TRABAJO FIN DE GRADO PROCESS DESIGN AND CONTROL OF DIMETHYL ETHER SYNTHESIS Laura Martin Méndez ree ed INDUSTRIALRESUMEN "bo in wT Fa de a it prc pcan ‘ie most ep ea dni rong nis eli eo yo cor un rocecen cose Serie en ee ‘imines Co cc, 3 mene ols eee ‘eco cnn dren pal ne sn spe oxi yap el ier nb lt de Se Stowe ono resi de ny ee nges e ‘cin eco ante ula cro pobre en sr cess ‘Sera: avec ion yrs. Seer apis gona a St vi ip sis ei ‘eeepc on ie per ne ‘tlre ieee terse oes i) ‘it ar oi p,m a ‘st ns pd se el er pf ae) ‘Eile tpn Cones jane, ee nce pn rida rir 0 ‘movispinme ase senawr‘Seti Oru pt moma pa La ma eo ame ‘arc ams semen ree oo meee eee me pene reed copecntcma Do Ieee Sa por creme {Srnec ests ein po oa ‘shes de oe ec el ere ea mc Se irene ne ana ‘Seino new en cm cw Sain ny es apr, Fast pay ocndn attain ec sc date pn St tn pep el pect ee ‘rl ml ps Si Ss Po [resem cnrenin emul DAE 0 Eyecam ene Se vali isnn rats) menses dota ns tapeiosmepaer ‘Ercan er napa open St del ceo eran, (Shem prcoat ts bac oleh ates gen spear mae = ‘ual nl racing err stones oe pe ‘co Penne enlaces ee Resonant ste sc oarrasa dea, p hc sprue de rt oor songs ‘Seurane mesa meena oii 0 poli, pr su psi wizo st inti gree pepe np et ae ‘Sn i pr peso alse ‘Seine edna nape ce cum lc a pn a nna eng mai tony ‘Steve fomcass cat camel is Salas yar aaa § (des ers sobs Baby guns ta greet na See ERECTA et temps nn “Stet ic tin prs mera cee ee ad ‘Stiacaclnesicaalds yeaa ees coe ene, Siecle is Epp sna nen ‘pect overs ‘Sather Oy bgt Sees &y ts 9 ent pets we ‘aes sez bj deen de compe [op canner: om ass tee pe Exton en em in? co por nga Desa stn cn Se het pcre eet meso tee ‘Svs parm pened pes mene sn tN ot‘Mews lmnidedccnion alos, Res pu apes uc ‘ose psira ma hse orepsn rere tise Ser oee ‘ame ie i, em ‘Ren meric fr Po ‘Sum cesar yom nes ge “Saisie np eta amacmperns Jes sndss ‘Slt roc ep shy, Coue Va ct pas ls ‘imam teeny epnanre eb it (Src mung poe De spe rb Pel pope, me AON ‘Sonne comm nein peso debe rsaTABLE OF CONTENTS 52 Deanne yt tis — {Camp psi opens. 62. Mematiinda A aie 15. eres 7. et Ene BeaaeaeebeueeSo someon ohn 13 Leptin ate ni 132 Poet at —LIST OF TABLES Se — ct ia H ttre eos 3 La ====t ik gore TAI Recent a Soea sce = “Table 24 Speifeaion of RADFRAC divin fe T-101 omnes 33 el <<< ee ees ry ‘Table 4 Heat exchanger F-108 specifications. ~ 8 eed H ‘Table 37, Heat exchanger F-102 specifications. So on os ZI = ee — eames 4E B i i & Te 2 ot emer 107 son Tine a cctnge Eo amin Sie Sten = Tee Comper eam = Tinton buy gerne be COP el a Ta oe ei Tint ine rene TES Sl nen ils Tone outa co Tike pepteig Teno owas neaeerees naneereeyLIST OF FIGURES Hateniseeeessoeerertia Siac ‘etcetera { Lignssaer compo dag feet “ Leones : Sapiens: i owotesane Loa ee cae a i eaten meg iSomgtiemricanense 17. Aspen Pho Main hws mtn] pi = Bags hectare 12. Vaal gid pase DME tations along the iLIST OF SYMBOLS Ho Hse ALO: Ale © Gane ‘PAs Apri C100 Desa whe HPA aptVOC Velie Opie oop TSA. Tens Seing Ader 00 apa yen dont Fat pt Ct|, INTRODUCTION Dt er OME, LOC, 2g a ene Eel om pes a ‘SEkoctortness be ugh stew een caottmculsetehaet} i