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h i g h l i g h t s
For a hybrid system, steel fibres provide positive effects on the properties PFRG.
Higher first peak load and post peak response were observed in hybrid FRG.
Both toughness and equivalent flexural strength improve with the percentage of steel fibres.
a r t i c l e i n f o a b s t r a c t
Article history: In this study, the effects of steel and polypropylene fibre hybridization on the flexural performance of
Received 20 March 2017 fibre-reinforced geopolymer were investigated. Fibre reinforcement has emerged as a way to improve
Received in revised form 4 October 2017 the brittleness of geopolymer. There are currently several types of fibres available on the market.
Accepted 21 November 2017
When polypropylene fibre is used, it usually yields a large drop in strength immediately after the first
Available online 6 December 2017
crack, as well as a lower post-peak response, owing to its high flexibility and low stiffness. To resolve
these issues, a hybrid system is introduced using fibre with high strength and stiffness such as steel fibre.
Keywords:
In the present study, two hybridization systems are investigated: replacement and addition systems. For
Geopolymer
Hybrid fibre reinforced geopolymer
a replacement system, the polypropylene fibre is replaced gradually with steel fibre at a rate of 0.2% by
Flexural performance volume. For an addition system, the steel fibre is added into the mixture at the same rate. The results
Toughness and residual strength indicate that the hybridization of steel fibre can improve the flexural response, toughness, and residual
Polypropylene fibre strength of polypropylene fibre reinforced geopolymer to different degrees. Both the load dropping
Steel fibre and second peak are found to improve almost instantaneously. The toughness and residual strength also
increase gradually with an increase in steel fibre content.
Ó 2017 Elsevier Ltd. All rights reserved.
https://doi.org/10.1016/j.conbuildmat.2017.11.122
0950-0618/Ó 2017 Elsevier Ltd. All rights reserved.
38 P. Sukontasukkul et al. / Construction and Building Materials 161 (2018) 37–44
because the heat can accelerate the geopolymerization reactions In theory, a hybrid system is a combination of two or more
and promote an early gain in strength. Mermerdasß et al. [8] con- types of fibre in an FRC mixture with an objective of using the
cluded that the curing temperature and duration are both signifi- strength of one type of fibre to supplement the weaknesses of
cant factors in the activation of geopolymer. A curing the other [15]. There are two basic systems in hybrid FRC, replace-
temperature of 60 °C is considered the optimum temperature ment and addition. A replacement system is when one type of fibre
when applying a curing duration of 19–24 h depending on the type is replaced with another type of fibre; in this case, the fibre volume
and content of the binder. fraction will remain constant. An addition system is when a sup-
The mechanical properties of geopolymer have been found to be plement fibre is added to the base fibre; in this case, the fibre vol-
quite similar to those of hardened cement in that the material ume fraction will increase with the additional volume.
exhibits excellent compressive strength but is poor in tensile Briefly, polypropylene (PP) fibre was first invented to provide
strength (brittle). For conventional concrete, to improve the brittle- resistance to non-loading cracks in concrete. However, with
ness, small fibres are randomly mixed into the concrete mixture, advanced technologies in material science, a number of synthetic
which is called fibre reinforced concrete (FRC). For plain concrete, fibre types available on the market are capable of enhancing the
once a crack begins under loading, the crack will propagate quickly toughness and maintaining the residual load carrying capacity
and cause a rapid loss in load carrying capacity. For FRC, on the (after cracking) in concrete. However, polypropylene fibre does
other hand, the fibre distributed among the matrix will intercept have certain drawbacks owing to its low stiffness and flexibility.
the crack, causing it to slow down and even come to rest. This When subjecting to loading, and immediately after the first crack-
effect is the so-called crack bridging effect, which improves the ing, the load carrying capacity of PP-FRC tends to drop sharply until
toughness of the concrete and maintains the ability to carry a load the individual fibres are stretched to a certain point, at which the
after the first crack appears. load then increases again [15,16]. These are two of the weaknesses
In the case of geopolymer, the use of fibre to improve the brit- of PP fibre that require improvement, and a hybrid system might
tleness is comparatively new compared to conventional concrete. provide a solution.
