No

Material Active Centers Applications Results Paper Title

.
Nearly 100 % of Orange II Bimetallic Fe/Ti‐Based Metal–
was removed in the Fe/Ti- Organic Framework for Persulfate‐
MOF-NH2(3:1)/PS/Vis within Assisted Visible Light
Fe3+/Fe2+ and Photo-catalyst for
1 Fe/Ti-MOF-NH2 10 min. Photocatalytic Degradation of
Ti4+/Ti3+ degradation of orange II
PS as ammonium persulfate Orange II
(3:1) as ratio of Fe and Ti File name:
within MOFs. 10.1002@slct.201703134
MIL-101(Fe) revealed the best
photo-catalytic activation with
Iron(III)-based Metal-Organic
76% and 61% of
NO Frameworks as potential visible
MIL-101(Fe) light-driven catalysts
Photo-catalyst for conversion under solar and
2 MIL-88B(Fe) Fe3+ in MIL for the removal of NOx: A solution
removal of NOx UV cut-off illumination, for urban air purification
MIL-53(Fe)
respectively. The catalytic
10.1016@j.jphotochem.2018.09.008
stability still retain after
reaction process.
Fe(41wt%)-C/K-Fe-MOFs
showed a highest yield of C2-
C4 olefin generation as 33.6 Metal organic framework derived
iron catalysts for the direct
Fe-C/Fe-MOF Catalyst for mmol.g.cat-1.h-1 at XCO2 = 40%,
Iron oxide iron hydrogenation of CO2 to short chain
3 (Basolite F300 as hydrogenation of CO2 to
carbides 320 C, 30 bar, H2/CO2 = 3, olefins
o
Fe-BTC) short chain olefins
and 2400 mL.g-1.h-1. Herein, K 10.1021@acscatal.8b02892
is a promoter to enhance olefin
selectivity.
4 MOF-907 Fe3O SBUs Catalyst for microwave Poly methyl methacrylate A complex metal-organic
 product was obtained in 30
framework catalyst for
min with high yield (98%),
microwave-assisted radical
assisted radical
high molecular weight (20,680 polymerization
polymerization
g mol−1), and low
10.1038@s42004-018-0071-6
polydispersity (1.23).
When MIL-88A is combined
with persulfate, the
Rhodamine B (RB) dye
solution is decolorized
significantly. The
decolorization efficiency
reached ~80% after 2 hours. Iron-based Metal Organic
Framework, MIL-88A, as a
Heterogeneous This showed that the
Heterogeneous Persulfate Catalyst
Iron oxide cluster Persulfate Catalyst for
5 MIL-88A(Fe) combination of persulfate and for Decolorization of Rhodamine B
(Fe2O3) Decolorization of
in Water
Rhodamine B in Water MIL-88A effectively
decolorized the RB solution. 10.1039@C5RA01447F
In addition, unlike other iron-
containing MOFs, MIL-88A
can be synthesized just in
water without using toxic
solvents such as
DMF.
6 MIL- MIL- Photocatalyst for A series of new kind of MOF Synthesis of MIL-100(Fe)@MIL-
 hybrid photocatalyst based on
two different types of MOFs,
MIL-100(Fe) and MIL-53(Fe),
have been fabricated
successfully by dispersion of
53(Fe) as a novel hybrid
MIL-100(Fe) on the surface of
photocatalyst and evaluation
MIL-53(Fe). photocatalytic and
100(Fe)@MIL- 100(Fe)@MIL- degradation of methyl photoelectrochemical performance
The photocatalytic oxidation
53(Fe) 53(Fe) orange under visible light irradiation.
of methyl orange (10 ppm, 100
mL) in the presence of the
abdpour2018
photocatalyst achieved the
highest amount of 100% when
we used H2O2 and air bubbling
conditions during the
photocatalytic experiment.
The highest catalytic yields
were obtained as 77 %, 71 %
Treatment of Textile Effluent
Catalyst for degradation
and 68 % of Total Organic Containing Recalcitrant Dyes Using
of the model azo dyes
MOF Derived FeZSM-5
7 Fe-MOF@ZSM-5 Fe2+ such as Acid Blue 113, Carbon (TOC) for removal
Heterogeneous Catalyst
Methyl Orange and
process of Acid Blue 113,
Reactive Black.
ahmad2016
Methyl Orange and Reactive
Black 5, respectively.
8 Resin@MIL-53(Fe) MIL-53(Fe) plays Photocatalyst for Such an immobilization of the Resin modified MIL-53 (Fe) MOF
 resins significantly alters MIL-
53 (Fe) activity and
degradation selectivity of dye
pollutants; after 120 min of
visible light illumination (λ ≥
420 nm) removal yield of SRB
(24%) by the bare MIL-53
(Fe) was apparently improved for improvement of photocatalytic
Performance
a role a support to degradation of organic to 96% after MIL-53 (Fe) was
anchor resin dyes modified by Amberlite IRA
900, DMIL-53(Fe). araya2016

