Professional Documents
Culture Documents
For the
Virtual Internship - 2021
Semester 6
Bachelor of Technology,
Chemical Engineering Department,
GSFC University, Vadodara.
Group 2 - Progress Review Report 1
Group No. 2
Work type: Progress Review Report - 1
Title: Solvent Cement as Thermoplastic Adhesive : A study on possible modification to reduce cost
and improve properties
Industry Mentor,
Mr. Shemal Parmar
Table of Contents
WEEKLY REVIEW.............................................................................................................................4
1. INTRODUCTION............................................................................................................................ 5
2. CLASSIFICATION OF ADHESIVES............................................................................................5
2.1 Thermosetting adhesives........................................................................................................... 5
2.2 Thermoplastic adhesives........................................................................................................... 6
2.3 Elastomeric adhesives............................................................................................................... 6
3. CLASSIFICATION OF SOLVENT CEMENT............................................................................. 6
3.1 CPVC Solvent Cement..............................................................................................................6
3.2 UPVC Solvent Cement..............................................................................................................7
3.3 PVC Solvent Cement.................................................................................................................7
4. SPECIFICATIONS OF DIFFERENT CPVC & PVC SOLVENT CEMENT............................7
5. PRIMER - CLEANER AND IT’S SPECIFICATIONS..............................................................10
6. ANALYSIS OF PROPERTIES AND STRUCTURES OF CHEMICALS................................ 11
6.1 CPVC Chlorination Polyvinyl Chloride CAS 6864-82-8....................................................... 12
6.2 PVC Chlorinated Polyvinyl Chloride CAS 9002-86-28......................................................... 12
7. ANALYSIS OF ADHESIVE.......................................................................................................... 13
7.1 Gel Permeation Chromatography and Size-Exclusion Chromatography................................14
7.2 NMR........................................................................................................................................16
7.3 Thermal Analysis.....................................................................................................................17
8. RESULT AND OUTCOMES.........................................................................................................18
9. REFERENCES............................................................................................................................... 18
10. FIGURES AND TABLES............................................................................................................ 18
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WEEKLY REVIEW
This portion contains the weekly work-review by the students of Group 2.
Week 1 (22nd Feb - 1st March)
Finalization of the topic and discussion with Faculty Mentor
Week 2 (2nd March - 8th March)
Research Paper, Articles, literature and web-links collection;
Adhesive and solvent cement classification.
Week 3 (9th March - 15th March)
Ingredients and structures of Solvent cement
Week 4 (16th March - 22nd March)
No work had done as the Exam was going on.
Week 5 (23rd March - 29th March)
Properties and structures of Chemicals;
Primer - cleaner
Week 6 (30th March - 5th April)
Different Analysis method for Adhesives
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1. INTRODUCTION
Adhesives form an inextricable part of modern life. In fact it is difficult to imagine everyday life
without these bonding substances. Consider packaging, building, automobiles, dentistry, medicine,
consumer goods, piping and food industries — all these activities rely heavily on adhesive materials.
Use of adhesives in today’s technology continues to grow at a rapid pace throughout the world and
research in polymer science continues to increase.
For a successful application of an adhesive to a substrate (adherent), to reach a maximum adhesion, it
must be able to flow, penetrate, wet, and set. The adhesive in its final state must be a solid, high-
molecular-weight polymer that is able to carry and transfer mechanical forces. In order to meet these
four criteria, there are three ways in which adhesives are prepared: (1) A polymeric adhesive can be
dissolved or dispersed in a solvent; after application, the solvent is allowed to evaporate, leaving
behind the high molecular-weight polymer. (2) If the adhesive is a thermoplastic polymer, it can be
heated to melt and apply in a molten state; after application, it is allowed to cool and solidify in the
glue line. (3) An adhesive can be prepared by chemical reactions via a polymerization process to
convert monomer (low-molecular-weight starting unit) into polymer (high molecular-weight
material). Many natural adhesives are prepared based on the first method, and most of the synthetic
adhesives are prepared by the third method.
In essence, an adhesive is any substance, inorganic or organic, natural or synthetic, that is
capable of bonding substances together by surface attachment. The bonding power of an
adhesive depends heavily on its molecular weight or size of the molecules. Under a proper bonding
process, the adhesive with higher molecular weight provides a stronger bond. Hence the adhesive is a
high-molecular-weight substance, commonly known as a polymer.
