IIt-jee chemistry by n.j.

sir Organic chemistry

DAILY PROBLEM PRACTICE SHEET

Q.1 (D) will underog haloform reaction

O O O

IIRR
KOH
Q.2 Ph–C–H + H–C–H 

 H–C–O–K+ + Ph–CH2OH
(A)

O O O OH O O
CH2
C C + HO–CH2 H
+ C
Q.3
CH2OH CH2OH C=O CH2 C=O

Q.4 (i)
.. SS
(A)

O
–
O
HO

O
H–C–H + H–C–H  H–C–OD + H–C–H  H–C–O + CH3OD
O
–
O
–
O
(B)

OD OD 
– –
O O O O O
..JJ
(ii) D–C–H + OD–  D–C–OD  D–C–OD + D–C–H  D–C–O– + CH2–OD
D–C–H
HO O
HO D

O OH H O
Q.5 H–C + Ph–CH2 Ph––C––C
NN

O– –
OH O
(i) (ii)
OH O CH3 O CH3
Q.6 CH3–CH2–C–CH–C–H CH–C + CH–CH2OH
–
H CH3 CH3 O CH3

(i) (ii)
OH O OH CH2O O
OH O OH CH2OH O
Q.7 H
H–C–CH2–C–H CH2–C––––C–H
H–C–CH2–N CH2–C––––N
O O H CH2 CH2OH
H CH2OH
(ii)
(i)

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