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Journal of Geochemical Exploration 66 (1999) 427-439
Abstract
The mechanism of Au dispersion in sediments of mountainous desert environments has been studied in two different
areas of the Chilean Andes. The San Pedro de Cachiyuyo placer (ca. 1800 m a.s.1.) consists of alluvial fans and ephemeral
stream sediments deposited in a stable piedmont. The primary Au source is Cu-Au-bearing hydrothermal tourmaline
breccia. The relief of this area is low (1850 m) and the average annual rainfall is ca. 20 mm. The La Coipa area (ca.
4000 m a.s.1.) is characterized by a rugged relief. The annual average rainfall is ca. 100 mm. The sedimentary deposits
are less sorted than in San Pedro de Cachiyuyo and consist of ephemeral stream alluvium and slope deposits formed in a
periglacial environment. The primary Au sources are two volcanic-hosted epitheimal precious metal deposits. At San Pedro
de Cachiyuyo, the halo is less than 1 km in length and the highest Au concentration are observed at the break in slope
between the hillside and the piedmont. In the La Coipa area, Au was only detected by chemical analysis in the 125-63 p m
and < 6 3 k m fraction; however, the dispersion halo extends for over 10 km from the source. In both cases the geochemical
signal of gold was strongest in the fraction t 6 3 pm. O 1999 Elsevier Science B.V. All rights reserved.
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0375-6742/99/$ see front matter O 1999 Elsevier Science B.V. All rights reserved.
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PII: S O 37 5 67 42 (99 )O 004 5- X
428 G. Hérail et al. /.Touma1 of Geocheniical Exploration 66 (1999)427-439
specific features of geochemical exploration in these and elutriation. Gold grains were hand-picked under
environments, which are characterized by low-level a stereomicroscope, weighed (in order to obtain the
geochemical activity, poor soil development, me- grade of 'coarser' gold), micromorphologically de-
chanical weathering, dilution related to eolian sed- scribed and analyzed by electron microprobe. The
imentation, ephemeral stream and poorly reworked second group of samples (ca. 3 kg) was sieved and
sediments (i.e. Salpeteur and Sabir, 1989; Bogoch et separated into two fractions (125-63 pm and 4 3
al., 1993). pm). Gold content was determined by neutron ac-
In this paper the mechanism of Au dispersion in tivation. These analyses were made in comercial
desert mountainous areas is studied in two reference laboratory on 30-g samples. Gold content in frac-
zones of the Atacama desert: the San Pedro de tion >125 pm was directly estimated from the gold
Cachiyuyo placer and the alluvial sediments around grains obtained from the pan concentrates.
the La Coipa Ag-Au deposit (Fig. 1). In both areas
the primary source of detrital Au is known: in the
San Pedro de Cachiyuyo area (ca. 1850 m a.s.1.) 3. Geological setting and the source of detrital
the placer deposit is spatially related to a tourmaline gold
breccia pipe hosting Cu-Au mineralization, and at
La Coipa (4600 m a.s.1.) it is spatially related to At the latitude of San Pedro de Cachiyuyo and
an epithermal Ag-Au deposit. These two types of La Coipa areas (Fig. l), the Andes are formed,
primary mineralization, as well as the supergene from west to east, by the Coastal Cordillera, the
environments, are common in the Andes, particularly Central Depression, the Precordillera and the Main
in northern Chile. Cordillera. In the San Pedro de Cachiyuyo area, the
Central Depression (1500 m a.s.1.) is represented by
a low relief composed of Jurassic and Cretaceous
2. Sampling method and analytical procedure magmatic and sedimentary rocks locally covered by
the Atacama gravels (Miocene) and Plio-Quaternary
Detailed geological mapping and the definition sediments. The La Coipa region is located in the
and the distribution of sedimentary units and their Main Cordillera, a rugged relief area consisting of
stratigraphic relations were performed in each test Tertiary volcanic rocks belonging to the Maricunga
area. A stratigraphic column was established in each belt. In this area, Paleozoic and Mesozoic sequences
sampling locality and separate sedimentary units, are covered by caldera remnants and stratovolca-
representing different erosional and sedimentary noes of the Cenozoic magmatic arc (Davidson and
events, were identified and sampled. Sampling was Mpodozis, 1991; Mpodozis et al., 1995).
