Seema He SeaeURG TOM AL Prater AEF toya Nepal Engineering Questions Banik-2074 . Tae MID-WESTERN UNIVERSITY FACULTY OF ENGINEERING Examination Control Division 2072 Chaitra Full Marks [Pass Marks 1 Time Subject: Engineering Chemistry (SH108) Attempt all questions adidates are required to answer the questions in their Glin wordses Ageume suitable Values with stipulation if necessary Figures in margin indicate full marks State the postulates of Bohr's theory. Mention itS:success and fim Bett Define electrode potential and standard electrode, potential? St reduction electrode potential of Zn and GU Sre ©0.74v and +034v (113) respectively. Write the cell reaction and cellnotaton Whatis catalyst? How do the catalysts aifectthe rete n? Give examples (3) Why is ozone layer regarded as bof on the earth? Give its photechemisty. (1=4) Define organic polymer? Explain preparaton and uses of nylon-5,6 and teflon. (4+ Define transition met Why “do transition metats form colourtul 42344) compounds? Write tijeweasag ofmagnetism. ve What is hybridization ® Explain the formation of [Ni(NH.),P ion on the BESIS 944 of valence bond,theory and predict its geometry and magnetic dehawiour t What are explosives? Givé'the preparation and uses of tinirotolusn= GND. «3 What are paints2VWiite their functions. (#4) What is optically active compound? Explain the geometrical ISOMSTST 54 4) with suitable.examples. sh Define .elimination reaction? Discuss the E' and & mechanism with ae factors.goveming them.228 S700) 2-882] UM ‘EW SBEIBNE ey) 51 JOWEM IySseoONS OU, os igsuayooese}s ayy Buymoys apyjeulAye Ul WS|UeYdeW Uonoee! UoJen;Sqns Sepnl JJenszjowig 84) Ssndsiq {uORea! 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Candidates are require to answer the questions in theifawn words as far as p ossible GICs app Assume suitable values, with stipulation if necessary. ——— 9 Figures in margin indicate full marks. ts'0f Bohr's explanation. Derive an ar 9) Explain the formation of H-Spectrum in re equation for the radius of Bohr's third orbit for H-atom. Calculate the energy of afta) the electron moving in the orbit. (h=6.62x10 % JS, m=9.1x1 g, e= 1.610" 4 ey C, ,=8.85x1077kg! M? A?) : b) What do you mean by electrode potential and standard electrode potential? Briefly — explain the cell notation and cell reaction for Zn-Cu cell 5 es, } a) What’ do you mean byqcatalyst What are its characterisics and industrial ame rat zpplications? 5 ame b) What do you mean by-azoneplayer? State your understanding in ozone layer a1 depletion and itsjil effects 3 " ©) What do mean by air pollition? List out some of its remedies. 2 eer 4 2) Difierentate between. thermoplastic and thermosetting plastics with suitable AELCOLRe ‘examples. 2 WASP) *) Whratdoyoumeanty a polymer? Mention its types based on carbon-carbon linkage, 5 IA, He Explain the preparaton and use of PVC. : ©) Why,dostfansition elements form significant number of complexes? Explain with reader ufpy Te" compounds are colored while those of Ti#* are colorless? 5 1D), Eialamiybridization of HO ‘and CH, molecules and explain the cause of variation ““iivtbdnd angle in these molecules. 5 URearanad What are explosives? Give the preparation and uses of TNT: 243 rere sd at il} What do you mean by paints? Describe ail of its types. {and geometrical isomers. Discuss on unimolecar 3H © @) Differentials between optical Mere eriettution reaction mechanism in alkylhalides snows 6 nucleophilic re ey Uneorsamisty ec daeemeatncies on anand )) Azimuthal quantum numbers = 1) Effects of ozone layer depletion. fer Te, coro ae Uf © Scars arc tha rand io titre ore almost exacly ha same. « Cain Davisseateany HOM, A fazatearct Ty Accs Subject: Chemistry ntion its types and ext plain the wor a) What |s buffer solution? Met acidic buffer. b) What is catalyst? Explain the theories of catalysis 9. a) Whatis ozone layer? Menton its photochemistry. ib) Whatis polymer? Explain the polymers; polyphosp| transition metals? What is the cause fo of transition metals. formation of [Cu(N! predict ts geometry and magnetic behavior. 