CHALY ~Analytical Cremictry (Ascignmerrt 3)
CHAPTERS 82 So FAL oh
114. The sulfate ion concentration in natural water can be determined by measuring the turbidity
that results when an excess of BaCl, is added to a measured quantity of the sample. A
{urbidimeter, the instrument used for this analysis, was calibrated with a sories of standard
Na,SO, solutions. The following data were obtained in the calibration for sulfate concentrations,
a [| exmg soe Turbidimeter Reading, R
0.00 0.06
5.00 148
10.00 228
15.00 398
200 461
Thal there isa Iinear relationship between the instrument reading and concentration
(@.) Plot the data. and draw a strain line herwah the points by eye
wR
Y= 0.290 ¥ +0. len
= 5.9034
oe amony ore poinh , the leact ~cyvares ctepe:
0-23 thee
od fr leact-eqvarce inkrept » tne
Catibeation eye i OMe.
wes VOR init > beac hepaser
> te
D eat att eee
{6.) Compute the concentration of sulfate in a sample yielding a turbidimeter reading of
2.0. id abo ands dviain ar he cout of ation
Et Ae ismyln so GY | Cat
mn Be eit 8 0. cob
fe zeit
two ty (2) Erp (Sa fase en
Tie
+ Ce
Arte: The concentra aint
is J daiatin &
yt a at ts + aay22. Copper was determined in a river water sample by atomic absorption spectrometry and the
‘method of standard additions, For the addition, 100.0 yL of a 1000.0-p g/mL Cu standard was.
‘added to 100.0 mi of solution. The folowing data were obtained
‘ ‘Absorbance of reagent blank = 0.020
Gi} Absorbance of sample = 0.520
‘Absorbance of sample plus addition - blank = 1,020
(@.) Calculate the copper concentration in the sample,
Giten: Tota] volone, oF fil = 100.0 ul +(100.0xi0°ab)
athe adattien (Vp) Wy 1g0.1ab
+ lat oF dr th eo ® 100.0 ty lab
ont trata mda o Es Int
atatn ah nied nee. ony
' wine. unkaown lh ~ 100.0 ah
He on teed (% )
Foreule: = A Genie — ant)
a cu
hi pdeay ¥ Compe ¥atfgs)
Saas
ie __(0-80-0.800)
) =
(aan OEY] Ue
= Tab
= 0. 490
(0.499 $0.49 6)
eu) > 9-490 Coa + 0-909 (4)
gst ca = 0-4097
om cH = 0-409)
wo sil"
= 9-158
Aur. The (u) in te
Sample it