You are on page 1of 5

 

 
Material  Safety  Data  Sheet  
This  MSDS  complies  with  OSHA’s  Hazardous    
Communication  Standard  29  CFR  1910.1200  and  OSHA  form  174.    
 
BES  Ozonated  Water    
Rev.  Date  January  15,  2014  
 
SECTION  1.   CHEMICAL  PRODUCT  AND  COMPANY  IDENTIFICATION  
Product  Name   Water  with  Dissolved  Ozone  (Mild  Concentration)  
Synonym(s)   Ozonated  Water,  Ozone  Water,  O3  Water,  Trioxygen  Water,  
Triatomic  Oxygen  Water  
Chemical  Name   Dissolved  Ozone  Gas  in  Water  up  to  12.0  PPM  
Chemical  Formula   H2O  +  O3  
Product   Aqueous  Solution  of  Ozone  Dissolved  in  Potable  Water    
Description  
Contact   Biotek  Environmental  Science  Ltd.  
Information   5F.,  No.98,  Xingde  Rd.  Sanchong  Dist.,    
New  Taipei  City  24158,  Taiwan  (R.O.C.)  
Tel:  +886  (2)  8511-­‐1048  
Email:  service@besgroups.com  
Web:  www.besgroups.com  
 
SECTION  2.   COMPOSITION  AND  INFORMATION  OF  INGREDIENTS  
Material  Name   Water   Ozone  
CAS  Number   7732-­‐18-­‐5   10028-­‐15-­‐6  
RTECS   ZC0110000   RS8225000  
Chemical  Formula   H2O   O3  
Molecular  Weight   18.0  g/mol   48.0  g/mol  
Boiling  Point   100.0  °C   -­‐  111.9  °C  
Melting  Point   0.00  °C   -­‐192.7  °C  
Gas  Density  (0  ℃  at   999.8  g/L   2.4  g/L  
1atm)  
Vapor  Density     0.6  g/L   1.6  g/L  
Water  Solubility   -­‐   19  mg/L  
(20  ℃)  
Specific  Gravity   1   1.614  
Appearance   Colorless,  Liquid   Colorless,  Dissolved  Gas  
Odor   None   Pungent  
%  By  Weight   >  99.999  %   <  0.001  %  
 
SECTION  3.   HAZARD  IDENTIFICATION  
Material     HAZARD   ACGIH  TLV   OSHA  PEL  
None   -­‐   -­‐   -­‐  
 
 
 
 
 

  1  
 

 
SECTION  4.   PHYSICAL/CHEMICAL  CHARACTERISTICS  
Boiling  Point     Similar  to  water  (H2O  =  100  °C  or  212  °F  at  760  mm  Hg)  
Melting  Point   Similar  to  water  (H2O  =  0  °C  or  32  F  at  760  mm  Hg)  
Specific  Gravity   Equivalent  to  water  (H2O  =  1)  
Vapor  Pressure  
Equivalent  to  water  (H2O  =  17.5  at  20  °C  or  68  °F)  
(mm  Hg)  
Vapor  Density     Equivalent  to  water  (H2O  =  0.694;  Air  =  1)  
Evaporation  Rate     >  1  (Butyl  Acetate  =  1)    
Solubility  in  Water   100%  
Appearance  and  
Colorless  and  clear  liquid;  smell  similar  to  ozone  
Odor  
 
SECTION  5.   FIRE  AND  EXPLOSION  HAZARD  DATA  
Flash  Point   Not  Applicable    
Auto-­‐ignition  
Not  Applicable  
Temperature  
Flammable  limits   Not  Applicable  
Extinguishing  
Not  Applicable  
Media  
Special  Fire  
Fighting   Not  Applicable  
Procedures    
Unusual  Fire  and  
Not  Applicable  
Explosion  Hazards  
 
SECTION  6.   REACTIVITY  DATA  
Stability     Unstable,  decaying  to  ordinary  diatomic  oxygen:  2O3  !  3O2  
 
It  has  a  varying  half-­‐life  length,  depending  upon  atmospheric  
conditions  (temperature,  humidity,  and  air  movement).  In  an  
aqueous  solution  of  ozone  dissolved  in  water,  the  water-­‐
dissolved  ozone  decomposes  spontaneously  under  all  ordinary  
conditions.  Decomposition  is  accelerated  by  contact  with  solid  
surfaces,  by  contact  with  chemical  substances  and  by  the  effect  
of  heat.  
 
