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Alloy Austenite

Metallic material containing at least two elements. Face centred cubic lattice (fcc) mixed crystal
One of these elements must be a metal. structure formed from deposits above the G-S-E line
in an iron carbon diagram, also called Gamma mixed
Alloying addition crystal compound (pearlite or martensite). Austenite
Chemical element added to steel to influence its is normally only resistant above 911°C; by adding
properties in a certain way. In the main: nitrogen, alloy additives (Ni, Mn) and hyper quenching,
silicon, manganese, phosphorous, sulphur, chrome, Austenite also becomes resistant at room
nickel, molybdenum, copper, vanadium, tungsten, temperature. Austenite’s structure is non-magnetic,
cobalt, lead, aluminium, titanium, tantalum, niobium, tough and has a strength attained through strain
boron. hardening (manganese steel, nickel steel, chrome-
nickel steel). It is characterised by its high
temperature strength and good anti-corrosive and
anti-inflammatory properties.

Backwardation  
In future contracts for storable goods, e.g. Nickel,
the difference between the future price e.g. 3
months, and the cash price is usually positive (see
contango). A constellation is however feasible where
this difference can be negative, i.e. the cash price for
the product, such as Nickel, is higher than the
futures price. This can happen especially when it is
advantageous to hold a certain product in stock. If
for example there was a large sudden demand for a
product, then the cost of storage and insurance
would be outweighed by the value of this sought
after product. This is a backwardation.

Call Option Cobalt


A Call option signifies the right to buy an item or Chemical element Co. density 8.9 g/cm³. A light grey
value (e.g. a stock) at a predetermined fixed price, ferro-magnetic slightly ductile metal with a good
“strike price”, either during its validity period chemical stability. Co belongs to the Austenite
(American option) or at maturity (European option); family. With Cr or W it forms a wear and heat
there is however no obligation to buy. resistant hard alloy. Used as an alloy in extremely
tough construction steel, high-speed steel,
Carbide permanent magnetic materials and high temperature
Carbide is the reaction of carbon with a more alloys. Co is also used as a bonding agent in
electropositive element (anion with cation). In the sintered hard (metal) alloys.
structure of steel, a one such carbide is Fe3C, also
know as Cementite. Together with Ferrite it forms Contango
the structure Pearlite. The resistance of steel in a Contango is the difference between the cash and the
nealed condition is determined by the ferrous future price. It can be explained thus: if an object is
carbide content, since carbide has a high toughness bought today, yet ownership is deferred for 3
level. High-speed steel und hard metal alloys owe months, the capital is still committed. In addition to
their cutting edge to carbides of hard materials this the object may have to be stored, causing
tungsten, titanium, tantalum, niobium etc. Carbide is storage and insurance costs. The ensuing interest
used in the wear protection of surfaces (e.g. and costs are reflected in the contango. The
tungsten carbide). contango is usually favourable, but under certain
circumstances can become negative in which case it
Carbon is called a backwardation.
Chemical element: C. Naturally found in different
variations, crystalline in the form of diamonds, Copper
graphite or as amorphous carbon. In iron production Chemical element Cu, density 8.93 g/cm³ . Amongst
it is used as a reducing and carburisation agent. In all the technical non ferrous metals copper is the
steel production carbon is the alloy which transforms best electricity conductor, has a high corrosion
iron into steel. resistance and is extremely flexible. It is used either
in pure form or with a little alloy additive for parts
Charge which are heated (furnace nozzles, casting moulds,
Another name for infeed when placing in a electrodes for resistors), in heat conducting
metallurgic container. Charge is the introduction of apparatus (heating cooling elements), as a coating
the material, charge time the period of treatment. metal used in plating, as an alloy in bearings and
hard soldering. Electric arc furnaces have electrodes
Chromium of conductive copper. Cu is alloyed to steel in
Chemical element: Cr. density 6.92 g/cm³ (heavy volumes of between 0.2 and 0.5%. It increases its
metal). Cr belongs to the ferric family; it is one of the tensile strength, yield point and hardness. Copper
most important alloy metals. Either on its own or with content of over 0.2%, in combination with
other alloys it gives steel a good hardness (heat- phosphorous and other alloys, improves the
treated steel). It is a strong carbide former and weathering resistance. A precipitation hardening is
increases the firmness, hardness and yield strength possible with a copper content of 1.3%, since the
of steel (tool steel). Steels containing more than 12% solubility of copper in iron reduces with falling
(10.5%) Cr are corrosion resistant (non-rust). Cr temperatures. A damaging brittleness is caused with
improves the magnetic property (constant magnetic upwards of around 0.5% copper in steel.
materials contain up to 9% Cr). Cr decreases heat
conductivity, making high chromium steels difficult to
forge. Chromium coatings protect metal surfaces
against corrosion and abrasion. Steel can be
chromed by diffusion.

