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Article history: Organic Rankine Cycle (ORC) is a technology with important opportunities in heat recovery from energy
Received 9 February 2013 intensive industrial processes. This paper represents the first comprehensive estimate of ORC units that
Accepted 16 July 2013 can be installed in cement, steel, glass and oil&gas industries in the 27 countries of the European Union
based on an accurate methodology related to real plants in operation or under construction. An evalua-
tion of energy savings, depending on the number of operating hours per year and of the consequent
Keywords: decrease in CO2 emission and electricity expenditure, is also provided. The study, carried out in the
Organic Rankine Cycle (ORC)
framework of an European research project on heat recovery in energy intensive industries, found that,
Waste heat recovery
Cement
in the most convenient considered scenario, up to about 20,000 GW h of thermal energy per year can be
Steel recovered and 7.6 M ton of CO2 can be saved by the application of ORC technology to the investigated and
Glass most promising industrial sectors.
Oil&gas Ó 2013 Elsevier Ltd. All rights reserved.
Energy audit
0196-8904/$ - see front matter Ó 2013 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.enconman.2013.07.041
F. Campana et al. / Energy Conversion and Management 76 (2013) 244–252 245
Nomenclature
barriers for combined heat and power (CHP) applications. In their 2. Methodology for ORC potential assessment
wake, also heat recovery policies have been proposed [33]. Lowe
and Gereffi describe in [34] new opportunities offered by a new The methodology followed in order to estimate on large scale
sector, obtained by taking into account all firms involved into heat the ORC potential in EU27 industries is summarized in Fig. 2 and
recovery systems manufacturing. Their study presents a value explained in the following points:
chain (Fig. 1) for applications of industrial waste energy recovery.
The value chain is divided into four segments, where many in- 1. The most interesting industrial processes were identified. The
volved players and new job opportunities can be identified. Activ- selected industries are: (i) steel, (ii) cement, (iii) glass and (iv)
ities that would benefits of new heat recovery projects are not only oil&gas; this selection was done based on their considerable
related to industry: funding for R&D, GHG emissions reduction and energy consumption. In each selected industry, the most inter-
job opportunities are clear examples of social improvements. En- esting processes were identified using as key factors the
ergy efficiency policies [35], e.g. White Certificates in Italy [36], amount of wasted thermal power, the source cleanness and
industrial category initiatives like SPIRE 2030 [37] and Sustainable the high number of operating hours. For the steel industry,
Industry Low Carbon Initiative [38] are all helping the economic selected processes are: Electric Arc Furnaces (EAF) and rolling
sustainability of heat recovery. In this framework, a first large scale mills; in cement industry, clinker production is considered; in
estimation on heat recovery potential by means of ORC in energy glass industry, float glass production and finally gas turbines
intensive industries sectors is performed in this paper, based on in Gas Compressor Stations (GCS) and Gas Storage Fields (GSF)
a reduced group of input key parameters and on a large number are considered in oil&gas industry. For most of these processes
of installations, in order to quantify the amount of residual avail- there is an operating ORC system as reference.
able electric energy fully recoverable in EU27. 2. For every process, the most influent parameter for an estima-
The remainder of the paper is organized as follows. Section 2 tion of the potential ORC output power, named here Process
explains the methodology followed in order to estimate ORC power Capacity Parameter (PCP), was identified. Usually this is a daily
potential in the selected industries. Section 3 presents the amount or hourly capacity. The selected PCP is described in Table 1 for
of installable ORC power in EU27 cement plants and the recover- every considered process.
able energy – as a function of plants operating hours – and the con- 3. The value of PCP was detected for every plant of the identified
sequent savings in energy, costs and GHG emissions. Section 4 processes, namely: EAF, rolling mills, clinker production, float
presents the same estimation for steel industry – Electric Arc Fur- glass and gas turbines in GCS and in GSF.
naces and rolling mills, while Section 5 is related to glass industry. 4. Available energy audits were analyzed. The number of consid-
Section 6 presents ORC potential data for European Gas Compres- ered plants and of available audits for every process is shown
sor Stations (GCS). Finally, conclusions are given in Section 7. in Table 2. Energy audits provided the ORC power installed, or
Fig. 1. Heat recovery value chain [22]. Fig. 2. Methodology of analysis scheme.
246 F. Campana et al. / Energy Conversion and Management 76 (2013) 244–252
Fig. 3. Audit results; top: effect of PCP on ORC power and on specific power; bottom: hot source temperature and mass flow rate.
