The pH of @ bsffon setution cam he coleLeteot if
Given tha Rollourng infermradtions ;
+ the Ka of the wok acl,
» the 2puclibriiin concentration of the week ancl
and its conjugate bose (Soft).
Exo.
Cokeulete the pH of a buffin solution contacting
0.600 moldin”® piopanerc accd anol 0.F00 meldic?
Sodinin propamoats « (Ka propane aett =/-35 x16 Smaldet?
Wer
Cols COOH = Crs Coo% ey, + He,
Step 1s Write The cesth chissociation Constant Sep raucon .
Ka = Catlecoo J CH*]
(C.HeCooH]
Step 2 + Rearronge the trpresscon to mohe LH] Ha seb jot
([erHsCOoH]
CH*] = Ka* fesyscoo-]
Stop 3: Substhite the olecte given
(Ht] = bas x rot xe $22) = hor x 1 Fnelda?
Steph: Catertate the pi
pH= —leg,.CH'] = ~1eg.9(hor xe Sy = HdExsvecse |
Caletate the pH of buffer solid ton When Soem! of 0-1 melds?
CH3QooH mined with /50eln? fo38 tmotdlin”? CH3CO, Na.
(ka of CHaCooH = 7 (07S mek chin? )
Workings
Total buffer yoleme = £0 +180 200 chy?
LetscooH] = C1 XO = 0.025 mold
Zee
[CHscoo7] = (eH,co, We] = oa nies = 0.225 mest dlin”?
CHsCOCH 4, = CHSCODTEY * Hy
Ka~ Teiscood]
oye ka» (coe
cH] Tengcoo7]
= LTxI0 7x 2525
0.225
= 1.84 x 107% nat dm
p= ~ Fog CHT
a 1951, (81K)
= 572Exercise 2
Colemhote the pl of buffrr solition when 2-739 of
WH gc dessolued ih 2SOCm? OF Of motdin”? Als Og)
(Kp of MH = 1-8 x10F mol tn?)
Werkings
Wr (Wy cs) = 4+84 35.5 = 535
n(uec!) = 222 = 0. 0510 tek
Whe] =(olecr] = e050 x 188 _ -
Coste] = Cotlecr] x 1282 = 0.204 moldtn
(WHa] = O14 mark dan ®
NHseq) + 1,0 = Ne eg) + Oey
tw" JCow]
Ke Tes]
e Tus]
KL x 3.
CowJ= Ky Thm]
= bax x Lt = 8.82 KIOW® moldin™®
330%
pott= leg plcuall
= Heh 00 (882x100)
= $.05
ph + pod = 14
pt= 14— pO#
= 14-505 7 84SCabenkecting the pH of buffer salucion ihvelui'hg pKa
In on aecdic bafffne soldbion coicdarning a weok axed,
HA om ifs sodium salt, Nah
hey = Hoy they
Kege LHI] _ CHT Lott]
CHAT (acca J
acid [and] ‘
(ent 5 retio GESTE eetoemina 1]
H= pkat |
Fa taeeee 9g =
Similarly in otkabns buffer ,
(solt]
pou= pk, + logs iCokemlating the composition of o buffir solution
xa.
Exaeple | the composition of @ buffer sdution of pH 7-4
made by mixing solution of O11 mot din”? sock usm
dihydrogen phosphate anc 0-1 moldin™t disods um
hy drogan phosphote .
(ka of sodium dihyebrogen phosphate =6-22K/0 moda?)
Woekvgs
He POq¢g ==
HPomy + Ney
= CHAT LHP)
CH Por]
Hog?” Ka
(Heo CHT
disodium hydongen phosphate] . Ke
[sodium dhycbrogen plosp hots] auctilog ww PAD
_ b22Kx107F
antilog.,(-T#)
_ G22xI0
: 398K wo®
. = 2u
2156 on
The buffer egsttn con be exfebbahed by mining
Bitems of OF packed disodiurs hycbragen phosphate
73 godiinny achydnogen phosphale +
with [19 cm ef rf mel hin Soden dihydrogen phoxpExample 2°
Calculate the composition of on alholine buffer of
pi 4.TS mace boy beixing aguene NHg ancl NACI,
both of The same concentration. Cp Ke of WH; = 4-76)
Workings
pit pol =lh
pOH = 14 ~pH
= 14-49-15
= 415
NH; cyt Hep = Nie eg
= pk, tl Csalt }
pod= eke + log,, Tie]
potl=pKi + lo4.. creed
Cadeer] _
fea, THES] os ae
= #25 - 4.74 = O49
Cader] _ _ 3
wT arctiled ro (0.44) = 0:32 = 8%
The composition of thes buffor system is 32 volume
of MHECI and lve volume of NH3 and beth of
Hhe samme conondratie nCabeutecting the change in ph of a buffer station
Example :
Calearlate the change ih pH when
() 10:0 cin? of 1.00 mot elm? HElay
(B) 10.0 cin? fl on mel clin” > NecHes,
1s added te [00 dint of.0 buffer scludion conbeiteitag
a mrtuce of O10 mol of CHsCCOMe ih 1-00 din? of
+10 mol dtin”* CHsCOoH
(pKa for CHycooH = 4.76 )
Werkanga |
(@) pn(He= LeeXlee _ oo) met .
| Toco
CHy Cottey, cHacovey tH oy
[CHscooH] = O-lo FO-0/ = Ol! beret clin”?
[cH coon] = orto ores = 0.09 Mek cba”
tt J
Pac]
= 416 + (04 po(AL) = 467
pi= pka +t log¢, td
(B) n(Weok) = LECXleo gos med ,
Ht-+oH” —»> Ho
gmt chine?
(Cus coon] = O19 - 0-01 = > °" we
CeHseoor] = 0-10 #0" cals sol
p= pKa ono Ge aod
= 4-76 + [09,,| ony = 4S