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CHALY ~Analytical Cremictry (Ascignmerrt 3) CHAPTERS 82 So FAL oh 114. The sulfate ion concentration in natural water can be determined by measuring the turbidity that results when an excess of BaCl, is added to a measured quantity of the sample. A {urbidimeter, the instrument used for this analysis, was calibrated with a sories of standard Na,SO, solutions. The following data were obtained in the calibration for sulfate concentrations, a [| exmg soe Turbidimeter Reading, R 0.00 0.06 5.00 148 10.00 228 15.00 398 200 461 Thal there isa Iinear relationship between the instrument reading and concentration (@.) Plot the data. and draw a strain line herwah the points by eye wR Y= 0.290 ¥ +0. len = 5.9034 oe amony ore poinh , the leact ~cyvares ctepe: 0-23 thee od fr leact-eqvarce inkrept » tne Catibeation eye i OMe. wes VOR init > beac hepaser > te D eat att eee {6.) Compute the concentration of sulfate in a sample yielding a turbidimeter reading of 2.0. id abo ands dviain ar he cout of ation Et Ae ismyln so GY | Cat mn Be eit 8 0. cob fe zeit two ty (2) Erp (Sa fase en Tie + Ce Arte: The concentra aint is J daiatin & yt a at ts + aay 22. Copper was determined in a river water sample by atomic absorption spectrometry and the ‘method of standard additions, For the addition, 100.0 yL of a 1000.0-p g/mL Cu standard was. ‘added to 100.0 mi of solution. The folowing data were obtained ‘ ‘Absorbance of reagent blank = 0.020 Gi} Absorbance of sample = 0.520 ‘Absorbance of sample plus addition - blank = 1,020 (@.) Calculate the copper concentration in the sample, Giten: Tota] volone, oF fil = 100.0 ul +(100.0xi0°ab) athe adattien (Vp) Wy 1g0.1ab + lat oF dr th eo ® 100.0 ty lab ont trata mda o Es Int atatn ah nied nee. ony ' wine. unkaown lh ~ 100.0 ah He on teed (% ) Foreule: = A Genie — ant) a cu hi pdeay ¥ Compe ¥atfgs) Saas ie __(0-80-0.800) ) = (aan OEY] Ue = Tab = 0. 490 (0.499 $0.49 6) eu) > 9-490 Coa + 0-909 (4) gst ca = 0-4097 om cH = 0-409) wo sil" = 9-158 Aur. The (u) in te Sample it

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