There have been a few studies carried out in the area of fibre rein- This study therefore aims to investigate the flexural perfor-
forced geopolymer (FRG). For example, Genesa et al. [9] studied the mance of hybrid fibre reinforced geopolymer (HyFRG) applying
basic properties of steel fibre reinforced geopolymer (SFRG) with steel and polypropylene fibre. Both are macro-type fibre designed
fibre volume fractions varying from 0.25 to 1.0% and a concrete specifically to enhance the mechanical strength and toughness of
strength of 40 MPa. They found increases in both compressive concrete. Polypropylene fibre is used as the base, while steel fibre
and splitting tensile strengths of about 8.51% and 61.63%, respec- is used as a supplement. Steel fibre is used to replace or add to the
tively, in SFRG with the fibre volume fraction at 1%. polypropylene base FRC at an incremental rate of 0.2% of volume
Reed et al. [10] carried out tests on polypropylene FRG at three fraction. The flexural performance is achieved in accordance with
different proportions of 0%, 0.05%, and 0.15% by weight and under ASTM 1609. The results in terms of failure mode, toughness, and
two types of curing (ambient and oven). Their results showed an equivalent flexural strength are calculated and discussed.
increased compressive strength at a 0.05% weight fraction ratio
but a decrease at 0.15%. Shaikh [11] compared the flexural beha-
viours of steel fibre reinforced concrete (SFRC) and SFRG, and con- 2. Experimental procedure
cluded that both SFRC and SFRG exhibit similar deflection
hardening behaviours, although SFRG was shown to behave in a 2.1. Materials
more ductile manner with larger deflections at peak load.
In terms of fracture properties, Alomayri et al. [12] investigated The materials used as a binder phase consist of fly ash and silica
the mechanical and fracture properties of geopolymer mixed with fume. The fly ash is obtained from an electricity power plant in
cotton fibre at 0.3–1.0% by weight. They found the optimum cotton Lampang province, Thailand, and has a particle size of about 1–
fibre content is around 0.5% by weight, which provides the highest 100 lm (Table 1) and the silica fume is a by-product from the
flexural strength and fracture toughness of about 11.7 MPa and industrial production of silicon and ferro-silicon alloy, and has a
pffiffiffiffiffi particle size of about 0.03–0.3 lm (Table 1). The chemical solutions
1.12 MPa. m, respectively.
consist of a sodium hydroxide solution (NaOH) prepared using
Deepa Raj et al. [13] also studied the fracture properties of steel
hydroxide pellets mixed with water at a constant concentration
FRG using a three-point bending test on notched beams. The
of 14 M and a sodium silicate solution (Na2OSiO3) with specific
notched beams had a b/W ratio of 0.40 and fibre volume fractions
gravity of 1.60 at 20 °C. Two types of macro fibre were used: steel
of 0.25%, 0.50%, and 0.75%. The effect of the fibres was found to
and polypropylene, the properties and shapes of which are as
enhance the fracture properties of geopolymer such as the fracture
shown in Table 2. A chemical admixture, superplasticizer type F
energy and fracture toughness by 10–40% as compared to plain
(ASTM C494-81), was also used in the mix to ease the mixing
geopolymer.
procedure.
Karmar and Kumar [14] investigated the effects of a hybrid fibre
between steel and micro polypropylene fibre on properties includ-
ing the compressive, flexural, and splitting tensile strengths. The 2.2. Mix proportions
fibre combination used was steel fibre at 0.5% by volume with
the addition of micro polypropylene fibre at 10–50% of the steel Prior to determining the mixture proportion, a pre-test was car-
fibre volume. Their results showed that the optimum volume frac- ried out to determine the optimum sodium hydroxide solution
tions of micro PP fibre was 20% for compressive strength and 30% concentration that provides the greatest compressive strength of
for flexural strength. the geopolymer mortar, the results of which are shown in Fig. 1.
Table 1
Chemical composition of fly ash and silica fume.
Table 2
Fibre properties.
Fly ash to silica fume ratio of 90:10 by weight. Two tests were carried out: a compressive test (ASTM C39), and
Percentage of binder (fly ash + silica fume) to total weight of a flexural performance and toughness test (ASTM C1609) (Fig. 3).
0.65%.
Sodium hydroxide solution (NaOH) concentration of 14 M. Compression Test: This test was carried out according to ASTM
Sodium silicate solution (Na2OSiO3) to sodium hydroxide solu- C39 (compressive strength test method for cylindrical con-
tion (NaOH) ratio of 2.5 by weight. crete). Prior to the test, the specimen was polished at the both
Fine aggregate weight of 1613 kg with paste to fine aggregate of top and bottom surfaces, and the dimensions and weight were
1:2.75 by weight.
Table 3
Mixture proportion.
Fig. 8. Typical Flexural Responses of Single-Type (a) Polypropylene and (b) Steel FRG.
42 P. Sukontasukkul et al. / Construction and Building Materials 161 (2018) 37–44
the increase in strength of SFRG was also reported by Genesa et al. fracture test on SFRG and found an increase in both the first peak
[18]. In their study, the compressive strength, splitting tensile and ultimate strength occurs with an increase in steel fibre volume
strength, and modulus of rupture were found to increase by about fraction from 0.25 to 0.75%.