ab dts ep Ns eer pe ‘temper W pig mid pene hn: ipo rayon pry npn sneha dereetnarseeprete eden an See er tous beenemmireemen ‘Sem Sats dm ae cngy sss unt ea ni poses EE Blbcaeef seacegnceconumanyamnt cee Se Sse imc ten ng DME pene om renee msn Seep re i tin! Et DME fe cry ml key erp ‘Smid gh cent dt pte Se ait tilted wpe Du WSL), ean ere igdgee ts wte ‘hic prt he UN gn ges HN Sagi oe los Trewin nny sch ealegeangw ) Ls ei GDM som minty ail EG ago ‘p(s cpr race Chem ate St, Te ‘efor ml ahem Chote wih i ae Sd i he lr ine Scope oc DME ped eh epic ‘Senin hh ie tp ose perp‘Te pon of DME Sin sy rd ty sero an lin, Die ‘dlncenay perme pageant Feral mene DM sans os ioe na ps pe une endif ty re enn pt met he wy Canim my Cec lnm tt ter ema ee Eras poss steatosis ton ety vocal ced out ‘gent chipper nde coun ne2.aIM “hema pit dna pe oe asf mee lysine tien re an mao tes ee Sern. Init is ya ain Poco ene en ans py “iS a inn Sry, ten ‘Sti cage, we ‘te pole covenant teem re wus ras eng he poses wal ore Soci mapa ene he ue sin he sy i ra i ae i heen py of ‘Soci Seeman cece es a Wad Sunita eaSe som ter eons Pi3, METHODOLOGY ag ce daa no dst soi dtd in ‘Seraipata of ental soc me dr yet oat hie sie Ai earl gupta athe pee Dak Ses Se pe te to ss ns te eid canting fe anc ih the roe ‘sie n'a ind sci fro td pesto af spl ‘ohana Ieee lope ape ees om cppact de ene cana ‘Sincere ae ce ocd ee cee a Spee em ae airy cm edo dated ging sy ids copes Silanes, ng i wine, coplti of eh pt. Fe peste a Freie endnote pee deel Seeder pony rae tii, ln: mi ew Ao Ph Src sain nt ng soo an “in ay ech oom lc a pnoun REST HPLL ial RBATCH ue mde ao ac epee ene sien eda ess sp din sy ig spe ‘stot, ema cl enone aera ae ‘else tls st aed ps of nel eo sual ‘iia scap gem sesame hone eg a ‘ioe fn ol ar mre o'r ps mrmy a ‘ede rr am imi omer ote De ‘eye ee cn ad ac4, DME MARKETS iy td a apn pt ones th inion ry este of a a ps ‘mi DME LAG a LP wn cls cl tL sc SSC ey a Hwee Scan tee ea ieeeeea Poeeeceeeigs ete YALLSing DME ttn tl ed th tg Sein oem i ‘nue and ocr devant pene a sb ca ee ge pi ME a dane ig ag at he Front wetness oremn ‘ove fet iesenitow Onis rel tn ctooctn eer ee ‘ney end ply eg vere Sei ep et 48 mi eccariee tera tra re cece eee eerescentete res gerne eee cteeean kimi ty hd vm of DE ita (priest esp oe ane pe {ty set rp lg DE" Cae may mies DME etn fw conc enue pf TO og DME at Semi atin pny Sl a Sn “oman ced he Kon vee) pon nding we iita orem Koch es eves fs ORG maa as {Serdar po onc DMT at Stale Ae i cep wi tt he pmol a (Seat ofp te moun fDi Te stent oe OME evs Woe oof Wot ae DE omnes Sat ‘mm es cpp ic Se on amt erase ees Selene Sorel Sern Sei aoecyamna toate ea careemiad SESE ec tie aceonevi mien som eo cine nt Te ‘Sucoatcpaccet Sue pci See Schnee iceatemaniarerceae ta Eee Saas Serie swaaee eben hemor Siiasaoet5, PROCESS OPTIONS AND SELECTION ‘Salminen print oh hese pee Saleen em nce tl sd tn ce pon ae ok cn ‘if pti ng spe nner ne et ton i ipnajam em has he 1. Feodiac leton oat Sone api! eis ha ayo pale ak at Ae ‘mann ht bdo DM rate Them dear Seesmic rte she se Tso me Meco Sets tle comin spiny 10pm