The pH of @ bsffon setution cam he coleLeteot if Given tha Rollourng infermradtions ; + the Ka of the wok acl, » the 2puclibriiin concentration of the week ancl and its conjugate bose (Soft). Exo. Cokeulete the pH of a buffin solution contacting 0.600 moldin”® piopanerc accd anol 0.F00 meldic? Sodinin propamoats « (Ka propane aett =/-35 x16 Smaldet? Wer Cols COOH = Crs Coo% ey, + He, Step 1s Write The cesth chissociation Constant Sep raucon . Ka = Catlecoo J CH*] (C.HeCooH] Step 2 + Rearronge the trpresscon to mohe LH] Ha seb jot ([erHsCOoH] CH*] = Ka* fesyscoo-] Stop 3: Substhite the olecte given (Ht] = bas x rot xe $22) = hor x 1 Fnelda? Steph: Catertate the pi pH= —leg,.CH'] = ~1eg.9(hor xe Sy = HdExsvecse | Caletate the pH of buffer solid ton When Soem! of 0-1 melds? CH3QooH mined with /50eln? fo38 tmotdlin”? CH3CO, Na. (ka of CHaCooH = 7 (07S mek chin? ) Workings Total buffer yoleme = £0 +180 200 chy? LetscooH] = C1 XO = 0.025 mold Zee [CHscoo7] = (eH,co, We] = oa nies = 0.225 mest dlin”? CHsCOCH 4, = CHSCODTEY * Hy Ka~ Teiscood] oye ka» (coe cH] Tengcoo7] = LTxI0 7x 2525 0.225 = 1.84 x 107% nat dm p= ~ Fog CHT a 1951, (81K) = 572Exercise 2 Colemhote the pl of buffrr solition when 2-739 of WH gc dessolued ih 2SOCm? OF Of motdin”? Als Og) (Kp of MH = 1-8 x10F mol tn?) Werkings Wr (Wy cs) = 4+84 35.5 = 535 n(uec!) = 222 = 0. 0510 tek Whe] =(olecr] = e050 x 188 _ - Coste] = Cotlecr] x 1282 = 0.204 moldtn (WHa] = O14 mark dan ® NHseq) + 1,0 = Ne eg) + Oey tw" JCow] Ke Tes] e Tus] KL x 3. CowJ= Ky Thm] = bax x Lt = 8.82 KIOW® moldin™® 330% pott= leg plcuall = Heh 00 (882x100) = $.05 ph + pod = 14 pt= 14— pO# = 14-505 7 84SCabenkecting the pH of buffer salucion ihvelui'hg pKa In on aecdic bafffne soldbion coicdarning a weok axed, HA om ifs sodium salt, Nah hey = Hoy they Kege LHI] _ CHT Lott] CHAT (acca J acid [and] ‘ (ent 5 retio GESTE eetoemina 1] H= pkat | Fa taeeee 9g = Similarly in otkabns buffer , (solt] pou= pk, + logs iCokemlating the composition of o buffir solution xa. Exaeple | the composition of @ buffer sdution of pH 7-4 made by mixing solution of O11 mot din”? sock usm dihydrogen phosphate anc 0-1 moldin™t disods um hy drogan phosphote . (ka of sodium dihyebrogen phosphate =6-22K/0 moda?) Woekvgs He POq¢g == HPomy + Ney = CHAT LHP) CH Por] Hog?” Ka (Heo CHT disodium hydongen phosphate] . Ke [sodium dhycbrogen plosp hots] auctilog ww PAD _ b22Kx107F antilog.,(-T#) _ G22xI0 : 398K wo® . = 2u 2156 on The buffer egsttn con be exfebbahed by mining Bitems of OF packed disodiurs hycbragen phosphate 73 godiinny achydnogen phosphale + with [19 cm ef rf mel hin Soden dihydrogen phoxpExample 2° Calculate the composition of on alholine buffer of pi 4.TS mace boy beixing aguene NHg ancl NACI, both of The same concentration. Cp Ke of WH; = 4-76) Workings pit pol =lh pOH = 14 ~pH = 14-49-15 = 415 NH; cyt Hep = Nie eg = pk, tl Csalt } pod= eke + log,, Tie] potl=pKi + lo4.. creed Cadeer] _ fea, THES] os ae = #25 - 4.74 = O49 Cader] _ _ 3 wT arctiled ro (0.44) = 0:32 = 8% The composition of thes buffor system is 32 volume of MHECI and lve volume of NH3 and beth of Hhe samme conondratie nCabeutecting the change in ph of a buffer station Example : Calearlate the change ih pH when () 10:0 cin? of 1.00 mot elm? HElay (B) 10.0 cin? fl on mel clin” > NecHes, 1s added te [00 dint of.0 buffer scludion conbeiteitag a mrtuce of O10 mol of CHsCCOMe ih 1-00 din? of +10 mol dtin”* CHsCOoH (pKa for CHycooH = 4.76 ) Werkanga | (@) pn(He= LeeXlee _ oo) met . | Toco CHy Cottey, cHacovey tH oy [CHscooH] = O-lo FO-0/ = Ol! beret clin”? [cH coon] = orto ores = 0.09 Mek cba” tt J Pac] = 416 + (04 po(AL) = 467 pi= pka +t log¢, td (B) n(Weok) = LECXleo gos med , Ht-+oH” —»> Ho gmt chine? (Cus coon] = O19 - 0-01 = > °" we CeHseoor] = 0-10 #0" cals sol p= pKa ono Ge aod = 4-76 + [09,,| ony = 4S