METU-NCC CHM 107 GENERAL CHEMISTRY SECOND MIDTERM EXAMINATION November 29, 2014 Name, Surname: Time given : 120 mins Signature Section + Student ID: Key Constaits and equations: Na= 6.022x10" units/mole; R= 0.0821(L.atm)/(K.mol) or ‘8.314 J/(K.mol); h=6.626 x 105.83 Ru=2.179 x 1085 ; 00 < 108m/s 5 Ena Av = he/ds 2 an’ Me (mass ofcecron= 9-11X10"' kg; hV=hvy+im,9? 5 (ps2 (V-nb)=nRT sy] 377 3 |e | x 10831 | wou | sab07 a] a | os |e 2ase2 | sone | sors ZLB] RS ea] By ee ae pe m | Vv | c | im | re | co | wm | cy | mm | a | ce | ae 47a6r | 20.942 | 51996 | sasas | 55845 | 50.000 | seo | oxsue| s.r | 72s | ras | rage a z | me | om | te | ru fom | ro | om | cs | om | oo | so 5.1 | aze2 | v0.00 | 01726] casos | osu | (68) | s01.07 | soz.9s | soeso | sorer| steer | rs4a| users! rose r2r00| rasan | ast 3 ee wpe pa |e | we | | we] ey we] a] ae | ae | ey os] & | be tw | ote | w | me | oe | ie | me | a | me | om | om | ot | om | om | oa saat | sar0 sao seo | 19386 | rear | 10025 | 10222 | 10500 so5:7 | 20080 | zov00| 2072 | aosea| caem | aio | cee a |e otf oaas | 0s | or | woe | oe | ve | ain | te | a} tie] tis] ie 1 Fe | Re ar | op | se | oy | He | ome | os | Ry | ue | Ua | We | dup | von Ue gay | go | casa | ee | aon | arm | cee | en | rm | cas) | eon | cans | cab | ast est STS], aoe, epee ee ey ey a a “anaes ce} & | ons | pm | sn | cv | ca | tm | by | ho | & | im | wm | swore | vaoor | s4aze | 1145) | 1501 | 53.96 | 15725 | ssa | 16250 | reaa0 | re726 | ree | 17904] sra07 ~ potides Fc m | pa |u| sp | pe | am | cm | a | cr | es | pm | us | te zzz0e| asi] ossos| aan | ee) | aay | gem | can | sn | asm | easy | sm | ase Take two digits after the decimal point when you use atomic mass from the periodic table. SHOW ALL YOUR WORK Good Luck ©1. (12 pts.) You want to store 165 g of CO gas in a 12.5-L tank at room temperature (25°C). Calculate the pressure the gas using: i a aN (@) the ideal gas law and QV eat => Pads) = Mma, = GU AYi-Ol Neo, = BAH ml (0, > [Rants 734 abe | (a) SK (b) the van der Waals equation. (For CO2, a= 3.59 atm L*/mol” and b = 0.0427 Limol.) E L cre — (Ras + SE) (venb) = RAT = hea ~ OEE _ ot ¢ a (v-ab) v= Pog = At _ (12.3395 ( tve2s) (c) At what conditions does the deviation from ideality becomes significant? CH Les hone x Woy Perramee Ca) 2. (12 pts.) (a) Calculate the density of NO> gas at 0.970 atm and 35°C. MMino. eo Gos\no \ HG33 — 003224 = ied An Mien, = (ueoyinat) Coardehny _ 4949 Le aT (ownee as) (3034) as @) (b) Calculate the molar mass of a gas if 2.50 g occupies 0.875 L at 685 torr and 35°C. wm - mae (Bata oct re (8) so gins (or) mo ob) Co 345" | +3 (c)What are the mole fractions of each component in a mixture of 5.08 g of O2, 7.17 gof Nz, and 1.32 g of Fa? av No. = Obsgrcl 4 MLN, = rss) 5 UH = OST mol Weg= Basho ba Arka A0}Qmol = mg = Loire) \Roz = ON] See Oe] Amn + C62 - son (d) What is the partial pressure in atm of | each of the components of above mixture at (c), if it is held in a 12.40-L vessel at 15°C? Ke MaKe => [POH = OARS ain | ce] te ce CG) * (Pa, 2 008 w Baba | i — ALS shy Wiig,3. (10 pts.) A 0.2500-g sample of an Al-Zn alloy reacts with HCI to form hydrogen gas: 2. Al(s) + 6 H"(aq) > 2 AP*(aq) + 3 Ha(g) Zn(s) +2 W'(aq) > Zn*'aq) + H(g) The hydrogen gas produced has a volume of 0.147 L at 25°C and 755 mm Hg. What is the percentage of zinc in the alloy? Nn i Led& May be # fo mr 4 Wy, prokaed =D Ry. Qisfoad LOA g coun aot flags= tx 7 (esos Bea Yoswel = 0.00714 mt Lee Wg be mans of AL in al i Ocos{} mol = |m, Amol au x Sorel by 1500 — 014 O00} wal WL [res 5 * Lateat * ae ] 30 a 2 he ‘ Amel WL QZ oN Wel Oe FD _009STF 20,055 Mar + (OAMO— Max). 