of at mi cae ‘ip dibs eater tn ety St led eh pt ime be pdton eee wi tele a alec ac: tA roa Sem Pad ete Pl ‘atin some ane Sethe eos nies ek earl ‘ovesre Whetvneeet me ckesy poe betne a ne enn, we yt no a ea nt ‘Saktamapes Cocaomt eoc west nee ‘Stennis iern ass aotearoa om apy Someer, mening ec md gel wg rina i re ‘re ant of re st: mi aa ‘Seach ney pancetta ‘heim ea hey ls red ee Saale nik ‘Be mine ed ti DME pin se sity hab wer rt cove come oer ma The Soest a rit be iy cs ce lies i sm ine. Only SS ein sl sn a Ne, et ttbletruca patel ester recat de to ee ‘rt eof OME yes pees ‘2. Direct and indirect sytheemethods iat te cin pcs em tts nin ee mia ee ake ‘Sinvesonwsaant on ney anes ayaa, nny Dien pins ata 260 ake 2010H1 Mor Akama!) Sot ME ody eon fmt the lowing resto enyott e404 + HO lor Shatin 8) ‘Sys ammeter ihe re of emi at Nitin Am pnt i aye DepaSuton Rowe of Chel nny, Te Ege Cpe ‘im Sy Oia | ei at in iy ocr, man i, ‘Sats can nciecmeommdy and ep rnd anf cn ne ee epee ne et Diels Thonn stan 260k 201041 Mer that 0) ROH CHOC HO eS) costo e016 Aber sstatm 8) atl testo, tin son er i met tne Siew atewareieca ernest ed ec ester urement pohiroecieaemneiaac mae ‘etm ming rn rms shor HC aie ee ‘Soquel ey pe Dace mo et ps at ke pla ian ced ine dic ‘es mat ee ve neta el nan | ‘Epa a aoe sh Sa te ym mee a a ‘ere ton oad dt pn DE ‘Scepticism scone mp‘hip ann hese rp erie nl ‘ene me eyes tenet sr ns Ay ‘Sofi yas pease sa copes ‘ims rsh lh asc se ct ih ice ‘Spy ny bene ns my ep Apun er ‘Spe ee re tenemos yess nda ni Ths tetas am maneltsscme pa mcen ih ‘thm’ Morne te ng eee Hf eke rs pen Poe ‘smash # MP. sts col os hoe at ye nlite epet ns ae i ten ty ‘ed sth non te ree ee an Epoepnoscomts Frinton sn in ish tg ie id forte in it se bs fo ‘aon sn ume ae yn ef et esse Seat "frangsfene mes pee emimensan gripe Sab E-Ee—6, INDIRECT SYNTHESIS OF DME. Ins ts of in ts ast sme yp: nl ys 61.Componeats physi properties Bellows pil oerfalcmpan fo Ae Po(2. Reaction stlchiometry and nts, eta dente in ply mg isepetesonn ei itt” 0 FL ag (14S00RD Roos an 527 emai Ai fen aa ee ec SNmIsaraSate eo scat tmis chai Sccasrgenmeceet oh : tere Kran esr 435 (15) Newcomb pu ctperncitworerom nk mtn coe eeenaat 09 cop as -scHOH HO 05 ‘evra men tes 4 aie eh me Revemva ted np eign we ese eared Ty Po at we rte ps nro ag Hen cht (atza wmcin see 0 emgeCe async ecm Da Cbd stipulate Eres cs ig ae pc enon cnn ra ct og‘mp ase an ha esr ms ening es ein es fon «6, 2m re suey o Keo tansepst.onn ow Fay tl trys ee ine pr of li ty ye tetera ingyen ety SS e See eae ‘On tn rea wi te nbrbel OM on the so eat ming a Wd) molecule The Siciacwrcree cnet oH 01,004, OH flnmrlid ita tna expt ao (6 Relea EAT Pa en stabi 612128, Mermadynamis dats pti nt dag ha at iy E i Cant aaa aeA Praes dsign 64. ition eran DME Spi pat ardor ety DME is en 0 Scene of ann ehh compo pe» ‘inns bbc ep DE tenon ses wih cee Ss ne anh em aw {bn sem rah he eed mgeenten sens ma Tb ‘perenne: pss a ‘esnips pce mena supe Thc eteen Se pene chee abe cain A rl nse mn CO (Ofciuniioercum he itne sty cuss are ad leis wr ct) mene Sn snes ae hw | 0+ MOCO, sthse=-A