F. Campana et al. / Energy Conversion and Management 76 (2013) 244–252 247
Table 3 Table 4
Emission factors and energy cost in EU27 [40,41]. EU27 cement plants location and capacity [44].
Country Emission factor (t CO2/MW h) Energy cost (€/kW h) Country No. of plants Nominal capacity (Mt/yr)
Italy 0.405 € 0.12 Spain 38 48.3
Germany 0.503 € 0.10 Italy 59 38.6
Spain 0.430 € 0.08 Germany 33 28.8
France 0.092 € 0.07 France 31 21.6
UK 0.496 € 0.09 Greece 8 14.5
Belgium 0.254 € 0.09 Poland 11 14.0
Austria 0.161 € 0.10 Portugal 6 10.8
Czech Rep. 0.630 € 0.10 UK 12 10.4
Others 0.483 € 0.09 Others 61 60.8
Total EU27 259 247.8
unit installed in a cement factory is reported in Fig. 4. Raw materi- wet kilns will be replaced by dry ones, thus it is possible to con-
als are preheated in multiple cyclones which use exhausted gases sider them as dry kilns, in a future perspective. Eventually, the total
coming from the rotary kiln. Thermal energy of these gases number of cement plant considered is 241 out of 259.
(300–450 °C) can be recovered by means of a heat exchanger (1 The PCP for cement industry was expressed in daily capacity. In
in Fig. 4). After being cooked in rotary kiln at 1200 °C, clinker has order to estimate the daily capacity, the annual nominal capacity
to be cooled. The second heat source is represented by gases com- was used; a conservative representative capacity factor of 0.8 (a ce-
ing from this clinker cooler (300 °C) that are recovered by another ment plant has typically a continuous process at high production
heat exchanger (2). Usually heat exchangers work with diathermic rate) and a production stop of one month a year for maintenance
oil which maintains temperature at a stable value. Then heat is ex- were considered.
changed from diathermic oil to organic fluid and electricity is gen- A total of 21 energy audits were analyzed and the correspond-
erated by ORC unit. ing rA were calculated. Results are depicted in Fig. 5, reporting the
There are 259 cement plants in EU27, for a total amount of 389 rA values for the 21 plants. Plants can be distinguished depending
kilns, with an overall capacity of 247.81 millions of metric tons on the recovered heat source: there are cement plants in which
[44], located as reported in Table 4. Among these plants, 11 have it is possible to recover heat only from pre-hating cyclones (PRS,
not been considered because of their wet process: for this type of component 1 in Fig. 4) or from clinker cooler gases (CC, component
kiln, it is not convenient to install ORC systems, due to technical 2 in Fig. 4) or from both the sources (PRS + CC). Differences in rA
problems for the heat exchanges. For other 19 plants, the process values may be related to many factors affecting the actual installa-
type is not described: for 7 of those neither nominal capacity is ble ORC power, such as raw material humidity rate, average exter-
provided, thus it was not possible to estimate the ORC power. nal temperature, number of cyclones, year of startup, etc. The
For the 12 over 19 plants with given annual capacity but without calculated value of rP results equal to 1.01 kW per ton/day of pro-
process type specification, we decided to proceed with the algo- duced clinker. Referring to Italian plants, the adopted rP value is
rithm relying on BREF for cement industry [42], which reports that 0.75 kW per ton/day of produced clinker, the average value of rA re-
only the 2.5% of kilns works with wet process. According to [42] lated to this country (11 audits). The value of PCP of all the
Table 6
Energy recovered, emission and cost savings in cement industry.
Table 5
ORC power estimate for EU27 cement factories.
Table 7 Table 9
Number and nominal capacity of EU27 EAF and rolling mills [47]. Energy recovery, emission and cost savings in EU27 steel industry.
Country No. EAF Capac. (Mt/yr) No. rolling mills Capac. (Mt/yr) Country Energy Recovery Emission avoided Cost savings (mln
(GW hh/yr) (103 t CO2/yr) €/yr)
Italy 40 23.4 63 35.8
Spain 29 18.5 42 21.8 5000 h 8000 h 5000 h 8000 h 5000 h 8000 h
Germany 27 16.7 52 50.8
IT 572 916 206.9 331.0 71.3 114.0
France 20 7.6 38 31.3
GE 781 1250 343.5 549.6 80.0 128.0
UK 8 4.9 31 15.9
ES 557 891 184.1 294.6 45.4 72.6
Poland 9 4.5 19 9.7
FR 365 583 28.8 46.1 27.0 43.3
Belgium 7 4.7 9 16.6
UK 237 379 102.2 163.5 20.9 33.4
Romania 6 3.2 12 9.0
BE 272 436 66.8 107.0 23.7 38.0
Greece 5 3.5 6 3.2
AU 82 132 11.2 17.9 8.6 13.8
Czech Rep. 9 0.5 12 7.4
CZ 50 80 27.2 43.5 5.1 8.2
Others 30 14.0 78 50.2
Oth 824 1318 380.5 608.8 62.2 99.6
Total 190 101.7 362 251.8
EU27 3740 5984 1351 2162 344.3 550.8
Idle 11 14
Table 8
ORC gross power to install in EU27 steel industries. Table 10
EU27 flat glass plant distribution and production [48].
