Hohenstein Laboratories Bangladesh •122/1 Love Road • Tejgaon I/A •Dhaka-1208 Hohenstein Laboratories Bangladesh Limited

122/1 Love Road • Tejgaon Industrial Area

Sam Ree Dyeing (BD) Ltd. Dhaka-1208 • Bangladesh
Ghorashal, palash, Narshingdi .
Dhaka- 1613, Bangladesh

Textile Testing
Phone: +8809611004100
Fax: +888879289
J.Kanta@hohenstein.com

Client no. Contact person Our ref. Date

Kanta, Johny Yasmin sbu/fah 24.10.2020

Report no. 20.0.33467

Client : Sam Ree Dyeing (BD) Ltd.
Contact person : Md.Perves Rana
Phone: 01684438386
E-mail: admin.dept1@samreedyeing.com
Date of ord er : 06.10.2020
Sam ple Pick Up date : 13.10.2020
The following sample was collected by : Hohenstein laboratories Bangladesh Ltd.
Test sample Description : 1.1) After Treatment water, 2.1) sludge.

O n-site Effluent Treatm ent Plant (ETP) : Yes

Period of testing : 14.10.2020 to 24.10.2020

The report comprises 15 pages.

Our terms of business shall apply: Phone VAT REG No. Hohenstein Textile Testing Institute GmbH & Co. KG · County Court Stuttgart HRA 723464
www.hohenstein.de/pdf/agb_e.pdf +49 7143 271 0 DE262079343 Personally liable associate: Hohenstein Verwaltungs GmbH · County Court Stuttgart HRB 752904
Fax +49 7143 271 51 CEO: Dr. Stefan Droste · Company Headquarter is Boennigheim
Report No. 20.0.33467
Page 2 of 15 pages

Analytical report on the analysis of wastewater and Sludge samples according to STeP by OEKO-TEX® (Edition
02.2020) .

Sample Description
Order No.: NA Person in charge of sampling: Md. Jahirul islam
Customer: Sam Ree Dyeing (BD) Ltd Date of sampling: 13/10/2020
Contact person Md.Perves Rana On-site Effluent Treatment Plant (ETP): Yes

Wastewater sample 1.1

Sampling time: ☐ a.m. ☒ p.m. cross check sample taken by customer ☐ yes ☒ no
12 to 5 pm
Test sample Description: Outlet Wastewater (after treatment) at discharge point
State of sample / Odour at sampling: No odor Colour impression: blackish
Turbidity (visual impression): blackish Odour: No odor
Discharge Mode Direct discharge to environment (River)
Factory Type Dyeing & washing
Sludge sample 2.1
Sampling time: ☐ a.m. ☒ p.m. cross check sample taken by customer ☐ yes ☒ no
12 -5.00 pm
Test sample Description: 2.1 Sludge
State of sample / Odour at sampling: Odor Colour impression: reddish Look: slightly dull
Turbidity (visual impression): NA Odor Slightly musty
Discharge Mode Direct discharge to river
Factory Type Dyeing & washing

NA: not applicable

Report No. 20.0.33467
Page 3 of 15 pages

Photo of sampling Points

ETP plant O utlet Sa m pling Point (After Treatment)

Photo of Samples:

Outlet Sample Picture Sludge Sample Picture

Report No. 20.0.33467
Page 4 of 15 pages

Analytical Test Report:

Conventional parameters:

Limit values according to DETOX TO ZERO Sample Results

Conventional MRSL [mg/L]
Method
parameters Before After
Minimum Advanced Excellent Inlet
Treatment Treatment
Temperature [°C] DIN 38404-4 ∆15/ max. 35 ∆10 or 30 ∆5 or 25 -: -: -:
Total suspended ISO 11923 and DIN -:
100 mg/l 50 mg/l 15 mg/l -: -:
solids (TSS) 38409-1
LCK1014 COD Cuvette -:
COD 150 80 40 -: -:
test; (ISO 6060)
LCK138 LATON Cuvette -:
Total-N 20 mg/l 10 mg/l 5 mg/l -: -:
test; (ISO 11905-1)
pH value ISO 10523 6.0-9.0 6.5-8.5 7.0-8.0 -: -: -:

Colour (436 nm) 10 7 5 -: -: -:

Colour (525 nm) ISO 7887 7 5 3 -: -: -:

Colour (620 nm) 5 3 1 -: -: -:

LCK555 BOD5/BOD[n]
BOD5 50 25 15 -: -: -:
Cuvette test; (EN 1899-1)
LCK303 Ammonium
Ammonia as NH4-N Cuvette test; (ISO 7150- 10 mg/l 1 mg/l 0.5 mg/l -: -: -:
1)
Digestion and
Total-Phosphorus Determination by ICP-MS 5 mg/l 2.5 mg/l 0.5 mg/l -: -: -:
(DIN EN ISO 17294-2)
LCK390 AOX Cuvette -:
AOX 1 mg/l 0.50 mg/l 0.10 mg/l -: -:
test; (DIN EN ISO 9562)
Gravimetric
determination of hexane
HEM -:
extractable substances 10 mg/l 2 mg/l 0.5 mg/l -: -:
(oil and grease)
(EPA Method 1664
Revision B)
0.001 -:
Phenol-Index ISO 14402 0.5 mg/l 0.01 mg/l -: -:
mg/l

Persistent Foam - Not visible -: -: -:

Limit values according to DETOX TO ZERO Sample Results

Conventional MRSL [mg/L]
Method
parameters Before After
Minimum Advanced Excellent Inlet
Treatment Treatment
*Coliform according to DIN EN ISO to be -: -: -:
to be tested to be tested
[bacteria/100 mL] 9308-1 tested
-: test not conducted; n.d.: not determinable * Note: Test Subcontract at ISO 17025:2017 Accreditated Lab.