et (13ogra rad iho 0,0 pe Sima ee ae arin ydasmgitn fener pnt fC, myosin i ‘Stents data cn can cae tes SS Semin tiny en in es "pal fe ods inti ypu peer soe imethen ing ig amnion fan can ca 8 fo fess tae oe ci br ‘fe soty mod STOIC soc ml i oe al ere, sine) cern, Fear rg pe oa er ‘tsar un mea rnc Deg pier a pe sae eens nomenWo = sos wt {€0:43=CHOW HO sie) ‘tA now pnt of Lamhe pms hve ee money Be ae gm nce. cyl cy ech ice att ose ‘ee etfs Tene ce iy {if Rian afm yy ‘ea tn nl tt a HCD on 2. eee [ceva emt: igh re nae pum ute ‘Tip sgh ted nc ey ges ma ‘tilted nian gotta fan2 Netanya oe ‘ot on mp ger nays poarch ‘Sony eng ten diva wee eae cnet \ = ; SS Menon etn tino mene en ct mae ‘Sop iy ac sm narra htTe IC pee nr tg int ernie cig (powtep mela gta Tete Tp ta frat mg th nica an clingy Sd we FO, ‘Sino e's comer o 98% mal enon _ SEs tes ee aati a spn eh he es ‘eth pict tr ami hr te eed dette Hoy ‘aa Staton shch sane an poof yunaLON =CHOCI HO tou -Ih9 ‘hhh a te iy of ea a oc ly Sine ase dated, meena hi prcn nar d btnacc hn bet el e DME to Compe ‘ute opraion ne Ws teers ese terre ea ‘tS tnoy eaves neon sag by we tere fata ome Open eC m1 SSveckt Laas Seino muti STON a iain Tepe ee [Toes [enn imam [ometinoe | eskeettnerincn a tinate fit pf he res, mil toni pt 9 Aer aa naw pg “put tpl ea antl ‘hele uo, Duca ea mre sft emacs ne pes Sense snc! sn yn "Secteur tel ony elm eres SRE men igo Caen mo ou ese ye rm 4. pss, en iva ope ant fi i ce Rapemer ne buotetritarin feces [Liga dadanirne tte mca ease Fors mm nie ion stan, roi mie. ‘msm sie psn prs np sed py ok tna qu py o aa eae ib ed inten he swing sso es hws rine die mpnota) ‘neti get aii a ‘Steed oe ey ew evi allo BU meres ag Fo ae paca clement fens ts nde eat opera Te ee Imtocneee tr enprton es png tne none Lo ee ‘Sistieanucas pose pnt ee ey pec a ‘knee fe asso so di a ins At cee on march or eda en ot Its inne eae ee» ed ye denn nts lop te en aging oe sion CRD ty DME a eid Orn, teens fr te casine Ar 5 tht aeses lo rm ear intl er tis pc en in 5 SE Niece opeenns sty chaos ot fr ss my ar en rn at ‘the psn, perme ne sem, ne ‘iste tenth aca racna e ps Sena ‘Speacmatpenne Reson em eet so sh Sy ty ing af en en, Wt Sn ‘ted ot nnn Sd bel Ot se og gl ‘Sloe eter er an 'G a yd cy a oe CO ‘Senescence at ‘Setieunren ere aracn Tei won tamer ‘cn rete sn so Theme ‘ices nt een emer Te sted pe et eat ‘eek ie uit ope eer’ ‘mel yon he a ec, ‘Sieve smate Bros puta ort recog oy a ‘scm apy wg el ws iy. Pacem leh SSroctcimearariobeasmon if hemartiseneet omen ee nora bn emi pin wing ‘Sacer Soe tes ech Gent rene ml oi) Te ira‘Smee fn do 104°C ml ob i ination oe SEI et he ae ean SCR ney Spin te oe hs a ih ype fe ne pe aan th¢2 nah ae et ‘hoi nh nu pox marl ef 8 ary ah ‘ehh cen es ge eh an a ‘eam ao ced ges coi me ind rm a oon oh ‘Site ff uv ofthe ceo sarge ec we ‘wna tos kai: LPC ae | hr aren 35 sonny nay sends ‘Spt | bt om i! es fr tn enn PD ion he mn ptf (PFD 2) fr DME ‘cna sam ck ee en me ee ec ty et rads ee dog meso pe) et i DME, i lp ch i le wih ning ingen yal eRe amaranth ‘edit me Ao rend ne Stored pron fh pee mga cg ES Pt sp sa np ae, race