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Coordination Comp JD Lee
Coordination Comp JD Lee
: [ Oh Ne TENSION TYPE QUESTIONS, Se Passage 1: For Questions 1-2 Dena rae trea eae ante conning Baa Eceeataiciesesant tice ies oo "hc ems nkag heron or ambiente so senate sed orcs aig oh ems hese ian “. Which of te following ately matched eens ‘eet an a ec te Sires ore ‘Sinn oem Be eeemmeaeare seponrs tarred Soccernet epee aecenincn en taaes One ae ee aren Passage 2: For Questions 3-5 Fis maxi men re comps emp! io ‘Te cpa OM stalconpley, (a) [SKH,O)(NO,),)-4NH,: eras (@) [NUH ),(NO,),-2H,0: tetrahedra (©) [NH 10, 28,0: square planer (0) [N(NH,),(9,0),}°NO,); octahedra 5. Which ofthe flowing statements are tue for the second complex? (i) thas the EAN value of. {B) Ican show optical isomers (6) Heannot show geometrical isomerism {(D) produces tre fldreeing poi depron. Passage 3: For Questions 6-8 Same gas not only donate thet lone pat the ct ‘ra metal atom but also aceapt the elton cloud fo cena meta stom. This is known as synergic bondi 4 Inwicho the folowing eases isthe bond ener of C=O bond minimum? (A) Free CO molec. (0) Temina! CO group inn comples. (©) Doubly bridging CO in complex. () ipl bridging CO in a complex. 7 Sect the coret order forthe stretching eater (1 C-O bond the following compounds foc MoCO}PE), feeMtCO,(Pery, on re Mitac MC (PMe feted )'t>usin (8) Sno (0) trata, aac eee feuweont (B)V(CO),| pesenon Restoring Tp Questions os, 13 Wich ofthe foloing fas hipher mile od Passage 6: For Questions 14-16 passage 4: For Questions 9-11 Be Spoinsoltion aptly orn aad rhc val of the tal andy of Fo eptek asim? me wt o2 m3 so. for wich valve of wl te comple st show Fe caiomerie? a 2 63 () Atotties anor which value 0€ te cmpes wil how Facing pint presion?” ” we 3 62 oi Passage 5: For Questions 12-13 syeri bondi typ of bak one 42, Which of tbe following has higher stretching fe ne for C=O bond? i imiconPe) {@) {Nico),P3te91 Bom nove equal sechng teguen: {D) None ofthese C= [Coes 9) NH icon sores be odes (©) compan abo (oa os) ors Solara ane Then (A) USeecraipe (B) 1: 2etewoine {@ Lteearope () 5:teceratne 16, Doe tothe presence of ambiente ligands coor aston coopoands show omens. palladium Geant of te ype [PAGANS] and ipa eiscs) a (A) taka isomes. {B) ceordinaon women. (6) joomsoe Somers (D) omer bomen. Fie ee ee nthe folowing set of questions Statement 1 sten {nd corresponding Sateen liven below it Mark The correct answer a: (A) It both Statement 1 and Statement Tare Woe fod: Statement I isthe comeetexplaaarion of Statement (8) Ie both Statement 1 and Sttemest Tk ae tue bt Statement Il is not the comest xplnation £¢ Satomet is tue but Staterent ae. i fae but Statement Ist eas with ole ot the an 1 Statement ts Only eis PUNE): ‘cid (H,C,0,) 10 form [PCI tomer, Statement Mt The oxlae fon sa bidentate Het hich oeupiesajacent positions es 2. Statement Under the strong eld ligand only the Skgeneracy ofthe orbital ost Statement Afr spliting of the dorbitals also Hands ale aot lated anywhere 2, Statement ENO is Sedonor. Satemest I:The antibonding electron of NO is ery ‘hoch auscpine ta donate spar from is lone pat. “4 Statement Dithiooslate is bidentate ambidentate Vigan Statement Ata time either 140 S atoms or to O tome acta Jona sams 5. Statcmeat LPF, s weakest donor aswell as weakest ‘Septor somporcd to PMc, in synergic bonding. Statement :Me group is having +7 effect while atom haing feet.coc (eH 01 Samar - a acc oT ees st le eo mension net meester re mer ca fe fot sc he nebo dana sw perro RP momar OL Ren gja wet