Limit values according to DETOX TO ZERO Sample Results

Anions Method MRSL [mg/L]
Before After
Minimum Advanced Excellent Inlet
Treatment Treatment
LCK315 Cyanide Cuvette -: -:
Cyanide to be tested to be tested to be tested n.d
test; (ISO 6703-2)
Sulphides (as S2) ISO 10530 to be tested to be tested to be tested -: -: 0.036
LCK654 Sulfite (SO32-) to be tested to be tested to be tested -: -: -:
Sulfite
Cuvette test

-: test not conducted; n.d.: not determinable

Report No. 20.0.33467
Page 5 of 15 pages

Conventional parameters: (sludge)

Anions Method LOQ Reporting Limit Sample Results

Micro Dist distillation/LCK 315

Cyanide 0.2 mg/kg 1 mg/kg n.d
(equates to DIN ISO 11262)

MRSL parameters

Alkyplphenol (AP) and Alkylphenol Ethoxylates (APEOs)

Method DIN EN 18254-1:2016 (modified LC-MS/MS determination)
LOQ 1.0 µg/l (wastewater) ; 0.4 mg/kg for sludge
Limit values Limit values
according to according to DETOX
Sample Results
DETOX TO TO ZERO MRSL for
Substances CAS-No. ZERO MRSL Sludge
for
Wastewater 1.1 Wastewater 2.1 Sludge

various
11066-49-2
Nonylphenol, 25154-52-3
-: -:
(n-nonyl and iso-nonyl) 104-40-5
90481-04-2
84852-15-3
various
Octylphenol, 140-66-9
(n-octyl and iso-octyl) -: -:
27193-28-8
1806-26-4
5.0 µg/l 0.4 mg/kg
various
9016-45-9
Nonylphenolethoxylates -: -:
26027-38-3
(NPEO)
68412-54-4
(n-nonyl and iso-nonyl)
127087-87-0
37205-87-1
various
Octylphenolethoxylates 9002-93-1 -: -:
(OPEO) (n-octyl and iso-octyl) 9036-19-5
68987-90-6
-: test not conducted; n.d.: not determinable; LOQ: Limit of quantitation

Phthalates
Method Reference - ISO 18856 (modified: solvent extraction, GC-MS/MS determination)
LOQ 2.0 µg/l (wastewater) ; 2 mg/kg for sludge
Limit values Sample Results
according to Limit values
DETOX TO according to
Substances CAS-No. ZERO MRSL DETOX TO ZERO
for MRSL for 1.1 Wastewater 2.1 Sludge
Wastewater sludge

Dibutylphthalate (DBP) 84-74-2 n.d n.d

Di(2-ethylhexyl) phthalate (DEHP) 117-81-7 n.d n.d
Benzylbutylphthalate (BBP) 85-68-7 n.d n.d
- -
28553-12-0 n.d n.d
Di-isononyl phthalate (DINP)
68515-48-0
Di-n-octylphthalate (DNOP) 117-84-0 n.d n.d
Report No. 20.0.33467
Page 6 of 15 pages

26761-40-0 n.d n.d

Di-iso-decylphthalate (DiDP)
68515-49-1
Di-isobutylphthalate (DIBP) 84-69-5 n.d n.d
Di-n-hexylphthalate (DHP) 84-75-3 n.d n.d
Di-(2-methoxyethyl) phthalate n.d n.d
117-82-8
(DMEP)
Di-C7-11-branched and linear alkyl n.d n.d
68515-42-4
esters (DHNUP)
Di-n-pentylphthalate (DPP) 131-18-0 n.d n.d
Di-iso-pentylphthalate (DPP) 605-50-5 n.d n.d
Dipentylphthalate, branched and n.d n.d
84777-06-0
linear (DPP)
Di-C6-8-branched alkyl esters, C7-rich n.d n.d
71888-89-6
(DIHP)
Di-n-propylphthalate (DPrP) 131-16-8 n.d n.d
Di-iso-octylphthalate (DIOP) 27554-26-3 n.d n.d
Di-iso-hexylphthalate (DIHxP) 71850-09-4 n.d n.d
Di-cyclohexylphthalate (DCHP) 84-61-7 n.d n.d
Diethylphthalate (DEP) 84-66-2 n.d n.d
Di-n-nonylphthalate (DNP) 84-76-4 n.d n.d
Dimethylphthalate ( DMP) 131-11-3 n.d n.d
Dihexylphthalate, branched and linear n.d n.d
68515-50-4
( DHxP)
Iso-pentyl-n-pentylphthalate ( DPP) 776297-69-9 n.d n.d
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation

Flame Retardants
Reference - DIN EN ISO 22032:2009-07 (modified, solvent extraction, GC-MS/MS or HPLC-
Method
MS/MS determination)
LOQ 1.0 µg/l (wastewater) ; 0.03 mg/kg for sludge
Sample Results
Limit values
Limit values
according to
according to
DETOX TO
Substances CAS-No. DETOX TO ZERO
ZERO MRSL 1.1 Wastewater 2.1 Sludge
MRSL for
for wastewater
sludge