carried out in pits or channels on natural outcrops The San Pedro de Cachiyuyo Au placer is located
and samples of each sedimentary unit were taken. at the eastern border of the Central Depression (Mor-
Each sample was split in two parts: the first one, of timer, 1973), at an altitude of 1850 m a.s.l., on the
100-130 kg, was processed by gravimetric methods eastern flank of Delirio Hill, close to the foothills of
to separate the Au grains and the heavy minerals con- the Precordillera in the Atacama desert. The primary
centrate, the second, of ca. 3 kg, was used for geo- source of detrital Au is from hydrothermal min-
chemical analysis. In the San Pedro de Cachiyuyo eralization consisting of native Au associated with
area, 21 stratigraphicsections were described (Fig. 2) crisocola, cuprite, malachite, chalcosine and native
and 35 units were sampled. In the La Coipa area 24 Cu, hosted in the matrix of hydrothermal tourmaline
units were sampled in 21 sections (Fig. 3). breccias (Ortiz, 1974; Palacios and Lahsen, 1992;
The material from the first group of samples Delgado, 1992; Palacios et al., 1993) which crop
(100-130 kg) was sieved at 2 cm, the fraction upper out near the top of the Delirio Hill (Mina Delirio
2 cm are rejected and the fraction minor to 2 cm are in Fig. 2). The tourmaline breccia is hosted by
concentrated by sluicing and panning. To isolate the an Eocene monzonitic-granodioritic stock which in-
heavy fraction, the obtained concentrate was further trudes volcanic and sedimentary rocks assigned to
processed in the laboratory by magnetic separation the Neocomian. In this primary mineralization many
G.Hérail et al. /Journal of Gcoclzeinical Exploration 66 (1999)427-439 429
Triassic-Lower Cretaceous
volcanic and sedimentary rocks (from Mpodozis and Allmendinger, 1992)
Fig. 1. Location map of the study areas in the Chilean Andes (from Mpodozis and AUmendinger, 1992).
Au grains are 0.2 to 0.4 mm long but .some grains of mineralization occurs in the epithermal Au-Ag de-
0.4 to 2 mm size were also observed. posits at La Coipa and Can Can, hosted in a volcanic
The La Coipa mine (Fig. 3) is located in the complex of Late Oligocene-Early Miocene age and
Maricunga belt, at ca. 4600 m a.s.1. Primary gold in,Triassic black shales (Zentilli, 1974; Oviedo et
430 G. Hérail et al. /.Toimal of Geochemical Exploration 66 (1999)427-439
LL
Recent ephemeral stream
sediments
Alluvial deposits of the
Longitudinal Depression
(Atacama gravels)
+++++++++++
U
++++ Monzonitic and
+ + + + granodioritic intrusive
Andesites
Sampling
the sedim
Location
of cross
I
* . l Ø . * * * * *
A- ' 3 0
3Q
10
I
3 0
3 0
3Q
3 0
3 0
3 0
l + + + + k b-O I/
al., 1991, Swaneck, 1992; Mpodozis et al., 1995). non-oxidized zones bornite, chalcopyrite, chalcosite,
The volcanic complex has been subdivided into a covellite, enargite, tetrahedrite, tenantite, galena and
lower rhyolitic tuffaceous sequence, which is the sphalerite are observed. Native Au grains are smaller
host rock to most of the mineralization, and an up- than 50 pm (Swaneck, 1992).
per rhyolitic pyroclastic breccia sequence (Swaneck,
' 1992). Both units are intruded by dacitic domes
and affected by extensive hydrothermal alteration 4. Geomorphological environment, stratigraphy
which consists of pervasive silicification and ad- and sedimentology of the sampled sequences
vanced argillic alteration. Supergene leaching and
oxidation overprint the magmatic and hydrothermal 4.1. The San Pedro de Cachiyuyo placer
mineral assemblages. Gold is associated with alu-
nite and Ag minerals (native Ag, cerargirite, em- In San Pedro de Cachiyuyo, the average annual
bolite, yodargirite, argentojarosite, argentite). In the rainfall is 21.8 mm. These rainfalls take place in
E]
, # 1 # ,
Tuffs and breccia tuffs
* + + + +
Dacitic Domes v
i Black shales and sandstones
Fig. 3. Geological map of La Coipa, sample localities and golddispersion pattern in the alluvial deposits.