4. a. )\Whatare explosives? Give the preparation and uses of tino )) What are paints? Mention thelr 2P| ications. b. What are enantiomers? Mention the properties 5, a. What is substitution reaction? Discuss tl substitution reaction mechanism [Ps stereochemistry b. Write short note on: i) Standard hydrogen electrode ii) Valence bond theory 4 2 hazine and nylon -6, 6 variable valency? Mention ti} a = See es ze=e H,),J?" fon on the bast b) Explain the lycerine (TNG). a oesdaesa el SSeS 2073 Chaitra Pupject: Engineering Chemistry (SH 302) 1. (a) e anic cell formed by the tion What is galvanic celi?=Gonstruct a galv combination of zinc electrode & copper electrode. Write the cell reac! Z0.34V & E p..4an= 0.76 V) and cell notation (E csrscu (b) Define catalyst? Mention the types of catalyst and their characteristics. = 2. (a) Whatis ozonélayer? Give its photochemistry. (b) Whatis inorganic polymer? Mention the preparation and applicati polystyrene and teflon. 3. (a) = Whalyere transition metals? Why Zn is ni fare Wa ‘ot considered as typical ” tran: f metal? Mention the electronic configuration of Cr and Cu 4 (=e the formation of [Cu(NH,),F* ion on the basi of valence bond % theory and predict its geometry and magnetic behaviour. 4. (a) Whatare explosives? Give the preparation and uses of trinitrotol (TNT). What are paints? Write their functions. ion of uene (b) (c) Oefine enantiomers. ‘Meso com| i a eee at pounds and race! both are optically inactive’, give reason behind it . ee and SN’ 5. (a) What is nucleophilic substitution reactior t le yn? Compare SN' reaction conditions in alkyl halide showing the stereochemistry. Explain the terms; buffer solution and SiliconeNeeting Ques, “ . Si aes te stare wo aL. areTToTe ABI !aya Nepal Engineering Questions Bank-2074 me we st, (6 ©) -and nylon-¢ 5 able valenga ey Ei of Vi @ f valence, bondte: A he troglycerine (TN) (b) molecular nunce yihalide shows; \ (a) 1 (b) i) (a) (b) Subject: Engineering Chemistry Fefine buffer solution? Mention its types. Explain the working mechanism for acidic buffer. : Calculate the p" of a buffer solution when 200m! of 0.1 M acetic acid mixed with 400m! of 0.2M sodium acetate solution. (p'*=4.74) Define negative catalyst? Mention the characteristic of catalyst. What is soil pullution? Write its effects and possible remedies. What is polymer? Mention its types based on carbon-carbot Mention the preparation and use of bakelite. eam What are transition metals? Why do they have variabl@tyalliency? Also discuss about the agnetic’ property of the compounds of'the'transition metals yD Wrtite the postulates of Werner's theory. Explain the formation of {Cu(NH3)6]2+ ion on the basis of valuence bond theory and predict its geometry and magnetic behavior. & * Define explosives and mention their types== What are lubricants? Mention the functions offiubricants: What are optically active compounds? Define and explain enantiomers. ic. substitution "action? Discuss the unimolecular nucleophilic substitution reaction Mechanism in alkylhafide showing the stereochemistry. Rw Explain the térms; electrode potential and valence bond theory. Best of Luck (1#1+2) 2 (22) (144) (14443) (14142) (2+4) (1+) (1+2) (1+4) (14) (2.5+2.5) Farafery STECFET an aa WITT: OF I-NWGY ALaL CayToolor oY Horpretanl Etcct ferert FOTN SeTTST ouret fare Ae a1.0. faxarearer, SPomMeray AOA TEHTAT Tat STITT BR AOTC Per iu Geto! ca Heo UTey SSN CHAT SEL TE Tee WB VA ates eH MUTA aoet gree feax arg atwenr Hayul reretiewant yor heres Becta erate Test |