, 47 TERNARY BLEND, 11 20
STANDARD, 69 128 137 235 241 SURFACE ENERGY, 264 TERNARY SYSTEM, 11
STARVE FEEDING, 278 SURFACE FINISH, 42 201 277 TERPOLYMER, 62
STATIC DISSIPATION, 100 SURFACE MODIFICATION, 5 21 TEST EQUIPMENT, 110 134 235
STATIC ELECTRICITY, 136 47 74 91 244 300 280
STATISTICS, 100 128 136 162 169 SURFACE MORPHOLOGY, 155 TEST METHOD, 9 17 26 27 35 38
195 201 219 SURFACE PREPARATION, 5 74 42 57 58 62 75 76 84 95 96 110
STIFFNESS, 21 35 39 42 47 62 66 SURFACE PROPERTIES, 42 47 128 134 149 175 197 198 200
204 210 221 232 250 THERMO-OXIDATIVE 145 151 152 156 170 187 189
TEST SPECIMEN, 268 DEGRADATION, 101 110 155 192 227 229 236 237 278
TESTING, 9 17 26 27 35 38 42 57 164 TRANSPARENCY, 183 201 219
58 62 75 76 84 95 96 110 128 THERMOGRAM, 80 244
134 149 175 197 198 200 204 THERMOGRAVIMETRIC TRANSPORT PROPERTIES, 77
210 221 232 235 250 255 258 ANALYSIS, 2 3 8 9 13 15 16 18 TRICHLOROMETHYLOLIMIDE,
259 277 278 280 283 286 292 24 26 28 29 31 34 38 40 41 44 27
296 297 300 301 302 45 48 50 51 52 53 56 58 60 63 TRIETHYLENE TETRAMINE,
TETRAETHOXYSILANE, 58 64 65 68 75 77 79 85 88 92 94 39 203
TETRAMETHYLOL 95 96 97 103 109 110 113 117 TRIGLYCIDYL AMINOPHENOL,
CYCLOHEXANOL, 287 119 122 134 135 138 143 147 154
TEXTILE, 193 216 240 151 156 164 172 184 187 192 TRIMETHOXYSILANE, 155
THERMAL AGEING, 221 193 221 227 229 256 TRIPHENYL PHOSPHATE, 171
THERMAL ANALYSIS, 13 16 24 THERMOLYSIS, 12 TRIPHENYLPHOSPHINE, 161
48 60 75 80 83 92 151 158 160 THERMOMECHANICAL 203
164 165 170 188 211 217 235 PROPERTIES, 31 TRISDIMETHYLAMINO
THERMAL CONDUCTIVITY, 66 THERMOOXIDATIVE METHYLPHENOL, 203 230
100 138 DEGRADATION, 101 110 155 TUBING, 22
THERMAL CYCLING, 145 164 TUNGSTEN OXIDE, 234
THERMAL DECOMPOSITION, 1 THERMOOXIDATIVE TWIN-SCREW EXTRUDER, 6 7
4 38 45 54 68 128 130 180 201 STABILITY, 1 2 9 65 34 152 190 201
278 THERMOPLASTIC
THERMAL DEGRADATION, 1 4 ELASTOMER, 65 102 185 214
18 44 54 55 59 64 66 67 77 92 215 U
101 110 117 121 122 151 155 THERMOPLASTIC RUBBER, 65 ULTRA HIGH MOLECULAR
156 160 161 164 170 184 193 102 185 214 215 WEIGHT POLYETHYLENE,
198 211 216 217 221 252 277 TISSUE, 22 111
278 TITANIUM OXIDE, 234 ULTRASONIC TEST, 260
THERMAL EXPANSION, 22 62 TOLUENE, 175 ULTRAVIOLET IRRADIATION,
293 297 TORQUE, 93 122
THERMAL FLUCTUATION, 197 TORSION, 298 ULTRAVIOLET LIGHT, 122
THERMAL INSULATION, 32 185 TORSION PENDULUM, 52 UNDER THE BONNET
198 236 TORSIONAL PENDULUM, 52 APPLICATION, 136 219
THERMAL PROPERTIES, 1 4 5 TORSIONAL VIBRATION, 26 UNSATURATED POLYESTER,
8 14 18 19 23 26 29 31 34 41 TOUGHENED, 20 47 203 53 56 69 92 98 185 207 213 241
42 45 48 49 50 51 52 53 55 56 TOUGHENING AGENT, 8 20 28 277 280 294
57 58 59 64 65 66 67 73 77 80 34 35 47 57 125 130 141 145 UPHOLSTERY, 196
83 88 100 108 115 120 126 130 154 168 203 208 220 230 238 URETHANE POLYMER, 9 85 106
138 140 143 148 154 155 156 253 256 259 262 264 266 271 123
160 165 168 175 181 182 187 272 282 UV DEGRADATION, 122
188 221 228 230 235 236 244 TOUGHNESS, 8 20 21 35 47 52 57 UV RADIATION, 122
265 293 301 71 86 159 202 203 204 208 223 UV RESISTANCE, 179
THERMAL RESISTANCE, 1 2 4 235 265 266 270 273 274 275 UV STABILITY, 22 122
11 54 59 67 100 187 204 224 276 279 281 282 283 286 291
228 295 298
THERMAL STABILITY, 1 2 4 8 9 TOXICITY, 46 69 128 132 134 161 V
11 17 22 26 28 29 30 31 34 38 163 175 179 185 196 216 235 VANADIUM OXIDE, 234
45 47 51 54 55 56 59 63 65 67 255 VAPOUR, 21
75 76 88 92 95 96 104 107 109 TRANSFER MOULDING, 186 VAPOUR PHASE, 108 185 210
110 111 118 122 127 129 130 218 225 215
133 146 147 152 156 160 164 TRANSITION PHENOMENA, 224 VAPOUR PRESSURE
166 171 175 182 184 185 187 TRANSMISSION ELECTRON OSMOMETRY, 203
188 193 198 201 210 211 216 MICROSCOPY, 6 12 15 16 17 VARNISH, 240
219 221 224 227 229 234 236 24 28 29 31 35 38 39 40 41 43 VEHICLE CAB, 186
245 246 254 256 277 44 48 51 52 55 56 60 61 73 77 VEHICLE DOOR, 277
THERMAL TRANSITION, 8 221 78 79 86 87 89 90 94 95 96 97 VEHICLE EXTERIOR, 42 136 201
THERMALLY STIMULATED 98 103 113 114 117 122 126 127 VEHICLE INTERIOR, 62
CREEP, 300 130 134 138 140 141 142 144 VEHICLE SEAT, 235
Company Index
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