MSDS No

Material Safety Data Sheet

PAGE
GEOCOTE S-570 F1 1/9

1. CHEMICAL PRODUCT ＆ COMPANY IDENTIFICATION

1) Chemical Product Name : GEOCOTE S-570 F1
2) Use : Water-soluble anti-corrosive coatings
3) Manufacturer : L'BESTE GAT LTD.
- Head Office : 8F Line Bldg., 823-30, Yeoksam 1-dong, Gangnam-gu, Seoul, 135-933,
Korea
TEL : +82-2-579-3691, FAX : +82-2-579-3692
544-3, Sutae-Ri, Daeso-Myeon, Eumseong-Gun, Chungcheongbuk-Do, Korea
TEL : +82-43-882-2378, FAX : +82-43-881-2380
4) Supplier : L'BESTE GAT LTD.
5) Create department : R&D CENTER

2. HAZARD IDENTIFICATION
Flammable liquid: Category 3
Acute toxicity (oral) Category 4
1) Hazard, Risk Classification  Skin corrosion / irritation: Category 2
 Acute aquatic hazard: Category 1
 Chronic aquatic hazard: Category 1
2) Label Elements Including Precautionary Statements
Symbol Signal word Hazard statement
Harmful if swallowed
Causes skin irritation
Danger Very toxic to aquatic life
Toxic to aquatic life with long lasting effects
- Keep away from heat, sparks, open flames and high heat. -no
smoking
- Keep container tightly closed.
- Please join the container and receiving equipment or the
ground.
- Prevention - Use explosion-proof electrical, ventilating, lighting equipment.
- Please use only non-sparking tools.
- Take precautionary measures against static discharge.
- Wash thoroughly after handling the treated area.
- When using this product Do not eat, drink or smoke.
- Avoid release to the environment.
- Wear protective gloves, protective goggles or face protection
- If you feel uncomfortable swallowed, call a poison center.
- IF ON SKIN: Wash with plenty of soap and water.
- SKIN (or hair): Take off please remove all contaminated
clothing gets on. Rinse skin with water / shower.
- Treatment - Rinse mouth.
 - If skin irritation occurs medical attention, please seek advice.
 - Take off contaminated clothing and wash before reuse.
 - Please use the carbon dioxide, foam, powder fire extinguishers
to turn off the fire. Water disabled.
 - Please collect spillage
- Storage - Keep in a well-ventilated place. Keep cool.
- Disposal - Dispose the contents/container in accordance with
local/regional/national/international regulations.
3) Other Hazard∙Risk which are not included in the classification criteria
(e.g. dust explosion hazard)
Health : 2
Flammability : Not available
Reactivity : Not available
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3. COMPOSITION / INFORMATION ON THE INGREDIENTS

1) CHEMICAL COMPONENTS
COMPONENTS CAS. No Wt %
Zinc 7440-66-6 40-60
Aluminum 7429-90-5 3-15
Glycol 25265-71-8 10-20
Mineral spirits 64742-48-9 1-3
Surfactants 25322-68-3 2-8

4. FIRST-AID MEASURES
1. Eye contact
- In case of contact with substance, immediately flush eyes with running water at least 20
minutes.
- If eye irritation persists, get medical attention.
2. Skin contact
- Remove the contaminated clothes and food wear.
- Wash contaminated clothing before reuse.
- If skin irritation or rash occurs: Get medical attention.
- Make your material immediately upon contact with the skin and eyes and wash under running
water for 20 minutes or more.
- Prevent the spread when contaminated sites Meehan skin contact..
3. Inhalation
- Move to fresh air and breathe comfortably and relax.
- Carried out three teeth and nostrils, and if symptoms persist, please seek medical attention.
4. Ingestion
- Rinse mouth.
- Do not induce vomiting.
- If vomiting should occur spontaneously, keep airway clear.
- Get medical attention.
- Never give anything by mouth to an unconscious person.
5. Indication of immediate medical attention and notes for physician
- Contact staff when exposed to a special emergency measures and keep track of such
investigations.
  - Medical personnel are aware of the material to please and take protective measures.
     (Route of exposure)
  - Inhalation: Vapor may affect between can be irritating to nose, throat and airway.
  - Skin: may cause slight irritation depending on the severity and duration of exposure.
  - EYE CONTACT: it can cause slight eye irritation.

