0: BASF ‘The Chemical Company Safety Data Sheet 10-2043 Kaolin Slurry Revision date : 2011/08/27 Page iT Version: 3.0, (0522122/S0S_GEN_USIEN) 1, Product and Company Identification Use: Chemical ‘Company 24 Hour Emergency Response Information BASF CORPORATION CHEMTREC: 1-800-424-9300 4100 Campus Drive BASF HOTLINE: 1-800-832-HELP Florham Park, NJ 07932, USA. ‘Chemical family preparation 2. Hazards Identification ‘Stato of matter: quid Colour white (Odour faint odour Potential health effects Primary routes of exposure: RRoutos of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of enty for .g88e8 include inhalation and eye contact. Skin contact may be 8 route of enty fr liguiled gases Acute toxicity Ingestion may cause gastrointestinal disturbances. The product has not been tested. The statement has been ‘rived from products ofa similar structure or composition Inritation / corrosion: letaton i possible when the product comes in contact withthe skin, respiratory tractor the eyes. The product has not been tested. The statement has been derved from products of similar structure or composition. Sensitization: ‘Skin sensitizing effects were not observed in animal studies. The product has not been tested. The statement has been derive from products ofa similar stucture or composition Chronic toxicity: Carcinogenicity: The whole ofthe information available provides no indication ofa carcinogenic eftect Repeated dose toxicity: No adverse effects were chserved after repeated inhalatve exposure In animal ‘ludies. The product has not been tested. The statement has been derived from products of @ similar structure ‘or composition Reproductive toxicity: Not expected to cause reproductive toxiy. (based on composition)Safety Data Sheet 10-2043 Kaolin Slurry Revision date : 2011/04/27 Page: 27 Version: 3.0 (30522122/SDS_GEN_US/EN) Teratogenicity: The date avaiable for an assessment ofthe effect ofthe substance on developmental toxicly are not sufficient fora proper evaluation. Genotoxicity: The substance was not mutagenic in bacteria. The product has not baen tested. The statement hes been derived fom products ofa similar structure or compositon. 3. Composition / Information on Ingredients CAS Number Content (wiv) Chemical name Trs2185 Water 9708-41-41 Kaolin, calcined ‘Ammanium salt of modified acrylic copolymers NgTS-50083-NCD ‘Anatase (Ti02) 4. First-Aid Measures General advice: Remove contaminated clothing inhaled: Remove the affected individual into fresh air and keep the person calm, Assist breathing itnecessary. Immediate medical attention required on skin: Wash affectes areas thoroughly with soap and water. fitation develops, seek medical attention Hin oyes: Flush with copious amounts of water fora least 15 minutes. itation develops, seek medica attention. 1 swallowed Immediately rinse mouth and then drink plenty of water, dont induce vomiting, seek mecical attention. Never induce vomiting oF give anything by mouth f he vic fs unconscious or having convulsions Note to physician Treatment No data available 6. Fire-Fighting Measures Flash point > 300°F (Unspecified) Lower expiosion it, not applicable Upper expiosion limit nat applicable Salt.gniton temperature: not settigniing Suitable extinguishing media: \wator spray, foam, dry powder Hazards during firefighting: No particular hazards known, Protective equipment for fire-fighting: Firefighters should be equigped with self-contained breathing apparatus and tum-out gearSafety Data Sheet M10-2043 Kaolin Slurry Revision date : 2011/04/27 Page: 37 Version: 3.0, (30522122/SDS_GEN_USIEN) Further information: Dispose o re debris and contaminated extinguishing water In accordance with ofcial regulations. Product es non-combustible, fre extinguishing mathod of surounding areas must be eonsicered. 6. Accidental release measures Personal precautions: Use personal protective clothing. Avoid contact with skin and eyes. Environmontal precautions: Do not release untreated into natural waters, Cleanup Spils should be contained, solid, and placed in suitable containers fr disposal Further information: High risk of sipping dus to leakagetspilage of product 7, Handling and Storage Handling Goneral advice: Handle in accordance wih good industrial hygiene and safety practice. No special measures necessary Provided product is used correctly. Ensure adaquate ventiation Storage, Goneral advice: Store protected against freezing, 8. Exposure Controls and Personal Protection Respiratory protection: ‘Wear a NIOSH-cortfied (or equivalent organic vepour/parculate respirator as needed. Wear respiratory Protection if ventlaton is inadequate. Hand protection: (Chemical esistant protective loves Eye protection: Tightly ting safety goggles (chemical goggles) Wear face shied if splashing hazard exists General safety and hygiene measures: Hands andior face should be washed before breaks and at the end ofthe shift Avoid contact with skin and eyes, 9. Physical and Chemical Properties Form quia ‘Odour: faint edour Colour: waite Information on: Water Melting point: orcSafety Data Sheet 10-2043 Kaolin Slurry Revision date : 2011/08/27 Page: 4/7 Version: 3.0 (90522122/SDS_GEN_US/EN) Information on: Water Boiling point 100°C Information on: Water| Vapour pressure 234nPa (20°C) Literature data Relative density No data avaiable Vapour densi No data avaiable Parttoning coafticent ‘ot applicable r-actanoliwater (og Pow): Solbiity in water: (15°C) party