Adhesives are a very diverse and complex group of materials. They can manifest themselves in many
shapes and forms — they can be viscous liquids, powders, or cured products.
2. CLASSIFICATION OF ADHESIVES
2.1 Thermosetting adhesives
Thermosets molecules are cross-linked by strong covalent intermolecular bonds, forming
one giant molecule. Cross-linking is irreversible therefore thermosets cannot be
reprocessed.
Cross-linking is achieved in curing process initiated by heat, chemical agents, radiation or
evaporation of Solvents. Curing results in sharp increase of strength, elasticity and
stability of thermosets.
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CPVC tube can tolerate a temperature of 82.2℃. Without deforming, a feature that makes it
ideal for hot water installations.
This section reviews different type of CPVC and PVC Solvent Cement
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Heavy Duty CPVC Heavy Duty CPVC Medium CPVC All Weather CPVC Cement
Cement Industrial Cement Cement with UV Indicator
Color Orange Gray Orange Gold
Product Type CPVC Cement CPVC Cement CPVC Cement CPVC Cement
Set Type Standard (40 – 105 ° Standard (40 – 105 ° F) Standard (40 – 105 ° F) Standard (40 – 105 ° F)
F)
Maximum Use 200 200 200 200
Temperature ° F
Use Heavy-bodied cement Heavy-bodied solvent Medium-bodied orange For copper tube size (CTS)
for use on all cement formulated for cement for use on all CPVC hot and cold potable
schedules and classes use on PVC and CPVC schedules and classes water pipe and fittings up to
of CPVC pipe and Piping systems requiring of CPVC pipe and 2" diameter interference fit.
fittings up to 12" chemical resistance to fittings up to 6"
diameter with caustics, including diameter with
interference fit. Hypochlorite, mineral interference fit.
acids and aqueous salt
solutions.
Table 1 Specifications of CPVC Solvent Cement
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Set Type Cold Weather (< Standard (40 - 105° Standard (40 - 105° Standard (40 - Cold Weather Cold Weather (< 32° F)
32 ° F) F) F) 105° F) (< 32° F)
Maximum Use 140 140 140 140 140 140
Temperature °
F
Use Regular-Bodied Heavy-bodied
Medium-bodied Heavy Bodied Clear
Clear cement for blue or clear
clear cement for cement for use on all Medium-bodied Medium bodied, very fast
use on all cement for use
use on all schedules and classes clear cement for use setting, all weather clear
schedules and on all schedules
schedules and of PVC pipe and on all schedules and cement for use on all
classes of PVC and classes of
classes of PVC fittings up to 12" classes of PVC pipe schedules and classes of
pipe and fittings flexible and
pipe and fittings with interference fit, and fittings up to 6" PVC pipe and fittings up to
up to 4" for Sch. rigid PVC pipe
up to 6" diameter 18" for DWV diameter with 6” diameter with
40 and up to 2" and fittings up
with interference applications. interference fit. interference fit.
for Sch. 80. to 12" diameter
fit.Recommended Recommended for Recommended for Recommended for potable
Recommended for with
for use on potable potable water, potable water, water, pressure pipe,
potable water, interference fit.
water, drain, pressure pipe, and pressure pipe, conduit and DWV
pressure pipe,
waste, and vent conduit and DWV conduit and DWV. applications.
conduit and
systems. applications.
DWV.
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Structure
formula
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Application
PVC is an acronym for polyvinyl chloride. A resin is a material often used in the production of
plastics and rubbers. PVC resin is a white powder commonly used to produce thermoplastics.
Other members of the vinyl family can be used for similar applications, but PVC tends to be the
most popular member of that family
7. ANALYSIS OF ADHESIVE
Analysis or characterization is an essential step in working with adhesives. As a rule, such efforts are
directed toward a specific purpose that may focus on structural determination, curing reaction, and
size of the molecule, material design at a molecular level, process control, or failure analysis.