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  - Ingestion: May cause nausea, vomiting and diarrhea. When ingested in large amounts it can
be fatal. (Effects of overexposure)
-  Acute: This product is seen as the "route of exposure" may cause slight irritation. When
heated to a temperature of zinc can produce a zinc oxide gas which may cause "metal fume
fever" with a cough, headache, nausea, vomiting, chills, fever and characteristics. (This
serious eye irritation.)
- Chronic: Repeated / long-term exposure may cause skin defects.
The cause conjunctivitis can occur during long-term contact with the eyes.
Repeated ingestion may cause other effects as well as the visually impaired.

5. FIRE-FIGHTING MEASURES
1. Suitable (and unsuitable) extinguishing media
- Dry sand, dry chemical, foam, CO2 use. Do not use only water..
2. Specific hazards arising from the chemical
- Acid, an alkali, a halogen specific drug, or can be contacted with water to generate hydrogen
gas during storage for a long time.
  - Will be prohibited in contact with combustible materials.
  - Hydrogen gas is highly flammable, there is the potential to explode if mixed in the air, get
in tight places.
  - If the contact with water can result in methyl alcohol.
3. Special protective equipment and precautions for fire-fighters
- Rescuers should put on appropriate protective gear.
- Evacuate area and fight fire from a safe distance.
- Substance may be transported in a molten form.
- Dike fire-control water for later disposal; do not scatter the material.
- Move containers from fire area if you can do it without risk.
- Fire involving Tanks; Fight fire from maximum distance or use unmanned hose holders or
monitor nozzles.
- Fire involving Tanks; Cool containers with flooding quantities of water until well after fire is
out.
- Fire involving Tanks; Withdraw immediately in case of rising sound from venting safety
devices or discoloration of tank.
- Fire involving Tanks; Always stay away from tanks engulfed in fire.
- Fire involving Tanks; For massive fire, use unmanned hose holders or monitor nozzles; if
this is impossible, withdraw from area and let fire burn.

6. ACCIDENTAL RELEASE MEASURES

1. Personal precautions, protective equipment and emergency procedures
- Eliminate all ignition sources.
- Stop leak if you can do it without risk.
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GEOCOTE S-570 F1 4/9

- Please note that materials and conditions to avoid.

- Ventilate the area.
- Do not touch or walk through spilled material.
- Prevent dust cloud.
2. Environmental precautions and protective procedures
- Prevent entry into waterways, sewers, basements or confined areas.
- Avoid release to the environment
3. The methods of purification and removal
- Small Spill; Flush area with flooding quantities of water. And take up with sand or other
non-combustible absorbent material and place into containers for later disposal.
- Large Spill; Dike far ahead of liquid spill for later disposal.
- With clean shovel place material into clean, dry container and cover loosely; move containers
from spill area.
- Large spill liquid spills and blinded to Make a ditch.
  - Clean spills with a clean shovel and put it in the back loosely closed containers, dry
containers from spill area.
  - Prevent the spread covered with a plastic sheet during powder leakage. Keep dry.
  - Small spill Absorb with sand, non-flammable material and place in containers.

7. HANDLING AND STORAGE

1. Precautions for safe handling
- Do not handle until all safety precautions have been read and understood.
- Avoid breathing dust/fume/gas/mist/vapours/spray.
- Wash ... thoroughly after handling.
- Use only outdoors or in a well-ventilated area.
- Follow all MSDS/label precautions even after container is emptied because they may retain
product residues.
- Use carefully in handling/storage.
- Loosen closure cautiously before opening.
- Please note that there are materials and conditions to avoid.
2. Conditions for safe storage
- Store in a locked storage area.
- Empty drums are completely drained and properly prevents back into place immediately,
please drums regulator properly placed.

8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

1. Occupational Exposure limits
- Korea regulation : aluminum TWA = 10 mg/m³, Mineral spirits TWA = 1,350 mg/m³
- ACGIH regulation : aluminum TWA = 1 mg/m³
- Biological exposure index : Not available
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GEOCOTE S-570 F1 5/9