P
W
CL
432 G. Héruil et al./Joumul of Geocliemicul Exploration 66 (1999) 427-439
winter (July), and rarely lead to stream floods. The oped on the monzonitic-granodioritic intrusive. This
area had similar climatic characteristics during the old alluvial fan is overlain by a recent alluvial fan
Quaternary with sporadic wetter episodes as shown (Fig. 2) of similar characteristics,that also has a less
by the presence of carbonate-rich paleosols and by evolved soil.
high-energy ephemeral stream sequences. Sediments deposited by ephemeral streams in the
In the San Pedro de Cachiyuyo placer (Fig. 2), Delirio Creek consist of gravel, sand and few boul-
gold occurs in unconsolidated sedimentary units ders of andesites and breccias, which do not exceed 3
(boulders, gravels and sands) located at the base m in thickness. Sediments are unlithified, show sub-
of the Delirio Hill, ca. 400 m below the Mina parallel bedding, and commonly display cross-bed-
Delirio. These units represent alluvial fans, pediment ding. Layers of laminated coarse-grained sands are
deposits and sediments produced by ephemeral dis- abundant. Reverse-graded bedding and non-erosive
charges of the Delirio Creek. All these sediments are sole casts commonly observed, suggest mud flow
younger than the Middle Miocene Atacama Grav- contributions. As in the fan zone, a red carbon-
els, which are widespread in the piedmont and in ate-rich paleosol is interbedded with two sequences
the Central Depression (Cornejo et al., 1993). The of ephemeral stream sediments. Unlithified, recent,
break of the slope between the Cerro Delirio and gravel-sized sediments overlie the upper set of these
its piedmont is very sharp: the gradient along the deposits.
alluvial fans is 10% while the slope at Cerro Delirio
is -25%. At the present and throughout the Quater- 4.2. Slope deposits and ephemeral stream sediments
nary, geomorphological and sedimentary processes sampled in La Coipa area
differed from hill slope to pediment plain with rill
wash and mass wasting on the Cerro Delirio slopes La Coipa area is characterized by narrow deep
and fluvio-torrential flood on the piedmont. valleys whose bottoms are above 3900 m. The av-
The geology of the placer and the stratigraphic erage slope of Quebrada La Coipa is very steep. It
relationships of the sedimentary units are shown in varies from 15% upstream at the confluence with
Fig. 2. Upstream, near the Mina Delirio, the main Quebrada de Los Temeros (Fig. 3) to 7% between
sedimentary facies is a one to two meter thick collu- this confluence and sample point 23, and 3.6% be-
vial deposit. It consists of a matrix-supported,poorly tween this point and sample point 17. Annual mean
sorted gravel containing large fragments of mon- temperature is 11.C and average annual precipitation
zonite and tourmaline breccia (10-30 cm in size). does not exceed 100 mm. Precipitation mainly oc-
At the foot of the Delirio Hill, between the break curs in winter consisting in snowfalls which rarely
in slope and the upper part of the Delirio Creek, may lead to a stream flood; more frequently it causes
the colluvial facies grades to a complex alluvial sys- solifluction along the slopes. Sediments in the La
tem consisting of two alluvial fans and ephemeral Coipa district (Fig. 3) are less well sorted than in the
stream sediments (Fig. 2). The old alluvial fan is San Pedro de Cachiyuyo area. They have been de-
composed of angular fragments, mainly tourmaline posited by ephemeral streams and mass wasting de-
breccia and monzonite (10-30 cm in diameter) in posits produced by cryoclastism in a periglacial en-
a sandy matrix; locally, lenses of laminated coarse vironment. Sediments preserved on the slopes of the
sand appear. A soil level developed on the old al- Quebrada La Coipa (Fig. 3) consist of poorly strati-
luvial fan shows two horizons; the upper one (30 fied deposits containing volcanic rock fragments.
cm thick) consists of red sands and clays and the The alluvial deposits preserved in the bottom
lower one (50-100 cm thick) consists of a carbon- of the creeks comprise sands with fine lamination
ate-rich horizon (dusty caliche and latticework of and cross-bedding. These beds are normal-graded at
calcium carbonate veinlets). These two horizons are the bottom and reverse-graded at the top. Clasts in
interpreted as Bt and B Ca horizons of a paleosoil, the coarse layers are matrix-supported. These fea-
probably developed during more humid episodes, of tures suggest that sediments were deposited during
which the upper portion was eroded. Northwards, floods (mainly snow melt floods) with no reworking
this paleosoil directly overlies the pediment devel- phases.
G. Hérail et al. /.Toimial of Geocheiiiical Exploration 66 (1999) 427-439 433
Fig. 4. Gold dispersion pattem in the San Pedro de Cachiyuyo area. (A) Recent alluvial fans and upper sequence of ephemeral stream
sediments. (B) Old alluvial fans, lower sequence of ephemeral stream sediments and slope deposits.
