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Marks Scored : 49.

Question no 1
The coordination number of Na+ in NaCl crystal is:
        
 

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Option A :
6                                     

}

Option B :
2                                        

Option C :
4                                       

Option D :
8

Question no 2
Ice is less dense than water at
 
 

Option A :
0oC                                 

}

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Option B :
o
-4 C                                   

Option C :
4oC                                

Option D :
 2oC

Question no 3
Pressure remaining constant, at which temperature the volume of a gas will become twice of what it is at
o
0 C
 
 
 

Option A :
o
546 C          

Option B :
o
  200 C                              

Option C :
 546K         


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Option D :
273K

Question no 4
3
Number of molecules in one dm of water at STP is close to:
 

Option A :
23
x 10                     

}

Option B :
x 1023    

Option C :
23
x 10     

Option D :
23
55.4 x 6.02 x 10     

}

Question no 5

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When granulated zinc reacts with dilute sulfuric acid, hydrogen gas is given off. How does the volume of
the hydrogen evolved, when a sample of zinc reacts with an excess of acid, depend on temperature and
pressure?
 
 

Option A :
It increases with increase in temperature and is independent of pressure.

Option B :
It increases with decrease in temperature and is independent of pressure.

Option C :
It increases with increase in temperature and increases with increase in pressure.

Option D :
It increases with increase in temperature and decreases with increase in pressure.

}

Question no 6
Which graph is correct for a given mass of an ideal gas at constant pressure?
 
 

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Option A :

Option B :
 

}

Option C :

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Option D :
 

Question no 7

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A 2 g sample of hydrogen at temperature T and of volume V exerts a pressure P. Deuterium, , is an isotope


of hydrogen. Which of the following would also exert a pressure P at the same temperature T?
 
 

Option A :
2 g of deuterium of volume V

Option B :
4 g of deuterium of volume

Option C :
A mixture of 1 g of hydrogen and 2 g of deuterium of total volume V

Option D :
A mixture of 2 g of hydrogen and 1 g of deuterium of total volume 2V

Question no 8
Which solid exhibits more than one kind of chemical bonding?
 
 
 

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Option A :
 brass              

Option B :
copper                  

Option C :
 diamond         

Option D :
Ice

}

Question no 9
 
Which ion is most polarizing?
 
                                                                                              
 
 

Option A :
3+
Al     

}

Option B :
2+
Ba  

Option C :
2+
Mg      
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Option D :
+
Na

Question no 10
Which of the following solids has a simple molecular lattice?
 

Option A :
 magnesium oxide          

Option B :
sodium                                                            

Option C :
silicon(IV) oxide      

Option D :
sulfur

}

Question no 11
Which type of bond is responsible for intermolecular forces in liquid tetrachloromethane, CCl4?
 

Option A :
covalent bonding                           

Option B :
hydrogen bonding                                                                    

Option C :
 instantaneous dipole – induced dipole attractions   

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Option D :
permanent dipole – permanent dipole attraction

Question no 12
Why is boiling point of methane greater than that of neon? [Ar: H, 1; C, 12; Ne, 20]
 

Option A :
A molecule of methane has a greater mass than a molecule of neon

Option B :
A molecule of methane has more electrons than a molecule of neon

Option C :
Molecules of methane have stronger intermolecular forces than those of neon

Option D :
Molecules of methane form hydrogen bonds, but those of neon do not

Question no 13
Consider the following four compounds:
1. (CH3)3 CH

2. CH3CH2CH2OH

3. CH3CH2CH2SH
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4. CH3CH2CH2CH3

What is the order of increasing boiling point of the compounds (lowest rst)?

Option A :
1 4 3  2             

                                                       

}

Option B :
2 3  4  1                                                            

Option C :
 3  2   4   1        

Option D :
4  1   2   3

Question no 14
Which set of properties could apply to a non-ionic compound which has a giant lattice?
 

Option A :
Physical state at room temp        Electrical conductivity of the molten compound            m.p./oC

Liquid                                                               Does not conduct                                         -114

Option B :
Physical state at room temp        Electrical conductivity of the molten compound                                 
m.p./oC

Liquid                                                         Does not conduct                                                    Melts over a


temp. range

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Option C :
Physical state at room temp        Electrical conductivity of the molten compound                                 
m.p./oC

Solid                                                                Conducts well                                                                       808

Option D :
Physical state at room temp        Electrical conductivity of the molten compound                                 
m.p./oC

Solid                                                                   Does not conduct                                                            1610

}

Question no 15
Which of the following molecules will not form a hydrogen bond with another of its own molecules?
 
 
 

Option A :
 CH3CHO       

}

Option B :
CH3NH2                   

Option C :
   CH3OH      

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Option D :
  NH3

Question no 16
Solid carbon dioxide, CO2 (s) (dry ice), is used as a refrigerating agent because it readily changes directly
from the solid into the vapour state at a low temperature. What does this indicate the main intermolecular
bonding in CO2(s) to be?
 
