The document discusses reactions of carboxylic acids. Pt is used as a catalyst for the reaction of aromatic carboxylic acids with Cl2. Heating an alpha-halogenated acid with concentrated H2SO4 leads to an unsaturated acid. The reaction of an aliphatic carboxylic acid with Cl2 or Br2 to form an alpha-halo carboxylic acid is called the Hell-Volhard-Zelinsky reaction, which uses Pb as a catalyst. Carboxylic acids undergo reduction with lithium aluminum hydride to give primary alcohols.
The document discusses reactions of carboxylic acids. Pt is used as a catalyst for the reaction of aromatic carboxylic acids with Cl2. Heating an alpha-halogenated acid with concentrated H2SO4 leads to an unsaturated acid. The reaction of an aliphatic carboxylic acid with Cl2 or Br2 to form an alpha-halo carboxylic acid is called the Hell-Volhard-Zelinsky reaction, which uses Pb as a catalyst. Carboxylic acids undergo reduction with lithium aluminum hydride to give primary alcohols.
The document discusses reactions of carboxylic acids. Pt is used as a catalyst for the reaction of aromatic carboxylic acids with Cl2. Heating an alpha-halogenated acid with concentrated H2SO4 leads to an unsaturated acid. The reaction of an aliphatic carboxylic acid with Cl2 or Br2 to form an alpha-halo carboxylic acid is called the Hell-Volhard-Zelinsky reaction, which uses Pb as a catalyst. Carboxylic acids undergo reduction with lithium aluminum hydride to give primary alcohols.
1- During reaction of aromatic carboxylic acid with Cl2 ,
which of the following catalyst is used? (a) Pt (b) NaCl (c) Fe (d) Pb 2- Heating an alpha halogenated acid with ……leads to unsaturated acid. (a) CCl4 (b) Alcoholic KOH (c) KMnO4 (d) Conc. H2SO4 3- Reaction of aliphatic carboxylic acid with Cl2 or Br2 to form alpha halo carboxylic acid is called…. (a) Wurtz reaction (b) Koch reaction (c) Hell Volhard Zelinsky reaction (d) Kolbe’s reaction 4- Catalyst used in Hell Volhard Zelinsky reaction is….. (a) Ag (b) P (c) Pb (d) Pt 5- Carboxylic acid undergoes reduction with lithium Al hydride to give…… (a) Primary alcohol (b) Secondary alcohol (c) Tertiary alcohol (d) None 6- By distillation of calcium salts of carboxylic acids gives…. (a) Aldehyde (b) Ketones (c) Ether (d) Ester 7- A reaction in which carboxylic acid is treated with lithium chloride to form alkyl chloride is….. (a) Kochi reaction (b) Hunsdiecker reaction (c) Wurtz reaction (d) Kolbe’s reaction 8- Which of the following reactions are complimentary to each other? (a) Kochi and wurtz (b) Kolbe’s and hunsdiecker (c) Kochi and hunsdiecker (d) Kolbe’s and wurtz 9- The hunsdiecker reaction gives best result with ….. alkyl carboxylic acid. (a) Primary (b) Secondary (c) Tertiary (d) Both a and b 10- Kochi reaction gives best result with….alkyl carboxylic acid. (a) Primary (b) Secondary (c) Tertiary (d) Both b and c 11- Decarboxylation of silver salts of a carboxylic acid in the presence of bromine or chlorine to form alkyl halide is called…. (a) Kochi reaction (b) Hunsdiecker reaction (c) Wurtz reaction (d) Kolbe’s reaction 12- A reaction in which a carboxylic acid loses CO2 is called…… (a) Carboxylation (b) Decarboxylation (c) Esterification (d) None 13- When carboxylate salts are heated with soda lime….. are formed. (a) Alkanes (b) Alkenes (c) Alkynes (d) All 14- Carboxylic acid react with alcohol in the presence of a strong mineral acid to form…. (a) Alkanes (b) Ether (c) Ester (d) Alkynes 15- In Kolbe’s electro synthesis, carboxylate ion at anode is… (a) Oxidized (b) Reduced (c) Share (d) None