Typical  Dissolved  Ozone  (in  water)  Half  Life  Time  as  a  Function  
of  Temperature:  
 
Dissolved  In  Water  (pH  7)  
Half  Life  Time   At  Temp.  
~30  minutes   15  °C  
~20  minutes   20  °C  
~15  minutes   25  °C  
~12  minutes   30  °C  
 
~    8  minutes   35  °C  

  2  
 

 
Reactivity   In  an  aqueous  solution  of  ozone  dissolved  in  water,  the  water-­‐
dissolved  ozone  is  a  power-­‐oxidizing  agent  and  reacts  with  all  
oxidizing  materials,  both  organic  and  inorganic,  by  reactions  
either  with  the  molecular  ozone  or  hydroxyl  radicals  (OH),  the  
later  are  formed  when  ozone  decomposes  in  water.  It  is  
recommend  for  use  with  oxidation-­‐resistant  materials  to  
support  applications.    
Incompatibility   Avoid  contact  with  oxidizable  materials  that  is  unexpected  to  
participate  applications.  
Conditions  to  Avoid   None  Known  
Hazardous  
None  
Decomposition  
Hazardous  
Will  not  occur  
Polymerization  
 
SECTION  7.   HEALTH  HAZARD  DATA  
Threshold  Limit  
Not  Determined  
Value  
Route  of  Exposure     Eye       Skin       Inhalation       Ingestion      "Not  Hazardous  
Eye  Contact  Hazard   No  eye  irritation  is  expected  from  short-­‐term  exposure.  
Skin  Contact  
No  skin  irritation  is  expected  from  short-­‐term  exposure.  
Hazard  
Skin  Absorption   No  published  data  indicates  this  product  could  be  hazardous  
Hazard   when  absorbed  through  the  skin.      
Inhalation  Hazard   Inhalation  is  not  likely  to  be  a  primary  route  of  exposure  but  
could  become  irritating  of  aerosols  are  exposed  to  individual  for  
extended  period  of  time.      
Ingestion  Hazard   Not  Hazardous  
Effects  of  Acute  
Mild  eye  or  skin  irritation    
Exposure  
Effects  of  Chronic   Repeated  exposure  of  the  skin  to  concentrated  product  should  
Exposure   be  avoided  to  prevent  irritation  and  drying  of  the  skin.    
Emergency  and  First  Aid  Procedures  
Eye  Contact   If  exposure  to  water  containing  aqueous  solution  of  dissolved  
ozone  causes  irritation  to  eyes,  flush  eyes  with  plenty  of  clean,  
running  water  for  least  15  minutes,  lifting  the  upper  and  lower  
lids  occasionally.  Remove  contact  lenses  if  worn.  Seek  medical  
attention  if  irritation  persists.    
Skin  Contact     Not  likely  to  become  irritated  unless  repeatedly  exposed  to  large  
volumes  of  material.  If  irritation  develops,  rinse  affected  area  
with  ozone  free  potable  water.  If  irritation  continues  seek  
medical  advice.    
Inhalation     Inhalation  of  mists  could  lead  to  irritation  of  lungs.  If  symptoms  
develop,  move  individual  away  from  exposure  and  into  fresh  air.  
If  symptoms  persist,  seek  medical  attention.    
Ingestion     Not  Available  
 
 

  3  
 

 
SECTION  8.   PRECAUTIONS  FOR  SAFE  HANDLING  AND  USE  
Steps  to  Be  Taken   Mop  up,  or  absorb  with  an  inert  dry  material  and  place  in  an  
in  Case  Material  is   appropriate  waste  disposal  container.  
Released  or  Spilled  
Waste  Disposal  
Dispose  of  the  same  as  potable  rinse  water.  
Method  
Handling     Handling  of  the  same  as  potable  rinse  water.    
Storage   Not  Applicable.  Storage  is  not  expected.    
 
