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Marion Schomaker1
Measurement and Control of the Gloss
Christian Schräer2
Marc Lörcher2,* of Chocolate
Taste and melting behavior are important quality criteria for chocolate. Beyond
these, the gloss, snap, and texture are relevant. Different process parameters influ-
ence the gloss as well as other criteria such as shell life and fat bloom resistance.
In this work, a method to measure the gloss of chocolate is introduced and
adapted to small chocolate articles. With this, the gloss could be measured repro-
ducibly. Different process parameters are varied and the gloss of the chocolate is
determined. Various methods to improve the gloss are suggested and evaluated.
1 Introduction
1.1 Gloss Appearance
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Research Article 2337
a highly polished black glass standard with a defined refractive late, the bars are demolded and their gloss is measured. To
index and known specular reflectance at a specified angle. improve the chocolate production, the influence of various
The gloss value is dimensionless and given in gloss units parameters on the gloss of chocolate needs to be assessed. For
(GU). By means of comparative assessment of two chocolate this purpose, different series of experiments are carried out in
bars with different gloss, the human eye can detect a difference several consecutive works. In a first test series, Glaser [2] exam-
of 5–10 GU. Without direct comparison a difference of ined the gloss of dark, milk, and white chocolate regarding dif-
10–15 GU is recognizable. For illustration, ten sample boards ferent process parameters like (1) surface roughness of the
lacquered in the same nuance and with a matting agent, the gloss mould, (2) rate of tempering, (3) cooling temperature, (4) resi-
of the sample charts reduced gradually. In Fig. 3, the sample dence in refrigerator, (5) mold temperature, and (6) storage
charts and the corresponding gloss values are presented. time. The liquid chocolate mass is tempered and then filled
into molds, which are used in chocolate production, too. A
refrigerator of a molding plant is employed for cooling and
1.2 Chocolate Production cristallization. In each test series, only one parameter is varied,
while the others are constant.
Chocolate is a composition of fine solid particles from sugar, The test series by Hones [7] shows an application of spray
cocoa, and milk powder dispersed in a continuous fat phase coating. For this purpose, the layer was applied by spraying
based essentially on cocoa butter. Cocoa butter consists mainly onto the mold surface. After cooling the layer, the alveoli were
of triglycerides that are composed of stearic, palmitic, and oleic filled with tempered milk chocolate. To measure the gloss,
acid. The peculiarity of cocoa butter is the polymorphism, so these chocolate bars were removed from the mold.
the triglycerides appear in various crystal lattices. In 1966, Heilemann [8] analyzed the influence of the mold core used
Wille and Lutton [4] identified six different crystal forms by for manufacturing the polycarbonate molds in test series. He
differential scanning calorimetry (DSC) and X-ray diffraction compared the surface structure of the mold with the used mold
(XRD). Detailed analysis indicates that six polymorphs exist core in microscopic images. Additionally, milk chocolate bars
classified as I to VI modification. The crystallization behavior were produced with test molds, which were made with various
of these polymorphs depends on the processing conditions. mold cores.
Their melting point rises with increasing crystal form (I–VI), The relation of a static charged mold to the gloss of the choc-
whereby the I to IV modifications are thermodynamically olate bars was evaluated in a further test series [9]. With the aid
unstable. The crystal form V is necessary to obtain chocolate of a generator and a charging electrode, electrostatically charg-
with a high gloss appearance, strong contraction during solidi- ing of the mold surface is applied. For this purpose, it is neces-
fying, good shelf life and melting behavior. The gloss of choco- sary that there is a grounded plate under the mold. Therefore,
late depends essentially on the surface properties, which are the preheated empty mold is removed directly in front of the
influenced by the crystal forms of cocoa butter and the contain- pouring system out of the molding plant and is placed on a
ing solid particles [5, 6]. grounded surface. In a few seconds, the mold is electrostatically
charged and laid back on its position. Before pouring the tem-
pered chocolate in the alveoli, the electrostatic charge of the
2 Materials and Methods mold surface is measured with an electrostatic fieldmeter. After
cooling, the chocolate bars are demolded and the gloss is mea-
In general, the test procedure includes the following: For tem- sured to evaluate the effect of electrostatically charging.
pering the liquid chocolate, a disk-tempering machine is used.
Thereafter, the tempered chocolate is filled into molds and then
cooled. The cooling of samples takes places in the refrigerator 2.1 Measurement of Gloss
of a chocolate molding plant. After solidification of the choco-
The bars are measured with the gloss meter
Novo Curve (Rhopoint). Before starting
the test series, five different measure instru-
ments for gloss were compared. The Novo
Curve has been selected due to the small
measuring area with a diameter of 2 mm
which is an advantage for determining the
gloss of chocolate products with a small flat
surface. At an angle of 60, light encounters
the sample surface and the intensity of
reflected light at an angle of 60 is deter-
mined. The measurements are carried out
under controlled conditions (20–25 C am-
bient temperature, 50 % relative humidity)
with the Novo Curve. Gloss is reported as
Figure 3. Reference charts for gloss: same lacquer nuance with different quantity of gloss units based on measurements of ten
matting agent; from left to right gloss is increasing [3]. samples within every setting.
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Research Article 2338
2.2 Measurement of Static Charge reflection for a black body is low; therefore, the relation to
specular reflection is high in contrast to a white body, which
With an electrostatic fieldmeter (SIMCO, FMX-004) the field causes more diffuse reflection and consequently the relation of
strength and polarity is measured at a set distance without con- diffuse to specular reflection is low. This is the reason why the
tact. The field strength depends on the distance to the sample human eye identifies an illusion of a higher gloss of the dark
surface. Therefore, two integrated LEDs help to maintain the chocolate. The origin of this dependency is the increase of dif-
correct distance of 2.5 mm. Due to the given distance, the mea- fuse reflection. A rough surface leads to a higher diffuse reflec-
sured value is reported in volt. This electrostatic fieldmeter is tion of incident light. The percentage of direct reflection
used to detect the electrostatic charge on the mold surface for decreases, leading to a reduction of visual and measured gloss
the test series concerning the gloss of chocolate. value. Briones et al. [9] also determined that gloss depends on
the surface roughness.
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Research Article 2340
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Research Article 2341
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Research Article 2342
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4 Conclusions References
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