Country ORC POWER ORC power in Total ORC power in
in EAF (MW) rolling mills (MW) EU27 steel ind. (MW) Country No. of plants Product (103 t/yr)
Italy 92.9 21.7 114.6 Germany 11 1425
Germany 74.0 82.2 156.2 France 7 907
Spain 85.8 25.6 111.3 Italy 7 908
France 43.1 30.1 73.2 Belgium 7 907
UK 27.7 19.7 47.4 UK 5 645
Belgium 25.7 28.7 54.5 Spain 5 645
Austria 4.2 12.2 16.5 Poland 3 390
Czech Rep. 0.8 9.2 10.0 Portugal 1 127
Others 83.3 81.0 164.3 Other 9 1545
Total EU27 437.5 310.5 748.0 Total 58 7500
mills (33) and plate mills (39) for a total amount of 262 rolling ORC in EAF to be installed in Riesa (Germany) within H-REII Demo
mills. project by the end of 2013, many others are expected to follow.
The first application of heat recovery by ORC from re-heating
furnaces in hot rolling mills was started up in April 2013 in Singa-
pore. Hot rolling mills work with steel at temperature around 5. Waste heat recovery in EU27 glass plants: ORC potential
1500 °C and heat transfer is performed by direct exchange between
the organic working fluid and the heat source at temperature Glass industry can be divided depending on the manufactured
around 400 °C simplifying the system layout. In this case the PCP product. In this study, only flat glass plants have been considered,
was identified with reheating furnaces hourly capacity, expressed because energy audits for container glass were not available. De-
in metric tons per hour. Values were provided only for 209 rolling spite the cement and steel cases, it was not possible to access to
mills, thus categories of blooming and slabbing mills (15), billet a database with data for every single glasswork. This study is
mills (30) and many other facilities were excluded from the ORC mainly based on BREF for glass manufacturing [48], related to
potential calculation. the 2007–2008 period. This document reports the number of fur-
Six audits were available. The calculated rP value is equal to naces placed in EU27 (Table 11) and their proportion divided into
6.87 kW per ton produced every hour. We used this value in order ranges of daily production (Table 11). The PCP was identified in
to estimate potential for other mills without considering facility daily capacity. The rP value was calculated relying on 15 energy
type, because product type is not related to furnaces size. Results audits, one referring to a 1.3 MW ORC unit already operating in
for the installable ORC gross power in EU27 EAFs and rolling mills Italy, while six of these audits are related to plants in extra EU27
are presented in Table 8. countries, nevertheless these data have been used to calculate a
Potential recovery and savings are reported in Table 9. Consid- more accurate value of rP. These audits report ORC gross power,
ering 190 installations in EAFs and 209 in rolling mills, an energy but in some cases daily production data (PCP) is not available.
recovery between 3740 and 5984 GW h per year has been esti- Thus, PCP has been estimated referring to the proportion shown
mated, equal to around 0.58% of the final electricity consumption in Table 10, depending on ORC size. The average rP ratio is
of EU27 industry in 2010 [45]. Avoided emissions of CO2 account 2.7 kW ORC power per metric ton of tank daily capacity. For every
between 1.351 and 2.162 million metric tons, around 0.51% of
the total amount of carbon dioxide emitted in 2008 by EU27
Table 11
[45]. At current electricity price for industry (see Table 2), Euro- EU27 flat glassworks production ranges [48].
pean steel plants owners would save between 344 a 551 million
euro per year. Considering an average value of 3 million euro per t/day % No. of plants
installed ORC MW, the market size related to installations reaches <400 1 1
over 2 billion euro. 400–550 37 22
550–700 48 28
Steel represents the industry with most interesting possibilities
>700 14 7
of application in following years: after the first application of ORC
Total 100 58
in rolling mills started up in Singapore and the first application of
250 F. Campana et al. / Energy Conversion and Management 76 (2013) 244–252
Table 12
ORC power to install in EU27 flat glass industry.
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