NMAT REVIEW 2019 ORGANIC 8 BlocHenisTR MODULE A ss PROPERTIES spire [Sabet ee a a io [Yes [Yas Font ft es [No 1 [eT ves — The 20 N No__No_ [ves 3005. 1, Based on the data above, which substance Ijelyan erste compound? etait ast, 2 om an aldose 7 THON 40x10" TL HNO 45X10" ‘HL GHACOOH 60x 107 1. GHsNHSOH 46x10" , The table above shows the values of onkalion fanstant, Ky for Some acids and bases measured at 25%. 111M solons of the acds and bases given above are prepared and the corresponding conductance values freasured, which of the folowing Ghes the comect rangement In he order of decreasing conductivity? >> WV>T cll> >>I bivol>il> dI>V>Ml>il 3, which of ihe folowing technial grade ibortory Everts are most Skly to contain an appreciable amount Gf water due to hydrogen bonding? L. Diethyl ether TIL. Acetone oA, Hexane TV: Methanol eo) Land IT only 01, Hl and IV ony Bh, Wand 1V only 41,0, Wand 4. Which ofthe folowing description fs true about the ‘of 2 compound with a molecular formula Ci . entropy 6. free eneroy 11, Which fs nat re for a sigma bond? _2, strongest bond Grae ‘bformed by Sdeways overlapping o frst bond formed between atoms 4. determines te shape of the molecule re 12. The acthation energy, Eo of 2 certain eversor reaction 525 eal, The Ea fr the reverse reacton i ‘2 equal to 25 keal less than 25 kcal Bi greater than 25 keal drone ofthese 13, If each of the flowing is resonance szblzed, what Will be the correct arengement of he compounds ‘ecording fo their athe degree of aromatic character? ‘hepene > pyle > furan ». thiopene > furan > pyrole furan > pyro > thiopene d.furan > tlopene > pyrrle 14. Fats and os eontaln hich ofthe folowing? phosphate group _c)ghycerol lect d. cholestrol 15, An example of amino ac: ‘a benzene b. toluene c.gycne dhydrofsis 16, Which structure refers tothe number and sequence of ‘amino acids in a protein? ‘primary b. secondary c. teary d. quartenary 17, Amino acs extibit which property? 2. alltropism amphoterism . amphipathism dal 18, Protelns form which type of mbure in water? ‘soln. suspension ¢. collld — d.emulsion LEARNFAST REVIEW AND TUTORIAL HUB ~ NMAT REVIEWER19, Proteins are classed according to: fishape —. solubiity —¢, function 2p. Which of the following isan aca? a. GHOM 6, CHSCH,COOH b.cHOHs . CHCOCH, 21. An example of a carbohydrate is 3.CHOOH (CHO) 22. The wo coins of DNA ae held together Pasutde —bebydeogen e.tonk ape ISOMERISM AND NOMENCLATURE HL cts cus ° “© NH 2, wat confguation is shown by the ruta fern Sretgaebs, Gout Sasori 6 eine carton ORGANIC REACTIONS 4. all ofthese CGHOH d.cH 24, Niraton of phenol with dite HNO} yields o- ritrophenol and pritrophencl. Which of the folowing tals this result? Benzene orhoand para directing Phenolic group s orthoand pare directing. Neri acd Is ortho and para drecting. (Nive acd is meta directing. R-Mg--Br+CO2 —*2, 25, The equation above shows the reaction between a Gfinard reagent and carbon doxide. What compound wll res frm ths reaction? GR-GLOH D.R=CHO c.R-COOH d,R-COOR Cus ——> CHa + CoHu 26. When ofthe folowing processes is represented by the reaction above? 2. Substitution orecking by Synthesis 4. Poymerzaton 27. Which ofthe following struc? FL The action energy, Ea ofa certain exergonic reaction 1550 kel The Za for ine reverse reaction canbe 40 kel. IL Monosaccharides are simple sugars and examples are ‘uaa, glucose, ribose ad insuin i Enaymes bind ther substrates and hold them in 2 satealar orientation. 