CHEMISTRY SYLLABUS (10+2

)

Theory Paper Practical Paper

Time : 3 Hours Time : 3 Hours

Max. Marks: 70 Max. Marks 30 Total Marks : 100

THEORY STRUCTURE OF QUESTION PAPER

1.

There will be one Theory Paper comprising of 30 questions. All questions will be compulsory.

2.

Q Nos. 1-10 will be of 1 marks, Q.Nos. 11-18 will be of 2 marks each Q. No. 19-26 will be of 3-marks each, Q-Nos. 27 to 30 will be of 5 marks each.

3. 4.

In questions No. 27-30 there will be 100% choice. Distribution of approximate percentage over different dimension in the question paper will be as follows: i) ii) iii) Knowledge Understanding Application 30% 40% 30%

5.

Numerical problem will be set in any type of question, however the total weightage to numerical problem will be around 20%.

6.

There will be no question of the type. “Write short note on”, and objective type questions such as “Yes/No”, tick ( ) cross (x) fill in blanks, multiple choice,” true/false etc.

7. 8.

Use of log tables/unprogrammable calculator is allowed. A candidate will be provided with one answer book of 32 pages only. No extra contineous sheet will be provided.

6

points defects. Unit II: Solutions (Periods 12) Types of solutions. voids. amorphous and crystalline solids (elementary idea). depression of freezing point.. colligative properties . ionic. electrical and magnetic properties. Unit I Unit II Unit III Unit IV Unit V Unit VI Unit VII Unit VIII Unit IX Unit X Unit XI Unit XII Unit XIII Unit XIV Unit XV Unit XVI Title Solid State Solutions Electrochemistry Chemical kinetics Surface Chemistry General principles and processes of Isolation of Elements p-Block Elements d-and f-Block Elements Coordination Compounds Haloalkanes and Haloarenes Alcohols. unit cell in two dimensional and three dimensional lattices. expression of concentration of solutions of solids in liquids. osmotic pressure. packing in solids. covalent and metallic solids.P. Ketones and Carboxylic acids Organic Compounds containing Nitrogen Biomolecules Polymers Chemistry in Everyday life Total : Marks 4 5 5 5 4 3 8 5 3 4 4 6 4 4 3 3 70 Unit I: Solid State (Periods 12) Classification of solids based on different binding forces: molecular. elevation of B. solubility of gases in liquids. number of atoms per unit cell in a cubic unit cell.Unit wise distribution of marks is as follows: CLASS XII (THEORY) One Paper Time : 3 Hours 70 marks Unit No. Phenols and Ethers Aldehydes.relative lowering of vapour pressure. solid solutions. calculation of density of unit cell. determination of molecular 7 .

trends in physical and chemical properties. properties and uses of chlorine and hydrochloric acid. catalyst. oxidation. properties and uses. catalysis. homogenous and heterogeneous. preparation. Nernst equation and its application to chemical cells. Tyndall effect. factors affecting rates of reaction. properties and uses of sulphur dioxide sulphuric acid: industral process of manofacture. standard electrode potential. specific and molar conductivity variations of conductivity with concentration. preparation. properties of colloids. Unit IV: Chemical Kinetic (Periods 12) Rate of a reacation (average and instantaneous). reduction electrolytic method and refining. multimolecular and macromolecular colloids. factors affecting adsorption of gases on solids. copper. lyophilic. compounds of sulphur. halides (PCI3. simple oxides. order and molecularity of a reaction. preparation. colloidal state: distinction between true solutions. coagulation. Unit VI: General Principles and Processes of Isolation of Elements (Periods 8) Principles and methods of extraction . Ozone. colloids and suspensions.preparation. intergrated rate equations and half life (only for zero and first order reactions). Brounian movenment. trends in physical and chemical properties. corrosion. compounds of phosphorous: preparation and properties of phosphine. occurrence.physisorption and chemisorption. fuel cells. Phosphorous-allotropic forms. occurrence. oxidation states. abnormal molecular mass. Kohlrausch’s Law.concentration. emulsion types of emulsions. occurrence. oxidation states. compounds of halogens. oxidation states. electrolysis and laws of electrolysis (elementary idea). temperature. Sulphur . oxoacids of halogens (structures only). lead accumulator. Unit III: Electrochemistry (Periods 14) Redox reactions. electronic configuration. interhalogen compounds. Group 16 elements: General introduction. compounds of nitrogen: preparation and properties of ammonia and nitric acid. dioxygen. enzyme catalysis. conductance in electrolytic solutions. 8 . electronic configuration. Group 17 elements : General introduction. activity and selectivity. dry cell electrolytie cells and Galvanic cells. lyophobic. trends in physical and chemical properties. PCI5) and oxoacids (elementary idea only). EMF of a cell. properties and uses. oxoacids of sulphur (structures only). Unit VII: p-Block Elements (Periods 14) Group 15 elements: General introduction. electronic configuration. zinc and Iron. occurrence and principles of extraction of aluminium.allotropic forms. electrophoresia. no mathematical treatment) Unit V: Surface Chemistry (Periods 8) Adsorption . concentration. concept of collision theory (elementary idea. rate law and specific rate constant. oxides of nitrogen (structure only).masses using colligative properties. nitrogen . properties and uses.