Ferrite Ferro-Alloys
Metallographical description of the solid solution Intermediate products produced in coke furnaces,
(iron-carbon diagram) where carbon is dissolved electric arc furnaces or low furnaces, used as
interstitial in its lattice. Its maximum carbon additives in iron and steel productions, and contain
absorption is only 0.02%. Ferrite is only in low one or more of the following alloy elements: more
eutectoid steels, can be combined to form an alloy than 8% Si = Ferro silicon metal), more than 30%
(alloyed steel) and has a high magnetic permeability Mn (= Ferro manganese), more than 20 % Cr (=
up to 769°C. Pure ferrite materials possess less Ferro chrome), more than 40% W (=Ferro tungsten),
firmness, but high ductility. By forming alloys with Si more than a total of 10% of other alloys e.g. Cu, Al,
or Cr it gains a special property (electrical sheets). Ti, V, Mo, Nb, F, are standardised according to
Next to massive and grain boundary ferrite, with European standards and DIN 17560-17599, SEW
carbon contents of between 0.2 and 0.4% as a result 1740.
of quick cooling from high temperatures, it can form
square loop ferrite (Widmannstätten’scher Ferrite).
This brittle structure appears mainly in cast materials
and after welding.

Ferrite Steels
Steels which on solidification contain a ferrite
structure which heat cannot change. This property
depends upon ferrite formations. These steels are
heat resistant, possess especially strong magnetic
fields, do not allow quenching and tend to be coarse.

Hard (metal) alloys High temperature Steel


are composed mainly of (up to 95%) highly Is a austenite steel with very low C-content, at least
enamelled, very hard carbides, either of one carbide 13% Cr, high Ni content easily more than 10% even
type or of a carbide of varying types (W, Ti, Ta, Nb). up to 34%. These steels have good strength
Furthermore chrome or boron carbide as well as durability at temperatures between 550°C and
compounds of hard materials with nitrogen may be 600°C, even under long-term mechanical stress.
present. The remainder is binder phase, Fe, Co or Two types of alloys >20% Chrome and >30% Nickel
Ni. Co is the most used. Whereas carbide increases have this property even at temperatures of 900° to
the abrasion resistance and cutting property, the 1000°C. DIN 17459 pertains to circular tubes, DIN
binder phase creates a certain toughness and 17460 to sheets, coils, rods and forgings. Used
bending strength. These alloys are produced through mainly in building power stations where normal
pulverisation. Binding phase and hard materials are temperature steel (DIN 17175 and 17177) is not
mixed to a powder. The powder is then pressed and enough. Normal temperature and high temperature
sintered at temperatures higher than the melting steel are standardised in DIN 17240 for screws and
point of the binding phase. The structure then has nuts.
the appearance of rolled balls of carbide, with a
binding phase filling. High Speed Steel
An alloyed high grade steel, part of the tool steel
Hedging group, belonging to the steel group 32 (with Co) and
Hedging is to reduce the risk involved with 33 (without Co) (DIN EN 10 027-2). Characterised
by the alloys Cr, W, Mo and V, and, if applicable,
interest rates and price fluctuations. Losses on Co. High Speed Steel is extremely hard and tough,
highly corrosion resistant and has a keen cutting
the cash market should be compensated by ability, therefore suitable for tool making, also being
profits on the futures market. A future able to adjust to temperature changes. The chemical
contract is a binding agreement between two property and heat control of this steel gives it its
consistency and ability to take temperatures of
parties to buy or sell, and therefore receive or 600°C. Because of their toughness, only carbides
deliver and oxide ceramics have better cutting abilities than
high speed steel. They are used for metal cutting
tools. DIN 17 350, EN 10020.
a definite amount and
a certain type of product at
a fixed contract date at
a fixed price

A ‘long’ position obliges the buyer to pay the agreed


price at maturity of the contract and to accept
delivery. The corresponding ‘short’ position obliges
the seller to delivery at maturity of the futures
contract and to accept the agreed payment of the
goods.

