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9/10/2020 Polypropylene (PP) Plastic: Types, Properties, Uses & Structure Info

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The Definitive Guide to Polypropylene (PP)


Polypropylene (PP) is a rigid and crystalline thermoplas c used widely in everyday objects like packaging trays, household products, ba ery cases,
medical devices, etc. Explore this comprehensive guide and learn everything you need to know about this widely used thermoplas c.

Quick Links to the Detailed Profile:

» What is Polypropylene and What It's Used for?


» How PP is produced?
» Types of Polypropylene & their Benefits
» Main Differences Between PP Homo and PP Copolymer
» Proper es of Polypropylene
» Disadvantages of Polypropylene
» What is PP used for?
» Comparison of Polypropylene with Polyethylene
» Polypropylene Processing - Everything You Need to Know About It!
» 3D Prin ng with Polypropylene
» Is PP toxic? How to recycle PP?

Polypropylene and Its What is Polypropylene and What It's Used for?
Features
Polypropylene is a tough, rigid and crystalline thermoplas c produced from propene
(or propylene) monomer. It is a linear hydrocarbon resin. The chemical formula of
polypropylene is (C3H6)n. PP is among the cheapest plas cs available today.

Molecular Structure of Polypropylene

PP belongs to polyolefin family of polymers and is one of the top three widely used
polymers today. Polypropylene has applica ons both as a plas c and a fiber in:

Automo ve Industry
Industrial Applica ons
Consumer Goods, and
Furniture Market

It has the lowest density among commodity plas cs. Channel A


Some of the key suppliers of polypropylene are: Receive weekly
Enter your Em
A. Schulman - GAPEX®, ACCUTECH™, POLYFORT®, Fiberfil®, FERREX® and more
Borealis - Daplen™, Bormed™, Fibremod™ and more
ExxonMobil Chemical - ExxonMobil™, Achieve™
LyondellBasell - Ads f, Circulen, Hifax, Hostacom, Moplen and more
SABIC - SABIC® PP, SABIC® Vestolen, LNP™ THERMOCOMP™ and more
RTP Company - ESD C, ESD A, RTP 100, RTP 101 to 109 and more

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9/10/2020 Polypropylene (PP) Plastic: Types, Properties, Uses & Structure Info
Related Article

» View >18000 commercially available PP grades and > 350 suppliers in Omnexus Plas cs Database Soft-touch
The plas c database allows you to filter your search based on property (mechanical, electrical etc.),
utensils
applica ons, conversion mode and other dimensions for FREE! The Danish firm
Værktøjsfabrik
polypropylene
How to Produce Polypropylene? Industries avai
So ell to redes

These days, polypropylene is made from polymeriza on of propene monomer (an unsaturated organic
compound - chemical formula C3H6) by:

Ziegler-Na a polymeriza on or
Metallocene catalysis polymeriza on

Ziegler-Na a Polymeriza on

Or Metallocene Catalysis
Structure of PP Monomer Structure of Polypropylene
C3H6 (C3H6)n

Upon polymeriza on, PP can form three basic chain structures depending on the posi on of the methyl
groups:

Atac c (aPP) - Irregular methyl group (CH3) arrangement


Isotac c (iPP) – Methyl groups (CH3) arranged on one side of the carbon chain
Syndiotac c (sPP) - Alterna ng methyl group (CH3) arrangement

Polypropylene was first polymerized by German chemist named


Karl Rehn and an Italian chemist named Giulio Na a to a
crystalline isotac c polymer in 1954. This discovery soon led to a
large-scale produc on of polypropylene star ng in 1957 by the
Italian firm Monteca ni.

Syndiotac c polypropylene was also first synthesized by Na a


and his coworkers.

Types of Polypropylene & their Benefits


Homopolymers and Copolymers are the two major types of polypropylene available in the market.

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Polypropylene Homopolymer is the most widely u lized general-purpose grade. It contains only
propylene monomer in a semi-crystalline solid form. Main applica ons include packaging, tex les,
healthcare, pipes, automo ve and electrical applica ons.

Polypropylene Copolymer family is further divided into random copolymers and block copolymers
produced by polymerizing of propene and ethane:

1. Polypropylene Random Copolymer is produced by polymerizing together ethene and propene.


It features Ethene units, usually up to 6% by mass, incorporated randomly in the polypropylene
chains. These polymers are flexible and op cally clear making them suitable of applica ons
requiring transparency and for products requiring an excellent appearance.

2. While in Polypropylene Block Copolymer, ethene content is larger (between 5 and 15%). It has
co-monomer units arranged in regular pa ern (or blocks). The regular pa ern hence makes
thermoplas c tougher and less bri le than the random co-polymer. These polymers are suitable
for applica ons requiring high strength, such as industrial usages.