I G. Hérail et al. /Journal of Geocheniical Exploration 66 (1999)427-439 435
A B
Delirio Knick Piedmont Geomorphological
Hill I units
2100
illzits
2000
1900
1800
800
500
a
a
4
Au grade ppb I
fraction. In the ephemeral stream sediments of the ronment of transport (i.e. Hallbauer and Utter, 1977;
Delirio Creek, the main fraction ranges from 0.1 to Hérail, 1984; Hérail et al., 1990; Grant et al., 1991).
- 0.4 mm. Grains larger than 0.5 mm are very rare. The The morphological features of these Au grains of the
grain size distribution in the primary mineralization San Pedro de Cachiyuyo placer, their low flatness
and in the colluvium is Gaussian with a mean value index, weak bluntness and the preservation of their
of 0.2-0.4 mm. The discharges which originated primary crystalline marks indicate a short transport
the fans expelled the smaller Au grains and con- distance and few reworking phases (Lagos, 1996).
centrated the coarser grains (and as a consequence The core composition of detrital Au grains is con-
increased the Au content). Only the smaller gold sidered representative of the primary mineralization
grains were transported downstream and deposited (Desborough, 1970; Desborough et al., 1970; Hérail
with the lower-energy sediments of the ephemeral et al., 1990; Grant et al., 1991). In the different
streams where low Au contents predominate. sedimentary units of the alluvial complexes the core
The morphology of Au grains evolves during the composition is similar to that of the particle cores in
transport as a function of distance and of the envi- the primary mineralization (up to 10% Ag and 0.6%
436 G. Hérail et al. /Journal of Geochemical Exploration 66 (1999)427-439
Gold soiirce
I (aller Ovicdo. 1991 atid Swaneck, 1992)
4500
4000
3500
= Ikm
400
350
100
125-63pmsize
fraction 50
O
I 2' 3 4 5 619 89 23 II 24 13 14 15 16 17
Samples number
Fig. 6. Schematic cross-section summarizing the localization of gold source and gold distribution in ephemeral stream sediments of the
Quebrada La Coipa.
Cu), indic.ating that the placer gold comes from a the erosion and transport processes. At both sites
unique source, in this case the hydrothermal breccias the primary mineralization and the sediments were
of the Mina Delirio (Lagos, 1996). Some particles scarcely weathered and the erosion products were
have an incipient purification rim, suggesting only transported by ephemeral streams. In the placer as-
slight weathering. sociated with the stable piedmont and low relief of
San Pedro de Cachiyuyo, the higher Au values are
contained in the break of slope sediments. In this
S. Conclusion geomorphologic position the energy of the stream
flood is high, the sediments are reworked, and Au
Comparison between the geochemical Au disper- reconcentrated, during episodic floods. In contrast,
sion halos around primary Au sources in two areas in the periglacial environment of the high mountains,
of the Atacama desert (San Pedro de Cachiyuyo the larger quantities of cryoclastically released frag-
and La Coipa areas), combined with the study of ments, larger volume of water provided by snowfalls,
the morphology, size anld composition of the Au greater dissection and very fine grain size of Au pro-
grains within the halos, strongly support the hypoth- vided by the primary source have resulted in a wider,
esis that the distribution of detrital gold is mainly strongly diluted dispersion halo.
controlled by features characteristic of the primary From a practical point of view, in desert envi-
mineralization (e.g. grain size of native gold) and, ronments with a high relief, fine-fraction samples
particularly, by the geomorphology and nature of (minor 63 pm) are more effective. Anomalies can
Length (mm)
Fig. 7. Gold granulometric histogramsfrom colluvia, alluvial fan and ephemeral stream sediments of San Pedro de Cacliyuyo.
during the writing of this paper. We acknowledge fossil placer of the Witwatersrand. Mineral. Deposita 12, 293-
Andrew Tomlinson for the improvement of the En- 306.
glish version. R.Bogoch, W.K. Fletcher and C.R.M. Hérail, G., 1984. Géomorphologie et gîtologie de l’or détri-
tique (Piémonts et bassins intramontagneuxdu Nord-Ouest de
Butt are thanked for their reviews and relevant sug- l’Espagne). C.N.R.S., 456 pp.
gestions and corrections. Hérail, G., Fomari, M., Rouhier, M., 1989. Geomorphological
control of gold distribution and gold particle evolution in
glacial and fluvioglacial placers of Ancocala-Ananea basin,
southeastern Andes of Peru. Geomorphology 2,369-383.
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i
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