Iron  
Chemical element Fe, density 7.85 g/cm3 (heavy
metal). As a metal, softer and more pliable than
steel. It conducts electricity and heat better and is
more corrosion resistant. Chemically pure Fe is only
found naturally as meteor iron, otherwise only in
connection with other elements, mainly as an oxide
or carbonate. Technically pure Fe is only used for
special tasks. According to European standards pig
and cast iron are iron alloys with a C content of more
than 2 %.

ISO
Short for the International Organisation for
Standardisation, an institute which coordinates all
standards. The aim of ISO is to promote
standardisation worldwide, to aid the exchange of
goods and services, and to develop the mutual
cooperation of the various technical sectors. ISO
works on ISO-Standards, which should not be
modified in any way by its member states. In
Germany these are called DIN ISO-Standards.

LME (London Metal Exchange) LME Official Price


The LME is one of the leading international future Based on the LME settlement price the various
and option markets for raw materials. Contracts for prices for the different future contracts. The standard
the NE-Metals, copper, aluminium, lead, zinc, nickel, contract with the highest market liquidity runs for 3
tin and most recently the precious metal silver are months. The longest contract is for 27 months. The
traded. The origins of the LME go back to 1571 and official Future Price is based on the settlement price
Queen Elizabeth I. Metal and raw material dealers with the addition or subtraction of the Contango or
used to meet on a regular basis. Finally in 1877 the Backwardation.
London Metal Exchange Company was founded. For
in-depth information a visit to the LME website LME Settlement Price
(www.lme.co.uk) is recommended. The last price, not covered by a bid on the offer in
the cash market (for immediate delivery), at the end
LME trading day of the second ring in the morning session, i.e. the
The LME is a 24 hour market. Certain members (see price of the seller at the close. This price, which is
LME membership) are authorized to complete officially announced on the LME floor is valid for 24
contracts with customers day and night and are not hours and is the accepted reference price for the
restricted to floor trading. Floor trading begins at prompt delivery of the metals.
11.40 and each metal is traded for five minutes. At
12.20, when all metals have been traded once, there
is a 10 minute break, until 12.30 when all metals are
traded once more for five minutes. This second
phase is considered the more important since then
the Settlement and the Official Prices are
determined. After announcement of the Official
Prices the kerb trading begins. During the kerb all
eight contract metals are traded simultaneously. At
15.10 the afternoon session begins, identical to the
morning session with the exception of the Official
Prices.

LME Membership
Over time a multilevel structure of membership has
formed on the LME, accommodating the various
needs of metal and financial traders.
Category 1 - Ring dealing members: the highest
level, they may deal during the ring in the ring and
also outside the ring 24 hours in the open
marketplace. At the moment there are 15 companies
in this category, most of which have strong ties to
the raw material sector.
Category 2 - Associate Broker Clearing members:
These have all the privileges of Ring Dealing
members except they are not allowed to deal in the
ring.
Category 3 - Associate Trade Clearing Members:
These are not allowed to conclude contracts with
customers, nor deal in the Ring, but they may clear
their own exchange business.
Categories 4 – 7: these have no major influence on
the trading activities of the LME.

