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GOAL
• Earth Materials
• Organic Matter
• Composition and Internal Structure of the Earth
• Minerals
• Rocks
• Regolith
EARTH MATERIALS
• Matter is substance, unlike (but related to) energy , matter has mass and
occupies space.
• The three common states of matter we are familiar with are solid, liquid and gas
• Materials occurring in the same state can still differ substantially
• For example, lava and water are both liquids; one non-aqueous, one aqueous
• Both are very important in a wide variety of Earth processes
SOLIDS, LIQUIDS, AND GASES
• In the solid states, matter is firm or compact in substance with a definite volume and
density, and tends to retain its shape even if it is not confined, because its constituent
atoms are fixed (about to be fixed) in position relative to each other
• In the liquid states: matter has a definite volume but its constituent atoms are able to
flow freely past one another; the material does not retain its own shape but conforms
to the shape of its container, taking on a free surface under the influence of gravity
• In the vapor or gas states: matter takes on the shape of the container in which it is
contained, filling the container completely (or escaping into space if it is not confined),
while its constituent atoms can move freely and acquire a uniform distribution within
the container.
EARTH MATERIALS
• The three common states of matter we are familiar with are solid, liquid and gas
• Materials occurring in the same state can still differ substantially
• For example, lava and water are both liquids; one non-aqueous, one aqueous
• Both are very important in a wide variety of Earth processes
EARTH MATERIALS
CHANGE OF STATE
Matter can coexist in various states and phases. In (A), matter of uniform composition
(H2O) coexists in two different states (liquid and solid) and two different phases (water
and ice), separated by physical boundaries. In (B), different phases coexist in the same
state (oil and water, both liquids; different types of beans, all solids). In (C), there is
only one phase and one state, as is always the case with gases.
OTHER STATES OF MATTER
• Element
• A group of the same kind of atoms
• Approximately 90 natural elements and several synthesized in a
laboratory
• Organized in a periodic table so that those with similar properties
line up
THE PERIODIC TABLE
EARTH MATERIALS
• Chemical Bonding
• Formation of a compound by combining two or more elements
• Transferring or sharing electrons that allows each atom to attain a full
valence shell of electrons
• Octet Rule: Atoms tend to gain, lose, or share electrons until they are
surrounded by eight valence electrons
WHY ATOMS BOND
• Ionic Bonding
• Atoms gain or lose outermost (valence) electrons to form
ions (positively and negatively charged atoms).
• Ionic compounds consist of an orderly arrangement of
oppositely charged ions.
• Ionic bond: the attraction of oppositely charged ions to
one another
• Examples include:
• Halite (table salt)—NaCl
HALITE (NACL)—AN EXAMPLE OF IONIC BONDING
COMPOSITION OF MINERALS
• Covalent Bonding
• Atoms share a pair of
electrons
COMPOSITION OF MINERALS
• Sometimes two kind of ions form such strong bonds with each other that they
act like a single ion. Such a strongly bonded pair is called a complex ions:
• Earth Materials
• Organic Matter
• Composition and Internal Structure of the Earth
• Minerals
• Rocks
• Regolith
ORGANIC MATTER
• Earth Materials
• Organic Matter
• Composition and Internal Structure of the Earth
• Minerals
• Rocks
• Regolith
COMPOSITION AND INTERNAL STRUCTURE OF THE EARTH
• Earth inherited its overall composition from its location in the solar nebula
• Earth has internal layering that originated early in solar system history due to
chemical differentiation of the partially molten planet
• Layers are distinguished by composition, rock strength, and state of matter
COMPOSITION AND INTERNAL STRUCTURE OF
THE EARTH
• Mesosphere: “middle
sphere” within the
mantle
• Asthenosphere: “weak
sphere” in the
uppermost mantle
• Lithosphere: “rocky
sphere” the outermost
100 km
COMPOSITION AND INTERNAL STRUCTURE OF THE EARTH
• Of the 92 naturally
occurring chemical
elements, only 12 occur in
Earth’s crust
• The crust is dominated by
two elements
• Oxygen
• Silicon
• With the other ten
elements, these are
responsible for the
composition of all common
Earth materials
COMPOSITION AND INTERNAL STRUCTURE OF
THE EARTH
MINERALS: BUILDING BLOCKS OF ROCKS
Geologists define mineral as an naturally occurring inorganic solid that possesses an
orderly crystalline structure and a definite chemical composition that allows for some
variation.