The tunable degradation order

was demonstrated by
employing AMIL-53 (Fe) for
the selective degradation of
cationic dyes while DMIL-53
(Fe) for the degradation of
anionic dyes
2+
9 Fe-MOF-74 Fe Using H2O2 as an oxidant; 60% Solvothermal Synthesis of Fe-MOF-
74 and Its Catalytic Properties in
phenol conversion was
Phenol Hydroxylation
achieved at 20 oC in water
bhattacharjee2010
with 68 and 32% selectivity to
catechol and hydroquinone,
 respectively.
At an initial circumneutral pH
of 6.21, 89.0% of 0.36 mM
250 mL of 4-NP solution
could be degradated after 75
min by the heterogeneous
Fenton-like oxidation on the
0.08 g L-1 of Fe–C500 in the
presence of
Heterogeneous Fenton-like catalysis
7.8 mM H2O2. The results of of Fe-MOF derived magnetic
Heterogeneous catalyst activation energy and the carbon nanocomposites for
Fe-Cx devired Fe-
10 Fe-C for degradation of 4- degradation of 4-nitrophenol
MOF pyrolysis reaction kinetics showed Fe–
nitrophenol
C500 possessed a high catalytic
chen2017
activity in the heterogeneous
Fenton reaction of 4-NP.
Moreover, the prepared Fe–
C500 could be reused by an
external magnet, and still
retained good catalytic activity
with 52.4% degradation of 4-
NP at the fourth cycle.
11 MIL-101(Fe) Catalysts for Visible MIL-101(Fe) exhibited a Iron-Based Metal–Organic
MIL-101-NH2(Fe) Light-Driven Water Frameworks as Catalysts for Visible
higher value than MIL-101-
Oxidation Light-Driven Water Oxidation
 NH2(Fe).
MIL-101(Fe):
+ Oxygen evolution content:
36.5 μmol. chi2016

+ TON: 27.3
+ TOF: 0.1 s-1.
Reaction of 2,2′-azino-bis(3-
ethylbenzothiazoline)-6-
sulfonic acid (ABTS)
with H2O2, catalyzed by
Fe(III)PPIX-1 and -2, showed
that Fe(III)PPIX-1 is
Fe(III) Protoporphyrin IX
significantly more efficient
Encapsulated in a Zinc
than Fe(III)PPIX-2 and is Metal−Organic Framework Shows
Zn-MOFs
Catalyst for peroxidatic Dramatically Enhanced Peroxidatic
12 encapsulated Fe- Fe3+ superior to solid Fe(III)PPIX-
reaciton Activity
porphyrin
Cl. Fe(III)PPIX-1 was used to
catalyze the oxidation of
dare2018
hydroquinone, thymol, benzyl
alcohol, and phenyl ethanol by
tert-butyl-hydroperoxide with
t1/2 values that increase with
increasing substrate molecular
volume.
 Catalytic aerobic oxidation of
styrene resulted in the
NHPI/Fe(BTC)
formation of styrene epoxide,
NHPI(N-
hydroxyphthalimide ) benzaldehyde, and Aerobic Oxidation of Styrenes
is an organocatalyst that Catalyzed by an Iron Metal
in combination with Catalysts for Aerobic phenylacetaldehyde.
13 Organic Framework
transition metal can act Oxidation of Styrenes Conversion of styrene
as initiator of radical
chain oxidation of increases with time reaching dhakshinamoorthy2011
(cyclo)alkanes, alkanes,
alcohols, and benzylic 10% at 2 h
compounds
with an increase in the
selectivity toward epoxide
14 Fe(BTC) and MIL- Bronsted acid and Catalyst for oxidation While the commercial Fe(BTC) is Comparison of Porous Iron
100(Fe) Fe3+/Fe2+ reaction the best catalyst for Lewis Trimesates Basolite F300 and MIL-
acid reactions because of its
100(Fe)
As Heterogeneous Catalysts for
additional Brönsted acid sites,
Lewis Acid and Oxidation
MIL-100(Fe) would be the best Reactions:
choice for oxidation reactions Roles of Structural Defects and
due to the presence of Fe /Fe pairs,
3+
Stability
2+