soluble Misetbilty with water miscible Other Information: Range of particle size:< 0.1 um - 10 pm 10. Stability and Reactivity Conditions to avoid ‘Avoid extreme heat. Substances to avoid: metal sats Hazardous reactions: The product is chemically stable, Decomposition products: Hazardous decemposition products: carbon dioxide, carbon monoxide, hydrocarbons Corrosion to metals: Corrosive effects to metal are not anteipated (oxidizing properties: not fe-propagating, 11. Toxicological Acute toxicity Oral Type of valve: LD5O Species: rat Value > 2,000- 10,000 mgikg Intitation J corrosion. skin ‘Species: rabbit Result nonsatant ‘Method: OECD Guideline 408 eye ‘Species: rabbit Result non-iritant ‘Metiod: OECD Guideline 405 ther Information:Safety Data Sheet 10-2043 Kaolin Slurry Revision date : 2011/04/27 Page: 57 Version: 3.0 (80522122/SD$_GEN_US/EN) ‘Based on our experience and the information avaiable, no adverse heath effects are expectod if handled as ‘recommended with sutable precautions for designated uses. The statement was derived fom products of similar composition 12. Ecological Information Fish Acute OECD Guidetine 203 static ‘Brachydaniorero/LC50 (96 h):_> 100 mgt ‘Aquatic invertebrates, Acute ‘OECD Guideline 202, part 1 static Daphnia magnasEC50 (48 nj" > 100 mal ‘Aquatic plants “Tox to aquatic plants: OECD Guideline 201 green algae/EC5O (72 h}: > 100 magi "Nominal concentration. Microorganisms Toxicity to microorganisms: DIN EN ISO 8182-OECD 209-86/2021EEC,P. C actwated sludge, domestic/EC20 (0.5 hy. > 100 mt Zhe inttton ofthe degradation activity of activated sludge isnot antlpated when introduced to biological {teatment plants in appropriate low concentrations Degradabilty | Persistence Biological / Abjological Degradation Test method ‘OECD 2028, 150 9888; s8/202/EEC parc Method of analysis: BOC reduction ogres of elimination: >70% Evaluation Easily eliminated from water. “The product can be vitualy elmineted from water by abiotic processes e.g, ‘adsorpbon onto activated sludge Bioaccumulation Based on its structural properties, the polymer is not biologicaly avaiable, Accumulation in organisms isnot to be expected Other adverse etfocts: ‘Do not release untreated ino natural waters. Al the present stale of knowledge, no negative ecological effects are expected. Ecological data are determined by analogy 13, Disposal considerations Waste disposal of substance: Incinerate or dispose of ina licensed facity. Do not dlscharge into draine/surface waters/groundwater Container disposal: Dispose of ina licensed facity. Recommend crushing, puncturing or other means to prevent unauthorized use of used containersSafety Data Sheet 10-2043 Kaolin Slurry Revision date : 2011/04/27 Page: 67 Version: 3.0, (90522122/SD$_GEN_US/EN) 14, Transport Informati Land transport usboT Not classified as a dangerous good under transport regulatons Sea transport MDG Not classified as a dangerous good under transport regulations, Air transport IATAICAO. [Not classed as a dangerous good under transport regulations 15. Regulatory Information Fodoral Requlatior Rogistration status: Chemical TSCA,US released /isted (OSHA hazard category IARC 1, 2A o¢ 2B carcinogen: Chronic target organ effects reported; ACGIM ‘TLV esiapished EPCRA 3111312 (Hazard categories): ‘Acute; Chronic State regulations. ‘State RTK CASNumber Chemical name A.W, PA ‘Ammonium eal of mocties acre copolymers NJ.PA, MA NJTS-50081-NCD CAProp. 65: ‘THiS PRODUCT CONTAINS A CHEMICAL{S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM, 46. Other Information NFPA Hazard codes: Heath: Fre: 0 Reactivity Special HMIS I rating Heat 1s Flammabilly 1 Physicalhazard: 0 NEPA and Hills use numbering scale ranging tor 0 to 4 oincate he degree of hazard A value of zr0 means hat hs Substance possesses essently ne hazard ating feu ndeaes treme danger Ato sm the to rating {ystems are intended for iferen purposes, and use deren ctena, The NFPA pystom was developed 6 prove an ‘hrtho apt alot fo the Nazar af @materal an tho sevely, to emergency responders. The HMI system was designe {o communicate workplace hazard formato to employees who handle nazatous chemicalsSafety Data Sheet M10-2043 Kaolin Slurry Revision date : 2011/04/27 Page: 777 Version: 3.0 (30522122/SDS_GEN_US/EN) ‘We support worwide Responsible Care® intiatves, We value the heath and safety of our employees, Customers, suppless and neighbors, an the protection ofthe enwronment. Out commitment fo Responsible Care is integra to conducting our business and operating our facies ina safe and envrormentaty responsible fashion, supporting our customers and suppliers ensuring the eafe and environmentally sound harling of cut Breducs, and minimizing the impact of our operations on society and the environment during producaon, ‘slorage, transport, use and disposal of our products, [MSDS Propared by: BASF Na Product Ragulatons msds@basf.com MSDS Prepared on: 2011/0427 IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ‘ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE. IT IS PROVIDED FOR YOUR. GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATIONUUSE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION, ‘SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. INNO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR. TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT ‘THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK, END OF DATA SHEET