Professional Documents
Culture Documents
Material
Safety
Data
Sheet
This
MSDS
complies
with
OSHA’s
Hazardous
Communication
Standard
29
CFR
1910.1200
and
OSHA
form
174.
BES
Ozonated
Water
Rev.
Date
January
15,
2014
SECTION
1.
CHEMICAL
PRODUCT
AND
COMPANY
IDENTIFICATION
Product
Name
Water
with
Dissolved
Ozone
(Mild
Concentration)
Synonym(s)
Ozonated
Water,
Ozone
Water,
O3
Water,
Trioxygen
Water,
Triatomic
Oxygen
Water
Chemical
Name
Dissolved
Ozone
Gas
in
Water
up
to
12.0
PPM
Chemical
Formula
H2O
+
O3
Product
Aqueous
Solution
of
Ozone
Dissolved
in
Potable
Water
Description
Contact
Biotek
Environmental
Science
Ltd.
Information
5F.,
No.98,
Xingde
Rd.
Sanchong
Dist.,
New
Taipei
City
24158,
Taiwan
(R.O.C.)
Tel:
+886
(2)
8511-‐1048
Email:
service@besgroups.com
Web:
www.besgroups.com
SECTION
2.
COMPOSITION
AND
INFORMATION
OF
INGREDIENTS
Material
Name
Water
Ozone
CAS
Number
7732-‐18-‐5
10028-‐15-‐6
RTECS
ZC0110000
RS8225000
Chemical
Formula
H2O
O3
Molecular
Weight
18.0
g/mol
48.0
g/mol
Boiling
Point
100.0
°C
-‐
111.9
°C
Melting
Point
0.00
°C
-‐192.7
°C
Gas
Density
(0
℃
at
999.8
g/L
2.4
g/L
1atm)
Vapor
Density
0.6
g/L
1.6
g/L
Water
Solubility
-‐
19
mg/L
(20
℃)
Specific
Gravity
1
1.614
Appearance
Colorless,
Liquid
Colorless,
Dissolved
Gas
Odor
None
Pungent
%
By
Weight
>
99.999
%
<
0.001
%
SECTION
3.
HAZARD
IDENTIFICATION
Material
HAZARD
ACGIH
TLV
OSHA
PEL
None
-‐
-‐
-‐
1
SECTION
4.
PHYSICAL/CHEMICAL
CHARACTERISTICS
Boiling
Point
Similar
to
water
(H2O
=
100
°C
or
212
°F
at
760
mm
Hg)
Melting
Point
Similar
to
water
(H2O
=
0
°C
or
32
F
at
760
mm
Hg)
Specific
Gravity
Equivalent
to
water
(H2O
=
1)
Vapor
Pressure
Equivalent
to
water
(H2O
=
17.5
at
20
°C
or
68
°F)
(mm
Hg)
Vapor
Density
Equivalent
to
water
(H2O
=
0.694;
Air
=
1)
Evaporation
Rate
>
1
(Butyl
Acetate
=
1)
Solubility
in
Water
100%
Appearance
and
Colorless
and
clear
liquid;
smell
similar
to
ozone
Odor
SECTION
5.
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point
Not
Applicable
Auto-‐ignition
Not
Applicable
Temperature
Flammable
limits
Not
Applicable
Extinguishing
Not
Applicable
Media
Special
Fire
Fighting
Not
Applicable
Procedures
Unusual
Fire
and
Not
Applicable
Explosion
Hazards
SECTION
6.
REACTIVITY
DATA
Stability
Unstable,
decaying
to
ordinary
diatomic
oxygen:
2O3
!
3O2
It
has
a
varying
half-‐life
length,
depending
upon
atmospheric
conditions
(temperature,
humidity,
and
air
movement).
In
an
aqueous
solution
of
ozone
dissolved
in
water,
the
water-‐
dissolved
ozone
decomposes
spontaneously
under
all
ordinary
conditions.
Decomposition
is
accelerated
by
contact
with
solid
surfaces,
by
contact
with
chemical
substances
and
by
the
effect
of
heat.
Typical
Dissolved
Ozone
(in
water)
Half
Life
Time
as
a
Function
of
Temperature:
Dissolved
In
Water
(pH
7)
Half
Life
Time
At
Temp.
~30
minutes
15
°C
~20
minutes
20
°C
~15
minutes
25
°C
~12
minutes
30
°C
~
8
minutes
35
°C
2
Reactivity
In
an
aqueous
solution
of
ozone
dissolved
in
water,
the
water-‐
dissolved
ozone
is
a
power-‐oxidizing
agent
and
reacts
with
all
oxidizing
materials,
both
organic
and
inorganic,
by
reactions
either
with
the
molecular
ozone
or
hydroxyl
radicals
(OH),
the
later
are
formed
when
ozone
decomposes
in
water.
It
is
recommend
for
use
with
oxidation-‐resistant
materials
to
support
applications.
Incompatibility
Avoid
contact
with
oxidizable
materials
that
is
unexpected
to
participate
applications.
Conditions
to
Avoid
None
Known
Hazardous
None
Decomposition
Hazardous
Will
not
occur
Polymerization
SECTION
7.
HEALTH
HAZARD
DATA
Threshold
Limit
Not
Determined
Value
Route
of
Exposure
Eye
Skin
Inhalation
Ingestion
"Not
Hazardous
Eye
Contact
Hazard
No
eye
irritation
is
expected
from
short-‐term
exposure.
Skin
Contact
No
skin
irritation
is
expected
from
short-‐term
exposure.
Hazard
Skin
Absorption
No
published
data
indicates
this
product
could
be
hazardous
Hazard
when
absorbed
through
the
skin.