• Definition of a Mineral:
• Naturally occurring
• Generally inorganic
• Solid substance
• Orderly crystalline structure
• Definite chemical composition
• Definition of a Rock:
• A solid mass of minerals or mineral-like matter that occurs
naturally
Example
Sugar crystal
Oyster shell
Ice
Glass for beer bottle, or volcanic glass
Opal
HOW DO MINERALS FORM?
Minerals can change forms when pressure and temperature conditions are changing.
HOW DO MINERALS FORM?
• Precipitation of Mineral
Matter
• Ions dissolved in an
aqueous solution
reach saturation and
start forming
crystalline solids
• A drop in temperature
or water loss through
evaporation can cause
ions to reach
saturation
HOW DO MINERALS FORM?
Minerals have definite crystalline structures and chemical compositions that give them
unique sets of physical and chemical properties shared by all samples of the mineral
• Optical Properties
• Luster
• Appearance of a mineral in reflected light
• Two basic categories:
• Metallic
• Nonmetallic
• Includes vitreous or glassy luster, dull or earthy luster,
pearly luster, silky luster, greasy luster
SUBMETALLIC AND METALLIC LUSTER OF
GALENA (PbS)
PHYSICAL PROPERTIES OF MINERALS
• Optical Properties
• Ability to transmit light
• Opaque—no light is transmitted
• Translucent—light, but no image is transmitted
• Transparent—light and an image are visible through the sample
• Diaphaneity: meaning the light-transmitting qualities of a mineral (This word originates from
the Greek word diaphanes, meaning transparent).
• Transparent describes a mineral that transmits light and through which an object may be
seen. Most gem- stones are transparent and many are priced on the quality of their
transparency.
• Translucent describes a mineral that is capable of transmitting light diffusely but is not
transparent. Although a translucent mineral allows light to be transmitted, it will not
show a sharp outline of an object seen through it.
• Opaque describes a mineral that is impervious to visible light, even on thin edges of the
mineral. Most metallic minerals are opaque.
PHYSICAL PROPERTIES OF MINERALS
• Optical Properties
• Color
• Generally unreliable for mineral
identification
• Often highly variable due to
impurities or slight changes in
mineral chemistry
PHYSICAL PROPERTIES OF MINERALS
STREAK IS OBTAINED ON AN UNGLAZED PORCELAIN PLATE
• Optical Properties
• Streak
• Color of a mineral in its
powdered form
• Not every mineral
produces a streak when
rubbed across a streak
plate
PHYSICAL PROPERTIES OF MINERALS
COMMON CRYSTAL HABITS
• Crystal Shape or
Habit
• Characteristic
shape of a
crystal or
aggregate of
crystals
CRYSTAL HABITS
In contrast, crystal habit is the general
shape of a mineral, which also includes
irregularities due to growth.
Aggregate
Individual Crystal Terms: Crystal Terms:
•Arborescent
•Acicular •Botryoidal
•Bladed •Dendritic
•Blocky •Druse
•Equant •Encrusting
•Fibrous •Geode
•Platy •Granular
•Phantomed •Globular
•Lamellar
•Prismatic •Mammillary
•Pseudomorph •Massive
•Sceptered •Micaceous
•Striated •Nodular
•Stubby •Oolitic
•Tabular •Pisolitic
•Twins •Radiating
•Rosette
•Stalactitic
•Sub-botryoidal
•Vugs
PHYSICAL PROPERTIES OF MINERALS
• Scale for measuring the hardness of a mineral. The Mohs hardness scale is
the more popular measurement for hardness, but its numbers are not
proportionate. Absolute hardness is proportionate, but not commonly
used.
• One should always use a fresh mineral surface to determine hardness:
• Sometimes, when one mineral is softer than another, portions of
the first will leave a mark on the second that may be mistaken for a
scratch. Such a mark can be rubbed off, whereas a true scratch will
be permanent.
• The surfaces of some minerals are frequently altered to a material
that is much softer than the original mineral. A fresh surface of the
specimen to be tested must be used.
• The physical nature of a mineral may prevent a correct
determination of its hardness. For instance, if a mineral is granular,
or splintery, it may break but appear to be scratched by a mineral
much softer than itself. It is always advisable when making the
hardness test to confirm it by reversing the order of procedure; that
is, try to scratch mineral Aby mineral B, but also try to scratch B by
A.