1. Enzymes ually work only in a particular pH range 31a tare rue allare tue ‘ll and IV are true Satvaretve 28. When suze syed, yi: 2 here en .lucase + gabctose Biakease + ructose 6. rose + pact 101 29, In a replacement reaction, elements that have the ‘mast ablity to hold ont their electrons are: _a. The mast chemical active “DoThe least chemically active Not generally involved in replacement reactions 4. None of the above is correct 30. The process involved in the reaction between 2n alia and fatty acid is cae a 2. allylation A, ester (A saponication ».calnaton 31. Using Markovnikey's rule in the hydration of alkenes atthe OA cc HD ‘CH,CH,CH,CH=CH2 5 CHJCHLCHCHTCHS ¢. CHICLCH:CHICHS net ch E.CCHICHCHCHS Db. CHCHCHCHOH 12. ety ethanoate undergoes hycrotss ad one of the products undergoes dehydration you wil make. Srethone ‘cetnanel ethaal S enene 33. compound X opty decolrizes in a saluion, of irom h Coe When X's supjected t0 ozord 18D products ne formed, namely buinone and propel | Wiha the suture of Leter A o. CHCHaC-CHCH2CHs ee b. CH:CHE=CHCHRCHs CHa 6. CHjCH2CH;CH2CH20H d. CH3CH,CH2CH=CHCH2CHs 234, In exer to snthessebutyropancate you would use: 2. GHOH ad CH;COOH b. GH,OH and CHCOOH .GHOH and C3H:C00H “8. CANON and GH:COOH 13, The conversion of methane into chloromethane In the presence ef UV ight se xan ot: beeep rein (cee aa ntstoton celmination 5 hydielysis LEARNFAST REVIEW AND TUTORIAL HUB ~ NMAT REVIEWER36. Given the graph below, what type of reaction iorwrd reaction represent? P= Te2con does the 2 Edothermic 1. Both A and © & Scthemie Neither & nor Activated Complex Time of Reaction isthe activation energy and AG ste change in Gibbs fre energy (Wma, ee +37, I the product of the reaction between CiHls and HBr is ‘rested with aqueous NaOH, you get... BCHCHO (DGHOH CGH 4. GHBn 38, In order to syrthesise butanal from I-bromebutane an. Ey reflux 1-bromobutane with aqueous KOH then oxidise frganc produc, distiling of the butanal . ref I-bromobutane with aqueous KOH then oxidise the ergante product by refluxing with acidified dicrromate reflux L-beomebutane with alcoholic KOH then oxidise the organic product by revluxing with acidified dichromate 4 reflux 1-bromobutane with alcoholic KOH then oxidise the organic product using distiation +8, Te reaction between an akohol and a carbarylic add iganexample of. 2. aon ‘elimination esterification BD ——PDHFHE O) ® © Oy Fer the above reaction, answer questions 42 to 43: 42, The enzyme substrate complex C BTheend product =D 44, Ketones can be prepared by the oxidation | primary akobols by secondary alcohols “€ tetany alcohos 4. camet be prepared by oxidation reactions 102 4 what process converts an aldehyde to carboxylic 01? 2; oxidation «reduction addition 4. substitution 46, Al proteins contain the elements C, H, © and! aN bs cp Fe 47. Whats the functional group present in formalin? a. aldehyde b. alcohol c ketone dam 48, Which othe foowig is most acide? a. CG CH:OH ‘. GiCH:COO! b. GHCOCHS 4. CHyCH:CHO 49, When 2-propanane undergoes reduction, what producti obtained? 2. propancic acid « propanal ,2-propane! 6. 2-propanal 50, What amine Is most basic? 2, aromatic _/b, secondary primary 4 tertiary LEARNFAST REVIEW AND TUTORIAL HUB ~ NMAT REVIEWER.