Ae The reaction is only spontaneous at low temperature. fe ‘The reaction Is spontaneous at all temperatures. . ‘The 46° becomes less favorable as temperature increases, * _ The reaction is spontaneous at high temperatures, 27. For which of these reactions will the difference between the AH® and AE® be the greatest? © 2HaQe fl) > 2H20 @) + O2(g) + GalOals) + ca0 (5) +cOr(@ + NOWg+.05(g)-> NO2ig) + 021g) Z # 2GH6(g)+ 702(g) > 4C02(g) + 6H20 (1) 28. The normal freezing point of ammonia is -78°C. Predict the signs of AH, AS, and AG “Gedy. fOr ammonia when ft freezes at -20°C and 1 atm. tre aid © AH<0,48<0,4G=0 as os © AH<0,4S>0,46<0 © AH>0,AS<0,4G>0 \e) at <0,4s < 0,46 <0 29. Anegative sign for AG indicates that, at constant T and P, * The reaction is exothermic. © The reaction is fast. . reattion is endothermic. 7 © The reaction is spontaneous. : 30. Ozone in the can react with nitric oxide to form nitrogen diaxide and oxygen 62%. Calculate the free energy of the reaction at 25°C if the enthalpy of the reaction is - Ane 199 ki/mol and the entrapy of the reaction Is -4.1 J/mol K. tH wre © ©1020 ki/mot © -1.22 % 10° ki/mol G* BR - Ths pa 200 moh SES (259g a 198 Kd ~102-6T alla |. PROBLEM SOLVING @S pts: Solye the following problems, Show complete solutions. 1. (5 pts) A sample of the compound MSO, weighing 0.01131 8 reacts with barium butane CcHro (g); and He (g) are -2540.2, -2877.6, and -285.8 , respectively. Use these data to calculate the heat of hydrogenation of 1,3-butadiene to butane: Cie (g) + 2H2 (8) + CaHr0 (g) Please take time to check whether you correctly followed all Instructions. ~ Please make sure all details (your name, signature, teacher's names, etc.) on the cover of your bluebook are correct. Submit your exam bluebook AND the exam questionnaire if you are done and vacate the room quietly