8.5, 61.6, and 24.0%, respectively when 1% steel fibre were added The fibre type and content also have a strong influence on the
into the geopolymer mixture. Deepa Raj et al. [13] carried out a percentage of load drop. For polypropylene FRG, because the PP
fibres are highly flexible with low stiffness, a significant drop in
load is often observed (Fig. 8a, Table 4). A maximum drop of
around 75% has been observed in 0.5% PFRG. The percentage of
drop decreases with an increase in fibre content. For steel fibres,
owing to the high strength and stiffness, the load is able to increase
more quickly than when polypropylene fibres are added (Fig. 8b).
The percentage of drop for SFRG falls at around 12–15%.
For the Hybrid FRG, the flexural responses are as shown in Fig. 9
and Table 5. The hybridization of steel fibre either through replace-
ment or addition affects the flexural responses during every stage.
At an early stage (pre-peak), the effect of the steel fibre causes an
increase in the first peak load. Immediately after the first cracking,
the steel fibres improve the percentage of load drop. The second
peak was also found to increase with the percentage of steel fibres
applied.
Considering the first peak load, and comparing between the
replacement and addition systems, the replacement system
appears to show clearer effects of steel fibre than the addition sys-
Fig. 10. Toughness of Single-Type FRG.
tem because the increase in peak load for the addition system is
Table 4
Comparison between First and Second Peaks of Single-Type FRG.
Table 5
Comparison between First and Second Peaks of Hybrid-Type FRG.
Hybrid type Fibre proportion 1st Peak (kN) Load Dropping 2nd Peak (kN)
kN %
Replacement 1PFRG 8.7 3.8 56.2% 14.3
0.8P/0.2S-HyFRG 10.5 7.9 24.9% 20.5
0.6P/0.4S-HyFRG 11.4 9.0 20.9% 24.3
0.4P/0.6S-HyFRG 11.6 9.5 17.9% 28.7
0.2P/0.8S-HyFRG 12.5 11.2 10.2% 30.8
1SFRG 12.9 11.3 12.4% 36.1
Addition 1PFGR 8.7 3.8 56.2% 14.3
1.0P/0.2S-HyFRG 9.0 8.4 13.6% 19.1
1.0P/0.4S-HyFRG 10.3 7.8 18.4% 20.7
1.0P/0.6S-HyFRG 11.1 10.0 10.3% 28.8
1.0P/0.8S-HyFRG 11.3 10.9 3.8% 28.0
1.0P/1.0S-HyFRG 11.5 10.4 9.9% 30.3
Table 6
Toughness and Equivalent Flexural Strength.
obviously the direct result of the increasing fibre volume fraction. value of 1SFRG because the total fibre volume fraction is controlled
However, for the replacement system, in which the total volume at 1.0%. However, for a-HyFRG, the increase in total fibre content
fraction remains constant at 1.0%, the increase in first peak load affects the flexural performance differently. The addition of steel
is clearly a reflection of the effectiveness of the steel fibre alone. fibre into a smaller amount of fibre content is likely to improve
the toughness gradually, but in higher fibre content, a difficulty
in mixing and a non-uniform distribution of the fibres can cause
3.2.2. Toughness and equivalent flexural strength a negative effect on the performance of the FRG.
The toughness and residual strength are calculated according to The equivalent flexural strength (EFS) indicates the ability of a
ASTM C1609. Toughness is the area under the load deflection specimen to carry a load after the first cracking occurs, and is
curve; it indicates the amount of energy the specimen is able to somewhat related to the post-peak response of a specimen. For
absorb under loading up to a certain deflection. In general, two single-type FRG, PFRG exhibits an EFS of about 31%–85%, whereas
toughness values are determined at 2 different deflections: L/600
and L/150. The equivalent flexural strength refers to the load carry-
ing capacity of the specimen after first cracking as a percentage of
the first peak load. The results from our study are given in Table 6
and Figs. 10–12.
For single-type FRG, regardless of the fibre type, the toughness
is found to increase with the increase in fibre content (Fig. 10). A
similar finding was also reported by Deepa Raj et al. [13], who
showed that the fracture toughness and fracture energy of SFRG
were found to increase with the increase in fibre volume fraction.
When comparing between the two types of fibres, the steel fibres
provide a higher toughness than polypropylene fibres at the same
volume fraction owing to better post peak performance.
The results of the toughness of HyFRG are shown in Figs. 11 and
12. Regardless of the hybrid type considered, the toughness was
found to increase with the percentage of replacement or addition
of steel fibre, although the rate of increase has a tendency to slow
down with a high steel fibre content. In the case of the r-HyFRG,
the toughness with a large deflection (L/150) never exceeds the Fig. 11. Toughness of r-HyFRG.
44 P. Sukontasukkul et al. / Construction and Building Materials 161 (2018) 37–44
Acknowledgements
References