citer. renin in Fite nusterof rh * peo ose sooo site pr. Ica fon FeO (Femou ee 2: Suppo ere: ie sae sah ricoh tes eet ae onan seid rani tae! Of (Sderot er of ora anon oon wk cea he Svat Da (i) Neate, errs Ah Neat eens UvpNumberotderoiones (0) Nami of emetic (ueaNeaue 4. Te numberof conta pater (oT, (oro, c.PUoNJ8_——— (olFant reco (arty Pee0 Fi 7 > met BAK SSM co sce sa stent st Seay come te a i some ait Both tHe 109 POKES he agg oe — eae nce ey 6: a a a [coven)ipnNO.):] Leger PERE uaepe by 38 28 8 rpc Hy and for Rh 1 le" eae or ee er I wih open me oes scrips fe i and ing cons ay = & etCO, 4. Te coordination numberof the cet atom in [CaN 50,]N0, 40, The umber of opal active isomers or the com seca frmula[Ma 11 Tee umber of unpaired electrons inthe se of tals complex [CotH0) is ‘2. Thenumberof empire electrons present in [NB 12. The sumo stereoisomers of complex compler and complex in flowing reaction inet cums. Ina A comp Ta it one of emer eo aap 2B me ») BtComplec) aa In cach of efor gusion Foetaeesteneen seen ‘ments in Coluesn | noe einige hoe in Colm I ae abled a P)(Q). RS) ‘nd Any ven statement in Coma fan av "st mtchig wih one ormor statements in Coli 4. mani peses other epecnehadeti gannt “Cah Goel Chapsi eaten} emetic OFRAEDTANT +) Change ts emer freer ‘dereumen rs CR) EAN asd et (Ofpiono) ene : DCLG» (Charen santero feattoncsiio "set wae (Canpeis naps teiest —— yc be etl ample pe wih he apr Tonal oe ‘ine|__toveg_ Ta IMAARET ) Algoma eames i, meena ce (@) [MAB (0) Treader of Stcosonen fo. 1R) Tee paar of peometreal (OMAR < (D)iMavase (9) Thesmader oes Se compe cmponnt wih he RET wy (rot @) [ero Omar ® FAO “Match he posses cared ot withthe changes cbered Calor (a) (MAB AT AMAR AT ©) DMCABDHT =A IMABRA I — (@ (0) (ape? Naat ® (0) [M(AA I AMAA AT 5. Match the comple compounds withthe proper, depicted by them. Celina ‘Cour TAIFACO)]” Hybridization sa (@) [CNH,),C,] (0) Hybridization. (©) [rm,f* (Eats geomet @){za(ey),!——_) Lowspincveee. (1) Esti opiat ee ‘atc he pir of complex ompouns th e rn tes that are diferent in them. Galena Goma (A) [Ma(NH,), 50, (P) Hybridization. ‘and {Co(H,0),]Ch, (8) (NH,),{MCL) (Q) Magnetic momest and K,[NiCL.] bce (©) KFe(CN),0,) {(R) Magnetic bebaviout, 2d KCN] (9) lesa cond> The gamber of gometial Som prods fox: Toe saber of seremeoen is ineesed 0 othl of (be orga xr deseaed to taf tbe ong 7.Mach the pair of complex compounds with the ‘properties tat arame them. camel Corn (ANTHGLOL!" (PY Hybridization sas]MoNH A @ Acar (@) Magnetic moment value and (PECL (©) (FADMG,T (RY) EAN vale, aad N(DNG).T (@)[FACOLP ans (8) Shape. [Nicout 1, Mat the coordination compler withthe number of toner formed ‘court ‘Caunait DOMABY 7) Conplextovng wo opal ative mers B)MapeI — (Q) Complerdaving ourS aie —_ BRET essen : omar sneer oat ge Oa oh = rng Om ia (e600 "igh-spincompley, ——~ CODUAAAT Come vaio (a) tot © tevin conn pe ener Ofte comer. ooo ° Paarup haar m ational wai _) @ep'tybritzaio, smsscomacnierrenmiat yO ao) LA) oo ‘6.(0) 23. (A) 30. (B) 28 eae : 2) 3. ( 30) 10.00) ae . +0) ey 20) 5.14) 2@ oo! ba an 1 ee ee «x0 7A) 148) oe ans sp ome dee tt 0.0 eanerix) RAO) HAO) 17. (AD) oO pom woe) a(ay(cnd) — 71A)B sn (ayouD) AEM) Apia Ce) ted OS) Compe ye eit +0) +o) ‘wy 8 20) tm mM +0 20 no 8 @) “0 +o 2 8 eit pe “o 70) + no 20) * inca 6A) 81) 10. (D) Integer Anomer Type Questions a tipene4 oo ewnwe anms 96 tu 20 56 ta) 10.4 13.7 m2 20) ari aT Ose PCO) .(7) 1) NLD. 90.09). (yarn cniBen a0) (yao (amon wo wr KR) (1.10) (ARNON) 9, ca) (0,48. er.) t (Ch =1P.10.08) (Aracmennisycr) (01-0). OO. ee @219) wo O45) ee