 
 

Option A :
 covalent bonding                       

Option B :
hydrogen bonds                

Option C :
 ionic bonding            

Option D :
 van der Waals’s forces

}

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Question no 17
Molecular attraction and size of the molecules in a gas are negligible at:
 
 

Option A :
Critical point            

Option B :
  High pressure                

Option C :
 High temperature and low pressure   

Option D :
Low temperature and high pressure

Question no 18
At STP, the order of root mean square speed of molecules of H2, N2, O2 and HCl is:
 
                                                                  
 
 

Option A :
 H2 > N2 > O2 > HCl       

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}

Option B :
HCl > H2 > O2 > N2              

Option C :
HCI > O2 > N2 > H2      

Option D :
 N2 > O2 > H2 > HCl

Question no 19
At constant volume, for a xed number of mole of a gas, the pressure of the gas increases with rise of
temperature due to:
 
 
 

Option A :
Increase in average molecular speed   

}

Option B :
Increase in number of mole 

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Option C :
Increase in molecular attraction                    

Option D :
Decreases in mean free path

Question no 20
For a given mass of a gas, if pressure is reduced to half and temperature is increased two times, then the
volume would become:
 
 

Option A :
V/4            

Option B :
6V             

Option C :
2
 2V          

Option D :
 4V

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}

Question no 21
The particles would be stationary in a lattice only at:
 
 
 

Option A :
 273 K  

Option B :
0K                               

}

Option C :
298K         

Option D :
373K

Question no 22
NaCl is an example of which of the following crystal system:
 
 

Option A :
Triclinic              
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Option B :
Hexagonal                                                                   

Option C :
Tetragonal           

Option D :
Cubic

}

Question no 23
In a simple cubic unit cell, the contribution of the atom placed at one of the corners towards the unit cells
is:
 

Option A :
1

Option B :

}

Option C :

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Option D :

Question no 24
+ -
How many Na ions are there around each Cl ion in NaCl crystal ?
 
 

Option A :
2               

Option B :
4                                      

Option C :
6                          

Option D :
 8

© 2020 All rights reserved


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Question no 25
In the closest packing of atoms of metals, what fraction of the total volume is occupied by the atoms?
 
 

Option A :
52.4%                         

Option B :
74.0%                       

}

Option C :
47.6%                          

Option D :
68%

Question no 26
Amorphous solids:
 
 

Option A :
Possess sharp melting points                    

Option B :
  Undergo clean cleavage when cut with knife                                                                 

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Option C :
Do not undergo clean cleavage when cut with knife                              

Option D :
 Possess orderly arrangement over long distances

Question no 27
A solid X melts slightly above 273 K and is a poor conductor of heat and electricity. To which of the
following categories does it belong:
 
 
 

Option A :
Ionic solid      

Option B :
Covalent solid             

Option C :
Metallic           

Option D :
Molecular

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}

Question no 28
Metallic crystalline solids:
 
 

Option A :
Have low melting point and boiling point                 

Option B :
Are bad conductors            

Option C :
Are good conductors of heat and electricity

Option D :
Only conduct heat

Question no 29
For a covalent solid, the units which occupy lattice points are :
 
              
 

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Option A :
Atoms              

}

Option B :
Ions                            

Option C :
  Molecules       

Option D :
Electrons

Question no 30
Which is incorrect statement regarding to states of matter:
 
 

Option A :
the simplest state is the gaseous state

Option B :
the most abundant state in the universe and on the earth is plasma state

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}

Option C :
the most abundant state around us is solid

Option D :
less common state is liquid state

Question no 31
The particle motion in solid is
 
 

Option A :
Vibratory as well as rotatory                

                                 

Option B :
  Only Rotatory              

Option C :
 Only vibratory  

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Option D :
Vibratory as well as translatory

}

Question no 32
In liquids, intermolecular forces are
 
 
 

Option A :
 Very weak                

Option B :
Very strong                      

Option C :
 Reasonably strong

Option D :
Ion-dipole force

Question no 33
Mathetically, Boyle’s law can be represted as
 

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Option A :
V  ∝ 1/P                 

Option B :
    PV = K                

Option C :
 P1V1 = P2V2                    

Option D :
 All of these

}

Question no 34
What factor of pressure should be applied on a gas to decrease its volume three times?
 
 

Option A :
1/3     

Option B :
1/2               

}
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Option C :
3/1                                 

Option D :
1/4

Question no 35
With increase of temperature from T1 to T2 isotherm moves away from the both  axes because of
 
 
 

Option A :
Increase in pressure      

Option B :
Increase in volume                

}

Option C :
 Increase in mass         

Option D :
 Both A and B

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Question no 36
At a given temperature and pressure, 14g Nitrogen will have same volume as 14g of
            
 

Option A :
 Carbon dioxide        

Option B :
Carbon monoxide                       

}

Option C :
  Oxygen             

Option D :
Neon       

Question no 37
If P, V, M, T and R are pressure, volume, molar mass, temperature and gas constant respectively , then for
an ideal gas the density is given by
 

Option A :
RT/PM                          

Option B :
 P/RT                             

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Option C :
    M/V                                           

Option D :
  PM/RT

}

Question no 38
A gas with lowest density
 
 