freons. DDT. uses. substitution reactions (directive influence of halogen for monosubstituted compunds only) Uses and environmental effects of . Ethers: Nomenclature. Phenols: Nomenclature. Actionoids .Group 18 elements: (General introduction. Phenols and Ethers (Periods 12) (Periods 12) Alcohols: Nomenclature. physical and chemical properties. tetrachloromethane. identification of primary. methods of preparation. electronic configuration. Unit X: Haloalkanesa and Haloarenes. Haloarenes: Nature of C-X bond. Ketones and Carboxylic Acids (Periods 12) Aldehydes and Ketones: Numenclature. iodoform. Preparation and propertics of K2Cr2O7 and KMnO4. mechanism of substitution reactions. uses. electronic configuration. mechanism of dehydration. isomerism. magnetic propertics. physical and chemical properties. acidic nature of phenol. Unit XI: Alcohols. trichloromethane. methods of preparation. Haloalkanes: Nomenclature. nature of carbonyl group. extraction of metals and biological systems). some important compounds . uses. general trends in properties of the first row transition metals metallic character. oxidation states. physical and chemical properties. oxidation states. IUPAC nomenclature of mononuclear coordination compounds bonding. ionization enthalpy. Unit XII: Aldehydes.Electronic configuration. Unit IX: Coordination Compounds (Periods 12) Coordination compounds . secondary and teritary alcohols. electrophillic substitution reactions. coordination number. colour catalytic property. methods of preparation. ligands. occurrence and characteristics of transition metals. uses of phenols. alloy formation. Lanthanoids-electronic configuration. trends in physical and chemical properties.methanol and ethanol. Occurrence. importance of coordination compounds (in qualitative analysis. oxidation states. natuer of C-X bond. chemical reactivity and lanthanoid contraction. Unit VIII: d and f Block Elements (Periods 14) General introduction.dichloro methane.introduction. interstitial compounds. methods of preparation. colour. magnetic properties and shapes. physical and chemical properties (of primary alcohols only). ionic radii. physical and chemical properties. and mechanism of nuclcophilic addition. 9 .

physical and chemical properties. Diazonium salts: Preparation. identification of primary. acidic nature. monosaccahrides (glucose and fructose). importance. Unit XIV: Biomolecules (Periods 8) Carbohydrates . Proteins . bakelite. 3. 10 . glycogen).Elementary idea of α-amino acids.annalgesica.reactivity of alpha hydrogen in aldehydes. methods of polymerization (addition and condensation). lactose.Classification (aldoses and keloses).preservatives. nylon. classification.natural and synthetic. tranquilizers. antimicrobials. secondary structure. methods of preparation. polypeptides proteins.will be mentioned at relevant places in context. cellulose. antifertility drugs. Unit XVI: Chemistry in everyday life : 1. chemical reactions and importance in synthetic organic chemistry. Unit XIII: Organic compounds containing Nitrogen (Periods 10) Amines: Nomenclature. 2. antibiotics. antisecptics. oligosaccharides (sucrose. Some importance polymers. primary structure. structure. Cyanides and Isocyanides . enzymes. polyesters. uses. uses. antacids. artificial sweetening agents. Vitamins . natural and synthetic like polythene. copolymerization. antihistamines. Chemicals in food. maltose). secondary and teritary amines. uses. Carboxylic Acids: Nomenclature.soaps and detergents. polysaccharides (starch. (Period 8) Chemicals in medicines . disinfectants. cleansing action. teritary structure and quaternary structure (qualitative idea only). denaturation of proteins. Nucleic Acids: DNA & RNA. Cleansing agents . methods of preparation. physical and chemical properties. rubber. Unit XV: Polymers (Periods 8) Classification . peptide bond.Classification and functions.

CLASS XII (PRACTICALS) STRUCTURE OF QUESTIONS PAPER One Practical Paper Time : 3 Hours 30 marks Experiments Volumetric Analysis Mixture Analysis Content Based Experiment Project Class record & Viva NOTE :Brief write up carrying 2 marks (If in the Question paper) question on preparation of crystals (Time for write up 5 minutes). (vii) (viii) (ix) (x) Preparation of original solution Correct group detection Systematic detection of ion Any two confirmatory tests of cation ( 1 marks each) Step wise distribution of marks of questions on volumetric analysis. (i) (ii) (iii) (iv) (v) (vi) Physical nature Dry heating test Flame test Charcoal cavity test dil H2SO4 conc. H2SO4 test 1/2 1/2 1/2 1/2 1 1/2 10 Marks 8 Marks 4 Marks 4 Marks 4 Marks (If anion is detected under dil H2SO4 test full credit of 1½ marks is to be given there and then) Confirmalory test (any two ) 1½ marks each 3. Stepevise distribution of marks of questions on salt analysis. 1/2 1 1 2 11 .