PHYSICAL PROPERTIES OF MINERALS
• Other Properties:
• Taste
• Halite tastes like salt
• Feel
• Talc feels soapy
• Graphite feels greasy
• Magnetism
• Magnetite can be picked up by a magnet
• Lodestone is a natural magnet
PHYSICAL PROPERTIES OF MINERALS
• Other Properties:
• Optical properties
• Calcite has double refraction
• Reaction to dilute hydrochloric acid
• Carbonates will effervesce in
acid
MINERAL STRUCTURES AND COMPOSITIONS
• Mineral Structures
• Unit cells
• Atomic arrangement that results in the basic building blocks of a mineral crystal
• Minerals can be constructed of the same unit cells and have different external forms
• Examples of minerals with cubic unit cells include:
• Fluorite—crystals are cubes
• Magnetite—crystals are octahedrons
• Garnets—crystals are dodecahedrons
CUBIC UNIT CELLS
MINERAL STRUCTURES AND COMPOSITIONS
• Mineral Structures
• Steno’s Law or Law of
Constancy of Interfacial
Angles
• Regardless of
crystal size, the
angles between
equivalent crystal
faces of the same
mineral are
consistent
MINERAL STRUCTURES AND COMPOSITIONS
• Classifying Minerals
• A collection of specimens that exhibit similar internal structure and chemical
compositions are called mineral species
• Mineral species are then further divided into mineral varieties
• Examples of varieties of quartz
• Smoky quartz: contains trace amounts of aluminum
• Amethyst: contains trace amounts of iron
• Mineral species are assigned to mineral classes
• Silicates, carbonates, halides, and sulfates are different mineral classes
HOW MINERALS ARE CLASSIFIED
• Silicate Structures
• Minerals with independent
tetrahedra
• Oxygen ions are bonded
with positive ions (such as
Mg2+, Fe2+, Ca2+)
• Examples include:
• Olivine
• Garnet
• Form hard, dense
equidimensional crystals
that lack cleavage
THE SILICATES
• Silicate Structures
• Minerals with chain or sheet structures
• Polymerization—the SiO4 tetrahedra can link to one another in a variety
of configurations
• Accounts for the high variety of silicate minerals
• Tetrahedra can form single chains, double chains, and sheet structures
• Some oxygen ions are “shared” between tetrahedra
THE SILICATES
• Silicate Structures
• Minerals with three-dimensional framework
• All oxygen ions are “shared” between tetrahedra
• Examples include:
− Quartz
− The feldspars
Five Basic Silicate Structures
THE SILICATES
• Talc has a sheet structure framework bonded with Mg ions and is a very soft mineral
COMMON SILICATE MINERALS
• The feldspars are the most common silicate group and make up more than 50
percent of Earth’s crust
• Quartz is the second-most abundant mineral in the continental crust and the only
common mineral made completely of silicon and oxygen
COMMON SILICATE MINERALS
COMMON SILICATE MINERALS
• Divided into groups based on the negatively charged ion or complex ion that the
members have in common
• Make up approximately 8 percent of Earth’s crust
COMMON NONSILICATE MINERAL GROUPS
IMPORTANT NONSILICATE MINERALS
• Carbonates
• Composed of the carbonate ion (CO32−) and a positive ion
• Two most common carbonates are calcite (CaCO3) and dolomite CaMg(CO3)2
• Primary constituents in limestone and dolostone
IMPORTANT NONSILICATE MINERALS
• Earth materials
• Organic matter
• Composition and internal structure of the Earth
• Minerals
• Rocks
• Regolith
ROCKS
A:plutonic rocks
B: Volcanic rocks
C: Metamorphic rocks
D: sedimentary rocks
E: fossil-containing
limestone
OUTLINE
• Earth materials
• Organic matter
• Composition and internal structure of the Earth
• Minerals
• Rocks
• Regolith
REGOLITH
• Literally “blanket rock,” the regolith forms a layer draped over most of
Earth’s surface
• Three categories describe most of the various materials of the regolith
• Saprolite: rock that is weathered in situ
• Sediment: loose rock and mineral particles
• Clastic sediment (broken particles)
• Chemical sediment (dissolved material)
• Soil: contains organic matter mixed with minerals, can support rooted
plants
REGOLITH