Polypropylene, Impact Copolymer – Propylene Homopolymer containing a co-mixed Propylene


Random Copolymer phase which has an ethylene content of 45-65% is referred to PP impact
copolymer. It is useful in parts which require good impact resistance. Impact copolymers are mainly
used in packaging, houseware, film, and pipe applica ons, as well as in the automo ve and electrical
segments.

Expanded Polypropylene - It is a closed-cell bead foam with ultra-low density. EPP is used to produce
three-dimensional polymer foam products. EPP bead foam has higher strength to weight ra o,
excellent impact resistance, thermal insula on, and chemical and water resistance. EPP is used in
various applica ons ranging from automobiles to packaging, from construc on products to consumer
goods and more.

Polypropylene Terpolymer - It is composed by propylene segments joined by monomers ethylene and


butane (co-monomer) which appear randomly throughout the polymer chain. PP terpolymer has
be er transparency than PP homo. Also, the incorpora on of co-monomers reduces crystalline
uniformity in the polymer making it suitable for sealing film applica ons.

Polypropylene, High Melt Strength (HMS PP)– It is a long chain branched material, which combines
both high melt strength and extensibility in the melt phase. PP HMS grades have a wide mechanical
property range, high heat stability, good chemical resistance. HMS PP is widely used to produce so ,
low density foams for food packaging applica ons as well as used in automo ve and construc on
industries.

PP Homopolymer vs. Copolymer – How to decide between the two?

PP Homopolymer PP Copolymer

Bit so er but has be er impact strength;


High strength to weight ra o and s ffer & tougher and more durable than
stronger than copolymer homopolymer
Good chemical resistance and weldability Be er stress crack resistance and low
Good processability temperature toughness
Good impact resistance High processability
Good s ffness High impact resistance
Food contact acceptable High toughness
Suitable for corrosion resistant structures Not preferable for food contact
applica ons

The poten al applica ons for PP homopolymer and PP copolymer are nearly iden cal

This is because of their extensively shared proper es. As a result, the choice between these two
materials is o en made based on non-technical criteria.

Interesting Material Properties of Polypropylene


Keeping informa on about the proper es of a thermoplas c beforehand is always beneficial. This helps
in selec ng the right thermoplas c for an applica on. It also assists in evalua ng if the end use
requirement would be fulfilled or not. Here are some key proper es and benefits of polypropylene:

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1. Mel ng Point of Polypropylene - The mel ng point of polypropylene occurs at a range.
Homopolymer: 160 - 165°C
Copolymer: 135 - 159°C

2. Density of Polypropylene - PP is one of the lightest polymers among all commodity plas cs. This
feature makes it a suitable op on for lightweight\weight saving applica ons.
Homopolymer: 0.904 – 0.908 g/cm3
Random Copolymer: 0.904 – 0.908 g/cm3
Impact Copolymer: 0.898 – 0.900 g/cm3

3. Polypropylene Chemical Resistance


Excellent resistance to diluted and concentrated acids, alcohols and bases
Good resistance to aldehydes, esters, alipha c hydrocarbons, ketones
Limited resistance to aroma c and halogenated hydrocarbons and oxidizing agents

4. Flammability: Polypropylene is a highly flammable material

5. PP retains mechanical & electrical proper es at elevated temperatures, in humid condi ons and
when submersed in water. It is a water-repellent plas c

6. PP has good resistance to environmental stress cracking

7. It is sensi ve to microbial a acks, such as bacteria and mold

8. It exhibits good resistance to steam steriliza on

Learn more about all polypropylene proper es and their values - ranging from mechanical and
electrical to chemical proper es; and make the right selec on for your applica on.

How addi ves help improve PP proper es?

Polymer addi ves like clarifiers, flame retardants, glass fibers, minerals, conduc ve fillers, lubricants,
pigments and many other addi ves can further improve PP physical and/or mechanical proper es. For
example:
PP has poor resistance to UV, hence addi ves like hindered
amines provide light stabiliza on and enhances the service life as Search PP Grades Based on
compared to unmodified polypropylene. Their Reinforcement Method

Further, fillers (clays, talc, calcium carbonate…) and


reinforcements (glass fiber, carbon fiber…) are added to achieve
significant proper es related to processing and end use
applica on.

Development & the use of new addi ves, latest polymeriza on


processes as well as blending solu ons significantly increase
polypropylene performance. Hence, today PP is less seen as a low
cost solu on, but much more as a high performance material
compe ng with tradi onal engineering plas cs and some me
event metal (e.g. long glass fiber reinforced PP grades).

