Cambridge International AS Level Chemistry Answers to end-of-chapter questions

Answers to EOCQs
Chapter 14 b 140 g of C2H4 = 140
28  mol = 5 mol [1]
396 g of C2H4Cl2 = 396
99  mol = 4 mol [1]
1 a i carbon (Ar = 12.0): 85.7 g of C per 100 g of
compound yield = 45  × 100% = 80% [1]
85.7 = 7.14 mol of C per 100 g of compound c
12.0 H Cl Cl H
[1]
H C C Cl H C C Cl
hydrogen (Ar = 1.0): 14.3 g of H per 100 g of
compound H H H H
14.3 = 14.3 mol of H per 100 g of compound
1.0 1,1-dichloroethane 1,2-dichloroethane
[1]
[1 mark for each correct displayed formula;
ratio number of atoms of H 14.3
=
number of atoms of C 7.14
= 2 [1]
1 mark for each correct name] [4]
empirical formula = CH2  [1] d i I is substitution [1]
ii Relative molecular mass of empirical ii II is addition [1]
formula, CH2 = 12 + 2 = 14 Total = 13
Relative molecular mass of unknown
molecule = 56
So the number of units of the empirical
formula is 56
14 = 4
So the molecular formula is (CH2) × 4 = C4H8
[1]
b i H H
C H3 C H H3C CH3
H H
C C C C C
C
H C H H CH3 H H
H H
but-1-ene trans-but-2-ene cis-but-2-ene
[1 mark for each structure] [3]
[1 mark for each name] [3]
ii
H H
C H
H C C
H
C H
H
H

2-methylpropene
[1 mark for the structure, 1 mark for the
name][2]
Total = 13

2 a i 600 g of C2H6 = 600

30  mol = 20 mol[1]
ii 20 mol[1]
iii 148.5 g of C2H4Cl2 = 148.5
99  mol = 1.5 mol[1]
yield = 1.5
iv 20  × 100% = 7.5% [1]

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