- OSHA regulation : Not available

- NIOSH regulation : Not available
- EU regulation : Not available
- Other : Not available
2. Appropriate engineering controls
- Use process enclosures, local exhaust ventilation, or other engineering controls to control
airborne levels below recommended exposure limits.
- If user operations generate dust, fume, or mist, use ventilation to keep exposure to airborne
contaminants below the recommended exposure limit.
- Facilities for storing or utilizing this material should be equipped with an eyewash facility
and a safety shower.
3. Personal protective equipment
Respiratory protection
- Wear NIOSH or European Standard EN 149 approved full or half face piece (with goggles)
respiratory protective equipment when necessary.
- In case exposed to particulate material, the respiratory protective equipment as follow is
recommended. ; filtering face-pieces respirator or air-purifying respirator, high-efficiency
particulate air(HEPA) filter media or respirator equipped with powered fan, filter media of
use(dust, mist, fume)
- In lack of oxygen(< 19.5%), wear the supplied-air respirator or self-contained breathing
apparatus.oxygen
Eye protection
- Wear breathable safety goggles to protect from particulate material causing eye irritation or
other disorder.
- An eye wash unit and safety shower station should be available nearby work place.
Hand protection
- Wear appropriate protective gloves by considering physical and chemical properties of
chemicals.
Body protection
- Wear appropriate protective clothing by considering physical and chemical properties of
chemicals.

9. PHYSICAL AND CHEMICAL PROPERTIES

1) Appearance(physical state, color etc) : Silver paste viscosity
2) Odour : Light and sweet aroma oil
3) Odour Threshold : No data
4) pH : Not applicable
5) Melting point / Freezing point : No data
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GEOCOTE S-570 F1 6/9

6) Initial Boiling point and boiling range : ca 230℃
7) Flash point : ca 120℃
8) Evaporation rate : Min - 2.9%, Max - 12.6%
9) Flammability(solid, gas) : No data
10) Upper/lower flammability or explosive limits : No data
11) Vapor pressure : >1.3pa
12) Solubility : Mixed in any proportion
13) Vapor Density : ca 4.65
14) Specific gravity : 1.6±0.2(20℃)
15) Partition coefficient:n-octanol/water : Not applicable
16) Auto-ignition temperature : Not applicable
17) Decomposition temperature : Not applicable
18) Viscosity : No data
19) Molecular mass : Not applicable

10. STABILITY AND REACTIVITY

1. Chemical stability and Possibility of hazardous reactions
- May decompose at high temperatures into forming toxic gases.
- Containers may explode when heated.
- Some of these materials may burn, but none ignite readily.
- Non-combustible, substance itself does not burn but may decompose upon heating, then
produce corrosive and/or toxic fumes.
2. Conditions to avoid
- Acid, alkali, water, chlorinated compounds, oxidizers, heat, sparks, open flame ignition
sources such as
3. Incompatible materials
- Combustibles, reducing agents
4. Hazardous decomposition products
- Under some conditions (high temperature, acidic or basic and upon contact) is zinc, and can
form the hydrogen gas in a limited place, that may explode in a sealed air-air or during
mixing.
  - Which may contain a thermal decomposition carbon, oxygen toxicity of the silicon and zinc.
  - Upon contact with water that can produce methyl alcohol.

11. TOXICOLOGICAL INFORMATION

1. Acute Toxicity
Oral (LD50, Rat) : Category 4
zinc : 630mg/kg
Glycol : 5,660mg/kg
Mineral spirits : 15,000mg/kg
Surfactants : 600mg/kg
(Forecast: 300 <ATEmix <2,000mg / kg, Category 4)
Inhalation (LD50, Rabbit):
Glycol : 2,700mg/kg
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GEOCOTE S-570 F1 7/9

Mineral spirits : 3,160mg/kg
(Prediction: ATEmix> 2,000mg / kg, etc.)
Dermal : No Data
2. Skin corrosion/ irritation : Category 2
Constituent content is less than 10% containing (skin irritation)
3. Serious eye damage/ irritation : Not available
4. Respiratory sensitization : Not available
5. Skin sensitization : Not available
6. Carcinogenicity :
The content of the component is excluded from Category 2 separated by less than 1%
7. Mutagenicity : Not available
8. Reproductive toxicity : Not available
9. Specific target organ toxicity (single exposure) :
Category 3 components are excluded from the content of divided according to the less than
20%
10. Specific target organ toxicity (repeat exposure) : Data Not classified due to lack
11. Aspiration Hazard :
Ingredient content of the category 1, except in the segment according to the less than 10%

12. ECOLOGICAL INFORMATION

1. Ecological toxicity
- Acute toxicity : Category 1
- Chronic toxicity : Category 1

zinc : LC50: 0.24mg / L (fishes), EC50: 0.354mg / L (crustaceans), EC50: 0.106mg / L

Glycol : LC50: 1,300mg / L (fish)
Mineral spirits : LC50: 2,200mg / L (fishes), LC50: 2.6mg / L (crustaceans)
Surfactants : LC50: 20,000mg / L (fish)
2. Persistence And Degradability : No data

3. Bioaccumulation Potential : No data

4. Mobility In Soil : No data
5. Other Adverse Effects : No data

13. DISPOSAL CONSIDERATIONS

1. Disposal method
Waste must be disposed of in accordance with federal, state and local environmental control
regulations.