Disadvantages of Polypropylene

Poor resistance to UV, impact and scratches


Embri les below -20°C
Low upper service temperature, 90-120°C
A acked by highly oxidizing acids, swell rapidly in chlorinated solvents and aroma cs
Heat-aging stability is adversely affected by contact with metals
Post molding dimensional changes due to crystallinity effects – this can be solved with nuclea ng
agents » Watch video
Poor paint adhesion

Key Areas of Applications of Polypropylene


Polypropylene is widely used in various applica ons due to its good chemical resistance and weldability.
Some common uses of polypropylene include:

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1. Packaging Applica ons: Good barrier proper es, high strength, good surface finish and low cost
make Polypropylene ideal for several packaging applica ons.

a. Flexible Packaging: PP films’ excellent op cal clarity and low moisture-vapor transmission make
it suitable for use in food packaging. Other markets shrink-film overwrap, electronic industry
films, graphic arts applica ons, disposable diaper tabs and closures, etc. PP Film is available
either as Cast Film or bi-axially orientated PP (BOPP).
b. Rigid Packaging: PP is blow molded to produce crates, bo les, and pots. PP thin walled
containers are commonly used for food packaging.

2. Consumer Goods: Polypropylene is used in several household products and consumer goods
applica ons including translucent parts, housewares, furniture, appliances, luggage, toys etc.

3. Automo ve Applica ons: Due to its low cost, outstanding mechanical proper es and moldability,
polypropylene is widely used in automo ve parts. Main applica ons include ba ery cases and trays,
bumpers, fender liners, interior trim, instrumental panels and door trims. Other key features of
automo ve applica ons of PP include low coefficient of linear thermal expansion and specific
gravity, high chemical resistance and good weatherability, processability and impact/s ffness
balance.

» Follow all that Happens in Automo ve Market

4. Fibers and Fabrics: A large volume of PP u lized in the market segment known as fibers and fabrics.
PP fiber is u lized in a host of applica ons including raffia/slit-film, tape, strapping, bulk con nuous
filament, staple fibers, spun bond and con nuous filament. PP rope and twine are very strong and
moisture resistant very suitable for marine applica ons.

5. Medical Applica ons: Polypropylene is used in various medical applica ons due to high chemical
and bacterial resistance. Also, the medical grade PP exhibits good resistance to steam steriliza on.
Disposable syringes is the most common medical applica on of polypropylene. Other applica ons
include medical vials, diagnos c devices, petri dishes, intravenous bo les, specimen bo les, food
trays, pans, pill containers, etc.

» Follow Latest Medical Industry Updates

6. Industrial Applica ons: Polypropylene sheets are widely used in industrial sector to produce acid
and chemical tanks, sheets, pipes, Returnable Transport Packaging (RTP), etc. because of its
proper es like high tensile strength, resistance to high temperatures and corrosion resistance.

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Usefulness of Polypropylene Films


PP film is among the leading materials today used for flexible packaging as well as industrial
applica ons. Two important forms of polypropylene films include:

Cast Polypropylene Film

Cast polypropylene commonly known as CPP and widely known for its versa lity.
Super resistance to tears & puncture
Greater transparency and be er heat resistance at high temperatures.
Excellent moisture and atmospheric barriers
High permeability to water vapor

Biaxially Oriented Polypropylene Film

Biaxially oriented polypropylene film (BOPP) is stretched in both transversal and longitudinal direc ons,
producing molecular chain orienta on in two direc ons.
Orienta on increases tensile strength and s ffness
Good puncture and flex crack resistance over wide range of temperatures
Have excellent gloss and high transparency can be glossy, clear, opaque, ma e or metalized
Efficient barrier against oxygen and moisture

PP vs. PE – Selecting the Suitable Polymer


Though Polyethylene and Polypropylene are similar in physical proper es but here are key points to
consider to select the polymer suitable to your needs.

Polypropylene Polyethylene

Monomer of polypropylene is propylene


Monomer of polyethylene is ethylene
It can be produced op cally clear
Polyethylene can only be made translucent
It is lighter in weight
like a milk jug
PP exhibits a high resistance to cracking,
Its physical proper es allow it to stand up
acids, organic solvents and electrolytes
be er in cold temperatures, par cularly
It has high mel ng point and good when using it as signs
dielectric proper es
It is a good electrical insulator
PP is non-toxic
PE offers good tracking resistance
It is s ffer and resistant to chemicals and
Polyethylene is sturdy as compared to
organic solvents compared to polyethylene
Polypropylene
PP is more rigid than polyethylene

» View all PP Commercial Grades » View all PE Commercial Grades

Polypropylene Processing Conditions


Polypropylene can be processed virtually by all processing methods. The most typical processing
methods include: Injec on Molding, Extrusion, Blow Molding and General-Purpose Extrusion.