Details of written part Correct indicator Correct end point Balanced equation Solution in burette General calculations ½ ½ 2 1 1 5 Practical Part Initial reading Final reading Correct use of pipetle Correct end point Three concordent readings Correct titre value 1 1 ½ ½ ½ 1½ 5 Full credit of + 2 % variation and deduct ½ mark for additional 0. PRACTICALS Evaluation Scheme for Examination Volumetric Anaysis Salt Analysis Content Based Experiment Class record and viva Investigatory Project Total Marks 10 8 4 4 4 30 12 .1 ml variation.

(b) Study of reaction rates of any one of the following: (i) Reaction of iodide ion with hydrogen peroxide at room temperature using different concentration of iodide ions. (ii) Reaction between potassium iodate. Preparation of potassium ferric oxalate. (Periods 4) Preparation of Organic Compounds Preparation of any two of the following compounds 13 . C. Electrochemistry 2+ 2+ (Periods 6) (Periods 2) Variation of cell potential in Zn/Zn llCU /Cu with change in concentration of electrolytes (CuSO4 or ZnSO4) at room temperature. Enthalphy of neutralization of strong acid (HCl) and strong base (NaOH) Determination of enthalpy change during interaction (Hydrogen bond formation) between acetone and chloroform. (b) Study of the role of emulsifying in stabilizing the emulsions of different oils. arsenious sulphide.starch. Thermochemistry Any one of the following experiments i) ii) iii) Enthalphy of dissolution of copper sulphate or potassium nitrate. Chemical Kinetics (a) Effect of concentration and temperature on the rate of reaction between sodium thiosulphate and hydrochloric acid. i) Chromatography chromatography and determination of Rf values. KlO3 and sodium sulphite : (Na2SO3) using starch solution as indicator (clock reaction). E. ii) Separation of constituents present in an inorganic mixture containing two cations only (constituents having wide difference in Rf values to be provided). Preparation of Inorganic Compounds i) ii) G. D. Lyophelic sol .Practicals Syllabus (Periods 6) A.aluminium hydroxide. Surface Chemistry (a) Preparation of one lyophilic and one lyophobic sol. egg albumin and gum. B. F. ferric hydroxide. (Periods 4) (Periods 2) Separation of pigments from extracts of leaves and flowers by paper Preparation of double salt of ferrous ammonium sulphate or potash almum. Lyophobic sol .

Anions CO . Ca2+. Iodoform. ketonic. K. Zn2+. Co2+. alcoholic.i) ii) iii) iv) v) H. Ni2+. NO.CH COO4 3 222232 (Periods 14) 2 3 4 2 4 3 (Note: Insoluble salts excluded) Few Suggested Projects Study of diffusion of a solid into a liquid. Mn2+. (Periods 8) (Students will be required to prepare standard solutions by weighing themselves). Fe3+. C O -. S . I . Al3+. carboxylic and amino (primary) groups. Mg2+ NH4+. I. As3+. aldehydic. Cations . Sr2+. Ba2+. 14 . NO. PO . (Periods 6) Test for the functional groups present in organic compounds: Unsaturation. Qualitative analysis Determination of one cation and one anion in a given salt. Br . Aniline yellow or 2-Napthol aniline dye. Ferrous ammonium sulphate. SO3. Cu2+. (Periods 4) Determination of concentration/molarity of KMnO4 solution by titrating it against a standard solution of : (i) (ii) Oxalic acid.Pb2+. fats and proteins in pure form and detection of their presence in given food stuffs. Acetanilide Di-benzal accetone p-Nitroacetanilide. phenolic. SO . CI. Study of carbohydrates. J.

.. Preparation of rayon threads from various cellulose sources.... Study on quantity of casein present in different samples of milk. gram flour.. etc (with respect to time. Study of dyeing fabries under various conditions. Determination of rate of evaporation of different liquids.... Compasitive study of the rate of formation on following materials wheat.. effect of temperature.... Study of the acidity of different samples of the tea leaves and reasons for the variation in their tests.. sand of different qualities...juice... Note : Any other investigatory project can be performed I which involves about S periods of work with the approval of the teacher.. Study of effect of metal coupling on die corrosion of iron. volume and stremyth).. 15 ... Study of the presence of inseeticide/presicide (nitrogen contining) in vegetables and fruits. patato juice............ Study of presence of oxalate ions in guava fruit at different stages of riperings... Study of the dialysis of different sewage water sample and identification of different ions in rsulting solutions...... Determination of the dosage of bleaching powder required for disipfections of different .. Determination of rate of flow of solution and liquids horizontally.. Analysis of fruit and vegetable prices for the content (acids and mineral a present in them)....Determination of the minimum quantity of manganese dioxide required as a catalyst for the preparation of oxygen gas. Preparation of soyabean milk and its comparision with the natural milk with respect to curd formation... Study of the effect of acids and bases on the tensile strength of fibres..of water (taken from different sources). foods.... taste etc. Study of the setting of mixtures of cement with lime. rice husk. Extraction of essential oils present in Su Study of .. flour.... Study of the effect po Study of digestion of starclity salivary anylase and effect of pH and temperature on it.... Investigation of the foaming capacity of different washing soaps and the effect of addition of soduim carbonate on thera....... carrot juice and or ...