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Chemistry – A European Journal / Volume 24, Issue 42

Communication

Acyl Radicals from Terminal Alkynes: Photoredox‐Catalyzed Acylation of Heteroarenes

Shaista Sultan , Dr. Masood Ahmad Rizvi , Jaswant Kumar , Dr. Bhahwal Ali Shah 

First published: 25 May 2018

https://doi.org/10.1002/chem.201801628
Citations: 19

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Abstract
A photoredox‐mediated acylation reaction of electron deficient heteroarenes with terminal
alkynes is reported. The method relies on oxidative cleavage of phenylacetylenes for generation of
acyl radicals as a key enabling feature. The reaction is regioselective with broad substrate scope.
Quantum yield investigations support a radical chain mechanism.

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