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PP’s resin iden fica on code is 5.

PP is 100% recyclable. Automobile ba ery cases, signal lights, ba ery cables, brooms, brushes, ice
scrapers, etc., are few examples which can be made from recycled polypropylene (rPP).

The PP recycling process mainly includes mel ng of waste plas c to 250°C to get rid of contaminants
followed by removal of residual molecules under vacuum and solidifica on at nearly 140°C. This
recycled PP can be blended with virgin PP at a rate upto 50%. The main challenge in PP recycling is
related to its amount consumed – currently nearly 1% PP bo les are recycled as compared to 98%
recycling rate of PET & HDPE bo les together.

The use of PP is considered safe because it does not have any remarkable effect from an occupa onal
health and safety point of view, in terms of chemical toxicity.

Commercially Available Polypropylene (PP) Grades

TORAYCA® TLP8169 Toray

TORAYCA® TLP8169 by Toray is polypropylene. It is reinforced with 30% long carbon fiber. It is light
weight grade and features excellent strength, s ffness, dimensional accuracy and sliding... view
more

TORAYCA® TLP8148 Toray

TORAYCA® TLP8148 by Toray is polypropylene. It is reinforced with 20% long carbon fiber. It offers
excellent mechanical strength/rigidity, low specific gravity and high creep-, fa gue- & abrasion...
view more

Ultrasint® PP nat 01 BASF 3D Prin ng Solu ons

Ultrasint® PP nat 01 by BASF is a translucent, polypropylene (PP) based powder for laser sintering
process as an alterna ve to polyamide. It offers an excellent plas city, high elonga on, low... view
more

RTP 100 ABR RTP Company

RTP 100 ABR by RTP Company is an abrasion resistant polypropylene (PP) grade. Exhibits good wear
and fric on resistance, flame retardancy and conduc vity against third-party abraders. It replaces...
view more

RTP 105 CC TFE 15 RTP Company

RTP 105 CC TFE 15 by RTP Company is PTFE lubricated, glass fiber filled polypropylene grade. It
offers wear and fric on resistance, reduced s ck-slip phenomenon by selec ng materials based
on... view more

View All Products

Polypropylene Properties and Their Values

Property Value

Dimensional Stability

Coefficient of Linear Thermal Expansion 6 - 17 x 10-5 /°C

Shrinkage 1 - 3%

Water Absorp on 24 hours 0.01 - 0.1%

Electrical Performances

Arc Resistance 135 - 180 sec

Dielectric Constant 2.3


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1. Injec on Molding
Melt temperature: 200-300°C
Mold temperature: 10-80°C
Drying is not necessary if stored properly
High mold temperature will improve brilliance and appearance of the part
Mold shrinkage lies between 1.5 and 3%, depending on processing condi ons, rheology of the
polymer and thickness of the final piece

Watch free video tutorial to improve PP cycle me and limit part shrinkage

2. Extrusion (tubes, blow and cast films, cables, etc.)


Melt temperature: 200-300°C
Compression Ra o: 3:1
Cylinder Temperatures: 180-205°C
Pre-Drying: No, 3 hours at 105-110°C (221-230°F) for regrind

3. Blow molding
4. Compression molding
5. Rota onal molding
6. Injec on blow molding
7. Extrusion Blow Molding
8. Injec on stretch blow molding
9. General-Purpose Extrusion

Expanded Polypropylene (EPP) may be molded in a specialized process. Being an ideal material for
injec on molding process, it is majorly used for batch and con nuous produc on.

3D Printing with Polypropylene


As a tough, fa gue resistant and durable polymer, PP is ideal for low strength applica ons. Due to its
semi-crystalline structure and heavy warping, it is currently difficult to use polypropylene for 3D
Prin ng processes.

Today, several manufacturers have op mized PP proper es or even created blends with improved
toughness making it suitable for 3D Prin ng applica ons. Hence, it is recommended to thoroughly refer
to documenta on provided by supplier for prin ng temperature, prin ng bed, etc., while 3D Prin ng
with polypropylene...View all PP Grades Suitable for 3D Prin ng

Polypropylene is suitable for:


Complex models
Prototypes
Small series of components, and
Func onal models

3D printing Polypropylene (PP) lamen…


lamen…

(Credit: FormFutura)

Is PP toxic? How to recycle PP?


