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Lecture 1
Dr. M. Coley
1
Fluid Characteristics
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Course Outline & Description
6 lectures
11/2 questions – Paper 1
Textbooks
Unit Operations of Chemical Engineering
Warren L. McCabe, J. Smith & P. Harriot
McGraw-Hill
Introduction to Chemical Engineering
Walter Badger & Julius Banchero
McGraw-Hill
Fluid Mechanics – 9th ed
J.F. Douglas, J. Gasiorek & J. Swaffield
ELBS Longman 3
What is a Fluid?
A fluid is a substance that may flow.
A fluid is a substance that deforms continuously
when subjected to a shear stress.
Characteristics:
Its constituent particles may continuously change
their positions relative to one another.
A fluid offers no lasting resistance to the
displacement of one layer over another.
If a fluid is at rest, no force tangential to the surface
on which it acts (shear force) can exist in it. 4
Fluid Characteristics
Any fluid, no matter how viscous, will flow, even
imperceptibly, when a net shear force is applied.
A fluid will continue to flow as long as such force is
applied.
A solid, even if very plastic, will not flow unless a net
shear force exceeds a certain value.
Gases:
Widely spaced molecules with small intermolecular forces
Take volume and shape of container
gas
liquid
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Fluid Mechanics
Most chemical processes are conducted in the
fluid phase
Reasons:
- cheaper to handle
- easier to react
- easier to transport
Solids often fluidized for easier handling
Fluid Statics
Properties of fluids at rest
Fluid Mechanics
Fluid Dynamics
Properties of fluids in motion7
Fluid Statics?
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Effects of Fluid Dynamics?
9
Fluids & their Properties
Fluid at Rest
- no shear forces are acting
- forces acting must be perpendicular
to planes they act on 10
Fluid in Motion
Layers of
fluid slide
over each
other
Fluid under
shear
stress
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Fluids & their Properties cont’d
gases
Fluids both will flow
liquids
All fluids will flow regardless of viscosity
Liquids
• takes shape of container - leaves free space
• Shape will change if shear stress exists
• No stress at ≡M – deforms in response to shear stress
Gases
• Occupy entire container
• Expand continuously unless restrained 12
Fluid in Motion - Gas
Easy to compress
No fixed volume
Fluid Layer 1
F F
Fluid Layer 2
Upper layer moving faster, & will draw lower layer with a force F.
Lower layer will retard upper layer with equal, opposite force F
Newton’s Hypothesis
For the straight & parallel motion of a given fluid, the tangential stress
between two adjoining layers is proportional to the velocity gradient in
a direction perpendicular to the layers.
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Newtonian & Non-Newtonian Fluids
= حF/A ≈ du/dy
= حμ(du/dy)
Newtonian Fluids
• Viscosity independent of rate of shear
• Viscosity independent of magnitude of shear stress
• Fluid viscosity is constant with pressure applied & rate of flow
• Time independent fluid – viscosity unchanged with time of force
• Eg. most fluids, water 17
Newtonian & Non-Newtonian Fluids
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Non-Newtonian Fluids
Bingham Plastic
Resist small shear stress
Flow readily if larger stress is applied
Flow with large stress is Newtonian
Eg. toothpaste, jellies
Pseudo-plastic
Includes most non-Newtonian fluids
Curve passes through origin but bends downwards
Fluid more viscous at low shear stress
Less viscous at high stress
Attraction between particles diminish - disrupted
Called shear-thinning fluids 19
Non-Newtonian Fluids
Dilatant
Viscosity increases with velocity gradient
Shear thickening fluids
Eg. starch suspensions
Thixotropic fluids
- viscosity decrease with time
- fluids expands or structure breaks down
- interaction between particles reduces
- eg. paints
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Non-Newtonian Fluids
Rheopectic Fluids
Viscosity increases as shear rate increases
Behavior is opposite to thixotropic
Eg: gypsum suspension
Visco-elastic fluids
Have elastic properties
Will spring back when stress is released
Eg: egg white
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