Adhesives may be synthesized by many processes; very often the precise conditions used have an
effect on the structure of the product. Because of the statistical nature of the polymerization process,
most polymers show a distribution of molar mass or molecular weights, which may be averaged in
several different ways. Any physical or performance property of a polymer may be related to one or
more average molecular weights, the type of average being determined by the physical averaging
process inherent in the method used to measure the property. Thus, a complete description of the
molecular weight distribution of a polymer is important to understand its physical, rheological, and
mechanical properties.
The molecular weight of an adhesive is of prime importance in its preparation, application, and
performance. The effect of molecular weight on the tensile strength or bonding power of an adhesive
is illustrated in Figure.
At very low molecular weights, the ultimate tensile stress is near zero. As the molecular weight
increases, the tensile strength rapidly increases, then gradually levels off. Hence, the useful bonding
and mechanical properties of an adhesive are heavily dependent on its molecular weight. Normally,
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bonding power does not begin to develop in adhesives until a minimum molecular weight above
5,000 is achieved. Above that size, there is a rapid increase in the mechanical performance of
adhesives as their molecular weights increase. For analysis or characterization of adhesives, the first
step is to determine the molecular weight or degree of polymerization. The molecular weights of
adhesives can be determined by chemical or physical methods of functional group analysis or by
measurement of the colligative properties, light scattering, ultracentrifugation, or dilute solution
viscosity.
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The Gel permeation chromatography or SEC is a liquid column chromatographic technique in which
an adhesive solution is introduced onto a column packed with a rigid porous gel and is carried
through the column by a solvent or solvents (mobile phase). Ideally, size separation is achieved by
differential pore permeation. Under the influence of the solvent stream passing down the column, the
smaller molecules in the adhesive go into and out of more pores in the packing than do the larger
molecules. Hence, larger molecules are eluted from the column earlier than smaller ones and are
detected by means of some suitable instruments.
The separation is based on the hydrodynamic volume of a polymer molecule. This hydrodynamic
volume is converted to a molecular weight or equivalent molecular weight compared to the
hydrodynamic volume of a calibrated polymer by means of a calibration curve.
Figure 3 Relationship between molecular weight and retention volume for gel permeation
chromatography; calibration curve
Specific molecular weights in GPC can be determined only from a calibration curve. Calibration
requires chromatographing several samples of the specific polymer type that have narrow molecular
weight distributions and known molecular weights covering the entire range of interest. The peak
retention volumes of the sample are then plotted graphically against the known molecular weight
average. The molecular weight average of the unknown is determined from the calibration plot and
the peak retention volume and is in the units of the calibration curve, Mw , Mn , or Mv.
In GPC or SEC the distribution coefficient of a solute species is defined in terms of the fraction of
the intraparticle volume, Vs, which is accessible to the solute so that
Vt − Vm
K=
Vs
For large, totally excluded molecules, Vt = Vm and hence K = 0. For small solute molecules which
can enter all the pores, Vt = Vm + Vs and hence K = 1. Separation therefore occurs only where solute
molecules obey the condition 0 < K < 1.
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7.2 NMR
NMR is an abbreviation for Nuclear Magnetic Resonance. An NMR instrument allows the molecular
structure of a material to be analyzed by observing and measuring the interaction of nuclear spins
when placed in a powerful magnetic field. For the analysis of molecular structure at the atomic level,
electron microscopes and X-ray diffraction instruments can also be used, but the advantages of NMR
are that sample measurements are non-destructive and there is less sample preparation required.
Fields of application include bio, foods, and chemistry, as well as new fields such as battery films
and organic EL, which are improving and developing at remarkable speed. NMR has become an
indispensable analysis tool in cutting-edge science and technology fields.
NMR instrument composition
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9. REFERENCES
“Handbook of Adhesive Technology” by A. Pizzi, Universite' de Nancy IEpinal, France and K. L.
Mittal, Hopewell Junction, New York, U.S.A.
Online at “http://www.substech.com/dokuwiki/doku.php?id=classification_of_adhesives”
“Handbook of Adhesion” by D. E. Packham, University of Bath, Bath, UK
Online at “https://www.plumbingsupply.com/the-great-pvc-primmer-debate.html”
Online at “https://www.kenresearch.com/blog/2018/12/india-pvc-solvent-cement-market-
research-report-ken-research/”
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