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Chem Unit 2 PDF
Chem Unit 2 PDF
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Marks Scored : 49.
Question no 1
The coordination number of Na+ in NaCl crystal is:
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Option A :
6
}
Option B :
2
Option C :
4
Option D :
8
Question no 2
Ice is less dense than water at
Option A :
0oC
}
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Option B :
o
-4 C
Option C :
4oC
Option D :
2oC
Question no 3
Pressure remaining constant, at which temperature the volume of a gas will become twice of what it is at
o
0 C
Option A :
o
546 C
Option B :
o
200 C
Option C :
546K
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Option D :
273K
Question no 4
3
Number of molecules in one dm of water at STP is close to:
Option A :
23
x 10
}
Option B :
x 1023
Option C :
23
x 10
Option D :
23
55.4 x 6.02 x 10
}
Question no 5
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When granulated zinc reacts with dilute sulfuric acid, hydrogen gas is given off. How does the volume of
the hydrogen evolved, when a sample of zinc reacts with an excess of acid, depend on temperature and
pressure?
Option A :
It increases with increase in temperature and is independent of pressure.
Option B :
It increases with decrease in temperature and is independent of pressure.
Option C :
It increases with increase in temperature and increases with increase in pressure.
Option D :
It increases with increase in temperature and decreases with increase in pressure.
}
Question no 6
Which graph is correct for a given mass of an ideal gas at constant pressure?
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Option A :
Option B :
}
Option C :
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Option D :
Question no 7
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Option A :
2 g of deuterium of volume V
Option B :
4 g of deuterium of volume
Option C :
A mixture of 1 g of hydrogen and 2 g of deuterium of total volume V
Option D :
A mixture of 2 g of hydrogen and 1 g of deuterium of total volume 2V
Question no 8
Which solid exhibits more than one kind of chemical bonding?
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Option A :
brass
Option B :
copper
Option C :
diamond
Option D :
Ice
}
Question no 9
Which ion is most polarizing?
Option A :
3+
Al
}
Option B :
2+
Ba
Option C :
2+
Mg
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Option D :
+
Na
Question no 10
Which of the following solids has a simple molecular lattice?
Option A :
magnesium oxide
Option B :
sodium
Option C :
silicon(IV) oxide
Option D :
sulfur
}
Question no 11
Which type of bond is responsible for intermolecular forces in liquid tetrachloromethane, CCl4?
Option A :
covalent bonding
Option B :
hydrogen bonding
Option C :
instantaneous dipole – induced dipole attractions
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Option D :
permanent dipole – permanent dipole attraction
Question no 12
Why is boiling point of methane greater than that of neon? [Ar: H, 1; C, 12; Ne, 20]
Option A :
A molecule of methane has a greater mass than a molecule of neon
Option B :
A molecule of methane has more electrons than a molecule of neon
Option C :
Molecules of methane have stronger intermolecular forces than those of neon
Option D :
Molecules of methane form hydrogen bonds, but those of neon do not
Question no 13
Consider the following four compounds:
1. (CH3)3 CH
2. CH3CH2CH2OH
3. CH3CH2CH2SH
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4. CH3CH2CH2CH3
What is the order of increasing boiling point of the compounds (lowest rst)?
Option A :
1 4 3 2
}
Option B :
2 3 4 1
Option C :
3 2 4 1
Option D :
4 1 2 3
Question no 14
Which set of properties could apply to a non-ionic compound which has a giant lattice?
Option A :
Physical state at room temp Electrical conductivity of the molten compound m.p./oC
Option B :
Physical state at room temp Electrical conductivity of the molten compound
m.p./oC
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Option C :
Physical state at room temp Electrical conductivity of the molten compound
m.p./oC
Option D :
Physical state at room temp Electrical conductivity of the molten compound
m.p./oC
}
Question no 15
Which of the following molecules will not form a hydrogen bond with another of its own molecules?
Option A :
CH3CHO
}
Option B :
CH3NH2
Option C :
CH3OH
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Option D :
NH3
Question no 16
Solid carbon dioxide, CO2 (s) (dry ice), is used as a refrigerating agent because it readily changes directly
from the solid into the vapour state at a low temperature. What does this indicate the main intermolecular
bonding in CO2(s) to be?