Inhalation
Hazard
Inhalation
is
not
likely
to
be
a
primary
route
of
exposure
but
could
become
irritating
of
aerosols
are
exposed
to
individual
for
extended
period
of
time.
Ingestion
Hazard
Not
Hazardous
Effects
of
Acute
Mild
eye
or
skin
irritation
Exposure
Effects
of
Chronic
Repeated
exposure
of
the
skin
to
concentrated
product
should
Exposure
be
avoided
to
prevent
irritation
and
drying
of
the
skin.
Emergency
and
First
Aid
Procedures
Eye
Contact
If
exposure
to
water
containing
aqueous
solution
of
dissolved
ozone
causes
irritation
to
eyes,
flush
eyes
with
plenty
of
clean,
running
water
for
least
15
minutes,
lifting
the
upper
and
lower
lids
occasionally.
Remove
contact
lenses
if
worn.
Seek
medical
attention
if
irritation
persists.
Skin
Contact
Not
likely
to
become
irritated
unless
repeatedly
exposed
to
large
volumes
of
material.
If
irritation
develops,
rinse
affected
area
with
ozone
free
potable
water.
If
irritation
continues
seek
medical
advice.
Inhalation
Inhalation
of
mists
could
lead
to
irritation
of
lungs.
If
symptoms
develop,
move
individual
away
from
exposure
and
into
fresh
air.
If
symptoms
persist,
seek
medical
attention.
Ingestion
Not
Available
3
SECTION
8.
PRECAUTIONS
FOR
SAFE
HANDLING
AND
USE
Steps
to
Be
Taken
Mop
up,
or
absorb
with
an
inert
dry
material
and
place
in
an
in
Case
Material
is
appropriate
waste
disposal
container.
Released
or
Spilled
Waste
Disposal
Dispose
of
the
same
as
potable
rinse
water.
Method
Handling
Handling
of
the
same
as
potable
rinse
water.
Storage
Not
Applicable.
Storage
is
not
expected.
SECTION
9.
CONTROL
MEASURES
Respiratory
Protection
Not
Required
for
Normal
Use
of
this
Product
(Specify
Type)
Ventilation
Local
Exhaust
Preferable
Special
NA
Mechanical
Preferable
Other
NA
(General)
Protective
Gloves
Not
Required
Eye
Protection
Not
Required
Other
Protective
Not
Required
Equipment
SECTION
10.
SPECIAL
PRECAUTIONS
AND
COMMENTS
Precautionary
Certified
testing
of
BES’s
systems
by
NSF
(National
Sanitation
Labeling
Foundation)
has
shown
that
under
normal
conditions
of
use,
aqueous
solution
containing
mild
levels
of
ozone
gas
dissolved
in
portable
water
do
not
present
a
safety
hazard
when
contact
to
the
individual
is
incidental.
Precautions
To
Be
Ozone
in
the
form
of
gas
can
be
released
from
ozonated
water
Taken
in
Detecting
even
after
it
has
been
properly
dissolved.
This
amount
is
usually
Off-‐gas
very
small
and
through
the
smell
may
be
detectable.
In
this
aqueous
medium
range
concentrations
(0-‐12.0
ppm),
the
amount
of
off-‐gas
is
not
a
health
concern.
When
used
in
a
room
with
normal
ventilation,
levels
of
ozone
gas
being
released
into
the
air
have
been
supported
by
BES
Group
with
tests
to
show
that
to
be
well
below
the
periodic
exposure
levels
established
by
OSHA
for
worker
safety
through
the
utilization
of
BES’s
product
technology.
Exposure
Limit
Ozonated
Water
Ozone
Off-‐gas
Reference
US-‐OSHA:
0.10
ppm
8
hr
(TWA)
US-‐OSHA:
0.30
ppm
15
min
(STEL)
Not
Applicable
UK-‐COSHH:
0.10
ppm
8
hr
(TWA)
UK-‐COSHH:
0.20
ppm
15
min
(STEL)
4
Japan-‐JISHA:
0.10
ppm
8
hr
(TWA)
Precautions
in
A
room
for
installation
of
the
product
should
be
mechanically
Room
Ventilation
ventilated
using
either:
Conditions
• A
ventilation
system
that
provides
at
least
5
air
changes
per
hour,
or
• A
two-‐stage
ventilation
system
that
uses
a
general
and
an
emergency
system.
Under
normal
conditions,
the
general
system
should
provide
at
least
three
air
changes
per
hour.
In
the
event
of
higher
ozone
off
gassing,
the
emergency
system
should
provide
at
least
30
air
changes
per
hour.
An
ozone
monitor
in
the
ozone
room
must
automatically
activate
the
emergency
system
when
the
ozone
concentration
exceeds
0.05
ppm.
Precautions
in
The
off-‐gas
destruct
component
built-‐in
with
the
product
must
Engineering
be
regularly
replaced
for
maintenance.
Check
the
particular
Controls
model’s
product
technical
datasheet
for
replacement
period
and
follow
the
recommendation.
DISCLAMER
This
material
safety
data
sheet
is
provided
as
in
information
resource
only.
It
should
not
be
taken
as
a
warranty
or
representation
for
which
the
preparer
assumes
legal
responsibility.
While
we
believe
the
information
contained
herein
is
accurate
and
compiled
from
sources
believed
to
be
reliable,
it
is
the
responsibility
of
the
user
to
investigate
and
verify
its
validity.
The
buyer
assumes
all
responsibility
of
using
and
handling
the
product
in
accordance
with
applicable
federal,
state
or
local
regulations.
5