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2. Disposal precaution
Consider the required attentions in accordance with waste treatment management regulation.

14. TRANSPORT INFORMATION

1. UN Number : Not applicable
- International regulations
     Maritime transport: subject to the provisions of the IMO / IMDG.
     Air transport: comply with the ICAO / IATA regulations.
  - All. National regulation
    Land transport: Fire Services Act, subject to the Occupational Health and Safety Act.
     Maritime transport: subject to the provisions of the Bill of Lading.
     Air transport: Aviation comply with the regulations.
2. UN Proper shipping name : Not applicable
3. Transport Hazard class : Not applicable
4. Packing group : Not applicable
5. Marine pollutant : Not applicable
6. Special precautions
Dangerous goods shall not conduct or damaged shipping container fall, one housing the
downfall of the dangerous or hazardous materials.

15. REGULATORY INFORMATION

1. KOREA Regulatory information

- Occupational Safety and Health Regulation :
[Zinc] managed hazardous substances
   [Aluminum] managed hazardous materials, special medical diagnostic substances (diagnostic
period: 12 months).
               Working environment measurement target substance (diagnostic period: 6 months)
exposure limits set material
- Toxic Chemical Control Act : Not regulated
- Dangerous Material Safety Management Regulation :
[Zinc] second-class metal powder 500Kg
   [Glycol] The four kinds of petroleum third (aqueous) (4,000L)
  [Mineral spirits] The second four kinds of petroleum (non-aqueous) (1,000L)
   [Surfactant] The fourth current third petroleum
- Wastes Control Act :
[Glycol] designated waste
   [Mineral spirits] hazardous waste
   [Surfactant] designated waste
- Other regulation (internal and external)
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Internal information
Persistant Organic Pollutants Acts : Not regulated
2. Foreign Regulatory Information
External information

EU EU
EU classification
classified information classified information
(Classification)
(Risk phrases) (safety phrases)
S2, S43, S46, S60,
Zinc F;R15-17/N;R50-53 R15, R17, R50/53
S61
Aluminum F;R15-17 R15, R17 S2, S7/8, S43
Glycol Xi;R36 R36 S2, S24, S26
Mineral spirits R45, R46, R65 R45, R65, R46 S53, S45

U.S.A management information (OSHA Regulation) : Not regulated

U.S.A management information (CERCLA Regulation) : Not regulated
U.S.A management information (EPCRA 302 Regulation) : Not regulated
U.S.A management information (EPCRA 304 Regulation) : Not regulated
U.S.A management information (EPCRA 313 Regulation) : This corresponds (zinc, aluminum)
Substance of Rotterdam Protocol : Not regulated
Substance of Stockholm Protocol : Not regulated
Substance of Montreal Protocol : Not regulated

16. OTHER INFORMATION

1) Information source and references : L'BESTE GAT R&D CENTER
2) Issuing date : July 28, 2017
3) Revision number and date : July 28, 2017 (rev.0)
All information, recommendations and suggestions appearing herein concerning our product are
based upon tests and data believed to be reliable. However, it is the user's responsibility to
determine the safety, toxicity and suitability for his own use of the product described herein.
Since the actual use by others is beyond our control, no guarantee, exposed or implied, is
made by L'BESTE GAT KOREA Ltd. as to the effects of such use, the results to be obtained
or the safety and toxicity of the product nor does L'BESTE GAT KOREA Ltd. assure any
liability arising out of use, by others, of the product referred to herein. The information herein
is not to be construed as absolutely complete since additional information may be necessary or
desirable when particular or exceptional conditions or circumstances exist or because of
applicable laws or government regulations. To the best of our knowledge, although certain
hazards are described herein, we cannot guarantee that these are the only hazards which exist

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