Polybromobiphenyls (PBBs) 59536-65-1 n.d n.d

Monobromobiphenyls (MonoBB) various n.d n.d
Dibromobiphenyls (DiBB) various n.d n.d
Tribromobiphenyls (TriBB) various n.d n.d
Tetrabromobiphenyls (TetraBB) various n.d n.d
Pentabromobiphenyls (PentaBB) various n.d n.d
Hexabromobiphenyls (HexaBB) various - - n.d n.d
Heptabromobiphenyls (HeptaBB) various n.d n.d
Octabromobiphenyls (OctaBB) various n.d n.d
Nonabromobiphenyls (NonaBB) various n.d n.d
n.d n.d
Decabromobiphenyl (DecaBB) 13654-09-6
Polybrominated diphenyl ethers n.d n.d
various
(PBDEs)
Monobromodiphenylethers n.d n.d
various
(MonoBDEs) - -
Dibromodiphenylethers (DiBDEs) various n.d n.d
Tribromodiphenylethers (TriBDEs) various n.d n.d
Tetrabromodiphenylethers Various n.d n.d
(TetraBDEs) 40088-47-9
Pentabromodiphenylethers Various n.d n.d
(PentaBDEs) 32534-81-9
Hexabromodiphenylethers Various n.d n.d
(HexaBDEs) 36483-60-0
Heptabromodiphenylether, n.d n.d
Various
Heptabromodiphenylethers
68928-80-3
(HeptaBDEs)
Octabromodiphenylether various n.d n.d
Report No. 20.0.33467
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(OctaBDEs) 32536-52-0
Nonabromodiphenylether various n.d n.d
(NonaBDEs) 63936-56-1
Decabromodiphenylether n.d n.d
1163-19-5
(DecaBDE)
n.d n.d
Tris-(2,3-dibromopropyl)phosphate
126-72-7
(TRIS)
Tris(2-chloroethyl)phosphate n.d n.d
115-96-8
(TCEP)
3194-55-6 n.d n.d
Hexabromocyclododecane 134237-50-6
(HBCDD) and all main diastereomeres 134237-51-7 - -
identified (α-, β-, γ-) 134237-52-8
25637-99-4
Tetrabromo-bisphenol A (TBBPA) 79-94-7 n.d n.d
Bis(2,3-dibromopropyl)phosphate n.d n.d
5412-25-9
(BIS)
2,2-Bis(bromomethyl)-1,3-propanediol n.d n.d
3296-90-0
(BBMP)
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation

Other Flame Retardants

Reference - DIN EN ISO 22032:2009-07 (modified, solvent extraction, GC-MS/MS or HPLC-
Method
MS/MS determination)
LOQ 0.5 µg/l (wastewater) ; 0.25 mg/kg for sludge
Limit values Sample Results
Limit values
according to
according to
DETOX TO ZERO
Substances CAS-No. DETOX TO
MRSL for 1.1 Wastewater 2.1 Sludge
ZERO MRSL
sludge
Wastewater
Tris(1,3-dichloro-isopropyl)phosphate n.d n.d
13674-87-8
(TDCPP)
Tris-(aziridinyl)-phosphine oxide) n.d n.d
545-55-1
(TEPA)
Flame retardants which contain toxic n.d n.d
various
metals like antimony or arsenic
10043-35-3 n.d n.d
Boric acid
11113-50-1
Diboron trioxide 1303-86-2 n.d n.d
1303-69-4 - - n.d n.d
Disodium tetraborate, anhydrous 1330-43-4
12179-04-3
Tetraboron disodium heptaoxide, n.d n.d
12267-73-1
hydrate
Antimony trioxide 1309-64-4 n.d n.d

n.d n.d
Tri-o-cresyl phosphate 78-30-8
Trixylyl phosphate 25155-23-1 n.d n.d
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation

Arylamines (Azo)
Method DIN EN ISO 14362-1 and DIN EN ISO 14362-3 (both modified; HPLC-MS/MS determination)
LOQ 0.1 µg/l (wastewater) ; 0.2 mg/kg for sludge
Limit values
Limit values
according to
according to
DETOX TO ZERO Sample Results
Substances CAS-No. DETOX TO ZERO
MRSL for
MRSL for
Sludge
wastewater
1.1 Wastewater 2.1 Sludge
4-Aminobiphenyl; 4-Aminodiphenyl 92-67-1 -: -:
Benzidine 92-87-5 -: -:
- -
4-Chloro-o-toluidine 95-69-2 -: -:
2-Naphthylamine 91-59-8 -: -:
Report No. 20.0.33467
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o-Aminoazotoluene -: -:
97-56-3
(C.I. Solvent Yellow 3, C.I. 11160)
2-Amino-4-nitrotoluidine 99-55-8 -: -:
4-Chloroaniline 106-47-8 -: -:
2,4-Diaminoanisole 615-05-4 -: -:
4,4’-Diaminodiphenylmethane 101-77-9 -: -:
3,’3-Dichlorobenzidine 91-94-1 -: -:
3,3’-Dimethoxybenzidine 119-90-4 -: -:
3,3’-Dimethylbenzidine 119-93-7 -: -:
4,4’-Methylenedi-o-toluidine 838-88-0 -: -:
p-Cresidine, 6-methoxy-m-toluidine 120-71-8 -: -:
4,4’-Methylene-bis-(2-chloro-aniline) 101-14-4 -: -:
4,4’-Oxydianiline 101-80-4 -: -:
4,4’-Thiodianiline 139-65-1 -: -:
o-Toluidine 95-53-4 -: -:
2,4-Tolylendiamine 95-80-7 -: -:
2,4,5-Trimethylaniline 137-17-7 -: -:
o-Anisidine (2-Methoxyaniline) 90-04-0 -: -:
C.I. Solvent Yellow (4- -: -:
60-09-3
Aminoazobenzene)
2,4-Xylidine 95-68-1 -: -:
2,6-Xylidine 87-62-7 -: -:
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation, -: test not conducted