nr he ee es ee {Soria eyo ra ie copes es, SESE, Aedes ‘cir cn 5) epee ma eb pe ‘elute iy ome vl eu of 1S pra a Te chSerpent lt oto in oer a an ne oe ler of DME me sn ok ay nt tie amt fe pe berrrrrTear han ae(65. epee Segoaeeree armrest ‘ry lech gut ee oda Doig pcos pein cts fr ronment be ety SATS oar pr Son atom san » somite R10) Inti ren hy hos scaing of en Th i {ves poe ye on ay (CSE este are ae Sern i rc an ee Al te > Stityyactesaentenetaoe———— nr iran of amir ee ig a Tepe] GtoH me | oaemne z ah Sa a samme mn pe er eee ‘lens ying uate priv cons fe sp tnd "rn iwi 9 mpm of ADRAC Tater nn rr apni win Sige nia meh pins ‘oust ies es tier enone rere ie ‘nono kenya re hy ‘her apne or sn, amphi eed he i ere dg ‘essa me) eo sed DSTWU wah ns C13oye tere nt te See ea ate lerias ‘ons a high eemane pana lon tit we ‘Te ae pai i a fr dp an io: SPD pv DST (eps bd ADPEAG burt se pimp ot pay See tl oe on es aete elif th the rein ct ope the ee ‘line wig tera ach ure een Dv ofa sae ‘a raquo ne ‘fe iat of BADERAC 20, ml yf dee DME Te By deine he ratty ae ets a ing iin he pris ie maroreaenetoremitet Sinceretn ene 23 dog ane Flamin sre eta lait, 1.20, ened fmt nd ete {eye Ti ony Tred aoe a agPail rer wi type ie ction ad Sng of rit Pina bb ety pry pms de {pc nays he mim phi abe weg rob d me sda ae lm a Set a sete [ST ef dg nic iT nd pent a ea da ae Sate ted i nt aT‘Astle, S18 MA eto ini thi ‘teeming of here. se ah et cag amen el {Spm er pido abo cng hehe ee Sean os onan pe PyCant aaa ae‘ea fh ecg cng to su ly, no pcs ‘nein apart shen Campin mtn ypc it oto campo tinct Selma oboe Tvenes tele intense peered sie a [Spe fbncr ean sata songs et ct{Saha Toon testo ede eto ne sete tetperte es op tc tte ietaamaee aes ee ree es aes eaiearenase oan sheen imeretear se eee oe eepment nh ny ie hen ig one np ti ihe ots np Sn heemroeene ees ‘hte ope He Spt nde haha pape7, PROCESS CONTROL ‘stom rate sen ee mn on rr Scioscia Aout pa ee Spe Seu lec ove tl ech yews Surin pen neon ‘tht one pe ale Sung spy ed a fsa chon eps ne wih ep in Campo oma sr mpi escent esmnnm ‘stent alte wwe aol ema aap ou er oscnapotan coats ce Men ey pt a Sree nis tage crn [ide thse pr he ave mb oe ome cong iy ow The ‘Si ween meres epvne ramet te eed ‘Scie sp slats hig 72.Compresors ‘en cain at me yy ena ‘amie hove nt lp a inc od ‘en oct Ween Sac nin acm fsa fm ‘como mae Sc pe vil seme mie Steete cc ena reper scl ny mation be Fatih nm tn Ara ih sshere et e ‘Soa ata th are pag aed epee ‘Beer mun ec, cc yn on, ‘See mad wry high enn Wl one ent xn ‘ce Thay hen the ton emanate ‘Sm mre Ter sent hemes tere me i le cy mpm sopra pti step erent Sept henaraectensaag moms 75. Distilaion oamns 2B pepe sin ton me ci recs it i ty ‘Se tpn nied pases ne ol yt eo ar ann cm syne psn ‘Eee trctmes cet nar ai acre sree ‘perdi eet etm ty open permed ‘Since not Ned te ‘gee ey lo omTa ao aMcence oO8, WASTE TREATMENT AND ENVIRONMENTAL CONSIDERATIONS, scien ep os sg nr pepe Asi te nr Ec 017 in ps ose et ‘none en ‘cai ens open 1. ened hein an evn Shes ‘Beyond mn ie ni ei dng (Sit dou rae tas ns peroneal ‘ete yl pen instep et Trompe mpc inno ee