which seem to give rise

dhakshinamoorthy2012
to an interchange without
compromising the crystal structure.
In detail, Fe(BTC) performed a high
conversion the ring-opening of
styrene oxide to 2-methoxy-1-
phenylethanol. (Yield = 99% after
1h).
 In contrast to the ring-opening of
epoxide, the performance
of MIL-100(Fe) for oxidation
reactions was found better than
that of Fe(BTC) in the
case of aerobic oxidation of
thiophenol, leading to
diphenyldisulfide. (Yield = 81%
after 24h).

Direct arylation of benzoazoles with

heterogeneous catalyst aldehydes utilizing metal–organic
for the direct arylation of framework Fe3O(BDC)3 as
15 Fe3O(BDC) Yield : 93% after 3h at 100 oC
azoles with a recyclable heterogeneous catalyst.
benzaldehydes
doan2017
Cross-dehydrogenative coupling of
heterogeneous catalyst VNU-20 was more active towards
coumarins with Csp3–H bonds
for the this reaction than numerous other
using an iron–organic framework as
16 VNU-20 crossdehydrogenative
homogeneous and heterogeneous a productive heterogeneous catalyst
coupling of coumarins
with Csp3–H bonds catalysts
doan2018
17 MIL-53(Fe) Catalytically oxidize The asprepared MIL-53(Fe) Metal–organic framework MIL-
TMB, ABTS and OPD exhibited enhanced peroxidase-like 53(Fe): Facile microwave-assisted
by H2O2 to produce a 5 activity, and could catalytically synthesis and use as a highly active
typical colour reaction peroxidase mimetic for glucose
oxidize TMB, ABTS and OPD by
biosensing
H2O2 to produce a colour reaction.
The as-prepared MIL-53(Fe) shows
3,3,5,5-tetramethylbenzidine dong2015
(TMB) o-phenylenediamine much higher affinity to H2O2 over
(OPD), and 2,2’-azino-bis(3-
 other MOFs-based peroxidase
mimetics and MIL-53(Fe)
peroxidase mimetics by CE-based
solvothermal method, which is
ethylbenzothiazoline-6-sulfonic
acid) diammonium salt (ABTS)
probably due to the
10 purely octahedral structure and
small sized crystals of the MIL-
53(Fe) obtained by MW-based
synthesis method.
18 Pd/MIL-101(Fe)- Catalyst for a visible- The resulting Pd/MIL-101(Fe)-NH2 Visible-Light-Induced Catalytic
NH2 light-induced transfer exhibited excellent catalytic Transfer Hydrogenation of
hydrogenation of performance towards a visible-light- Aromatic Aldehydes by Palladium
benzaldehyde Immobilized on Amine-
induced transfer hydrogenation of
Functionalized Iron-Based Metal-
benzaldehyde by producing a benzyl Organic
alcohol yield of 77% with a full Frameworks
benzaldehyde conversion in the
presence of TEA-HCOOH. In dong2018
addition to benzaldehyde, biomass-
based renewable platform molecules
such as furfural and 5-
hydroxymethylfurfural (HMF) were
successively converted into the
corresponding alcohols with the
yields of 29% for furfuryl alcohol
and 27% for 2,5-
dihydroxymethylfuran (DHMF),
respectively, which are the highest
 yields reported so far by visiblelight-
induced transfer hydrogenation
method
Fe-based Metal-Organic
An optimum benzene conversion of Frameworks (MOFs) for Highly
Photocatalytic for 30.6% was achieved with a Selective Photocatalytic Benzene
MIL-100(Fe) and
19 Benzene Hydroxylation Hydroxylation to Phenol
MIL-68(Fe) H2O2/benzene ratio of 3:4 over MIL-
reaction to Phenol
100(Fe) after 24 h irradiations. Fe-MOF from benzene to phenol