SECTION  9.   CONTROL  MEASURES  
Respiratory  
Protection   Not  Required  for  Normal  Use  of  this  Product  
(Specify  Type)    
Ventilation     Local  Exhaust   Preferable   Special   NA  
Mechanical   Preferable   Other   NA  
(General)    
Protective  Gloves   Not  Required  
Eye  Protection     Not  Required  
Other  Protective  
Not  Required  
Equipment  
 
SECTION  10.   SPECIAL  PRECAUTIONS  AND  COMMENTS    
Precautionary   Certified  testing  of  BES’s  systems  by  NSF  (National  Sanitation  
Labeling   Foundation)  has  shown  that  under  normal  conditions  of  use,  
aqueous  solution  containing  mild  levels  of  ozone  gas  dissolved  in  
portable  water  do  not  present  a  safety  hazard  when  contact  to  
the  individual  is  incidental.    
Precautions  To  Be   Ozone  in  the  form  of  gas  can  be  released  from  ozonated  water  
Taken  in  Detecting   even  after  it  has  been  properly  dissolved.  This  amount  is  usually  
Off-­‐gas     very  small  and  through  the  smell  may  be  detectable.  In  this  
aqueous  medium  range  concentrations  (0-­‐12.0  ppm),  the  
amount  of  off-­‐gas  is  not  a  health  concern.    
 
When  used  in  a  room  with  normal  ventilation,  levels  of  ozone  
gas  being  released  into  the  air  have  been  supported  by  BES  
Group  with  tests  to  show  that  to  be  well  below  the  periodic  
exposure  levels  established  by  OSHA  for  worker  safety  through  
the  utilization  of  BES’s  product  technology.        
Exposure  Limit  
Ozonated  Water   Ozone  Off-­‐gas  
Reference  
  US-­‐OSHA:  0.10  ppm  8  hr  
(TWA)  
US-­‐OSHA:  0.30  ppm  15  min  
(STEL)  
Not  Applicable  
UK-­‐COSHH:  0.10  ppm  8  hr  
(TWA)  
UK-­‐COSHH:  0.20  ppm  15  min  
(STEL)  

  4  
 

 
    Japan-­‐JISHA:  0.10  ppm  8  hr  
(TWA)  
Precautions  in   A  room  for  installation  of  the  product  should  be  mechanically  
Room  Ventilation   ventilated  using  either:  
Conditions   • A  ventilation  system  that  provides  at  least  5  air  changes  per  
hour,  or  
• A  two-­‐stage  ventilation  system  that  uses  a  general  and  an  
emergency  system.  Under  normal  conditions,  the  general  
system  should  provide  at  least  three  air  changes  per  hour.  In  
the  event  of  higher  ozone  off  gassing,  the  emergency  system  
should  provide  at  least  30  air  changes  per  hour.  An  ozone  
monitor  in  the  ozone  room  must  automatically  activate  the  
emergency  system  when  the  ozone  concentration  exceeds  
0.05  ppm.  
Precautions  in   The  off-­‐gas  destruct  component  built-­‐in  with  the  product  must  
Engineering   be  regularly  replaced  for  maintenance.  Check  the  particular  
Controls   model’s  product  technical  datasheet  for  replacement  period  and  
follow  the  recommendation.      
DISCLAMER    
This  material  safety  data  sheet  is  provided  as  in  information  resource  only.  It  should  not  be  taken  as  a  
warranty  or  representation  for  which  the  preparer  assumes  legal  responsibility.  While  we  believe  the  
information  contained  herein  is  accurate  and  compiled  from  sources  believed  to  be  reliable,  it  is  the  
responsibility  of  the  user  to  investigate  and  verify  its  validity.  The  buyer  assumes  all  responsibility  of  
using  and  handling  the  product  in  accordance  with  applicable  federal,  state  or  local  regulations.      
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 

  5  

You might also like