CHEMISTRY DPP 2

BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

GOC: REACTION MECHANISM

1 Acetaldehyde reacts with semicarbazide, product will be :

(a) 𝐶𝐻3 𝐶𝐻 = 𝑁𝑁𝐻 − 𝐶𝑂 − 𝑁𝐻2
(b) 𝐶𝐻3 𝐶𝐻 = 𝑁𝐶𝑂𝑁𝐻𝑁𝐻2
(c) 𝐶𝐻3 𝐶𝐻 = 𝑁𝐻𝑁𝐻2

(d)

2 Cyanohydrin of the following compound on hydrolysis gives compound

that can show optical isomerism :
(a) HCHO (b) 𝐶𝐻3 𝐶𝐻𝑂
(c) 𝐶𝐻3 𝐶𝑂𝐶𝐻3 (d) All the above

3 In this reaction :
𝐻2 𝑂
𝐶𝐻3 𝐶𝐻𝑂 + 𝐻𝐶𝑁 → 𝐶𝐻3 𝐶𝐻(𝑂𝐻)𝐶𝑁 → 𝐶𝐻3 𝐶𝐻(𝑂𝐻)𝐶𝑂𝑂𝐻
an asymmetric centre is generated. The acid obtained would be :-
(a) D-isomer (b) L-isomer
(c) 50% D + 50% L-isomer (d) 20% D + 80% L-isomer

4 When two mole of alcohol reacts with 1 mole of ketone, it gives :-

(a) Hemiacetal (b) Acetal
(c) Hemiketal (d) Ketal

5 When acetone reacts with Grignard reagent it gives followed by

hydrolysis, it gives :
(a) 10 − 𝑎𝑙𝑐𝑜ℎ𝑜𝑙 (b) 20 − 𝑎𝑙𝑐𝑜ℎ𝑜𝑙
(c) 30 − 𝑎𝑙𝑐𝑜ℎ𝑜𝑙 (d) Methyl alcohol
 CHEMISTRY DPP 2

BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

6 Reaction of HBr with propene in the presence of peroxide gives

(a) 3-bromo propane (b) Allyl bromide
(c) n-propyl bromide (d) Isopropyl bromide

𝐻𝐵𝑟
7 Isobutene → “product”. The product is
𝐻2 𝑂2
(a) Isobutyl bromide (b) Tert. butyl bromide
(c) Tert. butyl alcohol (d) isobutyl alcohol

ANSWER KEYS
1.A 2.B 3.C 4.D 5.C 6.C 7.A