Very Short Answer Type Questions [1 Mark]

1 Which of the following isomers is more volatile 5 How will you convert
O-nitrophenol or p-nitrophenol? All India 2014 ) propene to propan-1-o1?
Refer to solution 7 on ) ethanal to propan-2-o/?
page 416
2 Of the two
hydroxy organic
the first one is basic and compounds ROH and R'OH,
Refer to solution 3 on page 417. Dehi 2h
other is acidic in 6 Give mechanism of
How is A different from R? behaviour preparation of
ethoxy
noxy ethans.
ethane ton
Delhi 2013C ethanol.
Refer to solution 3 on
3 How is toluene
page 415. Refer to solution 3 on page 436. Delhi 2013
obtained from phenol? Delhi 2013C
Refer to solution 4 on
7 Explain the following behaviours.
page 415. () Alcohols are more soluble in
4 0-nitrophenol has water than
lower boiling point than hydrocarbons of comparable molecular
Explain. p-nitrophenol. (i) ortho-nitrophenol is more acidic than
maeeSSes
Refer to Delhi 2013 C
solution 7 on page 416.
phenol. ortho-meh,
5 Write the Refer to solution 5 All India 2012
equation involved in the reaction Williamson's on
page 378.
ether synthesis. 8 Explain the mechanism of acid
All India 2013
Refer to text on page 430. catalysed hydration t
alkene to form corresponding alcohol.
6 Write the All India 201
equations involved in the following reaction. Refer to text on page 406.
Reimer-Tiemann reaction
Refer to text on page 414..
All India 2012 Short Answer Type ll
7 Draw the structural 1
Questions [3 Mark
formula of ()Write the mechanism of the following reaction.
molecule 2-methylpropan-2-ol
Delhi 20112
Refer to text on page 405. CHCHOH HBr CH,CH.Br+ H0
(i) Write the equation involved in
Short Answer TypelQuestions [2 Marks] reaction. Reimer-Tieman All India 2014
Refer to text on
1 Write the page 414.
equations involved in the following reactions. 2 Draw the structure and
) Reimer-Tiemann reaction name the product formed i te
(i) Williamson synthesis. following alcohols are oxidised. Assume that an exte
Delhi 2014 of oxidising agent is used
Refer to text on page 414 and 430.
) CHCHCH,CH,OH
2 Write the mechanism of
the following reaction. () 2-butanol
Delhi 2014 (in) 2-methyl-1-propanol
CH,CH,OHHB
CH,CH,Br+ HO Refer to text on page 412.
Refer to solution 2 Delhi 2012
on page 417. 3 State the
3 products of the following reactions
Explain the mechanism of the
following reaction. 0 CHCHCH,OCH, + HBr-
CH-CH2-OH CH2=CH+ HO ) (CH3),C-OCH
HI

Refer to text on page 411 and 412. All India 2013

OC2Hs
+ HBr
4 How will you convert the Foreign2012
following? Ethoxy benzene
) Propan-2-ol to propanone Refer to text on page 431
(i) Phenol to 2, 4, 6-tribromophenol? Delhi 2013
Refer to solution 8 on page 418.