Austin Fan Eric Shen Hunter Voltz Karinne Bernanke Outline • Prior Literature • Purpose • Hypothesis • Experimental Design • Measurables • Results • Next Steps Research - “Durable and Flexible Graphene Composites based on Artists’ paint for Conductive Paper Applications” Joseph E.Mates, Ilker S. Bayer, Marco Salerno, et. al. - Used acrylic emulsion artists’ paint containing chlorinated copper phthalocyanine pigment - Recorded thermal and electrical conductivity as well as shielding effects - “Graphene Oxide Nanopaint” - Identified corrosion-resistance and inhibition of bacterial growth and surface fouling as properties of GO-infused paint Purpose To test the thermal and electrical properties of graphene infused paint for various applications in construction, electronics, and e-textiles. We will compare our findings to literature graphene infused paint findings as well as unmodified paint. Hypothesis We believe that the infusion of graphene into paint will increase its thermal and electrical conductivity because of graphene’s innate high conductivity properties as a result of its structure. Set Up Procedure 1. Create a stock solution of 10% Paint solids in Acetone 2. Mix necessary amounts of MLG and acetone to achieve desired ratio of MLG to paint solids 3. Add stock solution to achieve MLG:Acetone solids 4. Sonicate for 5 minutes 5. Use airbrush to evenly coat paint onto rectangular wood piece. 6. Repeat for all ratios as well as repeating for Phi4 graphene Spray painting the Graphene Infused Examining the Density of paint Paint on the Acrylic board Completed piece Physical Observations • Phi4 Graphene is less dense, possibly indicating a higher quality graphene (less layers, more space in between layers) • Higher graphene content mixtures, when sprayed onto the acrylic, was noticeably darker as opposed to the lower graphene content mixtures, which was more green. • The 65:35 and 80:20 MLG:Paint solids, when sprayed, had a very hard time sticking to the acrylic - there was no paint solids to help the powdery MLG to stick to the acrylic Testing Electrical Resistivity
• Utilize the van der Pauw method with
measurements from a four probe meter • Measure all permutations of current and voltage probes • Perform calculations • 2 probe measurements ● Force a current through adjacent probes (A to B, for example) ● Record voltage across remaining probes (C to D) ● Van der Pauw Resistivity = V/I ● Sheet Resistivity = (π•RvdP)/ln(2)
Image retrieved from
https://www.microwaves101.com/encyclopedias/van-der-pauw-meas urements Changes in Experiment • Vary weight ratio of graphene to paint: • 10%, 20%, 35%, 50%, 65%, 80% • Perform experiment for graphene nanoplatelets and Phi4 graphene product. Compare both results. Results - 2 Point Measurements Trend Graph Van Der Pauw Results Future Changes • Thermal measurements - thermocouple • Changing the substrate • Phi4 vs MLG • Testing new types of graphene • Procedural Changes • Application method • Time constants Questions?