Option A :
O2                

Option B :
 NH3                

}

Option C :
  N2                              

Option D :
Ne

}
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Question no 39
The intermolecular attractive forces vary in the order
 
 

Option A :
Water < Alcohol < Ether       

Option B :
  Alcohol < Water < Ether                             

Option C :
Ether < Alcohol < Water

Option D :
Ether < Water < Alcohol

Question no 40
The chloroform and acetone are miscible due to:
 
 
 

Option A :
 Hydrogen bonding      

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}

Option B :
 

Van der Waals's force      

Option C :
Dipole-dipole force   

Option D :
 

 Dipole induced dipole force

Question no 41
If O2 is dissolved in H2O then which type of forces are present among these
 
 
 

Option A :
 Dipole-dipole force           

Option B :
London dispersion forces                 

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Option C :
 Dipole-induced force             

Option D :
All of these

}

Question no 42
Which one of the following halogen acids is a border line between dipole-dipole interaction and hydrogen
bonding:
 
 

Option A :
HF                 

Option B :
 HBr                          

Option C :
   HCl                  

Option D :
HI

}
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Question no 43
Exceptionally low acidic strength of HF is due to
 
 

Option A :
Strong polar bond           

Option B :
Small size of uorine                    

Option C :
 Strong hydrogen bonding     

Option D :
Van der Waal’s forces

Question no 44
NH3 shows maximum boiling point among hydrides of V-A group elements due to:
 
 
 

Option A :
Very small size of nitrogen           

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Option B :
Lone pair of electron present in nitrogen

Option C :
 Enhanced electro negativity character of nitrogen            

Option D :
Pyramidal structure of NH3

Question no 45
When water freezes it occupies 9% more space and its density
 
                                                                
 

Option A :
 Decreases           

}

Option B :
Increases                                       

Option C :
Remains constant

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Option D :
     Increases four times

Question no 46
During the cleansing action , the detergents attracts stain particles with a force
 
 

Option A :
Hydrogen bonding     

}

Option B :
 Dipole-induced dipole force          

Option C :
London force      

Option D :
Dipole-dipole force

Question no 47
Which one is false for evaporation?

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Option A :
Surface phenomenon               

Option B :
 Continuous             

Option C :
Exothermic   

Option D :
Cause cooling

Question no 48
On heating a liquid at its dynamic equilibrium, the concentration of molecules in vapour state as well as in
liquid state
 
 

Option A :
 Increase       

}

Option B :

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Decrease                

Option C :
 Remains constant    

Option D :
Neither increase nor decrease

Question no 49
Which liquid has lowest vapour pressure:
 
                                                            
 

Option A :
ethanol       

Option B :
mercury                   

Option C :
water             

Option D :

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glycerol

}

Question no 50
A substance with maximum vapour pressure at 25oC
 
    
 

Option A :
Diethyl ether     

}

Option B :
Methyl alcohol            

Option C :
Chloroform         

Option D :
Water

Question no 51
Correct order of boiling points of the given liquids is
 
 

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Option A :
H2O > HF > HCl > NH3               

Option B :
HF > H2O > HCl > NH3                                                  

Option C :
H2O > HF > NH3> HCl

Option D :
 HF > H2O > NH3> HCl

Question no 52
Heat of vaporization is minimum for
 
 
 

Option A :
HF            

Option B :
HBr                  

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Option C :
HCl    

Option D :
HI

Question no 53
The most important characteristic of a solid through which it is identi ed as crystalline solid
 
 

Option A :
De nite shape         

Option B :
Sharp melting point                             

}

Option C :
Geometrical arrangement of particles

Option D :

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 De nite volume

Question no 54
Which crystal has the largest lattice energy
 
                                                                         
 

Option A :
 KCl        

}

Option B :
MgO      

}

Option C :
   LiBr       

Option D :
NaF

Question no 55
An example of two dimensional layered structure covalent solid is
 
 
 

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Option A :
Ice            

Option B :
Sodium chloride           

Option C :
  Diamond        

Option D :
Graphite

}

Question no 56
Which of the following is a property of molecular solid?
 
 
 
 

Option A :
 Hardness and rigidity            

Option B :
High melting points    

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Option C :
Volatile nature   

Option D :
Good conductors of electricity

Question no 57
Which of the following inter molecular forces may be present in molecular solids
 
                                
 

Option A :
Dipole — dipole forces                 

Option B :
H- bonding                  

Option C :
  Van der Waal's forces       

 
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Option D :
All of the these

}

Question no 58
The theory which explains the malleability and ductility in metals is
 
 
 

Option A :
 Electron gas theory        

}

Option B :
Molecular orbital theory                         

Option C :
  Valance bond theory    

Option D :
Band theory

Question no 59
Which statement is not true about metallic solid?
 
 

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Option A :
They are ductile and malleable            

Option B :
 They are conductor of electricity                 

Option C :
Their conductivity increases with temperature

          

Option D :
They have metallic luster

Question no 60
Maximun Molar heat of vaporization is observed in
 
 

Option A :
 NH3   

}

Option B :
HCl    

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Option C :
SO2  

Option D :
All have same value 

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