Carcinogenic Dyes
Method Reference – DIN 54231, HPLC-MS/MS determination
LOQ 0.1 µg/l (wastewater) ; 0.1 mg/kg for sludge
Limit values Sample Results
Limit values
according to
according to
Substances CAS-No. DETOX TO
DETOX TO 1.1 Wastewater 2.1 Sludge
ZERO MRSL
ZERO MRSL
for wastewater
C.I. Acid Red 26 (C.I. 16150) 3761-53-3 n.d n.d
C.I. Acid Red 114 6459-94-5 n.d n.d
C.I. Acid Violet 49 1694-09-3 n.d n.d
C.I. Basic Blue 26 2580-56-5 n.d n.d
C.I. Basic Red 9 (C.I. 42500) 569-61-9 n.d n.d
C.I. Basic Violet 1 8004-87-3 n.d n.d
C.I. Basic Violet 14 (C.I. 42510) 632-99-5 n.d n.d
C.I. Direct Black 38 (C.I. 30235) 1937-37-7 n.d n.d
C.I. Direct Blue 6 (C.I. 22610) 2602-46-2 n.d n.d
C.I. Direct Blue 15 2429-74-5 n.d n.d
C.I. Direct Blue 218 28407-37-6 n.d n.d
C.I. Direct Brown 95 16071-86-6 n.d n.d
- -
C.I. Direct Red 28 (C.I. 22120) 573-58-0 n.d n.d
C.I. Disperse Blue 1 (C.I. 64500) 2475-45-8 n.d n.d
C.I. Disperse Orange 11 82-28-0 n.d n.d
C.I. Disperse Orange 149 85136-74-9 n.d n.d
C.I. Disperse Yellow 3 (C.I. 11855) 2832-40-8 n.d n.d
C.I. Solvent Yellow 1 60-09-3 n.d n.d
C.I. Solvent Yellow 2 (C.I. 11020) 60-11-7 n.d n.d
C.I. Solvent Yellow 14 842-07-9 n.d n.d
Lead chromate molybdate sulphate n.d n.d
12656-85-8
red (C.I. Pigment Red 104)
Lead sulfochromate yellow (C.I. n.d n.d
1344-37-2
Pigment Yellow 34
C.I. basic Green 4 (Chloride) 569-64-2 n.d n.d
C.I. basic Green 4 (free) 10309-95-2 - - n.d n.d
C.I. basic Green 4 (Oxalate) 2437-29-8 n.d n.d
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation
Report No. 20.0.33467
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Disperse Dyes
Method Reference - DIN 54231, HPLC-MS/MS determination
LOQ 1.0 µg/l (wastewater) ; 2.0 mg/kg for sludge
Limit values
Limit values
according to
according to
DETOX TO ZERO Sample Results
Substances CAS-No. DETOX TO ZERO
MRSL for
MRSL for
sludge
Wastewater
1.1 Wastewater 2.1 Sludge
C.I. Disperse Blue 1 (C.I. 64500) 2475-45-8 n.d n.d
C.I. Disperse Blue 3 (C.I. 61505) 2475-46-9 n.d n.d
C.I. Disperse Blue 7 (C.I. 62500) 3179-90-6 n.d n.d
C.I. Disperse Blue 26 (C.I. n.d n.d
3860-63-7
63305)
C.I. Disperse Blue 35 12222-75-2 - - n.d n.d
C.I. Disperse Blue 35 n.d n.d
56524-77-7
(Component 1)
C.I. Disperse Blue 35 n.d n.d
56524-76-6
(Component 2)
C.I. Disperse Blue 102 12222-97-8 n.d n.d
C.I. Disperse Blue 106 12223-01-7 n.d n.d
C.I. Disperse Blue 124 61951-51-7 n.d n.d
C.I. Disperse Brown 1 23355-64-8 n.d n.d
C.I. Disperse Orange 1 (C.I. n.d n.d
2581-69-3
11080)
C.I. Disperse Orange 3 (C.I. n.d n.d
730-40-5
11005)
C.I. Disperse Orange 37/59/76 n.d n.d
13301-61-6
(C.I. 11132)
C.I. Disperse Orange 149 85136-74-9 n.d n.d
C.I. Disperse Red 1 (C.I. 11110) 2872-52-8 n.d n.d
C.I. Disperse Red 11 (C.I. n.d n.d
2872-48-2 -
62015) -
C.I. Disperse Red 17 (C.I. n.d n.d
3179-89-3
11210)
C.I. Disperse Yellow 1 (C.I. n.d n.d
119-15-3
10345)
C.I. Disperse Yellow 3 (C.I. n.d n.d
2832-40-8
11855)
C.I. Disperse Yellow 9 6373-73-5 n.d n.d
C.I. Disperse Yellow 23 (C.I. n.d n.d
6250-23-3
26070)
C.I. Disperse Yellow 39 12236-29-2 n.d n.d
C.I. Disperse Yellow 49 54824-37-2 n.d n.d
C.I. Solvent Yellow 3 97-56-3 n.d n.d
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation

Organotin Compounds
Method Reference DIN EN ISO 23161 (GC-MS/MS determination)
LOQ 0.01 µg/l (wastewater) ; 0.2 mg/kg for sludge
Limit values Limit values
according to according to
Sample Results
Substances CAS-No. DETOX TO DETOX TO
ZERO MRSL ZERO MRSL
Wastewater 1.1 Wastewater 2.1 Sludge
Tetrabutyltin (TeBT) 1461-25-2 n.d n.d
Tributyltin (TBT) various n.d n.d
Various n.d n.d
Dibutyltin (DBT)
683-18-1
Monobutyltin (MBT) various n.d n.d
Various - - n.d n.d
Triphenyltin (TPhT)
668-34-8
Various n.d n.d
Diphenyltin (DPhT)
1011-95-6
Dioctyltin (DOT) various n.d n.d
Monooctyltin (MOT) various n.d n.d
Report No. 20.0.33467
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Tricyclohexyltin (TCyhT) various n.d n.d

Tripropyltin (TPT) various n.d n.d
Tetraethyltin (TeET) 597-64-8 n.d n.d
Bis(tributyltin) oxide (TBTO) 56-35-9 n.d n.d
Dibutyltin hydrogen borate 75113-37-0 n.d n.d
Trimethyltin (TMT) various n.d n.d
Triocthyltin (TOT) various n.d n.d
Dimethyltin (DMT) 753-73-1 n.d n.d
Monphenyltin (MPhT) 1124-19-2 n.d n.d
Monomethyltin (MMT) 993-16-8 n.d n.d
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation

Perfluorinated Compounds (PFCs)

Method DIN 38414-14, HPLC-MS/MS determination)
LOQ 0.01 µg/l (wastewater) ; 0.1 mg/kg for sludge
Limit values Limit values
according to according to
DETOX TO DETOX TO Sample Results
Substances CAS-No.
ZERO MRSL ZERO MRSL
for for sludge
Wastewater 1.1 Wastewater 2.1 Sludge
Perfluorobutanoic Acid (PFBA) and Various n.d n.d
- -
salts 375-22-4
Perfluoropentanoic Acid (PFPeA) and Various n.d n.d
- -
salts 2706-90-3
Perfluorohexanoic Acid (PFHxA) and Various n.d n.d
- -
salts 307-24-4
Perfluoroheptanoic Acid (PFHpA) and Various n.d n.d
- -
salts 375-85-9
7H-Perfluoroheptanoic Acid Various n.d n.d
- -
(7HPFHpA) and salts
Various n.d n.d
HPFHpA, and salts - -
1546-95-8
Perfluorooctanoic Acid (PFOA) and Various n.d n.d
50 µg/l 0.1 mg/kg
salts 335-67-1
Perfluoro-3,7-dimethyloctanoic Various n.d n.d
- -
acid (PF-3,7-DMOA) and salts 172155-07-6
Perfluorononanoic Acid (PFNA) and Various n.d n.d
- -
salts 375-95-1
Perfluorodecanoic Acid (PFDA) and Various n.d n.d
- -
salts 335-76-2
Perfluoroundecanoic Acid (PFUdA) Various n.d n.d
- -
and salts 2058-94-8
2H,2H,3H,3HPerfluoroundecanoic Various n.d n.d
- -
acid (4HPFUnA) and salts 34598-33-9
Tricosafluorododecanoic acid n.d n.d
Various
(Perfluorododecanoic Acid PFDoA) - -
307-55-1
and salts
Pentacosafluorotridecanoic acid n.d n.d
Various
(Perfluorotridecanoic Acid PFTrDA) - -
72629-94-8
and salts
Heptacosafluorotetradecanoic acid n.d n.d
Various
Perfluorotetradecanoic Acid (PFTeDA) - -
376-06-7
and salts
Various n.d n.d
Perfluorobutansulfonate (PFBS) and
375-73-5 - -
salts
599933-66-3
Perfluorohexansulfonate (PFHxS) and Various n.d n.d
- -
salts 355-46-4
Perfluoroheptansulfonate (PFHpS) Various n.d n.d
- -
and salts 375-92-8
Perfluorooctansulfonate (PFOS) and various n.d n.d
10 µg/l 0.1 mg/kg
salts 1763-23-1
Report No. 20.0.33467
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n.d n.d
1H,1H,2H,2H-Perfluorooctane
27619-97-2
sulfonic acid (1H,1H,2H,2H-PFOS) - -
307-35-7
and salts
Perfluoro-1-octanesulfonamide n.d n.d
754-91-6 - -
(PFOSA)
N-Methyl perfluorooctane n.d n.d
31506-32-8 - -
sulfonamide (N-Me-FOSA)
N-Ethyl perfluorooctane n.d n.d
4151-50-2 - -
sulfonamide (N-Et-FOSA)
N-Methyl perfluorooctane n.d n.d
sulfonamide ethanol (N-Me- 24448-09-7 - -
FOSE)
N-Ethyl perfluorooctane n.d n.d
sulfonamide ethanol (N-Et- 1691-99-2 - -
FOSE)
Henicosafluorodecane sulfonic n.d n.d
Various
acid (Perfluorodecane sulfonic - -
335-77-3
acid, PFDS) and salts

