TABLE B-1

INTERMOLECULAR FORCE PARAMETER

Substance Molecular Weight (M) Lennar-Jones Parameter

σ (Ao ) ϵ/K
(K)
Light elements :
H2 2.016 2.915 38.0
He 4.003 2.576 10.2
Noble gases :
Ne 20.183 2.789 35.7
Ar 39.944 3.418 124.0
Kr 83.80 3.498 225.0
Xe 131.3 4.055 229.0
Simple Polyatomic Substances :
Air 28.97 3.617 97.0
N2 28.02 3.681 91.5
O2 32.00 3.433 113.0
O3 48.00 - -
CO 28.01 3.590 110.0
CO2 44.01 3.996 190.0
NO 30.01 3.470 119.0
N2O 44.02 3.879 220.0
SO2 64.07 4.290 252.0
F2 38.00 3.653 112.0
Cl2 70.91 4.115 357.0
Br2 159.83 4.268 520.0
I2 253.82 4.982 550.0
Hydrocarbons :
CH4 16.04 3.822 137.0
C2H2 26.04 4.221 185.0
C2H4 28.05 4.232 205.0
C2H6 30.07 4.418 230.0
C3H6 42.08 - -
C3H8 44.09 5.061 254.0
n-C4H10 58.12 - -
j-C4H10 58.12 5.341 313.0
n-C5H12 72.15 5.769 345.0
n-C6H14 86.17 5.909 413.0
n-C7H16 100.20 - -
n-C8H18 114.22 7.451 320.0
n-C9H20 128.25 - -
Cyclohexane 84.16 6.093 324.0
C6H6 78.11 5.270 440.0
(CH3)2CO 58 4.600 560.2
Other organic compounds:
CH4 16.04 3.822 137.0
CH3Cl 50.49 3.375 855.0
CH2Cl2 84.94 4.759 406.0
CHCl3 119.39 5.430 327.0
CCl4 153.84 5.881 327.0
C2N2 52.04 4.38 339.0
COS 60.08 4.13 335.0
CS2 76.14 4.438 488.0
CONFIDENTIAL BKC1617I/BKF2432

TABLE B-2
FUNCTIONS FOR PREDICTION OF TRANSPORT PROPERTIES OF GASES AT
LOW DENSITIES

KT/ϵ or KT/ϵAB ΩD,AB KT/ϵ or KT/ϵAB ΩD,AB

(For mass diffusity) (For mass diffusity)
2.50 0.9996
0.30 2.662 2.60 0.9878
0.35 2.476 2.70 0.9770
0.40 2.318 2.80 0.9672
0.45 2.184 2.90 0.9576

0.50 2.066 3.00 0.9490

0.55 1.966 3.10 0.9406
0.60 1.877 3.20 0.9328
0.65 1.798 3.30 0.9256
0.70 1.729 3.40 0.9186

0.75 1.667 3.50 0.9120

0.80 1.612 3.60 0.9058
0.85 1.562 3.70 0.8998
0.90 1.517 3.80 0.8942
0.95 1.476 3.90 0.8888

1.00 1.439 4.00 0.8836

1.05 1.406 4.10 0.8788
1.10 1.375 4.20 0.8740
1.15 1.346 4.30 0.8694
1.20 1.320 4.40 0.8652

1.25 1.296 4.50 0.8610

1.30 1.273 4.60 0.8568
1.35 1.253 4.70 0.8530
1.40 1.233 4.80 0.8492
1.45 1.215 4.90 0.8456

1.50 1.198 5.0 0.8422

1.55 1.182 6.0 0.8124
1.60 1.167 7.0 0.7896
1.65 1.153 8.0 0.7712
1.70 1.140 9.0 0.7556

1.75 1.128 10.0 0.7424

1.80 1.116 20.0 0.6640
1.85 1.105 30.0 0.6232
1.90 1.094 40.0 0.5960
1.95 1.084 50.0 0.5756

2.00 1.075 60.0 0.5596

2.10 1.057 70.0 0.5464
2.20 1.041 80.0 0.5352
2.30 1.026 90.0 0.5256
2.40 1.012 100.0 0.5170

2
CONFIDENTIAL BKC1617I/BKF2432