Option A :
covalent bonding
Option B :
hydrogen bonds
Option C :
ionic bonding
Option D :
van der Waals’s forces
}
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Question no 17
Molecular attraction and size of the molecules in a gas are negligible at:
Option A :
Critical point
Option B :
High pressure
Option C :
High temperature and low pressure
Option D :
Low temperature and high pressure
Question no 18
At STP, the order of root mean square speed of molecules of H2, N2, O2 and HCl is:
Option A :
H2 > N2 > O2 > HCl
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}
Option B :
HCl > H2 > O2 > N2
Option C :
HCI > O2 > N2 > H2
Option D :
N2 > O2 > H2 > HCl
Question no 19
At constant volume, for a xed number of mole of a gas, the pressure of the gas increases with rise of
temperature due to:
Option A :
Increase in average molecular speed
}
Option B :
Increase in number of mole
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Option C :
Increase in molecular attraction
Option D :
Decreases in mean free path
Question no 20
For a given mass of a gas, if pressure is reduced to half and temperature is increased two times, then the
volume would become:
Option A :
V/4
Option B :
6V
Option C :
2
2V
Option D :
4V
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}
Question no 21
The particles would be stationary in a lattice only at:
Option A :
273 K
Option B :
0K
}
Option C :
298K
Option D :
373K
Question no 22
NaCl is an example of which of the following crystal system:
Option A :
Triclinic
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Option B :
Hexagonal
Option C :
Tetragonal
Option D :
Cubic
}
Question no 23
In a simple cubic unit cell, the contribution of the atom placed at one of the corners towards the unit cells
is:
Option A :
1
Option B :
}
Option C :
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Option D :
Question no 24
+ -
How many Na ions are there around each Cl ion in NaCl crystal ?
Option A :
2
Option B :
4
Option C :
6
Option D :
8
Question no 25
In the closest packing of atoms of metals, what fraction of the total volume is occupied by the atoms?
Option A :
52.4%
Option B :
74.0%
}
Option C :
47.6%
Option D :
68%
Question no 26
Amorphous solids:
Option A :
Possess sharp melting points
Option B :
Undergo clean cleavage when cut with knife
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Option C :
Do not undergo clean cleavage when cut with knife
Option D :
Possess orderly arrangement over long distances
Question no 27
A solid X melts slightly above 273 K and is a poor conductor of heat and electricity. To which of the
following categories does it belong:
Option A :
Ionic solid
Option B :
Covalent solid
Option C :
Metallic
Option D :
Molecular
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}
Question no 28
Metallic crystalline solids:
Option A :
Have low melting point and boiling point
Option B :
Are bad conductors
Option C :
Are good conductors of heat and electricity
Option D :
Only conduct heat
Question no 29
For a covalent solid, the units which occupy lattice points are :
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Option A :
Atoms
}
Option B :
Ions
Option C :
Molecules
Option D :
Electrons
Question no 30
Which is incorrect statement regarding to states of matter:
Option A :
the simplest state is the gaseous state
Option B :
the most abundant state in the universe and on the earth is plasma state
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}
Option C :
the most abundant state around us is solid
Option D :
less common state is liquid state
Question no 31
The particle motion in solid is
Option A :
Vibratory as well as rotatory
Option B :
Only Rotatory
Option C :
Only vibratory
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Option D :
Vibratory as well as translatory
}
Question no 32
In liquids, intermolecular forces are
Option A :
Very weak
Option B :
Very strong
Option C :
Reasonably strong
Option D :
Ion-dipole force
Question no 33
Mathetically, Boyle’s law can be represted as
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Option A :
V ∝ 1/P
Option B :
PV = K
Option C :
P1V1 = P2V2
Option D :
All of these
}
Question no 34
What factor of pressure should be applied on a gas to decrease its volume three times?