Method DIN 38402 Part 51 (modified: solvent extraction, GC-MS/MS determination)

LOQ 1 µg/l (wastewater) ; 1 mg/kg for sludge
Limit values Limit values Sample Results
according to according to
DETOX TO DETOX TO
Substances CAS-No.
ZERO MRSL ZERO MRSL 1.1 Wastewater 2.1 Sludge
for for sludge
Wastewater
1H,1H,2H,2H-perfluoro-1-hexanol n.d n.d
2043-47-2 - -
(4:2 FTOH)
1H,1H,2H,2H-perfluoro-1-octanol n.d n.d
647-42-7 - -
(6:2 FTOH)
1H,1H,2H,2H-perfluoro-1-decanol n.d n.d
678-39-7 - -
(8:2 FTOH)
1H,1H,2H,2H-perfluorooctylacrylate n.d n.d
17527-29-6 - -
(6:2 FTA)
1H,1H,2H,2H-perfluorodecylacrylate n.d n.d
27905-45-9 - -
(8:2 FTA)
1H,1H,2H,2H- n.d n.d
17741-60-5 - -
perfluorododecylacrylate (10:2 FTA)
1H,1H,2H,2H-Perfluoro-1-dodecanol n.d n.d
865-86-1 - -
(10:2 FTOH)
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation

Chlorobenzenes and Chlorotoluenes

Method DIN EN 17137:2019-02 (modified solvent extraction, GC-MS/MS determination)
LOQ 0.1 µg/l (wastewater) ; 0.2 mg/kg for sludge
Limit values Sample Results
Limit values
according to
according to
Substances CAS-No. DETOX TO ZERO
DETOX TO ZERO 1.1 Wastewater 2.1 Sludge
MRSL for
MRSL for sludge
Wastewater
Chlorobenzene 108-90-7 n.d n.d
1,2-Dichlorobenzene 95-50-1 n.d n.d
1,3-Dichlorobenzene 541-73-1 n.d n.d
1,4-Dichlorobenzene 106-46-7 0.62 µg/l n.d
1,2,3-Trichlorobenzene 87-61-6 n.d n.d
1,2,4-Trichlorobenzene 120-82-1 n.d n.d
1,3,5-Trichlorobenzene 108-70-3 n.d n.d
- -
Tetrachlorobenzene 12408-10-5 n.d n.d
1,2,3,4-Tetrachlorobenzene 634-66-2 n.d n.d
1,2,3,5-Tetrachlorobenzene 634-90-2 n.d n.d
1,2,4,5-Tetrachlorobenzene 95-94-3 n.d n.d
Pentachlorobenzene 608-93-5 n.d n.d
Hexachlorobenzene 118-74-1 n.d n.d
Chlorotoluene Various n.d n.d
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2-Chlorotoluene 95-49-8 n.d n.d

3-Chlorotoluene 108-41-8 n.d n.d
4-Chlorotoluene 106-43-4 n.d n.d
2,3-Dichlorotoluene 32768-54-0 n.d n.d
2,4-Dichlorotoluene 95-73-8 n.d n.d
2,5-Dichlorotoluene 19398-61-9 n.d n.d
2,6-Dichlorotoluene 118-69-4 n.d n.d
3,4-Dichlorotoluene 95-75-0 n.d n.d
3,5-Dichlorotoluene 25186-47-4 n.d n.d
2,3,6-Trichlorotoluene 2077-46-5 n.d n.d
2,3,4-Trichlorotoluene 7359-72-0 n.d n.d
2,4,5-Trichlorotoluene 6639-30-1 n.d n.d
2,4,6-Trichlorotoluene 23749-65-7 n.d n.d
3,4,5-Trichlorotoluene 21472-86-6 n.d n.d
α, α, α-Trichlorotoluene 98-07-7 n.d n.d
α ,2,4-Trichlorotoluene 94-99-5 n.d n.d
α ,2,6-Trichlorotoluene 2014-83-7 n.d n.d
α ,3,4-Trichlorotoluene 102-47-6 n.d n.d
α, α,2,6-Tetrachlorotoluene 81-19-6 n.d n.d
2,3,4,5-Tetrachlorotoluene 76057-12-0 n.d n.d
α, α, α,2-Tetrachlorotoluene 2136-89-2 n.d n.d
α, α, α,4-Tetrachlorotoluene 5216-25-1 n.d n.d
2,3,4,5,6-Pentachlorotoluene 877-11-2 n.d n.d
2,3,4,6-Tetrachlorotoluene 875-40-1 n.d n.d
2,3,5,6-Tetrachlorotoluene 29733-70-8 n.d n.d
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation

Chlorinated and other Solvents

Method ISO 20595 (modified: Headspace GC-MS)
LOQ 1.0 µg/l (wastewater) ; 2.0 mg/kg for sludge
Limit values Limit values
according to according to
Sample Results
Substances CAS-No. DETOX TO ZERO DETOX TO ZERO
MRSL for MRSL for sludge
Wastewater 1.1 Wastewater 2.1 Sludge
Dichloromethane 75-09-2 n.d n.d
Trichloromethane (Chloroform) 67-66-3 n.d n.d
Tetrachloromethane n.d n.d
56-23-5
(Carbontetrachloride)
Chlorinated ethanes and ethenes Various n.d n.d
1,1,2-Trichloroethane 79-00-5 n.d n.d
1,1-Dichloroethane 75-34-3 n.d n.d
1,2-Dichloroethane 107-06-2 n.d n.d
Trichloroethylene 79-01-6 n.d n.d
- -
Tetrachloroethylene 127-18-4 n.d n.d
1,1,1-Trichloroethane 71-55-6 n.d n.d
1,1,1,2-Tetrachloroethane 630-20-6 n.d n.d
1,1,2,2-Tetrachloroethane 79-34-5 n.d n.d
Pentachloroethane 76-01-7 n.d n.d
75-35-4 n.d n.d
1,1-Dichloroethylene
(Various)
1,2,3-Trichloropropane 96-18-4 n.d n.d
Hexachlorobutadiene 87-68-3 n.d n.d
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation

Other VOCs
Method ISO 20595 (modified: SPE enrichment with GC-MS determination or Headspace GC-MS)
LOQ 1.0 µg/l (wastewater) ; 2.0 mg/kg for sludge
Limit values Limit values
according to DETOX according to DETOX
Sample Results
Substances CAS-No. TO ZERO MRSL for TO ZERO MRSL for
Wastewater sludge
1.1 Wastewater 2.1 Sludge
Methyl-ethyl-ketone 78-93-3 - - n.d n.d
Benzene 71-43-2 - - n.d n.d
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Toluene 108-88-3 - - n.d n.d

Ethylbenzene 100-41-4 - - n.d n.d
Xylene 1330-20-7 - - n.d n.d
Styrene 100-42-5 - - n.d n.d
Cyclohexanone 108-94-1 - - n.d n.d
2-Ethoxyethyl acetate 111-15-9 - - n.d n.d
Acetophenone 98-86-2 - - n.d n.d
N,N-Dimethylformamide - - n.d n.d
68-12-2
(DMAc)
1-Methyl-2-pyrollidone (NMP) 872-50-4 - - n.d n.d
2-Phenyl-2-propanole 617-94-7 - - n.d n.d
Bis(2-methoxyethyl)-ether 111-96-6 - - n.d n.d
N,N-Dimethylacetamide (DMF) 127-19-5 - - n.d n.d
2-Ethoxyethanol 110-80-5 - - n.d n.d
2-Methoxyethanol 109-86-4 - - n.d n.d
2-Methoxyethylacetate 110-49-6 - - n.d n.d
2-Methoxypropylacetate 70657-70-4 - - n.d n.d
Ethylene glycol dimethyl ether - - n.d n.d
110-71-4
(EGDME)
Triethylene glycol dimethyl - - n.d n.d
112-49-2
ether (TEGDME, trigyme)
Formamide 75-12-7 - - n.d n.d
o-Xylene 95-47-6 - - n.d n.d
m-Xylene 108-38-3 - - n.d n.d
p-Xylene 106-42-3 - - n.d n.d
o-Cresole 95-48-7 - - n.d n.d
m-Cresole 108-39-4 - - n.d n.d
p-Cresole 106-44-5 - - n.d n.d
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation

Chlorinated phenols
Method Reference- DIN EN 12673 (solvent extraction, GC-MS/MS determination)
LOQ 0.5 µg/l (wastewater) ; 0.05 mg/kg for sludge
Limit values
according to Limit values
Substances CAS-No. DETOX TO ZERO according to
1.1 Wastewater 2.1 Sludge
MRSL for DETOX TO ZERO
Wastewater MRSL for sludge
Pentachlorophenol (PCP) 87-86-5 -: -:
Tetrachlorophenols 25167-83-3 -: -:
2,3,4,5-Tetrachlorophenol 4901-51-3 -: -:
2,3,4,6-Tetrachlorophenol 58-90-2 -: -:
2,3,5,6-Tetrachlorophenol 935-95-5 -: -:
Trichlorophenols 25167-82-2 -: -:
2,4,6-Trichlorophenol 88-06-2 -: -:
2,3,4-Trichlorophenol 15950-66-0 -: -:
2,3,5-Trichlorophenol 933-78-8 -: -:
2,3,6-Trichlorophenol 933-75-5 -: -:
2,4,5-Trichlorophenol 95-95-4 -: -:
3,4,5-Trichlorophenol 609-19-8 -: -:
Dichlorophenols 25167-81-1 - - -: -:
2,3-Dichlorophenol 576-24-9 -: -:
2,4-Dichlorophenol 120-83-2 -: -:
2,5-Dichlorophenol 583-78-8 -: -:
3,4-Dichlorophenol 95-77-2 -: -:
3,5-Dichlorophenol 591-35-5 -: -:
2,6-Dichlorophenol 87-65-0 -: -:
Monochlorphenols various -: -:
2-Chlorophenol 95-57-8 -: -:
3-Chlorophenol 108-43-0 -: -:
4-Chlorophenol 106-48-9 -: -:
Salts and Esters from the above -: -:
various
mentioned Chlorophenols

- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation, -: test not conducted
Report No. 20.0.33467
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Chlorinated Paraffines
Method DIN EN ISO 12010 (solvent extraction, GC-NCI-MS/MS determination)
LOQ 5 µg/l (wastewater) ; 1 mg/kg for sludge
Limit values
Limit values
according to
according to
DETOX TO ZERO Sample Results
Substances CAS-No. DETOX TO ZERO
MRSL for
MRSL for
sludge
Wastewater
1.1 Wastewater 2.1 Sludge
Short-chain chlorinated Paraffins n.d n.d
85535-84-8
(SCCP) (C10-C13)
- -
Middle chained chlorinated n.d n.d
85535-85-9
paraffines (MCCP), C14-17

- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation

Heavy Metals
Method Digestion and Determination by ICP-MS ( DIN EN ISO 17294-2 )
Sample Results
Limit values Limit values
according to DETOX according to
Substances CAS-No.
TO ZERO MRSL for DETOX TO ZERO 1.1 Wastewater 2.1 Sludge
Wastewater and MRSL for sludge
LOQ and LOQ
Cadmium (Cd) 7440-43-9 100 µg/l /0.1 µg/l - / 2 mg/kg -: -:
Lead (Pb) 7439-92-1 100 µg/l /1.0 µg/l - / 2 mg/kg -: -:
Mercury (Hg) 7439-97-6 10 µg/l /0.05 µg/l - / 0.2 mg/kg -: -:
Page 14 of 15 pages

Nickel (Ni) 7440-02-0 200 µg/l /1.0 µg/l - / 2 mg/kg -: -:

Chromium (Cr) 7440-47-3 200 µg/l /1.0 µg/l - / 2 mg/kg -: -:
Arsenic (As) 7440-38-2 50 µg/l /1.0 µg/l - / 2 mg/kg -: -:
Copper (Cu) 7440-50-8 1000 µg/l /1.0 µg/l - / 2 mg/kg -: -:
Zinc (Zn) 7440-66-6 5000 µg/l /5.0 µg/l -/ 2 mg/kg -: -:
Manganese (Mn) 7439-96-5 - /1.0 µg/l - / 2 mg/kg 30 µg/l 98 mg/kg
Antimony (Sb) 7440-36-0 -/1.0 µg/l -/2 mg/kg -: -:
Cobalt (Co) 7440-48-4 50 µg/l /1.0 µg/l -/2 mg/kg -: -:
Silver 7440-22-4 -/1.0 µg/l -/2 mg/kg -: -:
Method Photometry (ISO 17075-1)
Sample Results
Limit values
Limit values
according to
according to DETOX
Substance CAS-No. DETOX TO ZERO
TO ZERO MRSL for 1.1 Wastewater 2.1 Sludge
MRSL for sludge
Wastewater and
and LOQ
LOQ
Chromium VI 18540-29-9 50 µg/l /1.0 µg/l -/2 mg/kg -: -:
-: test not conducted; n.d.: not determinable, -: test not conducted

Polycyclic Aromatic Hydrocarbons (PAHs)

Methode DIN 38407-39 (F 39) (solvent extraction, GC-MS/MS)
LOQ 1.0 µg/l (wastewater) ; 0.6 mg/kg for sludge
Limit values Limit values
according to according to DETOX
Sample Results
Substances CAS-No. DETOX TO ZERO TO ZERO MRSL for
MRSL for sludge
Wastewater 1.1 Wastewater 2.1 Sludge
Acenaphthene 83-32-9 -: -:
Acenaphthylene 208-96-8 -: -:
Anthracene 120-12-7 - - -: -:
Benzo[a]anthracene 56-55-3 -: -:
Benzo[a]pyrene 50-32-8 -: -:
Report No. 20.0.33467
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Benzo[b]fluoranthene 205-99-2 -: -:
Ben(e) pyrene 192-97-2 -: -:
Benzo[ghi]perylene 191-24-2 -: -:
Benzo[k]fluoranthene 207-08-9 -: -:
Benzo[j]fluoranthene 205-82-3 -: -:
Chrysene 218-01-9 -: -:
Dibenz[a,h]anthracene 53-70-3 -: -:
Fluoranthene 206-44-0 -: -:
Fluorene 86-73-7 -: -:
Indeno[1,2,3-cd]pyrene 193-39-5 -: -:
Naphthalene 91-20-3 -: -:
Phenanthrene 85-01-8 -: -:
Pyrene 129-00-0 -: -:
- No Limit values; n.d.: not determinable; LOQ: Limit of quantitation, -: test not conducted

Bangladesh, 24.10.2020
Head of Textile & Chemical Testing Expert for Customer Service

Johny Yasmin Kanta Faruk Ahmed

The results relate only to the test samples submitted. This report must only be reproduced in full and not in extract form. Use of the report in advertising or the publication of free interpretations of
the results is only allowed with the express permission of the Hohenstein Institute. Only the signed original report is legally binding. Documents and materials delivered by the client, especially
test samples will be retained for 3 months, provided their condition allows it. A storage period of 10 years applies to the legally regulated area.
The accreditation applies for the methods listed in the annex to the certificate (accreditations http://www.hohenstein.de/de/about_hohenstein/accreditation/accreditation.html) – marked A in
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