Martensite Metal
Needle-shaped, very hard brittle substance, formed Chemical elements which are distinguished by their
by a rapid cooling of austenite during quenching, so strong reflective powers and are good heat and
that carbon has no time to diffuse. When heated electricity conductors. Metals have a crystalline
(tempered) at high temperatures (up to 720°C and structure with a lattice of metallic attachments, have
for as long as 10 hours), martensite forms ferrite with good durable properties and are readily pliable. They
spheroid cementite. are distinguished according to density as heavy and
light metals (bordering 4.5 g/cm³), chemically as
Martensitic steels precious and non precious metals. Similar properties
Because of its martensitic alloy content, this is hard are classified in the periodical table for the groups
steel formed already by air cooling, such as high alkaline, earth alkaline and rare earth metals.
speed steel, steels with 3-6% Mn and >=0.5% C, Further distinctions are ferrous and non-ferrous
steels with 5-8% Ni and more than 5% C, and such metals.
with at least 5% Cr and more than 0.5% C. The
martensitic Cr and high speed steels are easily Molybdenum
hardened and used as tool steel. Chemical element: Mo, density 10.2 g/cm³ (heavy
metal). White greyish metal used as an alloy in steel.
Melting Loss It increases toughness and high temperature
Carbon oxidisation is a characteristic dimension in strength, hinders the brittleness of chrome and
steel refining. By blowing oxygen the smelting is manganese heat treatable steel. Forming carbide it
decarbonised. The melting loss (in %) shows how increases the corrosion resistance in low alloyed
much carbon was removed from the smelting. heat resistant steel. In high speed steel and higher
Reactor points for carbon melting loss are to be alloyed steel Mo can be a replacement for tungsten
found directly under the oxygen stream, on the fire to a certain extent. Mo has an edge layer
resistant lining of the converter, on the interface carburisation effect in case-hardened steel. In
metal/CO-bubbles and in the metal-emulsion slag. austenite steel it increases the hot temperature
Melting loss curves indicate the time needed for strength and corrosive resistance.
decarbonisation in every refining job.
MT
metrische Tonne

Nickel Nickel Options (LME)


Chemical element Ni. Density 8.9% g/cm³ (heavy On the underlying nickel future contacts, nickel
metal). Nickel belongs to the austenite family. Steel options (calls/puts) have maturities of up to 27
is made corrosion resistant by adding at least 8% months; declaration date (the last day on which the
nickel. Nickel improves the durability and coating option can be exercised) is the first Wednesday of
and increases the toughness, especially at low the month in which the option matures, delivery date
temperatures. Nickel is close-grained, lowers the is the third Wednesday in the month of maturity.
overheating sensitivity and increases the electrical
resistance. Non-alloyed stainless steel
This term has been newly defined with the
Nickel-base alloy introduction of DIN EN 10020. Previously it was
This is a collective name for alloys of Nickel and used for all stainless steels where, apart from
other metals, Cu, Cr, Fe, Mo, with a good heat and carbon, no other alloy was added. Now the term
corrosion resistance. They are referred to by many non-alloyed stainless is used for steels which have a
trade names. W. Nr. 2.4360 is NiCu 30 Fe, an alloy higher purity than quality steels, especially with
with approx. two thirds nickel and one third copper. It regard to non metallic inclusions. This steel is used
is both extremely tough and corrosion resistant mainly for quenching and tempering or surface
(sulphuric acid, hydrochloric acid, hydrofluoric acid, hardening. There are many regulations in place to
saline solutions) and is therefore used in pickling control harden-ability, firmness and toughness, so
plants, chemical apparatus and sea water that the highest standards are maintained.
equipment. There are also cast iron alloys containing
nickel of more than 50%, with about 20% Cr and a Non ferrous metals
significant amount of Co with additives of Mo, Ti, Al This is the collective term for all metals except iron.
and Fe. They are used for high technical and They are distinguished according to density (above
temperature demands. Sheets for various usage can or below 4.5 g/cm³) as heavy or light metals, as low
be plated with a nickel-base alloy (explosive plated, or high smelting, as precious and non-precious non-
roll plated). A range of nickel-base alloys can be ferrous metals.
found in the steel-iron list. Their product number
begins with 2.

Nickel Future contract (LME)


Contract size: 6 mt, currency: US-dollar, minimum
price change: 1 US-dollar per mt, delivery date for
physical nickel: daily for the 3 month future contract,
every Wednesday for the following 3 months and
every third Wednesday for the next 15 months
(totally 27 months). Quality: primary nickel with 99.8
% nickel content with a chemical analysis according
to the ASTM Specifications. Form: cathodes, pellets
or briquettes.

Phosphorous Put option


Chemical element, P, density 1.8 g/cm³ (non metal). A put option is the right to sell a certain item or value
Embrittles steel material and is therefore combined (e.g. a stock) at a predetermined fixed price, “strike
with a limy slag when refining raw iron containing price”, during (American Option) or at the end of
phosphorous. Machining steel contains a certain (European Option) the contract period.
amount of P. In low alloyed steel P affects
atmospheric corrosion. Phosphorous enhancement
on grain boundaries is the reason for temper
embrittlement. Phosphor alloyed high strength deep
drawn steel is a modern lightweight solution in the
car industry.