All plas cs have a ‘Resin Iden fica on Code/ Plas c Recycling Code’ based on the type of resin used.

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9/10/2020 Polypropylene (PP) Plastic: Types, Properties, Uses & Structure Info

Dielectric Strength 20 - 28 kV/mm

Dissipa on Factor 3 - 5 x 10-4

Volume Resis vity 16 - 18 x 1015 Ohm.cm

Fire Performances

Fire Resistance (LOI) 17 - 18%

Flammability UL94 HB

Mechanical Proper es

Elonga on at Break 150 - 600%

Flexibility (Flexural Modulus) 1.2 - 1.6 GPa

Hardness Rockwell M 1 - 30

Hardness Shore D 70 - 83

S ffness (Flexural Modulus) 1.2 - 1.6 GPa

Strength at Break (Tensile) 20 - 40 MPa

Strength at Yield (Tensile) 35 - 40 MPa

Toughness (Notched Izod Impact at Room


20 - 60 J/m
Temperature)
Toughness at Low Temperature (Notched Izod
27 - 107 J/m
Impact at Low Temperature)

Young Modulus 1.1 - 1.6 GPa

Op cal Proper es

Gloss 75 - 90%

Haze 11%

Transparency (% Visible Light Transmission) 85 - 90%

Physical Proper es

Density 0.9 - 0.91 g/cm3

Glass Transi on Temperature -10°C

Radia on Resistance

Gamma Radia on Resistance Poor

UV Light Resistance Fair

Service Temperature

Duc le / Bri le Transi on Temperature -20 to -10°C

HDT @0.46 Mpa (67 psi) 100 - 120°C

HDT @1.8 Mpa (264 psi) 50 - 60°C

Max Con nuous Service Temperature 100 - 130°C

Min Con nuous Service Temperature -20 to -10°C

Others

Steriliza on Resistance (Repeated) Poor

Thermal Insula on (Thermal Conduc vity) 0.15 - 0.21 W/m.K

Chemical Resistance

Sa sfactory
Acetone @ 100%, 20°C
Ammonium hydroxide, 30% @ 20°C

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Ammonium hydroxide, diluted @ 20°C Sa sfactory

Aroma c hydrocarbons @ 20°C


Non Sa sfactory
Aroma c hydrocarbons @ hot condi ons

Benzene, 100% @ 20°C


Limited
Butylacetate, 100% @ 20°C

Butylacetate, 100% @ 60°C


Non Sa sfactory
Chlorinated solvents @ 20°C

Chloroform @ 20°C Limited

Dioctylphtalate, 100% @ 20°C Sa sfactory

Dioctylphtalate, 100% @ 60°C Limited

Ethanol, 96% @ 20°C

Ethyleneglycol (Ethane diol), 100% @ 100°C

Ethyleneglycol (Ethane diol), 100% @ 20°C Sa sfactory

Ethyleneglycol (Ethane diol), 100% @ 50°C

Glycerol, 100% @ 20°C

Hydrogen peroxide @ 30%, 60°C


Limited
Kerosene @ 20°C

Methanol, 100% @ 20°C


Sa sfactory
Methylethyl ketone, 100% @ 20°C

Mineral oil @ 20°C


Sa sfactory
Phenol @ 20°C

Silicone oil @ 20°C


Sa sfactory
Sodium hydroxide, 40%

Sodium hydroxide, 10% @ 20°C Sa sfactory

Sodium hydroxide, 10% @ 60°C


Sa sfactory
Sodium hypochlorite, 20% @ 20°C

Strong acids, concentrated @ 20°C Sa sfactory

Toluene @ 20°C Limited

Toluene @ 60°C
Non Sa sfactory
Xylene @ 20°C

Check Latest News About PP Now!

4 Comments on "The Defini ve Guide to Polypropylene (PP) "

Sameeha F Sep 8, 2020


Very informa ve ar cle and video. A very good a empt. The presenter for Nuclea on video was excellent. It is a good thing to hire professionals for presenta on s
is kept engaged.

Melissa B Oct 23, 2018

https://omnexus.specialchem.com/selection-guide/polypropylene-pp-plastic 10/11
9/10/2020 Polypropylene (PP) Plastic: Types, Properties, Uses & Structure Info
looking for the so ening temperature of Polypropylene when used during manufacturing. I have an applica on in which the material is under a prepregnated carbo
would like to know at what temperature it begins to so en to allow the material enough me to sink into the female mold shape of the bond tool.

Jeff E Sep 3, 2017


Great explana on and detail. Can be used for both engineers and sales knowledge - one of the best we have seen

deepak b Aug 24, 2017


excellent ar cle and video

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