The zerath lous of thennedynamics Therma) eguihbnun : stote in which no ch take place blw wo"ebsed siplems in contach wl cock By definition, two sysiems in thermol eguilidsum have. the some, Sonfersure Let A,8& stems ia thermal op uit Bc — 4 Experi —> hand C are also iA thermal eguil = Be aerate lanl of thermoclynaries Consider ayems ABC each Consisting oP a const. mass. of different Puuds \yz const. > % is vasalle (=> RV are independent 7 Faq const. > Va is erece +t. vor. To apes macroscopic state ap fluid ef given. mass and ee we need only Fond V J Ler Ae ia thermo) saqle. independent variable Act of RNa ot Pred temper abe. © = isothenn Thermodynamic temperature T 5 [T]ap= Ae Ckelvin) Kelvin scale temperate ef eguil system of Bgud wale, ice and water Vapor = 278.16K Qksius Scale femperodwe of freeaing re af wader at Nom = 0°e (degrees Cobsius) 8 (°c) = Tk) - 273.15-2- Relahonsp blw 4. Propertes & a sys Ok eguil. = squeten ¥ sole Pe ROT) Low- prsswe ops py ak “Ss Faas R= asia je tmolt Rs ok