Rust Free Stainless Steel


In 1958 the Informationsstelle Edelstahl Rostfrei (ISER) – the Stainless Steel Information Office - was founded as
a joint organisation by stainless steel producers, processors, traders, refiners, alloy manufacturers and other
interested parties. The aim was to provide company neutral information about this complex material and its varied
usages. From the beginning it soon became clear that there was a need to have one single concise collective
name from amongst the various terms, norms and marketing names of producers; this became ‘Stainless Rust
Free’ shortened to ‘Rust Free’, which then became a registered trade mark used by many stainless steel
processors as part of their advertising strategy. The term is however erroneously sometimes used for non rust
steels (DIN EN 10088).

Stainless Steel Spectral analysis


Is a collective term for those steels which have been The process of qualifying chemical elements in
smelted in a special procedure (secondary steels (qualitative spectral analysis) and of
metallurgy), have a high purity and react consistently determining their quantity (quantitive spectral
to heat treatment. There are two types according to analysis). In an active state, each element sends out
their chemical properties (DIN EN 10 020); non- a collection of rays according to its components.
alloyed (steel group 10-18) and alloyed (steel group Using a prism the frequency of the various rays can
20-89). It is differentiated according to its use, as be separated and projected next to one another on a
structural, engineering, container, tool, high-speed screen, where they can be determined according to
or ball-bearing steel. Steel is also characterised by position (deflection) and intensity. The position
its properties: chemically resistant, non corrosive, characterises the element, the intensity its mass
heat resistant, high temperature alloy, suitable for weight. With a spectroscope the evaluation is
welding purposes, and with special physical or determined by the viewer, with a spectrometer by
magnetic properties or yield levels. photocells and electronic evaluation. The process
releases a discharge.
Scrap
Material with a high metal content, which is used not
only as a cooling agent, but also as a secondary raw
material in steel production. Scrap can also be
alloyed or non-alloyed. Scrap is accrued in a steel
works and outside scrap is bought in. There are ten
different types of scrap: old scrap, new scrap, heavy
old scrap, shredder scrap, waste combustion scrap,
waste scrap, steel turnings, bales made of new light
sheet scrap and new scrap. The scrap list is neither
internationally recognised nor standardised.

Tantalum Tool steel


Chemical element, Ta, density 16.6 g/cm³, melting Stainless steel of high durability, high corrosion
point: 2,995 +/- 25°C. Greyish white, ductile metal resistance and high toughness suitable for tool
with a high chemical stability at room temperature. Is making. It must also be able to adjust to wide ranges
used in its pure form, or as an alloyed additive, for of temperature change. Tool steel is characterised
heavy duty parts. Used with Niobium (Nb) as a as cold forming steel (i.e. non-alloyed or low alloyed
stabiliser in chemically resistant steels and as for surface work at temperatures of less than
tantalum carbide for use in carbides. 200°C), hot-work steel and high speed steel. DIN
17350.
Titanium
Chemical element, Ti, density 4.5 g/cm³ (light metal). Tungsten
Ti, with its alloys, is to be found in apparatus and Chemical element W, density 19.3 g/cm. Grey,
aeroplane assembly thanks to its firmness, low robust metal, resistant to chemical attacks at room
density and high corrosion resistance. Ti is a much temperature. W is extremely hard with high
used alloy (stabilises steel and stainless temperature strength. It is a valuable alloy for steel
construction steel). In austenitic non rust steel it as it increases corrosion resistance. With cementite
binds the carbon so preventing its separation. it forms carbide, type M3C and M6C. W is especially
Titanium carbides are found in hard wearing stellite good for tool steel, providing a good cutting edge,
types. Titanium oxide (rutile) is used as a welding and for permanent magnets. Because of its
additive. hardness it is fated to be a hard metal alloy.

Tungsten carbide
Is one of the most important components of hard
metal alloys.

VANADIUM
Chemical element V, density: 6.07 g/cm³. Ductile silvery white metal. In steel V. has the following impact:
increases tensile strength, yield and high temperature strength, decreases brittleness. V. produces fine grain
material and makes steel impervious to overheating.

Yield
Ratio (in %) of utilisable material to deployed material, e.g. the yield of a smelting oven in total or of an added
alloyed element or a rolling mill (of applied weight).

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