0.0 153 0.1463 & » | Macs 0.05335 au] > [Mus OI gta] > Bias aim * Noo = FRY, 4. (0 pis.) (a) The monatomic ions A* and Bare froelectronic. If the atomic number of Ais. = 16, write the set of four x questa igs! for all the valence electrons of neutral B atom yA = ty 187 =) B rey 21 hochOrs Be Oe [Aectron : = = 1 aie | 4 5 ° MD ee 3 ‘ . Be e 4 e fo gyal. € 3. 3 z -2 xy a G pts.) (b) Arrange the following groups of atoms in order of increasing size. Explain your reason. —s, dewene i) Ba, Si, F FC 31 Cb 1 edad ii) St, 8, C2 Sader @ pis) (©) In each of the following sets, which atom or ion has the smallest ionisation ° dere, energy? Explain your reason. hint ; suodley = DNOF Sapa Peat Hier) Shady” oc!) Th \e ii) S*, S,S* st7 bas N small - 35. (12 pts.) Bond dissociation energy of Clg) is given as 244kJ/mol. Which of the following transition(s) in the hydrogen atom will generate a photon with enough energy to break the bond in a Cla(g) molecule according to the following reaction? 3 7” Bod Bq, = Buy d_ Ch(g) ——> Cl(g) + Cl(g) : a bind Show your work. Given that for hydrogen atom, AE=—R,(--ty = = WOT AWS msec non L i) From m3 t0 ng-2 NB) fo ~\4 pe Ny eee I eee OR, y, 2-200 ( i” | STeaaE ee 3,DL6 MOS Dwr ah | CK Bod aqy) ii) From n=4 to n=3 5 {oN i 44 oss S saan sts(d x) = AO8K WF DS RF ereyh! C 2 Bend Baz4) iii) from m2 to nyo zi --18 Ay Lares 4 eee = AGIOS eG =) Proah \ ( > Bord Enyy ) 6. (10 pts.) Light of wavelength 276 nm shines on a piece of magnesium metal. If the binding energy of magnesium metal is 5.90 x 10°" J, what is the speed of the ejected electron? Ax Tow Ex= 4 z 4 mS 39(7-195 x10 mb) Gad 3 ee eee We Ww 1g “4 4 ely 2 Sime nw ial ’ " : see S.3y pms 4 10IT HO Ly —_— —=— aF |7. (18 pts.) Fill out the following table. Species | SE: SOs CIF: Central atom S ‘Total number of valence electrons Lewis Structure Give the name of the | electron pair | dee Leh ll geometry Give the name of molecular geometry | Qe ph (Molecular shape) Beak Give the hybrid orbital type for the central atom 8. (10 pis.) Fill in the blanks a) The electrons in filled lower shells will have little impact on an element’s chemical properties. The inner electrons which lies closer to the nucleus, are referred to as core, lp kcons b) Instead of interacting with the full nuclear charge, electrons in multi-electron atoms interact with an ol that is smaller than the full charge because of shielding effects. c) The amount of energy that we would have to supply to induce the following. reaction is call__ P\or sors a LK X(@) te > Xe) d d) Any energy state which is not the lowest possible energy state is referred to as an €) The amount of energy that we would have to supply to induce the following reaction iscall_jarn\¥eQIN 2 pet . X(g) > Xe) te . f) The energy released when isolated atoms form a covalent bond is called bon ei 2 bree and the distance between the nuclei of the bonded atoms is called ‘ wi. 2) A pair of electrons shared by two atoms in a Lewis structure is referred to as a boryling hese i : h) Ina gas mixture, ’on average, lighter molecules move fe he than heavier molecules. i) Molecules having permanent dipoles are called _Fycal (4 «* molecules. 5