Option A :
1/3
Option B :
1/2
}
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Option C :
3/1
Option D :
1/4
Question no 35
With increase of temperature from T1 to T2 isotherm moves away from the both axes because of
Option A :
Increase in pressure
Option B :
Increase in volume
}
Option C :
Increase in mass
Option D :
Both A and B
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Question no 36
At a given temperature and pressure, 14g Nitrogen will have same volume as 14g of
Option A :
Carbon dioxide
Option B :
Carbon monoxide
}
Option C :
Oxygen
Option D :
Neon
Question no 37
If P, V, M, T and R are pressure, volume, molar mass, temperature and gas constant respectively , then for
an ideal gas the density is given by
Option A :
RT/PM
Option B :
P/RT
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Option C :
M/V
Option D :
PM/RT
}
Question no 38
A gas with lowest density
Option A :
O2
Option B :
NH3
}
Option C :
N2
Option D :
Ne
}
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Question no 39
The intermolecular attractive forces vary in the order
Option A :
Water < Alcohol < Ether
Option B :
Alcohol < Water < Ether
Option C :
Ether < Alcohol < Water
Option D :
Ether < Water < Alcohol
Question no 40
The chloroform and acetone are miscible due to:
Option A :
Hydrogen bonding
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}
Option B :
Option C :
Dipole-dipole force
Option D :
Question no 41
If O2 is dissolved in H2O then which type of forces are present among these
Option A :
Dipole-dipole force
Option B :
London dispersion forces
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Option C :
Dipole-induced force
Option D :
All of these
}
Question no 42
Which one of the following halogen acids is a border line between dipole-dipole interaction and hydrogen
bonding:
Option A :
HF
Option B :
HBr
Option C :
HCl
Option D :
HI
}
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Question no 43
Exceptionally low acidic strength of HF is due to
Option A :
Strong polar bond
Option B :
Small size of uorine
Option C :
Strong hydrogen bonding
Option D :
Van der Waal’s forces
Question no 44
NH3 shows maximum boiling point among hydrides of V-A group elements due to:
Option A :
Very small size of nitrogen
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Option B :
Lone pair of electron present in nitrogen
Option C :
Enhanced electro negativity character of nitrogen
Option D :
Pyramidal structure of NH3
Question no 45
When water freezes it occupies 9% more space and its density
Option A :
Decreases
}
Option B :
Increases
Option C :
Remains constant
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Option D :
Increases four times
Question no 46
During the cleansing action , the detergents attracts stain particles with a force
Option A :
Hydrogen bonding
}
Option B :
Dipole-induced dipole force
Option C :
London force
Option D :
Dipole-dipole force
Question no 47
Which one is false for evaporation?
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Option A :
Surface phenomenon
Option B :
Continuous
Option C :
Exothermic
Option D :
Cause cooling
Question no 48
On heating a liquid at its dynamic equilibrium, the concentration of molecules in vapour state as well as in
liquid state
Option A :
Increase
}
Option B :
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Decrease
Option C :
Remains constant
Option D :
Neither increase nor decrease
Question no 49
Which liquid has lowest vapour pressure:
Option A :
ethanol
Option B :
mercury
Option C :
water
Option D :
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glycerol
}
Question no 50
A substance with maximum vapour pressure at 25oC
Option A :
Diethyl ether
}
Option B :
Methyl alcohol
Option C :
Chloroform
Option D :
Water
Question no 51
Correct order of boiling points of the given liquids is
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Option A :
H2O > HF > HCl > NH3
Option B :
HF > H2O > HCl > NH3
Option C :
H2O > HF > NH3> HCl
Option D :
HF > H2O > NH3> HCl
Question no 52
Heat of vaporization is minimum for
Option A :
HF
Option B :
HBr
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Option C :
HCl
Option D :
HI
Question no 53
The most important characteristic of a solid through which it is identi ed as crystalline solid
Option A :
De nite shape
Option B :
Sharp melting point
}
Option C :
Geometrical arrangement of particles
Option D :
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Question no 54
Which crystal has the largest lattice energy
Option A :
KCl
}
Option B :
MgO
}
Option C :
LiBr
Option D :
NaF
Question no 55
An example of two dimensional layered structure covalent solid is
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Option A :
Ice
Option B :
Sodium chloride
Option C :
Diamond
Option D :
Graphite
}
Question no 56
Which of the following is a property of molecular solid?
Option A :
Hardness and rigidity
Option B :
High melting points
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Option C :
Volatile nature
Option D :
Good conductors of electricity
Question no 57
Which of the following inter molecular forces may be present in molecular solids
Option A :
Dipole — dipole forces
Option B :
H- bonding
Option C :
Van der Waal's forces
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Option D :
All of the these
}
Question no 58
The theory which explains the malleability and ductility in metals is
Option A :
Electron gas theory
}
Option B :
Molecular orbital theory
Option C :
Valance bond theory
Option D :
Band theory
Question no 59
Which statement is not true about metallic solid?
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Option A :
They are ductile and malleable
Option B :
They are conductor of electricity
Option C :
Their conductivity increases with temperature
Option D :
They have metallic luster
Question no 60
Maximun Molar heat of vaporization is observed in
Option A :
NH3
}
Option B :
HCl
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Option C :
SO2
Option D :
All have same value
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